scholarly journals Correlation of Optical and Mechanical Properties of Silver Nanoparticles Sensitized Europium Doped Magnesium Zinc Sulfophosphate Glasses

2020 ◽  
Vol 2 (2) ◽  
pp. 147-155
Author(s):  
Ibrahim Mohammed Danmalam ◽  
Ibrahim Bulus

Magnesium-zinc-sulfophosphate glasses with various concentration of Silver nanoparticles (AgNPs) of molar composition 63.5P2O5–20MgO –15ZnSO4–1.5Eu2O3 –yAgNps (y = 0.0, 0.1, 0.3, 0.5, 0.7,0.9 and 1.1 g in excess) were prepared via melt-quenching method.  As-synthesized glasses were characterized at room temperature to determine the relationship between structural and mechanical properties. Densities of glasses were increased from 3.0720 to 4.3304 g.cm-3 with increase in AgNPs embedding levels, suggesting the network shrinkages and enhanced compactness. The Young’s, shear and bulk modulus of glasses were observed to enhance with the increase in AgNPs contents. The Poisson’s ratio of the studied glasses was increased from (0.0978 to 0.1416) while the values of both Vickers hardness (from 0.0658 to 0. 0.0682 GPa) as well as  (from 0.8350 to 0.8916) were increased. The proposed glass composition may be useful for the development of hard surface engineering.

2018 ◽  
Vol 11 (02) ◽  
pp. 1850026 ◽  
Author(s):  
Guangning Hou ◽  
Lijie Cao ◽  
Chaomin Zhang ◽  
Jinan Xia ◽  
Guishun Li

La2O3 and ZrO2 co-doped silicate glasses were fabricated using melt-quenching method. The network structure, Vickers hardness and elastic modulus of the glasses were measured to investigate their mechanical properties. Our results indicated that the prepared samples exhibited high strength network structures with excellent mechanical performance. The Vickers hardness exceeded 858[Formula: see text]HV, and the elastic modulus reaches 100[Formula: see text]GPa. They increased approximate 37% and 18.6%, respectively, more than the most hardness and modulus reported for this type of glasses, while their transmittance in visible spectrum range was over 90%.


2012 ◽  
Vol 736 ◽  
pp. 307-315 ◽  
Author(s):  
Murugavel Suresh ◽  
Satyam Suwas

Mg alloys show limited room temperature formability compared to its lightweight counterpart aluminium alloys, which is a main obstacle in using this metal for most of the structural applications. However, it is known that grain refinement and texture control are the two possibilities for the improvement of formability of magnesium alloys. Amongst the approaches attempted for the texture weakening, additions through of rare-earth (RE) elements have been found most effective. The relationship between the texture and ductility is well established. In this paper, the effect of rare earth addition on texture weakening has been summarized for various magnesium alloys under the two most common modes of deformation methods.


2012 ◽  
Vol 512-515 ◽  
pp. 377-381 ◽  
Author(s):  
Jin Rong Lu ◽  
Yang Zhou ◽  
Yong Zheng ◽  
Shi Bo Li ◽  
Zhen Ying Huang ◽  
...  

In this paper, a new type of Ti3SiC2/Cu composites with the volume fractions of 30% Ti3SiC2 particle was prepared by hot pressing and vacuum sintering respectively. The effects of sintering temperature and holding time on the density, resistance and Vickers hardness of Cu-30vol%Ti3SiC2 composite were investigated. The results show that the mechanical properties of the composites prepared by hot pressing are better than that prepared by vacuum sintering. The relative densities of Cu-30vol% Ti3SiC2 composites are rather high in suitable sintering conditions. It achieved 100% for the composites prepared by hot pressing at 930°C for 2h, and 98.4% for the composites prepared by vacuum sintering at 1250°C for 1h. At the same time, the maximum Vickers hardness reached 1735MPa at 900°C by hot pressing. The resistance and Vickers hardness of the composites decreased with an increase in sintering temperature, whereas the density increased. Scanning electron microscope (SEM) and energy-dispersive spectroscopy (EDS) were used to observe the microstructure of the composites. The relationship between microstructure and mechanical properties was discussed.


2012 ◽  
Vol 2012 (CICMT) ◽  
pp. 000406-000410
Author(s):  
Hiroki TSUDA ◽  
Jun AKEDO ◽  
Shingo HIROSE ◽  
Keishi OHASHI

The possibility and mechanical improvement of the infrared ceramic coatings fabricated on fluoride substrates at room temperature by aerosol deposition (AD) were investigated aiming to optical components for infrared applications and devices. The yttria coating possibility fabricated on barium fluoride substrates by the AD process was found by adjusting one of the deposition conditions. The optical and mechanical properties of the fabricated ceramic coatings, which are important in practical applications, were evaluated by transmittance and hardness measurements respectively. The mechanical hardness of the fabricated yttria single coatings was increased to 4 times higher than that of the barium fluoride substrates. Furthermore, by an additional layer on a barium fluoride substrate, the mechanical properties of the fabricated multi-coatings including an upper yttria layer were improved from that of the single yttria coating on the barium fluoride substrate, retaining the IR transmittance of the single yttria coating at the wavelength of 10μm.


2010 ◽  
Vol 160-162 ◽  
pp. 915-920
Author(s):  
Shao Jiang Lin ◽  
Da Peng Feng ◽  
Qi Nian Shi

This work presents the possibility of obtaining high density austenitic stainless steel parts by powder metallurgy (PM) and sintered in vacuum. Mechanical properties such as tensile strength, yield stress, elongation rate and Vickers hardness were measured by using a tensile testing machine and a Vickers hardness tester at room temperature. Microstructural characterization was performed by means of optical microscopy and scanning electron microscopy (SEM). The effect of sintering temperature on densification and mechanical properties of PM austenitic stainless steel has been investigated. The results show that density and mechanical properties were increased with the increase of sintering temperature, but when the sintering temperature is above 1340 °C, they increased slowly. The highest mechanical properties were obtained when sintering temperature was 1340 °C.


2018 ◽  
Vol 19 (12) ◽  
pp. 3937 ◽  
Author(s):  
Izabela Barszczewska-Rybarek ◽  
Grzegorz Chladek

Bioactive dimethacrylate composites filled with silver nanoparticles (AgNP) might be used in medical applications, such as dental restorations and bone cements. The composition of bisphenol A glycerolate dimethacrylate (Bis-GMA) and triethylene glycol dimethacrylate (TEGDMA) mixed in a 60/40 wt% ratio was filled from 25 to 5000 ppm of AgNP. An exponential increase in resin viscosity was observed with an increase in AgNP concentration. Curing was performed by way of photopolymerization, room temperature polymerization, and thermal polymerization. The results showed that the polymerization mode determines the degree of conversion (DC), which governs the ultimate mechanical properties of nanocomposites. Thermal polymerization resulted in a higher DC than photo- and room temperature polymerizations. The DC always decreased as AgNP content increased. Flexural strength, flexural modulus, hardness, and impact strength initially increased, as AgNP concentration increased, and then decreased at higher AgNP loadings. This turning point usually occurred when the DC dropped below 65% and moved toward higher AgNP concentrations, according to the following order of polymerization methods: photopolymerization < room temperature polymerization < thermal polymerization. Water sorption (WS) was also determined. Nanocomposites revealed an average decrease of 16% in WS with respect to the neat polymer. AgNP concentration did not significantly affect WS.


2021 ◽  
Vol 1016 ◽  
pp. 917-921
Author(s):  
Haruka Miyano ◽  
Keisuke Takemoto ◽  
Hiromoto Kitahara ◽  
Shinji Ando

In this study, tensile tests of rolled Mg-Li alloy and Mg-Ce alloy sheets were carried out at room temperature to investigate effects of alloying additions on the relationship between mechanical properties and activities of slip systems in magnesium polycrystals. In Mg-Li alloy, ductility increased while strength decreased by lithium addition. Frequency of non-basal slips increased with increasing lithium content. In Mg-Ce alloy, strength and ductility were similar pure magnesium, and non-basal slips were hardly activated. Since critical resolved shear stress of non-basal slips were decreased by lithium addition, ductility of magnesium was increased while its strength was decreased.


1998 ◽  
Vol 553 ◽  
Author(s):  
T. Okada ◽  
T. Nakamura ◽  
K Mitsugi ◽  
K Kozawa ◽  
T Matumura ◽  
...  

AbstractTo apply the ductile structural materials, the quasicrystal dispersion in aluminum alloys is one of effective methods. We have investigated mechanical properties of quasicrystal dispersed Al- Li-Cu alloy prepared by the twin-type piston anvil apparatus. The slow cooled samples are hard and ductile. The evaluated values of brittleness are from 6.0 to 14 erg for Ef, from 0.52 to 0.73MNm−3/2 for K1c and from 5.5 to 7.7 Nm−1 for Gic for the fastest and slowest cooled samples, respectively. The hardness of the quasicrystal dispersed Al-Li-Cu alloy is higher than that of the other commercial aluminum alloys. Based on the relationship between Vickers hardness and proof stress of aluminum alloys, we estimate the specific strength of Al-Li-Cu quasicrystal alloy. The maximum value is the higher than that of Ti alloys.


2009 ◽  
Vol 1215 ◽  
Author(s):  
Ken Kurosaki ◽  
Masato Ito ◽  
Yuki Kitano ◽  
Hiroaki Muta ◽  
Masayoshi Uno ◽  
...  

AbstractFine bulk samples of delta-phase Hf hydride with various hydrogen contents (CH) ranging from 1.62 to 1.72 in the atomic ratio (H/Hf) were prepared, and their thermal and mechanical properties were characterized. In the temperature range from room temperature to around 650 K, the heat capacity and thermal diffusivity of the samples were measured and the thermal conductivity was evacuated. The elastic modulus was calculated from the measured sound velocity. The Vickers hardness was measured at room temperature. Effects of CH and/or temperature on the properties of Hf hydrides were discussed. At room temperature, the thermal conductivity values of the Hf hydrides were 23 Wm−1K−1. The Young's and shear moduli and the Vickers hardness of Hf hydride decreased with increasing CH.


2007 ◽  
Vol 534-536 ◽  
pp. 1077-1080 ◽  
Author(s):  
Junichi Matsushita ◽  
Kenji Shimao ◽  
Yoshiyuki Machida ◽  
Takumi Takao ◽  
Kiyokata Iizumi ◽  
...  

Several boride sintered bodies such as TiB2, ZrB2, and SiB6 were previously reported. In the present study, the sinterability and physical properties of chromium boride (CrB2) containing chromium carbide (Cr3C2) sintered bodies were investigated in order to determine its new advanced material. The samples were sintered at desired temperature for 1 hour in vacuum under a pressure by hot pressing. The relative density of sintered bodies was measured by Archimedes’ method. The relative densities of CrB2 addition of 0, 5, 10, 15 and 20 mass % Cr3C2 composites were 92 to 95 %. The Vickers hardness of the CrB2 with 10 and 15 mass % Cr3C2 composites were about 14 and 15 GPa at room temperature, respectively. The Vickers hardness at high temperature of the CrB2 addition of 10 mass % Cr3C2 composite decreased with increasing measurement temperature. The Vickers hardness at 1273 K of the sample was 6 GPa. The Vickers hardness of CrB2 addition of Cr3C2 composites was higher than monolithic CrB2 sintered body. The powder X-ray diffraction analysis detected CrB and B4C phases in CrB2 containing Cr3C2 composites.


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