scholarly journals FUNCTIONAL MODELING OF CARBON SORBENTS SYNTHESIS CONTROL

2019 ◽  
Vol 14 (1) ◽  
pp. 39-46
Author(s):  
V. V. Burlyaev ◽  
E. V. Burlyaeva ◽  
A. I. Nikolaev ◽  
B. V. Peshnev
Keyword(s):  
Functional Model ◽  
Carbon Sorbent ◽  
Sorption Properties ◽  
Raw Material ◽  
Synthesis Process ◽  
Phase Method ◽  
General Description ◽  
Functional Modeling ◽  
Technological Parameters ◽  
Carbon Sorbents

The formalized model of carbon sorbent synthesis control based on the methodology for functional modeling is constructed. The correlations between the directions of use and the properties of carbon sorbents are revealed. The characteristics that are essential regardless of the direction of use of the sorbent, in particular, sorption properties and strength are identified. The technologies based on the gas-phase method of obtaining carbon material are considered, the analysis of individual stages of the process of obtaining carbon sorbents is carried out. The analysis of the influence of the technological parameters of the synthesis on the properties of sorbents is carried out. On the basis of the established relationships, a functional model has been built that provides a hierarchically ordered, structured, visual description of the management of carbon sorbent synthesis. The simulation is performed “from top to bottom” from the most general description to the detail. The resulting model is a set of interrelated graphical diagrams. At the initial stage, the synthesis of carbon sorbent is considered as a single process, the input parameters of which are hydrocarbon gas, the activating agent and the material form factor, the output - carbon sorbent, and the control parameters are the requirements for strength and sorption properties. Then the synthesis process is decomposed. The control processes (analysis of raw material properties and matrix selection), technological processes (raw material preparation) and mixed processes are distinguished as a result of decomposition. The model includes a consistent description of the technological parameters selection (temperature, gas flow and time) for both stages of the synthesis process. The model is the base for information support providing for the production of carbon sorbents with the required properties.

Criteria for the Selection of Synthetic Polymeric Waste as a Raw Material for Producing Carbon Sorbents with Predetermined Properties

2020 ◽  
Vol 24 (10) ◽  
pp. 13-19
Author(s):  
Ya.I. Vaisman ◽  
I.S. Glushankova ◽  
L.V. Rudakova ◽  
A.A. Surkov ◽  
A.S. Atanova
Keyword(s):  
Raw Materials ◽  
Synthetic Polymer ◽  
Raw Material ◽  
Technological Parameters ◽  
Polymer Waste ◽  
Factors Affecting ◽  
Carbon Sorbents ◽  
Degree Of Aromaticity ◽  
Polymeric Waste ◽  
Selection Of

The results of studies on the thermal processing of synthetic multi-tonnage polymeric waste (polypropylene, polycarbonate, textolite, PET, organoplastics and tire rubber) with the production of carbon sorbents for technological and environmental purposes are presented. The influence of the nature of the activating agent and the conditions of the process with the production of sorbents with predetermined properties was studied. Analysis of the research results allowed us to establish that the main factors affecting the yield of carbonizate and the formation of a porous structure of carbon sorbents from synthetic polymer waste are the degree of aromaticity and the location of benzene rings in the polymer structure, the proportion of oxygen in the precursor. The criteria for selecting synthetic polymer wastes as raw materials for obtaining carbon sorbents with predetermined properties are established. The results of the research can be used in the development of technologies for obtaining carbon sorbents with predetermined properties from waste synthetic polymers and the selection of technological parameters for processes.

Comparison of a Non Electrostatic Surface Complexation Model and Surface Phase Theories for Prediction of Future Sorption Properties.

2004 ◽  
Vol 824 ◽  
Author(s):  
Allan T. Emrén ◽  
Anna-Maria Jacobsson
Keyword(s):  
Aqueous Solution ◽  
Chemical Potential ◽  
Surface Complexation ◽  
Sorption Properties ◽  
Phase Method ◽  
Detailed Knowledge ◽  
Surface Phase ◽  
Surface Complexation Model ◽  
Advantages And Disadvantages ◽  
The One

AbstractIn performance assessments, sorption of radionuclides dissolved in groundwater is mostly handled by the use of fixed Kd values. It has been well known that this approach is unsatisfying. Only during the last few years, however, tools have become available that make it possible to predict the actual Kd value in an aqueous solution that differs from the one in which the sorption properties were measured.One such approach is surface complexation (SC) that gives a detailed knowledge of the sorption properties. In SC, one tries to find what kinds of sorbed species are available on the surface and the thermodynamics for their formation from species in the bulk aqueous solution. Recently, a different approach, surface phase method (SP), has been developed. In SP, a thin layer including the surface is treated as a separate phase. In the bulk aqueous solution, the surface phase is treated as a virtual component, and from the chemical potential of this component, the sorption properties can be found.In the paper, we compare advantages and disadvantages of the two kinds of models. We also investigate the differences in predicted sorption properties of a number of radionuclides (Co, Np, Th and U). Furthermore, we discuss under which circumstances, one approach or the other is preferable.

FUNCTIONAL PURPOSE RABBIT MEAT ROLL

2021 ◽  
pp. 132-139
Author(s):  
Zhuldyz Isakovna Satayeva ◽  
Nurbibi Sovetovna Mashanova ◽  
Ainur Bolatbekovna Nurtayeva ◽  
Erzhan Talgatuly Akimzhanov
Keyword(s):  
Nutritional Value ◽  
Meat Product ◽  
Nutritional Supplements ◽  
Physicochemical Analysis ◽  
Raw Material ◽  
Technological Parameters ◽  
New Type ◽  
Rabbit Meat ◽  
High Level ◽  
Functional Purpose

The article presents the results of the development of a new type of rabbit meat product - meatloaf. The consumption of healthy and nutritious foods rich in macro- and micronutrients, low in lipids and cholesterol, as well as various nutritional supplements, is preferable for the modern consumer. One of the promising types of meat as a dietary raw material is rabbit meat. As a result of the studies, a physicochemical analysis was carried out, the amino acid composition of rabbit meat was determined, and an organoleptic and tasting assessment of rabbit meatloaf was given. The technological scheme, the recipe is developed and the technological parameters of the meatloaf preparation are determined. It is recommended to store meatloaf no more than 10 days at a temperature of 0–2 °C with a humidity of 85-90 %. Meatloaf from rabbit meat has functional properties, contains a large number of vitamins PP – 174.3 mg, potassium minerals – 5052.8 mg, magnesium – 382.4 mg, phosphorus – 2875 mg, sodium – 8598.7 mg.The results of the nutritional and biological value of rabbit meatloaf allow us to make an informed conclusion about the high level of their nutritional value, which clearly illustrates the values of quality indicators.

scholarly journals Synthesis of Fe3O4/Pt Nanoparticles Decorated Carbon Nanotubes and Their Use as Magnetically Recyclable Catalysts

2011 ◽  
Vol 2011 ◽  
pp. 1-10 ◽  
Author(s):  
Hongkun He ◽  
Chao Gao
Keyword(s):  
Carbon Nanotubes ◽  
Pt Nanoparticles ◽  
Reduction Reaction ◽  
Raw Material ◽  
Synthesis Process ◽  
High Catalytic Activity ◽  
Hydrolysis Method ◽  
Recyclable Catalysts ◽  
Temperature Solution ◽  
Average Size

We report a facile approach to prepare Fe3O4/Pt nanoparticles decorated carbon nanotubes (CNTs). The superparamagnetic Fe3O4nanoparticles with average size of4∼5 nm were loaded on the surfaces of carboxyl groups functionalized CNTs via a high-temperature solution-phase hydrolysis method from the raw material of FeCl3. The synthesis process of magnetic CNTs is green and readily scalable. The loading amounts of Fe3O4nanopartilces and the magnetizations of the resulting magnetic CNTs show good tunability. The Pt nanopaticles with average size of 2.5 nm were deposited on the magnetic CNTs through a solution-based method. It is demonstrated that the Fe3O4/Pt nanoparticles decorated CNTs have high catalytic activity in the reduction reaction of 4-nitrophenol and can be readily recycled by a magnet and reused in the next reactions with high efficiencies for at least fifteen successive cycles. The novel CNTs-supported magnetically recyclable catalysts are promising in heterogeneous catalysis applications.

scholarly journals Carbon Nanosorbent for Purification Different Biomolecules

2011 ◽  
Vol 14 (1) ◽  
pp. 41
Author(s):  
Z.A. Mansurov ◽  
A.R. Kerimkulova ◽  
S.A. Ibragimova ◽  
E.Y. Gukenheimer
Keyword(s):  
Carbon Nanostructures ◽  
Large Scale ◽  
Carbon Materials ◽  
Raw Materials ◽  
Carbon Sorbent ◽  
Nanostructured Carbon ◽  
Lipid Complex ◽  
Carbon Sorbents ◽  
Physico Chemical ◽  
Chemical Studies

The article presents the results of physico-chemical studies on the development of nanostructured carbon materials from domestic raw materials. Were obtained and tested micro-mesoporous carbon sorbents for molecular-sieve chromatography of markers and investigated the applicability of carbon sorbents for the separation of protein-lipid complex, and plant bio-stimulator. Carbon sorbents have well-developed porous structure but their disadvantage is the weak mechanical<br />strength. Recently it was shown that some carbon nanostructures have enormous strength. Thus arose the need to give the nano structured elements to carbon sorbent. Creating carbon sorbents containing nanocarbon structure was the aim of our study, as these by sorbents will be very useful for large-scale purification of biomolecules.

scholarly journals Immobilized Microalgae-Based Photobioreactor for CO2 Capture (IMC-CO2PBR): Efficiency Estimation, Technological Parameters, and Prototype Concept

Atmosphere ◽  
2021 ◽  
Vol 12 (8) ◽  
pp. 1031
Author(s):  
Marcin Dębowski ◽  
Mirosław Krzemieniewski ◽  
Marcin Zieliński ◽  
Joanna Kazimierowicz
Keyword(s):  
Carbon Dioxide Emissions ◽  
Functional Model ◽  
Biomass Concentration ◽  
Co2 Concentration ◽  
Ambient Air ◽  
Co2 Uptake ◽  
Co2 Removal ◽  
Exhaust Gas ◽  
Technological Parameters ◽  
Efficiency Estimation

Microalgae-mediated CO2 sequestration has been a subject of numerous research works and has become one of the most promising strategies to mitigate carbon dioxide emissions. However, feeding flue and exhaust gas into algae-based systems has been shown to destroy chloroplasts, as well as disrupt photosynthesis and other metabolic processes in microalgae, which directly limits CO2 uptake. CO2 biosequestration in existing photobioreactors (PBRs) is also limited by the low biomass concentration in the growth medium. Therefore, there is a real need to seek alternative solutions that would be competitive in terms of performance and cost-effectiveness. The present paper reports the results of experiments aimed to develop an innovative trickle bed reactor that uses immobilized algae to capture CO2 from flue and exhaust gas (IMC-CO2PBR). In the experiment, ambient air enriched with technical-grade CO2 to a CO2 concentration of 25% v/v was used. The microalgae immobilization technology employed in the experiment produced biomass yields approximating 100 g DM/dm3. A relationship was found between CO2 removal rates and gas volume flux: almost 40% of CO2 was removed at a feed of 25 dm3 of gas per hour, whereas in the 200 dm3/h group, the removal efficiency amounted to 5.9%. The work includes a determination of basic process parameters, presentation of a developed functional model and optimized lighting system, proposals for components to be used in the system, and recommendations for an automation and control system for a full-scale implementation.

scholarly journals Naked oat is promising raw material for deep grain processing

2019 ◽  
Vol 20 (5) ◽  
pp. 447-455
Author(s):  
N. R. Andreev ◽  
V. G. Goldstein ◽  
L. P. Nosovskaya ◽  
L. V. Adikaeva ◽  
E. O. Golionko
Keyword(s):  
Agricultural Research ◽  
Starch Content ◽  
Raw Material ◽  
Coarse Grained ◽  
Cellulolytic Enzymes ◽  
Technological Parameters ◽  
Naked Oat ◽  
Grain Processing ◽  
North East ◽  
The North

During the research conducted at the All-Russian Research Institute for Starch Products there has been developed a technological mode of using cellulolytic enzymes to reduce the viscosity of grain pulp obtained by grinding naked oat grains soaked in a sodium metabisulphite solution. As the experimental data had been processed, the optimum technological parameters of the process were determined: the consumption of the enzyme preparation Viscoferm was 200 g/t of grain and the dura-tion of fermentation by constant stirring for 2.5 hours at pH 4.6 and temperature 50°C. Under laboratory conditions there has been studied the possibility of starch processing of naked oat grain samples Vyatka, Percheron, 857h05, 766 h05 varieties grown in the Federal Agricultural Research Center of the North-East named N.V. Rudnitsky. Technological assessment based on grain processing in the laboratory using the “plant on the table” method has shown that the yield of coarse-grained starch A in the processing of naked oat using cellulolytic enzymes is 51.4-53.9%, i.e. higher than that of filmy oats, rye Falenskaya 4 and Vyatka 2, wheat and triticale. Low starch content in fiber (7.7-8.7% dry substances DS of fiber) was found in comparison with the results obtained from the processing of filmy oats, Falenskaya and Vyatka 2 rye varieties, wheat and triticale (11.2 - 13.9% DS of fiber). Fiber output by the processing of naked oats is 7.3 - 8.8% DS of grain, by the processing of other types of grain 10.3 - 17.5% DS of grain. The yield of small-grain starch B in the processing of the studied varieties of naked oat is 19.2 - 20.8% DS of grain, that is higher than this value obtained by processing of filmy oats and wheat, but lower than by pro-cessing of rye and triticale. Isolated carbohydrate-protein concentrate, including starch B and proteins, is recommended for use with the extract and fiber as a component for the production of feed.

scholarly journals Research of Loop Transferred Structures on V-Bed Flat Knitting Machine

2020 ◽  
Vol 8 (6) ◽  
pp. 2565-2570
Keyword(s):  
Mechanical Properties ◽  
Service Sector ◽  
Breaking Strength ◽  
Life Time ◽  
Volume Density ◽  
Raw Material ◽  
Loop Length ◽  
Technological Parameters ◽  
Pattern Effect ◽  
Stitch Density

Today, the production of knitwear is developing at a faster pace. In industry, trade and the service sector, the production of knitwear, combining high technology and low cost, with good consumer properties is urgently required. Consumers today are looking for comfort, fashion and style, which results in ever-changing demands on the apparel market. As the consumer’s requirements to quality and appearance of product are daily increasing, the attention to the question of replacement of a smooth cloth on wide assortment with pattern effect is sharply brought. This work deals with the analysis of technological parameters and physical-mechanical properties of the knit fabric with pattern effect. With the aim of to expand the assortments of knitwear and to use the technological capabilities of double-bed flat knitting machines in fullest extent possible, on the base of rib structure, by using of loop transference 2 new variants of combined structure were developed and recommended. Samples differ from each other by the rapport and pattern effect of the knit structure. Technological parameters, such as loop length, stitch density, surface and volume density, physical-mechanical properties, such as breaking strength and elongation of newly developed combined knit structures were also determined by experimental method. Loop length and stitch density are important variables, that by changing them, the surface and volume density can be changed, that can manage the raw material consumption and determine the quality of knit fabrics. Breaking strength and elongation are important and decisive parameters for end uses since low strength properties shorten the useful life time as well disable the functionality of these products. Patterns of influence of structural elements, such as transferred loops on the surface density and volume density of knitwear was established. It is found that offered structures have some advantages to compare to basic structure. On the aim of resource economy technology, they give a possibility of raw material expenditure decreasing 22-47%.

scholarly journals THE STUDY OF TECHNOLOGICAL PARAMETERS OF PECTIN CONTAINING RAW MATERIAL PROCESSING IN THE VEGETABLE-MILK FORCEMEATS TECHNOLOGY

2016 ◽  
Vol 4 ◽  
pp. 29-36
Author(s):  
Grygoriy Deynychenko ◽  
Victoriya Gnitsevych ◽  
Tatiana Yudina ◽  
Iryna Nazarenko ◽  
Olena Vasylieva
Keyword(s):  
Material Processing ◽  
Milk Proteins ◽  
Raw Material ◽  
Experiment Planning ◽  
Technological Parameters ◽  
Medium Temperature ◽  
Methods Of Determination ◽  
Vegetable Milk ◽  
Β Carotene

The algorithm of the study that includes theoretical analysis and physical experiment was elaborated for the study of technological parameters of pectin containing raw material processing in the vegetable-milk forcemeats technology. The expedience of using carrot Shantenee, pumpkin Guiley and marrow Zolotinka as the sources of pectin substances in the technology of combined forcemeats on the milk base was grounded. Technological parameters of pectin containing raw material processing for realization of its target properties as an amendment and stabilizer of the structure in milk-vegetable forcemeats technology were theoretically grounded. The methods of determination of soluble pectin and protopectin content and also the methods of determination of рН medium were chosen. The methods of experiment planning and mathematical processing of experimental data were carried out using computer programs MS Excel 97 2003 and MatCAD. The influence of рН medium, temperature and duration of thermal processing of carrot, pumpkin and marrow on the process of accumulation of soluble pectin in them was studied. The formation technology of puree of the vegetables that have the increased viscosity and are not stratified at the storage and further use. Accumulation of soluble pectin that expresses the properties of structure stabilizer and favors the increase of vegetable puree viscosity causes the expedience of its use in milk-vegetable forcemeats technology. The use of vegetable puree in milk-vegetable forcemeats technology allows widen the assortment and provide the mutual enrichment of the receipt components of combined forcemeat masses with milk proteins, β-carotene, food fibers, vitamins and other functional ingredients.

scholarly journals Oxidization resistance and sorption properties of oleogels as new-generation fatty systems

2021 ◽  
pp. 89-95
Author(s):  
P.О. Nekrasov ◽  
◽  
N.A. Tkachenko ◽  
О.P. Nekrasov ◽  
О.M. Gudz ◽  
...  
Keyword(s):  
Sunflower Seed ◽  
Three Dimensional ◽  
Scientific Basis ◽  
Tocopherol Content ◽  
Sorption Properties ◽  
Dimensional Structure ◽  
Dispersed Phase ◽  
Technological Parameters ◽  
High Oleic Sunflower Oil ◽  
New Generation

Fats as complex mixtures of acylglycerols with lipid and non-lipid substances are an integral part of human nutrition. The presence of acylglycerols of trans-isomers of fatty acids causes many cardiovascular diseases and metabolic disorders. A promising approach to solving the problem of minimizing the content of these undesirable compounds in food recipes is to create a new generation of fat systems, oleogels, which are the subject of this study. High-oleic sunflower oil was used as a dispersion medium of oleogels, which allows obtaining systems with increased resistance to oxidation, as opposed to the oils of traditional kinds. Sunflower seed wax and tocopherols are chosen as a dispersed phase of these fatty systems. The choice of these components was based on their properties to create a three-dimensional structure in oleogels with specified thermomechanical characteristics. Currently, there is a lack of information on the influence of the content of the dispersed phase on the technological parameters of oleogels, namely oxidative resistance and sorption properties. The purpose of the presented work was to study these features of oleogels and establish their dependences on their composition. To solve this problem, the yield surface method is used in the work. The unknown values of the parameter vector were determined by using regression analysis algorithms. Deviation functionality was minimized by finding the appropriate combinations of the experimental series of predictors. A mathematical model was developed which allows predicting oxidative stability and sorption properties of oleogels based on the data on their composition. The suitable mass fractions of the components of the dispersed phase of oleogels have been determined as follows: tocopherol content is 0.10–0.14 wt.% and the sunflower seed wax content is 1.8–4.0 wt.%. The results obtained can serve as a scientific basis for the development of technology for the industrial production of oleogels as new generation fatty systems.

Sign in / Sign up

Export Citation Format

Share Document