scholarly journals Landscape and geochemical assessment of ecological condition of environmental protection territories

2019 ◽  
Keyword(s):  
Heavy Metals ◽  
Chemical Elements ◽  
Research Work ◽  
Chemical Properties ◽  
Threshold Level ◽  
Ecological Condition ◽  
Point Of View ◽  
Recreational Activities ◽  
Geochemical Conditions ◽  
Natural Park

Purpose. The problem of environmental pollution by heavy metals is one of the most important problems of the present and the near future. The compounds of these elements are characterized by high toxicity, mobility and ability to bio-accumulation. The aim of the study was to establish the main regularities of trace elements of the national natural park (NNP), to determine the indicators of their mobility for assessment of state of environment.Scientific novelty. The article discusses the features of distributing of heavy metals in the components of landscapes of the territory of the national natural park for realization of control and settlement of his concentration in accordance with the set norms.Results. The analysis of the landscape-geochemical conditions of the territory of the national natural park “Nyzhniosulskyi” has been performed. Consistent patterns of heavy metals distribution in the modern soil of the territory of NNP “Nyzhniosulskyi” have been determined. The analysis of landscape-geochemical conditions of the territory indicates that they generally contribute to the migration of chemical elements with land runoff as well as their significant vertical redistribution. The differentiation of landscape-geochemical conditions causes the fixation and accumulation of a significant number of natural and man-made chemical elements on the landscape-geochemical barriers (mechanical, redox, acid-alkaline, sorption, sorption-gley). This prevents from intense pollution of the vast majority of landscape regions in the park by polluting substances migrating from agricultural lands, which is confirmed by the results of the analysis of pollution sources and volumes. It was shown, that processes of transformation and migration of heavy metals compounds in the soil profile are determined by physical and chemical properties of soils.The analysis of the content of heavy metals in the soils of NNP “Nyzhniosulskyi” has shown that , the distribution of heavy metals is uniformly dispersive, but the variations in the content of certain heavy metals can range from ± 7% to ± 25%-35%. The greatest bioaccumulation capacity is expressed in biogenic microelements – manganese and cuprum. The analysis of heavy metals content in the landscape regions of NNP “Nyzhniosulskyi” has confirmed its dependence on available sources of technogenic contamination as well as the high degree of compliance of the nature of heavy metals distribution to the general laws of these processes in the soils of the relevant types. Most heavy metals get into the Sulyn aquatorium mainly during spring flood with snow melt water. The excess of Cd2+, Cu2+ and Pb2+ in water has been noted in comparison with the current threshold level value regulations.According to the results of the landscape-geochemical analysis of the NNP “Nyzhniosulskyi”, it can be stated that the territory from the ecological point of view is poorly contaminated and can be used for the development of recreational activities in compliance with a number of requirements.Practical significance. The results of this study have been introduced into practice of the NNP “Nyzhniosulskyi” in organizing and conducting research work, for planning tourist and recreational activities, forming tourist routes, and organizing recreational infrastructure.

scholarly journals MONITORING OF SOILS CONTAMINATION OF SOME REGIONS OF THE REPUBLIC OF ARMENIA WITH HEAVY METALS

2017 ◽  
Vol 17 ◽  
pp. 275-283
Author(s):  
G. A. Hambaryan ◽  
A. V. Santrosyan ◽  
Yu. R. Ishkhanyan
Keyword(s):  
Heavy Metals ◽  
Maximum Permissible Concentration ◽  
Chemical Elements ◽  
Ecological Monitoring ◽  
Ecological Condition ◽  
Background Concentration ◽  
Climatic Zones ◽  
Paradoxical Situation ◽  
Maximum Permissible Concentrations ◽  
The Republic

The paper is devoted to the problems of soils contamination of some regions of the Republic ofArmenia and a city of Yerevan with heavy metals. The results of analyses of the selected soil tests for the purpose ofdefinition of their contamination degree with heavy metals are listed. The statistical data on the background concentration of heavy metals in various soil-climatic zones of the Republic of Armenia, not influenced with appreciable anthropogenous impact is also given. The comparative analysis on presence of polluting chemical elements in soil is carried out for the approved norms of maximum permissible concentration and background indicators. The authors consider possible negative influences on environment as a result of soils contamination, in particular on biological activity of soil and processes of its self-cleaning. It’s noticed that maximum permissible concentrations are mainly developed only from hygienic positions which do not consider the variety ofsoils, in particular, their properties. As an example there are described the results of soils researches of some regions of the Republic of Armenia and there is noticed that a paradoxical situation arises when background contents toxic elements in soils exceed the established values of maximum permissible concentration. In the paper there is arisen the question on necessity of working out and introducing in practice ecological monitoring of the system of tentatively permissible quantity of chemical elements in soil, taking into account background concentration of heavy metals in various soil-climatic zones. Introduction of the specified system will allow reasonably and, what very important, reliably to estimate an ecological condition of soils and to define the influence of contamination on qualitative characteristics of soil as a result of anthropogenous influence.

Peculiarities of Recultivating the Ash Dump of Power Station-1 in the City of Khabarovsk

2014 ◽  
Vol 1051 ◽  
pp. 444-447
Author(s):  
A.A. Suprunova ◽  
L.T. Krupskaya ◽  
T.G. Borzenkova
Keyword(s):  
Heavy Metals ◽  
Chemical Elements ◽  
Research Work ◽  
Climatic Conditions ◽  
High Concentration ◽  
Power Station ◽  
Migration Intensity ◽  
Strong Winds ◽  
High Level ◽  
The City

The article presents the results of the research work on the peculiarities of recultivation of the ash dumps of power station No1 (PS1) in the city of Khabarovsk. The research showed that the climatic conditions of the region promote the dust dispersal of toxic agents from the surface of the ash dump. The pollution of the air basin here can be attributed to the extremely high level of pollution (EHP), the priority pollutant is the dust containing heightened concentrations of heavy metals (Pb, Mn, Cu, Cr, Co, Ni, Cd). As a result it leads to the deterioration of the population’s health, especially to the high level of respiratory organs diseases. The research of the sprouting of the herbaceous plants (mixture of timothy-grass, clover and mustard) on prepared model soils showed their healthy growth. The ash chemical composition was studied. It showed high concentration of toxic chemical elements (Hg, Be, Sr, Cd, V, Th, 40K, Cr, Mb, AS, Sb,Se, Te, Pb, Ni, Co). The migration intensity of heavy metals ions into the plants was analyzed. On the basis of the experimental research the optimum composition of the substrate was revealed and recommended for recultivating the ash dump of PS1, namely: soil+sand+ash. Climatic conditions of the Khabarovsk Krai do not permit to recommend the sand+ash substrate for recultivation because of strong winds.

scholarly journals Landscape geochemical conditions and patterns of inter-element redistribution of heavy metals in landscapes of Kivertsi National Nature Park “Tsumanska Pushcha”

2021 ◽  
Vol 30 (1) ◽  
pp. 165-178
Author(s):  
Anastasiia O. Splodytel ◽  
Liudmyla Yu. Sorokina ◽  
Oksana V. Lunova
Keyword(s):  
Heavy Metals ◽  
Chemical Elements ◽  
Water Retention Capacity ◽  
Moisture Regime ◽  
Geochemical Background ◽  
High Accumulation ◽  
Retention Capacity ◽  
Geochemical Conditions ◽  
Geochemical Parameters ◽  
Nature Park

nalysis of landscape geochemical conditions of the territory of Kivertsi National Nature Park “Tsumanska Pushcha” was carried out also the levels of pollution of landscapes within the park and adjacent territories were established. Features of the accumulation and distribution of pollutants in the landscapes of the territory under conditions of natural and Technogenic geochemical anomalies are considered. The landscapes of the studied migration classes (calcium, calcium carbonate, carbonate clayey, acidic calcium) are characterized by a relatively high coefficient of migration intensity due to relatively weak buffering capacity, low water retention capacity and contrasting moisture regime. However, strong gleyed horizons are able to fix contaminants during their surface movement. Using the methods of landscape geochemical research, analytical methods, data on the gross and mobile content of heavy metals were obtained and analyzed. The highest concentrations of manganese and chromium are found in soils differentiated on loess sediments, nickel and copper on glacial sediments. Most of the studied heavy metals exceed the regional geochemical background. In terms of the gross content in soils, trace elements form the following geochemical series: Zn>Cu>Pb>Ni>Mn>Cr. The accumulation of lead up to 2-3 MPC in forest litters is clearly traced. Dependences of the stability of landscapes to Technogenic pollution on the level of conservation of natural geochemical parameters of soils, the degree of their anthropogenic transformation and the level of heavy metals incomings have been established. All studied plants maximally accumulated Mn, Cu, Cr and minimally Zn and Ti which is consistent with the patterns of migration of these elements in the soil. The high accumulation of heavy metals in the aboveground part of the studied plants indicates a significant removal of elements from the soil, which, in turn, makes it possible to consider certain plant species as potential phytoremediators. According to the average values of the concentration of macro elements in plants, the following geochemical series is established: CaO>K2O>MgO>P2O5>SiO2>SO3> Al2O3> Fe2O3>Na2O>TiO2. On the basis of the data obtained, 4 types of biogeochemical bonds between chemical elements in the soil – plant system for the territory of the NPP were identified: V, Ti - soil> plant; Ni - soil <plant; Cr - soil> plant; Mn, Cu - soil <plant.

scholarly journals Potential Possibilities of Soil Mesofauna Usage for Biodiagnostics of Soil Contamination by Heavy Metals

2019 ◽  
Vol 38 (1) ◽  
pp. 1-10 ◽  
Author(s):  
Nadiia Yorkina ◽  
Olexander Zhukov ◽  
Olena Chromysheva
Keyword(s):  
Heavy Metals ◽  
Soil Contamination ◽  
Chemical Properties ◽  
Ecological Condition ◽  
Soil Biology ◽  
Soil Mesofauna ◽  
Functional Zones ◽  
Chemical Properties Of Soils ◽  
First Time ◽  
The City

AbstractThe study of potential possibilities of mesofauna as bioindicator of soil contamination by heavy metals is one of the most important areas of urban ecology and soil biology. The work presents the results of ecotoxicological and bioindicative assessment of the environment and the biota of the Melitopol urbosystem of Ukraine. The dynamics of chemical properties of soils in different functional zones of the city is analysed. The complex indices of pollution of environmental components are determined. A bioindicative assessment of the ecological condition of the territory of the urbosystem on the indicators of vitality of the soil mesofauna is carried out. For the first time, regional species-bioindicators for the territory of the city of Melitopol were determined. The ecomorphic structure of soil mesofauna of various functional zones of the city was revealed.

scholarly journals Assessment of Guava (Psidium Guajava L.) Wood Biomass for Briquettes’ Production

Forests ◽  
2018 ◽  
Vol 9 (10) ◽  
pp. 613 ◽  
Author(s):  
Tatiana Ivanova ◽  
Amilkar Mendoza Hernández ◽  
Jiří Bradna ◽  
Eloy Fernández Cusimamani ◽  
Juan García Montoya ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Chemical Elements ◽  
Chemical Properties ◽  
Calorific Value ◽  
Wood Properties ◽  
Psidium Guajava ◽  
Ash Content ◽  
International Standards ◽  
Published Data ◽  
Solid Biofuel

Residual biomass from guava (Psidium guajava L.), a common and widespread fruit tree native to Latin America, has been analyzed in the present research in order to determine the biomass quality and its potential use for energy purposes. Obtained biomass was grinded and compacted into the form of fuel briquettes. Determinations of solid biofuel parameters, i.e., physical, mechanical and chemical properties such as calorific value, moisture, ash content, volatile matter, mechanical durability, contents of the main chemical elements and heavy metals were performed according to international standards. As a result, not inconsiderable traces of heavy metals were found, with a concentration of zinc 4.57 mg kg−1 as the highest. Guava’s moisture content (9.8%) comfortably fulfilled the minimum standard requirements and the net calorific value as received (17.11 MJ kg−1) met the average value of a wood. However, measured sulphur content (0.063%) as well as ash content (3.74%) exceeded the maximum allowed limits for the graded wood briquettes and, therefore, guava wood briquettes should be rather categorized as non-woody A class briquettes. The results of the study can contribute significantly to the knowledge of guava wood properties and its potential as renewable solid fuel since there is little published data about it.

scholarly journals CНИЖЕНИЕ ТЕХНОГЕННОГО ПРЕСИНГА ПОЛИЭЛЕМЕНТНЫХ АНОМАЛИЙ ДЕВАСТИРОВАННЫХ ЛАНДШАФТОВ ПУТЕМ ФИТОМЕЛИОРАТИВНОГО ВОССТАНОВЛЕНИЯ

2016 ◽  
Vol 6 (01) ◽  
pp. 94-114 ◽  
Author(s):  
V.V. Popovich
Keyword(s):  
Heavy Metals ◽  
Background Radiation ◽  
Mine Waste ◽  
Coal Mines ◽  
High Capacity ◽  
Chemical Properties ◽  
Ecological Condition ◽  
Individual Plant ◽  
Transition Elements ◽  
Waste Dumps

<p>Formation of soil anomalies in the operation area and the mine waste dumps results in an accumulation of heavy metals in plants, particularly if the physic-chemical properties of soil to facilitate the transition elements available to form them. We have proved that the individual organs of plants have a high capacity for accumulation of heavy metals, which allows us to recommend them for landscaping of dumps and heaps like plants, is actively contributing to the stabilization of technologically impaired environment under conditions of significant contamination.</p><p>It should be noted that an embodiment of the ecological stabilization of anthropogenic disturbed territory, on which the landfills and waste dumps of coal mines, is the introduction of individual plant micro associations that will be investigated in more detail in our further work on the technologically impaired phytomelioration territory.</p><p>Despite the fact that the overgrowth of dumps and heaps helps to improve the environmental situation, the number of pollutants, including heavy metals, hydrosphere and lithosphere remains high. This is due to the fact that the soil is able to deposit the contaminants and can be long-term source of secondary pollution.</p><p>We proved that that dumps and heaps of coal mines led to an increase of industrial hazard in the region based on the research of background radiation, heavy metals contamination in edaphotopes and vegetation. We also studied the species diversity, the stage of overgrowing, distribution of individuals in the vegetation communities in devastated landscapes. Analysis of our research results testified the necessity of protective trees shield within devastated landscapes to improve the ecological condition of industrial congested region and increasing the productivity of disturbed lands.</p>

scholarly journals Pollution Discharge Scenario of Oil and Surfactants Manufacturing Industries along Dombivali Industrial Belt of Mumbai, India

2013 ◽  
Vol 22 ◽  
pp. 32-39
Author(s):  
P.U. Singare ◽  
S.S. Dhabarde
Keyword(s):  
Waste Water ◽  
Heavy Metals ◽  
Research Work ◽  
Chemical Properties ◽  
Total Solid ◽  
Solid Content ◽  
Manufacturing Industries ◽  
Toxic Heavy Metals ◽  
Total Solid Content ◽  
Physico Chemical

The paper deals with monitoring of pollution arising due to oil and surfactants manufacturing industries located along the Dombivali industrial belt of Mumbai, India. The study was carried for the period of one year from June, 2012 to May, 2013 to study the level of toxic heavy metals and the physico-chemical properties of waste water effluents discharged from the above industries. The maximum concentration of majority of heavy metals like Cu, Ni, Cr, Pb and Fe were recorded as 13.48, 3.90, 13.30, 1.75 and 15.89 ppm respectively, which were above the tolerable limit set for inland surface water. The maximum pH and conductivity values of the industrial waste water effluent were recorded as 10.05 and 27800 µmhos/cm respectively. The majority of physico-chemical parameters like chloride, cyanide, phosphate and total solid content were found to be maximum in the month of March having the respective values of 2340, 0.09, 3 5.2 and 8755 ppm. The effluent samples collected in the month of May was found to have low DO content of 3.33 ppm and high BOD content of 643 ppm. The alkalinity and COD values were reported to be maximum of 1988 and 4410 ppm respectively in the month of February. The hardness and salinity content was reported maximum of 131 and 5.76 ppm during the month of December and June respectively. The results of present research work indicates that time has come to move towards ecosystem specific discharge standards to maintain the health and productivity of natural resources on which the majority of Indians are dependent

Determination of Some Heavy Metals in Milk of Cow Grazing At Selected Areas, of Kaduna Metropolis

2017 ◽  
Vol 7 (7) ◽  
pp. 341 ◽  
Author(s):  
Mahmud Mohammed Imam ◽  
Zahra Muhammad ◽  
Amina Zakari
Keyword(s):  
Heavy Metals ◽  
Cadmium Toxicity ◽  
Research Work ◽  
The Body ◽  
Cow Milk ◽  
Scientific Model ◽  
Potential Health ◽  
Milk Samples ◽  
Lead And Cadmium ◽  
Digestion Technique

In this research work the concentration of zinc, copper, lead, chromium, cadmium, and nickel in cow milk samples obtained from four different grazing areas   (kakuri, kudendan, malali, kawo) of Kaduna metropolis. The samples were digested by wet digestion technique .The trace element were determined using bulk scientific model VPG 210 model  Atomic Absorption Spectrophotometer (AAS).. The concentration of the determined heavy metal were The result revealed that Cr,  Ni and Cd were not detected in milk samples from Kawo, Malali  and Kudendan whereas lead (Pb) is detected in all samples and found to be above  the stipulated limits of recommended dietary allowance (NRC,1989) given as 0.02mg/day. Cu and Zn are essential elements needed by the body for proper metabolism and as such their deficiency or excess is very dangerous for human health. However, they were found in all samples and are within the recommended limits while Cd (2.13 – 3.15 mg/kg) in milk samples from Kakuri was found to be above such limit (0.5mg/day). Cow milk samples analyzed for heavy metals in this research work pose a threat of lead and cadmium toxicity due to their exposure to direct sources of air, water and plants in these grazing areas, thereby, resulting to a potential health risk to the consumers.

The Effect of Crosslinking Agents on the Properties of Type II Collagen Biomaterials

2021 ◽  
Vol 57 (4) ◽  
pp. 166-180
Author(s):  
Maria-Minodora Marin ◽  
Madalina Georgiana Albu Kaya ◽  
George Mihail Vlasceanu ◽  
Jana Ghitman ◽  
Ionut Cristian Radu ◽  
...  
Keyword(s):  
Research Work ◽  
Cartilage Tissue Engineering ◽  
Chemical Properties ◽  
Cartilage Regeneration ◽  
Type Ii Collagen ◽  
Biomechanical Properties ◽  
Cartilage Tissue ◽  
Cross Linking ◽  
Type Ii ◽  
Crosslinking Agents

Type II collagen has been perceived as the indispensable element and plays a crucial role in cartilage tissue engineering. Thus, materials based on type II collagen have drawn farther attention in both academic and research for developing new systems for the cartilage regeneration. The disadvantage of using type II collagen as a biomaterial for tissue repairing is its reduced biomechanical properties. This can be solved by physical, enzymatic or chemical cross-linking processes, which provide biomaterials with the required mechanical properties for medical applications. To enhance type II collagen properties, crosslinked collagen scaffolds with different cross-linking agents were prepared by freeze-drying technique. The present research work studied the synthesis of type II collagen biomaterials with and without crosslinking agents. Scaffolds morphology was observed by MicroCT, showing in all cases an appropriate microstructure for biological applications, and the mechanical studies were performed using compressive tests. DSC showed an increase in denaturation temperature with an increase in cross-linking agent concentration. FTIR suggested that the secondary structure of collagen is not affected after the cross-linking; supplementary, to confirm the characteristic triple-helix conformation of collagen, the CD investigation was performed. The results showed that the physical-chemical properties of type II collagen were improved by cross-linking treatments.

Isatin: A Scaffold with Innumerable Biodiversity

2020 ◽  
Vol 20 ◽  
Author(s):  
Priyobrata Nath ◽  
Agnish Mukherjee ◽  
Sougata Mukherjee ◽  
Sabyasachi Banerjee ◽  
Samarpita Das ◽  
...  
Keyword(s):  
Biological Effects ◽  
Scientific Information ◽  
Research Work ◽  
Chemical Properties ◽  
Industrial Applications ◽  
Biologically Relevant ◽  
Extensive Information ◽  
Relevant Compound ◽  
A Minor ◽  
Clinical Conditions

: Isatin is an endogenous and a significant category of fused heterocyclic component, widely been a part of several potential biologically useful synthetics. Since its discovery, tons of research work has been conducted with respect to the synthesis, chemical properties, and biological and industrial applications. It contains indole nucleus having both lactam and keto moiety which while being a part of a molecular framework exerted several biological effects, viz.; antimicrobial, antitubercular, anticonvulsant, anticancer etc. Isatin derivatives are synthetically significant substrates, which can be utilized for the synthesis of huge diversified chemical entities of which few members emerged to be a drug. The reason for this review is to provide extensive information pertaining to the chemistry and its significance in altering several pathological states of isatin and its derivatives. A Structure Activity Relationships study thus developed through a gamut of scientific information indicates the importance of mostly electron withdrawing groups, halogens, nitro, alkoxy and to a minor extent groups with positive inductive effects, such as methyl at position 1, 5, 6 and 7 of isatin in alleviating several clinical conditions. It is also observed from the survey that the presence of two oxo groups at position 2 and 3 sometimes become insignificant as fusion with a heterocycle at those position resulted in a biologically relevant compound.

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