scholarly journals MAJOR AND TRACE ELEMENTS GEOCHEMISTRY OF ĐỒNG HO SEDIMENTS (QUẢNG NINH, VIET NAM): IMLICATION FOR PALEOENVIRONMENTAL CONDITION

Author(s):  
Vượng Nguyễn Văn

The Dong Ho sedimentary formation consists of gravel, sand and sandstone, mudstone interbeded with asphalt layer or oil shale cropping out at Quang Ninh is considered as outcrop of petroleum potential source rock and correlated to source rock of the Cenozoic basins on the continental shelf of Southeast Asia. Geochemical investigation  of major and trace elements content variation from 14 typical samples selected from diferent layers leads to divide the Dong Ho formation into two parts: the lower part characterized by unclear variation while the upper part exposing a more clear trend. The paleoenvironmental proxy and the CIA, CIW, PIA and CPA indices of the Dong Ho formation revealed high weathering intensity. V/Ni and C/Cr s vary from 0.14 to 1.52; and from 0.02 to 0.52 respectively indicate to oxic depositional environment. The provenance of the Dong Ho sedimentary layers come from the recycling of sedimentary source rocks and deposited within freshwater lacustrine environment dominated with humid climate with estimated mean annual rainfall of 1533 mm / yr ± 181 mm before changing to wet and reductioin environment during diagenesis.

2012 ◽  
Vol 610-613 ◽  
pp. 2904-2907
Author(s):  
Song Chen

The limestone soils and its source rock samples had been collected from Suzhou area for the testing about major and trace elements. The concentration value have been compared with the background and the migration coefficient(K) of element form source rock to soil have been calculated, the result showed: the elements Ca and Th are enrichment, the Al is loss seriously, the Ti, V, Cr, Mn, Zn, Rb, Sr., Zr, and Pb are basic fairly with the background value; the K, Cu, Fe and As are slightly higher than the soil background values; The elements Si, Ti, Mn, Zr, Pb and Th have high K in subsoil layer; the element Fe, Cr, As and Rb have the least K in subsoil layer; the element Al, V, Cu and Zn can be showed disorder with the more high migration coefficient in topsoil.


Author(s):  
Sebastian Grohmann ◽  
Susanne W. Fietz ◽  
Ralf Littke ◽  
Samer Bou Daher ◽  
Maria Fernanda Romero-Sarmiento ◽  
...  

Several significant hydrocarbon accumulations were discovered over the past decade in the Levant Basin, Eastern Mediterranean Sea. Onshore studies have investigated potential source rock intervals to the east and south of the Levant Basin, whereas its offshore western margin is still relatively underexplored. Only a few cores were recovered from four boreholes offshore southern Cyprus by the Ocean Drilling Program (ODP) during the drilling campaign Leg 160 in 1995. These wells transect the Eratosthenes Seamount, a drowned bathymetric high, and recovered a thick sequence of both pre- and post-Messinian sedimentary rocks, containing mainly marine marls and shales. In this study, 122 core samples of Late Cretaceous to Messinian age were analyzed in order to identify organic-matter-rich intervals and to determine their depositional environment as well as their source rock potential and thermal maturity. Both Total Organic and Inorganic Carbon (TOC, TIC) analyses as well as Rock-Eval pyrolysis were firstly performed for the complete set of samples whereas Total Sulfur (TS) analysis was only carried out on samples containing significant amount of organic matter (>0.3 wt.% TOC). Based on the Rock-Eval results, eight samples were selected for organic petrographic investigations and twelve samples for analysis of major aliphatic hydrocarbon compounds. The organic content is highly variable in the analyzed samples (0–9.3 wt.%). TS/TOC as well as several biomarker ratios (e.g. Pr/Ph < 2) indicate a deposition under dysoxic conditions for the organic matter-rich sections, which were probably reached during sporadically active upwelling periods. Results prove potential oil prone Type II kerogen source rock intervals of fair to very good quality being present in Turonian to Coniacian (average: TOC = 0.93 wt.%, HI = 319 mg HC/g TOC) and in Bartonian to Priabonian (average: TOC = 4.8 wt.%, HI = 469 mg HC/g TOC) intervals. A precise determination of the actual source rock thickness is prevented by low core recovery rates for the respective intervals. All analyzed samples are immature to early mature. However, the presence of deeper buried, thermally mature source rocks and hydrocarbon migration is indicated by the observation of solid bitumen impregnation in one Upper Cretaceous and in one Lower Eocene sample.


1992 ◽  
Vol 32 (1) ◽  
pp. 289 ◽  
Author(s):  
John Scott

The main potential source rock intervals are generally well defined on the North West Shelf by screening analysis such as Rock-Eval. The type of product from the source rocks is not well defined, owing to inadequacies in current screening analysis techniques. The implications of poor definition of source type in acreage assessment are obvious. The type of product is dependent on the level of organic maturity of the source rock, the ability of products to migrate out of the source rock and on the type of organic material present. The type of kerogen present is frequently determined by Rock-Eval pyrolysis. However, Rock-Eval has severe limitations in defining product type when there is a significant input of terrestrial organic material. This problem has been recognised in Australian terrestrial/continental sequences but also occurs where marine source rock facies contain terrestrially-derived higher plant material. Pyrolysis-gas chromatography as applied to source rock analysis provides, by molecular typing, a better method of estimating the type of products of the kerogen breakdown than bulk chemical analysis such as Rock-Eval pyrolysis.


2012 ◽  
Vol 616-618 ◽  
pp. 69-72
Author(s):  
Yi Bo Zhou ◽  
Guang Di Liu ◽  
Jia Yi Zhong

Based on the sequence stratigraphy study, the relation between dark mudstone ratio and sedimentary facies in different system tracts is observed and used to forcast the distribution of dark mudstones in the main formation combining with seismic data and well log. However, not all dark mudstones can generate hydrocarbon, so the source rock quality is quoted to calculate the thickness of the source rock within mudstone. The results show that the favored source rock in lake progressive system tracts and the bottom of highstand system tracts of Xiagou Formation and Chijinpu Formation are related to a group of reflectors with medium-strong amplitude, medium-low frequency and medium to comparatively good lateral continuity. The source rock of Xiagou Formation with high organic content and wide-range distribution is the major hydrocarbon source in Ying’er Sag, while Chijinpu Formation with thick dark mudstones is the potential source rock and the target of the further exploration.


2020 ◽  
Vol 113 (1) ◽  
pp. 24-42
Author(s):  
Emilia Tulan ◽  
Michaela S. Radl ◽  
Reinhard F. Sachsenhofer ◽  
Gabor Tari ◽  
Jakub Witkowski

AbstractDiatomaceous sediments are often prolific hydrocarbon source rocks. In the Paratethys area, diatomaceous rocks are widespread in the Oligo-Miocene strata. Diatomites from three locations, Szurdokpüspöki (Hungary) and Limberg and Parisdorf (Austria), were selected for this study, together with core materials from rocks underlying diatomites in the Limberg area. Bulk geochemical parameters (total organic carbon [TOC], carbonate and sulphur contents and hydrogen index [HI]) were determined for a total of 44 samples in order to study their petroleum potential. Additionally, 24 samples were prepared to investigate diatom assemblages.The middle Miocene diatomite from Szurdokpüspöki (Pannonian Basin) formed in a restricted basin near a volcanic silica source. The diatom-rich succession is separated by a rhyolitic tuff into a lower non-marine and an upper marine layer. An approximately 12-m thick interval in the lower part has been investigated. It contains carbonate-rich diatomaceous rocks with a fair to good oil potential (average TOC: 1.28% wt.; HI: 178 to 723 mg HC/g TOC) in its lower part and carbonate-free sediments without oil potential in its upper part (average TOC: 0.14% wt.). The composition of the well-preserved diatom flora supports a near-shore brackish environment. The studied succession is thermally immature. If mature, the carbonate-rich part of the succession may generate about 0.25 tons of hydrocarbons per square meter. The diatomaceous Limberg Member of the lower Miocene Zellerndorf Formation reflects upwelling along the northern margin of the Alpine-Carpathian Foreland. TOC contents are very low (average TOC: 0.13% wt.) and demonstrate that the Limberg Member is a very poor source rock. The same is true for the underlying and over-lying rocks of the Zellerndorf Formation (average TOC: 0.78% wt.). Diatom preservation was found to differ considerably between the study sites. The Szurdokpüspöki section is characterised by excellent diatom preservation, while the diatom valves from Parisdorf/Limberg are highly broken. One reason for this contrast could be the different depositional environments. Volcanic input is also likely to have contributed to the excellent diatom preservation in Szurdokpüspöki. In contrast, high-energy upwelling currents and wave action may have contributed to the poor diatom preservation in Parisdorf. The hydrocarbon potential of diatomaceous rocks of Oligocene (Chert Member; Western Carpathians) and Miocene ages (Groisenbach Member, Aflenz Basin; Kozakhurian sediments, Kaliakra canyon of the western Black Sea) has been studied previously. The comparison shows that diatomaceous rocks deposited in similar depositional settings may hold largely varying petroleum potential and that the petroleum potential is mainly controlled by local factors. For example, both the Kozakhurian sediments and the Limberg Member accumulated in upwelling environments but differ greatly in source rock potential. Moreover, the petroleum potential of the Szurdokpüspöki diatomite, the Chert Member and the Groisenbach Member differs greatly, although all units are deposited in silled basins.


Author(s):  
Putri Dwi Afifah ◽  
Budhi Setiawan

The research location is geologically located in Jambi Sub-basin composed by Peneta Formation (KJp), Airbenakat (Tma), and Muara Enim (Tmpm). Specifically this research focuses on the physical characteristics and geochemistry of Middle Miocene black shale from Airbenakat Formation. The purpose of this research is to determine whether the black shale of this formation has the potential as a source rock. The method of this research are field observation that includes the description of rock samples and geological mapping, and laboratory analysis including rock geochemical analysis. Three samples were taken from black and fine-grained shale. Total organic carbon (TOC) values of the three samples taken ranged from 0.38-0.42%, the weight of TOC indicates a potentially close enough to produce hydrocarbons. the pyrolysis results show that the S1 data gives a value below 0.5 HC/g and S2 gives a value below 2.5 HC/g, so it can be seen that the three rock samples that tested are not sufficient enough to produce hydrocarbons. Overall the sample has a S2/S3 ratio ranging from 0.09-0.23 and Tmax-HI data has values ranging from 8-19 mg HC/g TOC, so it can be seen that the ratio S2/S3 less than 1 and the value of the index hydrogen below 50 mg HC/g TOC, It can be concluded that the samples are derived from type IV kerogen. The maximum temperature (Tmax) of pyrolysis shows a value of less than 4350C, where the values range from 350-4280C. So, it can be interpreted that the three samples are immature source rocks because the catagenesis phase to produce hydrocarbons has not been achieved. The conclusions is the three samples of black shale tested indicate potential as immature source rock and has the close enough ability to produce hydrocarbons. The result of the analysis then comparable with the result analysis of Airbenakat Formation Black Shale in Palembang Sub-basin which has fair-well ability to produce hydrocarbons.  


2020 ◽  
Vol 45 (5) ◽  
Author(s):  
T. A. Adedosu ◽  
S. A. Alao ◽  
T.R. Ajayi ◽  
A. Akinlua

Gombe Formation is one of the promising potential source-rock of petroleum in the Gongola basin based on its appreciable amount of organic matter. The present study is therefore aimed at evaluating the hydrocarbon potential of Gombe Formation. Ditch-cutting samples were collected from the depth of 731.5 m to 1554.5 m from Gombe Formation that penetrated the Kolmani River-1 well. The source-rock potential was evaluated based on kerogen analysis and soluble organic matter content using Fourier Transform- Infra red spectroscopic (FT-IR) and Gas chromatography-Mass spectrometric (GC-MS) techniques respectively. There is presence of peak at 900-1000 cm-1 which is due to CH2 rocking vibration in long chain aliphatic substances, which is characteristic of liptinite macerals indicating good potential source-rock for oil and gas. The n-alkane ranges from C11-C33 maximizing at nC16 which suggests that the organic matter are majorly derived from marine organic matter. The Pr/Ph (1.49-1.92) shows that the organic matter was deposited under sub-oxic condition. The distribution of hopanes, homohopanes (C27-C29) steranes, (C0-C4) alkylated naphthalenes and (C0-C3) alkylated phenanthrenes indicate the presence of angiosperm, gymnosperm, algae, marine and bacteria input to the organic matter contained in the samples. Also the plot of DBT/P vs. Pr/Ph classifies the samples into zone 3 (i.e. marine shale and other lacustrine). Various maturity parameters computed from saturate biomarker and polycyclic aromatic hydrocarbon distributions shows that the samples are low mature with the moderately mature zone at the bottom (>1408.2 m) of Gombe Formation. In conclusion, the kerogen was probably derived from type II/III organic matter capable of generating both oil and gas and the moderately mature zone lies at the bottom of the Formation. Key words: Lacustrine, Gombe formation, Maturity, Hydrocarbon, Kerogen


2021 ◽  
Vol 5 (1) ◽  
pp. 50-59
Author(s):  
Ayad N. F. Edilbi ◽  
Kamal Kolo ◽  
Blind F. Khalid ◽  
Mardin N. Muhammad Salim ◽  
Sana A. Hamad ◽  
...  

This study reports on the petroleum potential of the Upper Triassic Baluti Formation in Bekhme-1 and Gulak-1 Wells from Akri¬-Bijeel Block within the Bekhme Anticline area, North of Erbil City. The area is a part of the Zagros Fold and Thrust Belt, and is locally situated within the High Folded Zone. Typically, the Baluti Formation is composed of gray and green shale calcareous dolomite with intercalations of thinly bedded dolomites, dolomitic limestones, and silicified limestones which in places are brecciated. The geochemical indicators obtained from Rock-Eval pyrolysis of Baluti samples gave Total Organic Carbon content (TOC wt. %) average values of 0.15 and 0.18 wt. % and potential hydrocarbon content (S2) average values of 0.78 mg HC/g rock and 0.58 mg HC/g rock for Bekhme-1 and Gulak-1 respectively, suggesting a source rock of poor potential. The type of organic matter is of mixed type II-III and III kerogens with an average Tmax value of 440 °C for both boreholes, exhibiting early to peak stage of thermal maturity. Considering the results of this study, it is concluded that Baluti Formation in the studied area can not be regarded as a potential source rock for hydrocarbon generation.


Geofluids ◽  
2021 ◽  
Vol 2021 ◽  
pp. 1-13
Author(s):  
Qian Deng ◽  
Haizu Zhang ◽  
Haozhe Wang ◽  
Zhiwei Wei ◽  
Bin Cheng ◽  
...  

A large amount of light crude oils have been found within 4000 to 7000 m deep strata of Cambrian, Ordovician, and Silurian reservoirs in the Tarim Basin, NW China. To enhance the understanding of parental materials of deep oils, a set of high-quality source rocks from the Yuertusi Formation in well Luntan 1 (maximum drilling depth of 8882 m) was studied in terms of their sedimentary condition and mechanism of organic matter enrichment. Total organic carbon (TOC) content, carbon isotope of kerogen (δ13Cker), and major and trace elements of the rocks from the Sinian Qigebulake, Cambrian Yuertusi, and Xiaoerbulake Formations in well Luntan 1 were analysed. The results showed that the δ13Cker value of the Yuertusi Formation barely changed with an average of -31.19‰. High TOC contents accompanied by enrichments of the bioessential trace elements, such as cadmium, chromium, copper, nickel, and zinc, occurred in the lower part of the Yuertusi Formation. Excess barium (Baxs) and phosphorus concentrations revealed high primary productivity during the deposition of the Yuertusi Formation. Moreover, variations in the enrichment factors of molybdenum, uranium, and vanadium and molybdenum-uranium covariation pattern indicated suboxic-anoxic conditions in the Qigebulake Formation, anoxic-euxinic conditions in the Yuertusi Formation, and suboxic-oxic conditions in the Xiaoerbulake Formation. The TOC contents were significantly correlated with the paleoproductivity and paleoredox parameters, indicating that high productivity and reducing conditions jointly controlled the organic matter accumulation and preservation in well Luntan 1.


2017 ◽  
Vol 36 (3) ◽  
pp. 355-372 ◽  
Author(s):  
Hua Liu ◽  
Jinglun Ren ◽  
Jianfei Lyu ◽  
Xueying Lyu ◽  
Yuelin Feng

The K1s, K1d, K1t, and K1a Formations are potential source rock intervals for hydrocarbon formation, all of which are part of the Lower Cretaceous system in the Baibei Depression in the Erlian Basin in China. However, no well has found oil flow because the hydrocarbon-generating potential of the source rocks has not been comprehensively evaluated. Based on organic geochemical and petrological analyses, all the source rocks possess highly variable total organic carbon and S1 + S2 contents. Total organic carbon and S1 + S2 contents indicate that the K1a2 Formation through the K1d1 Formation are source rocks that have fair to good generative potential and the K1d2 Formation through the K1s Formation are source rocks that have good to very good generative potential. The organic matter in the K1a2 Formation is dominated by Type I and II kerogen; thus, it is considered to be oil prone based on H/C versus O/C plots. Most of the analyzed samples were deposited in reducing environments and sourced from marine algae; thus, they are oil prone. However, only two source rock intervals were thermally mature with vitrinite reflectance values in the required range. Hydrocarbon-generating histories show that the K1t and K1a2 intervals began to generate hydrocarbons during the depositional period of the K1d2 and K1d3 Formations, respectively, and stopped generating hydrocarbons at the end of the depositional period of the late Cretaceous. Therefore, the main stage of hydrocarbon migration and accumulation was between the depositional period of the K1d2 and K1s Formations, and the critical moment was the depositional period of the late K1s Formation. The generation conversion efficiency reached approximately 55% in the K1a2 Formation and 18% in the K1t Formation at the end of the Cretaceous sedimentary stage. In general, the effective oil traps are those reservoirs that are near the active source rock in the generating sags in the Baibei Depression.


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