High Temperature Sliding of TiC Based Hardmetal Coatings Against TWIP Steel

Author(s):  
M. Varga ◽  
L. Janka ◽  
M. Rodríguez Ripoll ◽  
L.-M. Berger ◽  
S. Thiele ◽  
...  

Abstract Manufacturing of steel components is often done at high temperatures (HT) posing a serious challenge to components such as forming tools. Thermal spray coatings provide a cost-effective solution for surface protection under HT, corrosive environments and severe wear conditions. Thermally sprayed coatings based on cubic hard materials such as TiC and TiCN can provide an alternative to widely used Cr3C2-NiCr. While the latter possess a superb oxidation resistance and wear resistance at HT, they are prone to degradation in the presence of Mn, an element commonly alloyed in many modern steel grades such as TWIP (twinning-induced plasticity steel). In this study, a (Ti,Mo)(C,N)-29% Ni hardmetal feedstock powder was prepared by agglomeration and sintering. Coatings were deposited using a high velocity air-fuel (HVAF) spray process. The coating was benchmarked against a standard Cr3C2-NiCr coating obtained with the same spray process. Our work comprises analyses of the feedstock powder along with the resulting coating microstructure after deposition and heat treatment. Further, the HT sliding behavior against TWIP steel using a HT pin-on-disc tribometer at 700°C was investigated. The results showed a clear benefit of the TiCN-based coating, with almost no wear detected, while the Cr3C2-coating showed a significant wear loss. Based on these results, the TiCN-based coating is regarded as potential solution for prospective forming applications of modern high Mn steels, such as TWIP.

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Changling Zhuang ◽  
Jianhua Liu ◽  
Changrong Li ◽  
Daowen Tang

Abstract Fe-Mn-C-Al alloy is a new steel grade of TWIP steel developed in recent years. It has an excellent combination of elongation and tensile strength, as well as good anti-delayed fracture property. However, the crack sensitivity of this new TWIP steel has not been reported yet. In this study, differential thermal analysis (DTA) method was used, combined with professional thermodynamic software ThermoCalc to analyze the solidification behavior for Fe-Mn-C-Al alloys with different chemical compositions. Based on this, the crack sensitivity of TWIP steel is further determined. Through this study, it was found that Fe-Mn-C-Al TWIP steel may have a solidification sequence with high crack sensitivity, belonging to hypo-peritectic steel. Moreover, it was found that the carbon content has a large influence on the solidification behavior, and the manganese content also affects the solidification sequence. It can make the phase transition sequence of the solidification process change significantly, which may avoid the solidification behavior of hypo-peritectic reaction. The analysis results by thermodynamic software ThermoCalc are in good agreement with the experimental results. It displays thermoCalc can be a cost-effective way to develop Fe-Mn-C-Al TWIP steel. It is of great significance for shortening the development period of new Fe-Mn-C-Al steel grades.


2007 ◽  
Vol 124-126 ◽  
pp. 1601-1604 ◽  
Author(s):  
Yeon Wook Kim ◽  
Hee Jung Kim ◽  
Hyun Myung Shin

One of the most important use of thermal spray coatings is for wear resistance. In this work, the tribological properties of plasma prayed Al83.7Fe7Cr6.3Ti3 quasicrystalline coatings have been studied. The quasicrystal powders of Al-base alloys were produced by gas atomization unit in vacuum. The plasma spray process was used to produce quasicrystalline coatings. Then, friction experiments were carried out on a pin-on-disc-type tribometer. The results indicated that the friction coefficient of Al83.7Fe7Cr6.3Ti3 quasicrystalline coating is about 50% lower than that of Al70Fe13Cu10Cr7 quasicrystalline coating.


Author(s):  
Arputham Arul Jeya Kumar ◽  
Muniyandi Prakash ◽  
Abburi Lakshmankumar ◽  
Kesuboyina Haswanth

In this work, the wear loss of basalt fiber reinforced polypropylene/polylactic acid polymer composite was analyzed using pin-on-disc under dry sliding conditions. The polypropylene, polylactic acid, and basalt fiber (chopped fiber) are melted and mixed homogeneously using a twin-screw extruder, which is followed by an injection molding technique for specimen preparation. The specimens are named as PPB1 (polypropylene, 50%; polylactic acid, 35%; basalt fiber, 15%), PPB2 (polypropylene, 55%; polylactic acid, 30%; basalt fiber, 15%), and PPB3 (polypropylene, 60%; polylactic acid, 25%; basalt fiber, 15%) based on their weight fraction. The wear rate and coefficient of friction are measured for each sample subjected to three different loads and sliding velocities. It is observed from the wear mapping that the wear loss of sample PPB3 is relatively less when compared with the other samples. The scanning electron microscope images of the worn-out region of the sample reveal the fracture and dislocation of fibers in the matrix. The sample PPB3 shows low wear loss. It is due to the better cohesion between the fiber and the matrixes when compared with the other samples.


2017 ◽  
Vol 867 ◽  
pp. 19-28 ◽  
Author(s):  
J. Lakshmipathy ◽  
Subburaj Rajesh Kannan ◽  
K. Manisekar ◽  
S. Vinoth Kumar

In this article, an attempt was made to study the mechanical behaviour of AA7068 - 6 vol. % of MoS2 - X vol. % of WC (X = 0, 5, 10 and 15) hybrid aluminium composites produced by blend–press–sinter methodology. Compacted Powders (700MPa) were sintered at different temperatures (450 0c, 500 0c and 550 0c ) in order to find the influence of sintering temperature on mechanical properties and tribological behavior of AA7068 hybrid composites.The sintered samples have been characterized by x-ray diffraction (XRD) method for identification of phases and also to investigate the phase changes. The change in density, hardness and porosity values of composites were reported. The composite with 15 vol. % of tungsten carbide and 6 vol. % of MoS2 showed the highest hardness and density at the sintering temperature range of 550 0c. Pin-on-disc type apparatus was used for determining the wear loss occurring at different conditions. The hybridization of the two reinforcements enhanced the wear resistance of the composites, especially under high applied load, sliding distance and sliding speeds. Due to this, the hybrid aluminium composites can be considered as an outstanding material where high strength and wear-resistant components are of major importance, predominantly in the aerospace and automotive engineering sectors. The morphology of the wear debris and the worn out surfaces were analyzed to understand the wear mechanisms.


Author(s):  
G. Barbezat ◽  
S. Keller ◽  
G. Wuest

Abstract In the Automotive Industry the need for lower manufacturing costs, the use of less strategic material, and easier, faster, and more flexible routes for manufacturing are being looked for continuously. The environmental concerns relating to the use of galvanic coatings is growing. This has led to the examination of the plasma-powder spray process for the application of coatings for surface modification. In the area of engine cylinder bore coatings a major advance is taking place in the use of a rotating plasma spray device. This paper covers the use of a plasma-powder spray process for the coating of aluminum-silicon cylinder block bores using a rotating plasma gun capable of producing coatings of reliable microstructure and integrity. Properties and microstructures of the applied coatings will be presented. Test results will be shown that the necessary bond strength of the coating can be achieved without the use of a bond coat. Surface preparation prior to coating and surface finishing methods after coating will also be discussed. Experience in Europe, Japan and the Unites States will be discussed which show that the plasma-powder spray process offers a performance proven and cost effective solution for the coating of cylinder bores, thus demonstrating the future application potential for this technology.


Author(s):  
Albert E. Segall ◽  
Faruk A. Sohag ◽  
Faith R. Beck ◽  
Lokanath Mohanta ◽  
Fan-Bill Cheung ◽  
...  

During a Reaction Initiated Accident (RIA) or Loss of Coolant Accident (LOCA), passive external-cooling of the reactor lower head is a viable approach for the in-vessel retention of Corium; while this concept can certainly be applied to new constructions, it may also be viable for operational systems with existing cavities below the reactor. However, a boiling crisis will inevitably develop on the reactor lower head owing to the occurrence of Critical Heat Flux or CHF that could reduce the decay heat removal capability as the vapor phase impedes continuous boiling. Fortunately, this effect can be minimized for both new and existing reactors through the use of a Cold-Spray delivered, micro-porous coating that facilitates the formation of vapor micro-jets from the reactor surface. The micro-porous coatings were created by first spraying a binary mixture with the sacrificial material then removed via etching. Subsequent quenching experiments on uncoated and coated hemispherical surfaces showed that local CHF values for the coated vessel were consistently higher relative to the bare surface. Moreover, it was observed for both coated and uncoated surfaces that the local rate of boiling and local CHF limit varied appreciably along the outer surface. Nevertheless, the results of this intriguing study clearly show that the use of Cold Spray coatings could enhance the local CHF limit for downward facing boiling by more than 88%. Moreover, the Cold-Spray process is amenable to coating the lower heads of operating reactors.


Author(s):  
Do Le Hung Toan, Shuo-Jen Lee Do

Micro arc oxidation method has been developed in the field of surface protection of magnesium alloys and considered as a simple, highly effective, commercial and environmentally friendly method in industry. MAO coatings are fabricated on novel Mg-Al-Li-Zn alloy to improve the anti-corrosion performance of surface by using friendly alkaline electrolytes under a high electrical potential. The Taguchi method and optimal analysis are used to identify the effects of the three factors including current density, processing time and electrical frequency on coating’s characteristics. The results have shown that the main factor that affects coating thickness and corrosion resistance of coating is the processing time. The results obtained by optimal conditions are consistent with prediction values of Taguchi analysis. The thickness of the coating can help to improve the long-term corrosion protection of a MAO coating in corrosive environments.


2020 ◽  
Vol 37 (1−2) ◽  
Author(s):  
SRIDHAR ATLA ◽  
Prasanna Lakshmi Kaujala

The aluminium metal matrix composite reinforced with ceramic material of Silicon carbide (SiC) has good mechanical properties. However, aluminium based ceramic composites require improvements in their lubrication and tribological properties. In this study an attempt is made in the development of a new material through powder metallurgy technique by the addition of Graphite, which acts as a solid lubricant. This work investigated the influence of graphite on the wear behaviour of Al 7075/SiC /X wt.% graphite(X=0, 5 and 10) hybrid composite. The investigation reveals the effectiveness of incorporation of graphite in the composite for gaining wear reduction. The Al 7075 (aluminium alloy 7075) reinforced with SiC –graphite were investigated. The composites were fabricated using powder metallurgy route. The microstructures, material combination, wear and friction properties were analysed by scanning electron microscopy, XRD, and pin-on-disc wear tester. The newly developed aluminium composite has significant improvements in tribological properties with a combination of 5% Silicon carbide (SiC) and 5% Graphite. The test reveals that sliding distance of 1000 m and sliding speed of 1.5 m/s with applied load of 5 N result in minimum wear loss of 0.01062g and coefficient of friction as 0.1278.


Author(s):  
A.Ph. Ilyuschenko ◽  
N.I. Shipica ◽  
P.A. Vityaz ◽  
A.A. Yerstak ◽  
A.Y. Beliaev

Abstract This paper presents the results of a study on the wear resistance of plasma spray coatings made from Cr2O3-TiO2-CaF2 powders. The composite powders used were produced by self-propagating high temperature synthesis. They were then applied under various conditions in order to optimize the material system, spray process, and application procedures. Based on the results of microstructural examination and wear testing, the thermally sprayed composite coatings have excellent wear resistance, good adhesion, and are self-lubricating at high temperatures.


Author(s):  
E. Petrovicova ◽  
R. Knight ◽  
R.W. Smith ◽  
L.S. Schadler

Abstract Ceramic/polymer nanocomposites promise to be a new class of materials that will have wide application either for surface protection, providing low friction and inert corrosion barriers, or where tailored electrical and magnetic properties with increased abrasion and wear resistance are required. The high velocity oxy-fuel (HVOF) combustion spray process has been used to successfully process polymer-ceramic nanocomposites at 5 - 20 volume % of reinforcement. The latest results of process-structure- property relationship studies in silica and carbon black reinforced nylon 11 coatings are presented. It was found that the improvement in mechanical properties depends on the distribution and surface chemistry of the particulates and on the increase in matrix crystallinity due to the particulates.


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