scholarly journals Extraction, Characterization and Rheological Behavior of Tamarind Gum Under High Salinity

Author(s):  
Raíssa Carvalho ◽  
Alyce Leal ◽  
Luiz Carlos Palermo ◽  
Claudia Mansur

The objective of this work was to obtain tamarind gum from Tamarindus indica L. seeds, which are waste from the food industry. Tamarind gum was extracted by two methods and the highest yield achieved was 32.6% w/w, containing 69.25% w/w of organic matter, which was composed mostly of the nonionic polysaccharide xyloglucan. The greatest molar mass of the tamarind gum was Mw=7.16 x 105 g/mol with polydispersity index (PI) of 1.7. Evaluation of the rheological behavior of tamarind gum samples were carried out in two brines (total dissolved solids values of 29,711 mg/L and 68,317 mg/L, containing divalent ions) that simulated petroleum reservoir salinity levels, with different temperatures (25, 60 and 80°C). The rheological curves indicated high salt resistance of the gum samples. Under a shear rate of 7.3 s-1 the highest viscosity values found were approximately 86, 41 and 50 cP with at concentration of 5,000 ppm and temperatures of 25, 60 and 80ºC, respectively.

SPE Journal ◽  
2020 ◽  
Vol 25 (04) ◽  
pp. 1871-1883
Author(s):  
Mohamad Salman ◽  
Konstantinos Kostarelos ◽  
Pushpesh Sharma ◽  
Jae Ho Lee

Summary Unconventional plays pose a challenging set of operational conditions, including high temperature, high salinity, low permeability, and fracture networks. Aggressive development of these plays and the low primary recovery factors present an opportunity for using enhanced oil recovery (EOR) methods. This work presents a laboratory investigation of miscible ethane (C2H6) foam for gas EOR conformance in low-permeability, heterogeneous, harsh environments [<15 md, 136,000 ppm total dissolved solids (TDS) with divalent ions, 165°F]. The use of C2H6 as an alternative to carbon dioxide (CO2) offers several operational and availability strengths, which might expand gas EOR applications to depleted or shallower wells. Coupling gas conformance also helps improve displacement efficiencies and maximize overall recovery. Minimum miscibility pressure (MMP) displacement tests were performed for dead crude oil from the Wolfcamp Spraberry Trend area using C2H6 and CO2. Aqueous stability, salinity scan, and static foam tests were performed to identify a formulation. Subsequent foam quality and coreflood displacement tests in heterogeneous carbonate outcrop cores were conducted to compare the recovery efficiencies of three processes: gravity-unstable, miscible C2H6 foam; gravity-stable, miscible C2H6; and gravity-unstable, miscible C2H6 processes. Slimtube tests comparing C2H6 to CO2 resulted in a lower MMP value for C2H6. We identified a stable surfactant blend capable of Type I microemulsion and persistent foams in the presence of oil. Corefloods conducted with gravity-unstable miscible C2H6 foam, gravity-stable miscible C2H6, and gravity-unstable miscible C2H6 recovered 98.4, 61.9, and 42.6% oil originally in place, respectively. Our work shows that miscible C2H6 injection processes achieved significant recoveries even under gravity-unstable conditions. The addition of foam provides better conformance control, enhancing overall recovery at the laboratory scale, showing promise for field applications.


Molecules ◽  
2021 ◽  
Vol 26 (23) ◽  
pp. 7361
Author(s):  
Rania Dghaim ◽  
Zied Hammami ◽  
Rola Al Ghali ◽  
Linda Smail ◽  
Dalia Haroun

Adaptability to salinity varies between different varieties of date palm trees. This research aims to explore the long-term impact of different salinity irrigation levels on the mineral content of 13 date palm varieties grown in the United Arab Emirates (UAE). Date varieties were grown using three irrigation water salinity levels of 5, 10 and 15 dS m−1. The mineral composition (B, Ca, Cu, Fe, K, Mg, Na, P and Zn) of date palm fruits was determined using Inductively Coupled Plasma-Optical Emission Spectrometry (ICP-OES). High salinity levels showed no effect on the mineral content of Ajwat AlMadinah, Naghal, Barhi, Shagri, Abu Maan, Jabri, Sukkari and Rothan varieties. All date varieties remained good sources of dietary potassium, magnesium, manganese and boron even at high salinity levels. Increased salinity had no effect on the percent Daily Value (%DV) categories of most of the analyzed minerals. While no genotypes showed a general adaptation to different saline environments, Barhi, Ajwat Al Madinah, Khinizi, Maktoumi and Shagri varieties were more stable towards salinity variation. In the UAE, the genotype x saline-environment interaction was found to be high which makes it impossible to attribute the variation in mineral content to a single varietal or salinity effect.


2020 ◽  
Vol 865 ◽  
pp. 79-84
Author(s):  
Darem Ahmad ◽  
Roy Presswell ◽  
Hussam Jouhara

Water scarcity is growing and in particularly in regions where population is high. It is estimated by world wild life organization that two thirds of human population may face water shortage by 2025. However, the amount of water available on earth covers approximately two thirds of the total surface area, but most of the water is seawater. Seawater cannot be used for any human use due to the high salinity levels. Desalination processes have been implemented on various scales whereby reverse osmosis is the most successful. However, such system is too complex and expensive. An alternative system utilizing humidification-dehumidification process for desalination is proposed in this paper. The process involves the use of a novel hydrophobic membrane allowing the humidification. Two configurations have been tested in a closed loop cycle, namely: static and moving membrane. The results from the experiments have shown that the efficiency of the moving membrane configuration is higher than the static by 46%. And based on 1 Litre brine feed, 50% of the volume has been successfully desalinated.


Author(s):  
Douglas R. Reis ◽  
Fabrício B. Brum ◽  
Eduardo J. O. Soares ◽  
Jessiana R. Magalhães ◽  
Fabrício S. Silva ◽  
...  

ABSTRACT Several types of seeds have been initially used in the food industry due to the great potential that vegetable proteins have. Baru is a fruit commonly found in the Cerrado biome, having a high nutritional value. This paper aimed to determine and analyze the drying kinetics of whole and defatted baru almond flours at different temperatures. The flour resulting from almond milling was defatted using petroleum ether. The drying processes were performed at temperatures of 40, 50 and 60 ºC. The mathematical models of Page, Henderson and Pabis, Midilli & Kucuk, Thompson and Approximation of Diffusion were fitted to the experimental data. The results showed a noticeable effect of air temperature on the drying kinetics of whole and defatted baru almond flours. According to the statistical parameters of analysis, the models Midilli & Kucuk and Page were the ones with the best fits to the experimental data. The effective diffusivity values found ranged from 8.02 × 10–10 to 19.90 × 10–10 m2 s-1 and for the activation energy were 22.39 and 39.37 KJ mol-1 for whole and defatted almonds, respectively.


Processes ◽  
2020 ◽  
Vol 8 (7) ◽  
pp. 792
Author(s):  
Nurul Izzah Khalid ◽  
Nurul Shaqirah Sulaiman ◽  
Norashikin Ab Aziz ◽  
Farah Saleena Taip ◽  
Shafreeza Sobri ◽  
...  

Electrolyzed water (EW) shows great potential as a green and economical sanitation solution for the food industry. However, only limited studies have investigated the optimum electrolysis parameters and the bactericidal effect of acidic electrolyzed water (AcEW) and alkaline electrolyzed water (AlEW). Here, the Box–Behnken experimental design was used to identify the optimum parameters. The tests were conducted with different types of electrodes, electrical voltages, electrolysis times, and NaCl concentrations. There were no obvious differences observed in the physico-chemical properties of EW when different electrodes were used. However, stainless steel was chosen as it meets most of the selection criteria. The best-optimized conditions for AcEW were at 11.39 V, 0.65 wt.% NaCl, and 7.23 min, while the best-optimized conditions for AlEW were at 10.32 V, 0.6 wt.% NaCl, and 7.49 min. The performance of the optimum EW (AcEW and AlEW) compared with commercial cleaning detergents for the food industry was then evaluated. The bactericidal activity of AcEW and AlEW was examined against Escherichia coli ATCC 10536 at different temperatures (30 °C and 50 °C) for 30 s. The results show that both AcEW and AlEW have the ability to reduce the Escherichia coli to non-detectable levels (less than 2 log CFU/mL).


2015 ◽  
Vol 14 (2) ◽  
pp. 31 ◽  
Author(s):  
L. E. Silva ◽  
C. A. C. Santos ◽  
J. E. S. Ribeiro ◽  
C. C. Souza ◽  
A. M. S. Sant’Ana

Rheology attempts to define a relationship between the stress acting on a given material and the resulting deformation and/or flow that takes place. Thus, the knowledge of rheological properties of fluid materials such as vegetable oils generates auxiliary data that can be used in its storage and application. In this context, the aim of this study was to evaluate the rheological behavior of vegetable oils (cotton, canola, sunflower, corn and soybean) at different temperatures, using four rheological models (Ostwald- de-Waelle, Herschel-Bulkley, Newton and Bingham). The rheological properties were determined using a Thermo Haake rheometer with concentric cylinder geometry. Measurements were taken at 30, 45 and 60 °C by controlling the temperature using a thermostatic bath coupled to the equipment. The software Rheowin Pro Job Manager was used for process control and data record. The rheograms were obtained by measuring the values of shear stress varying the shear rate from 100 to 600 s-1 within 250 seconds. For the analysis of the apparent viscosity at different shear rates was applied simple linear regression until 2nd degree with the aid of SAS (SAS/Stat 9.2) program. The apparent viscosity data were submitted to analysis of variance and the averages were compared by Tukey test at 5% of probability. Higher temperatures of the samples were correlated to lower shear stress values, hence lower values for viscosity and consistency index were obtained, since it is known that the density and viscosity are highly sensitive to temperature and that the increase in temperature results in reduction of viscosity, benefiting the fluid flow. The models of Newton and Ostwald-de-Waelle were chosen to evaluate the rheological behavior of the samples, showing a good fit for the rheological data.


2014 ◽  
Vol 587-589 ◽  
pp. 1281-1285
Author(s):  
Xu Dong Li

Research shows that rheological property of asphalt relates directly to pavement property. To get a grip on the influence of different factors on rheological property of high modulus asphalt, this paper makes a systematic study of different temperatures, loading frequency, strain 70# base asphalt and rheological property of high modulus asphalt by the method of DSR measurement, and compared their anti-fatigue performance. The experiment’s results shows that high-modules asphalt has a low sensitivity of temperature. Compare with the base asphalt, the high-modules modified asphalt’s G*/sinδ will have a slower decrease rapid under the condition of temperature increase. Both asphalt’s G*/sinδ would decrease with the decrease of load frequency, high-modules asphalt has a higher G*/sinδ than base asphalt especially at the high temperature and low frequency.


Author(s):  
Eric Cayeux ◽  
Amare Leulseged

Abstract It is nowadays well accepted that the steady state rheological behavior of drilling fluids must be modelled by at least three parameters. One of the most often used models is the yield power law, also referred as the Herschel-Bulkley model. Other models have been proposed like the one from Robertson-Stiff, while other industries have used other three-parameter models such as the one from Heinz-Casson. Some studies have been made to compare the degree of agreement between different rheological models and rheometer measurements but in most cases, already published works have only used mechanical rheometers that have a limited number of speeds and precision. For this paper, we have taken measurements with a scientific rheometer in well-controlled conditions of temperature and evaporation, and for relevant shear rates that are representative to normally encountered drilling operation conditions. Care has been made to minimize the effect of thixotropy on measurements, as the shear stress response of drilling fluids depends on its shear history. Measurements have been made at different temperatures, for various drilling fluid systems (both water and oil-based), and with variable levels of solid contents. Also, the shear rate reported by the rheometer itself, is corrected to account for the fact that the rheometer estimates the wall shear rate on the assumption that the tested fluid is Newtonian. A measure of proximity between the measurements and a rheological model is defined, thereby allowing the ranking of different rheological behavior model candidates. Based on the 469 rheograms of various drilling fluids that have been analyzed, it appears that the Heinz-Casson model describes most accurately the rheological behavior of the fluid samples, followed by the model of Carreau, Herschel-Bulkley and Robertson-Stiff, in decreasing order of fidelity.


Agronomy ◽  
2019 ◽  
Vol 9 (10) ◽  
pp. 573 ◽  
Author(s):  
Jishi Zhang ◽  
Xilong Jiang ◽  
Yanfang Xue ◽  
Zongxin Li ◽  
Botao Yu ◽  
...  

As efforts to close crop production yield gaps increase, the need has emerged to identify cost-effective strategies to reduce yield losses through soil improvement. Maize (Zea mays L.) production in coastal saline soil is limited by high salinity and high pH, and a limited number of soil amendment options are available. We performed a field experiment in 2015 and 2016 to evaluate the ability of combined flue gas desulfurization gypsum and furfural residue application (CA) to reduce the maize yield gap and improve soil properties. We carried out the same amendment treatments (CA and no amendment as a control) under moderate (electrical conductivity (EC1:1) ≈ 4 dS m−1) and high (EC1:1 ≈ 6 dS m−1) salinity levels. Averaged over all salinity levels and years, maize yields increased from 32.6% of yield potential in the control to 44.2% with the CA treatments. Post-harvest CA treatment increased the calcium (Ca2+) and soil organic carbon (SOC) contents while decreasing the sodium (Na+) content and pH in the upper soil layer. Corresponding nitrogen, phosphorus, potassium, calcium, and magnesium accumulations in maize were significantly increased, and Na accumulation was decreased in the CA group compared with the control. The economic return associated with CA treatment increased by 215 $ ha−1 at the high salinity level compared with the control, but decreased at the moderate salinity level because of the minor increase in yield. The results of this study provide insight into the reduction of yield gaps by addressing soil constraints.


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