Influence of the synthesis method of tert-butylated triphenyl phosphates on the operational properties of fire-resistant fluids

2021 ◽  
Vol 02 ◽  
pp. 32-37
Author(s):  
A.S. Medzhibovskiy ◽  
◽  
A.S. Kolokolnikov ◽  
A.O. Savchenko ◽  
G.A. Poldushova ◽  
...  
Keyword(s):  
Gas Turbines ◽  
Power Plants ◽  
Phosphorus Oxychloride ◽  
Raw Materials ◽  
Hydrolytic Stability ◽  
Synthesis Method ◽  
Acid Number ◽  
Release Time ◽  
Triphenyl Phosphate ◽  
Prolonged Contact

Three substituted aryl esters of orthophosphoric acid are the base component of fire-resistant fluids used in the lubricating and electro-hydraulic control system at steam and gas turbines of power plants. In this paper, we studied the possibility of improving the physicochemical and performance properties of phosphates, which are made of the raw materials available in the Russian Federation: phenol and 4-tert-butylphenol by reducing the content of an undesirable component - unsubstituted triphenyl phosphate, which is particularly vulnerable towards water. According to the results of the work, the conclusions were made: - a decrease in the content of triphenyl phosphate to a level of 1% and below leads to some improvement (reduction) of the air release time and an increase in the hydrolytic stability (represented as reducing the change in acid number after prolonged contact with water) of the fire-resistant fluid based on mixed esters. The degree of change of these properties is quantified. - it is possible to achieve the minimum content of triphenyl phosphate by changing the phosphorylation technology. By carrying out the process stepwise, the possibility of the interaction of phosphorus oxychloride with unsubstituted phenol is substantially eliminated, that is why there is almost no probability of an undesirable component formation in the resulting mixture of esters.

scholarly journals Recent Advances in Fabrication of Non-Isocyanate Polyurethane-Based Composite Materials

Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3497
Author(s):  
Piotr Stachak ◽  
Izabela Łukaszewska ◽  
Edyta Hebda ◽  
Krzysztof Pielichowski
Keyword(s):  
Raw Materials ◽  
Synthesis Method ◽  
Polymeric Materials ◽  
Original Research ◽  
Significant Group ◽  
Oh Groups ◽  
New Class ◽  
Hazardous Chemical ◽  
Wide Range

Polyurethanes (PUs) are a significant group of polymeric materials that, due to their outstanding mechanical, chemical, and physical properties, are used in a wide range of applications. Conventionally, PUs are obtained in polyaddition reactions between diisocyanates and polyols. Due to the toxicity of isocyanate raw materials and their synthesis method utilizing phosgene, new cleaner synthetic routes for polyurethanes without using isocyanates have attracted increasing attention in recent years. Among different attempts to replace the conventional process, polyaddition of cyclic carbonates (CCs) and polyfunctional amines seems to be the most promising way to obtain non-isocyanate polyurethanes (NIPUs) or, more precisely, polyhydroxyurethanes (PHUs), while primary and secondary –OH groups are being formed alongside urethane linkages. Such an approach eliminates hazardous chemical compounds from the synthesis and leads to the fabrication of polymeric materials with unique and tunable properties. The main advantages include better chemical, mechanical, and thermal resistance, and the process itself is invulnerable to moisture, which is an essential technological feature. NIPUs can be modified via copolymerization or used as matrices to fabricate polymer composites with different additives, similar to their conventional counterparts. Hence, non-isocyanate polyurethanes are a new class of environmentally friendly polymeric materials. Many papers on the matter above have been published, including both original research and extensive reviews. However, they do not provide collected information on NIPU composites fabrication and processing. Hence, this review describes the latest progress in non-isocyanate polyurethane synthesis, modification, and finally processing. While focusing primarily on the carbonate/amine route, methods of obtaining NIPU are described, and their properties are presented. Ways of incorporating various compounds into NIPU matrices are characterized by the role of PHU materials in copolymeric materials or as an additive. Finally, diverse processing methods of non-isocyanate polyurethanes are presented, including electrospinning or 3D printing.

scholarly journals Clear Skies Ahead

2016 ◽  
Vol 138 (06) ◽  
pp. 38-43
Author(s):  
Lee S. Langston
Keyword(s):  
Gas Turbine ◽  
Gas Turbines ◽  
Power Plants ◽  
Electrical Power ◽  
Vital Role ◽  
Medium Size ◽  
Steady Increase ◽  
Innovative Design ◽  
Turbine Engine ◽  
Boom And Bust

This article discusses various fields where gas turbines can play a vital role. Building engines for commercial jetliners is the largest market segment for the gas turbine industry; however, it is far from being the only one. One 2015 military gas turbine program of note was the announcement of an U.S. Air Force competition for an innovative design of a small turbine engine, suitable for a medium-size drone aircraft. The electrical power gas turbine market experienced a sharp boom and bust from 2000 to 2002 because of the deregulation of many electric utilities. Since then, however, the electric power gas turbine market has shown a steady increase, right up to present times. Coal-fired plants now supply less than 5 percent of the electrical load, having been largely replaced by new natural gas-fired gas turbine power plants. Working in tandem with renewable energy power facilities, the new fleet of gas turbines is expected to provide reliable, on-demand electrical power at a reasonable cost.

Assessment of the Potential of Combined Micro Gas Turbine and High Temperature Fuel Cell Systems

2002 ◽  
Author(s):  
Dieter Bohn ◽  
Nathalie Po¨ppe ◽  
Joachim Lepers
Keyword(s):  
Fuel Cells ◽  
High Temperature ◽  
Fuel Cell ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Power Plants ◽  
Advanced Materials ◽  
Cell Systems ◽  
Micro Gas Turbine ◽  
Technological Assessment

The present paper reports a detailed technological assessment of two concepts of integrated micro gas turbine and high temperature (SOFC) fuel cell systems. The first concept is the coupling of micro gas turbines and fuel cells with heat exchangers, maximising availability of each component by the option for easy stand-alone operation. The second concept considers a direct coupling of both components and a pressurised operation of the fuel cell, yielding additional efficiency augmentation. Based on state-of-the-art technology of micro gas turbines and solid oxide fuel cells, the paper analyses effects of advanced cycle parameters based on future material improvements on the performance of 300–400 kW combined micro gas turbine and fuel cell power plants. Results show a major potential for future increase of net efficiencies of such power plants utilising advanced materials yet to be developed. For small sized plants under consideration, potential net efficiencies around 70% were determined. This implies possible power-to-heat-ratios around 9.1 being a basis for efficient utilisation of this technology in decentralised CHP applications.

Solar Concentrating Systems Using Small Mirror Arrays

2009 ◽  
Vol 132 (1) ◽  
Author(s):  
Joachim Göttsche ◽  
Bernhard Hoffschmidt ◽  
Stefan Schmitz ◽  
Markus Sauerborn ◽  
Reiner Buck ◽  
...  
Keyword(s):  
Power Plants ◽  
Raw Materials ◽  
Large Fraction ◽  
Steel Structure ◽  
Steel Structures ◽  
Cost Effective ◽  
Wind Loads ◽  
Drive Systems ◽  
Mirror Area ◽  
The Cost

The cost of solar tower power plants is dominated by the heliostat field making up roughly 50% of investment costs. Classical heliostat design is dominated by mirrors brought into position by steel structures and drives that guarantee high accuracies under wind loads and thermal stress situations. A large fraction of costs is caused by the stiffness requirements of the steel structure, typically resulting in ∼20 kg/m2 steel per mirror area. The typical cost figure of heliostats (figure mentioned by Solucar at Solar Paces Conference, Seville, 2006) is currently in the area of 150 €/m2 caused by the increasing price of the necessary raw materials. An interesting option to reduce costs lies in a heliostat design where all moving parts are protected from wind loads. In this way, drives and mechanical layout may be kept less robust, thereby reducing material input and costs. In order to keep the heliostat at an appropriate size, small mirrors (around 10×10 cm2) have to be used, which are placed in a box with a transparent cover. Innovative drive systems are developed in order to obtain a cost-effective design. A 0.5×0.5 m2 demonstration unit will be constructed. Tests of the unit are carried out with a high-precision artificial sun unit that imitates the sun’s path with an accuracy of less than 0.5 mrad and creates a beam of parallel light with a divergence of less than 4 mrad.

Erosion Resistance and Efficiency of Energy Exchangers

1982 ◽  
Author(s):  
W. J. Thayer ◽  
R. T. Taussig
Keyword(s):  
Power Plant ◽  
Fluidized Bed ◽  
Gas Turbines ◽  
Power Plants ◽  
Erosion Resistance ◽  
Operating Characteristics ◽  
Hot Gas ◽  
Point Increase ◽  
Effluent Stream ◽  
Plant Efficiency

Applications of energy exchangers, a type of gasdynamic wave machine, were evaluated in power plants fired by pressurized, fluidized bed combustors (PFBCs). Comparative analyses of overall power plant efficiency indicate that the use of energy exchangers as hot gas expanders may provide a 0.5 to 1.5 efficiency point increase relative to gas turbines. In addition, the unique operating characteristics of these machines are expected to reduce rotating component wear by a factor of 50 to 300 relative to conventional gas turbines operating in the particulate laden PFBC effluent stream.

Dynamic Behavior of a Solar Hybrid Gas Turbine System

2015 ◽  
Author(s):  
Christian Felsmann ◽  
Uwe Gampe ◽  
Manfred Freimark
Keyword(s):  
System Dynamics ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Power Plants ◽  
Thermal Power ◽  
Commercial Application ◽  
Worst Case ◽  
Electric Generator ◽  
New Findings ◽  
Component Development

Solar hybrid gas turbine technology has the potential to increase the efficiency of future solar thermal power plants by utilizing solar heat at a much higher temperature level than state of the art plants based on steam turbine cycles. In a previous paper the authors pointed out, that further development steps are required for example in the field of component development and in the investigation of the system dynamics to realize a mature technology for commercial application [1]. In this paper new findings on system dynamics are presented based on the simulation model of a solar hybrid gas turbine with parallel arrangement of the combustion chamber and solar receivers. The operational behavior of the system is described by means of two different scenarios. The System operation in a stand-alone electrical supply network is investigated in the first scenario. Here it is shown that fast load changes in the network lead to a higher shaft speed deviation of the electric generator compared to pure fossil fired systems. In the second scenario a generator load rejection, as a worst case, is analyzed. The results make clear that additional relief concepts like blow-off valves are necessary as the standard gas turbine protection does not meet the specific requirements of the solar hybrid operation. In general the results show, that the solar hybrid operational modes are much more challenging for the gas turbines control and safety system compared to pure fossil fired plants due to the increased volumetric storage capacity of the system.

scholarly journals A CVaR-Robust Risk Aversion Scheduling Model for Virtual Power Plants Connected with Wind-Photovoltaic-Hydropower-Energy Storage Systems, Conventional Gas Turbines and Incentive-Based Demand Responses

Energies ◽  
2018 ◽  
Vol 11 (11) ◽  
pp. 2903 ◽  
Author(s):  
Liwei Ju ◽  
Peng Li ◽  
Qinliang Tan ◽  
Zhongfu Tan ◽  
GejiriFu De
Keyword(s):  
Energy Storage ◽  
Risk Aversion ◽  
Decision Maker ◽  
Gas Turbines ◽  
Power Plants ◽  
Storage Systems ◽  
Economic Benefits ◽  
Virtual Power ◽  
Energy Storage Systems ◽  
Scheduling Model

To make full use of distributed energy resources to meet load demand, this study aggregated wind power plants (WPPs), photovoltaic power generation (PV), small hydropower stations (SHSs), energy storage systems (ESSs), conventional gas turbines (CGTs) and incentive-based demand responses (IBDRs) into a virtual power plant (VPP) with price-based demand response (PBDR). Firstly, a basic scheduling model for the VPP was proposed in this study with the objective of the maximum operation revenue. Secondly, a risk aversion model for the VPP was constructed based on the conditional value at risk (CVaR) method and robust optimization theory considering the operating risk from WPP and PV. Thirdly, a solution methodology was constructed and three cases were considered for comparative analyses. Finally, an independent micro-grid on an industrial park in East China was utilized for an example analysis. The results show the following: (1) the proposed risk aversion scheduling model could cope with the uncertainty risk via a reasonable confidence degree β and robust coefficient Γ. When Γ ≤ 0.85 or Γ ≥ 0.95, a small uncertainty brought great risk, indicating that the risk attitude of the decision maker will affect the scheduling scheme of the VPP, and the decision maker belongs to the risk extreme aversion type. When Γ ∈ (0.85, 0.95), the decision-making scheme was in a stable state, the growth of β lead to the increase of CVaR, but the magnitude was not large. When the prediction error e was higher, the value of CVaR increased more when Γ increased by the same magnitude, which indicates that a lower prediction accuracy will amplify the uncertainty risk. (2) when the capacity ratio of (WPP, PV): ESS was higher than 1.5:1 and the peak-to-valley price gap was higher than 3:1, the values of revenue, VaR, and CVaR changed slower, indicating that both ESS and PBDR can improve the operating revenue, but the capacity scale of ESS and the peak-valley price gap need to be set properly, considering both economic benefits and operating risks. Therefore, the proposed risk aversion model could maximize the utilization of clean energy to obtain higher economic benefits while rationally controlling risks and provide reliable decision support for developing optimal operation plans for the VPP.

Greenhouse Gas Emissions Calculation Methodology in Thermal Power Plants: Case Study of Iran and Comparison With Canada

2008 ◽  
Author(s):  
Farshid Zabihian ◽  
Alan S. Fung
Keyword(s):  
Climate Change ◽  
Greenhouse Gas ◽  
Global Climate Change ◽  
Gas Turbines ◽  
Electricity Generation ◽  
Power Plants ◽  
Global Climate ◽  
Thermal Power ◽  
Ghg Emissions ◽  
Thermal Power Plants

Nowadays, the global climate change has been a worldwide concern and the greenhouse gases (GHG) emissions are considered as the primary cause of that. The United Nations Conference on Environment and Development (UNCED) divided countries into two groups: Annex I Parties and Non-Annex I Parties. Since Iran and all other countries in the Middle East are among Non-Annex I Parties, they are not required to submit annual GHG inventory report. However, the global climate change is a worldwide phenomenon so Middle Eastern countries should be involved and it is necessary to prepare such a report at least unofficially. In this paper the terminology and the methods to calculate GHG emissions will first be explained and then GHG emissions estimates for the Iranian power plants will be presented. Finally the results will be compared with GHG emissions from the Canadian electricity generation sector. The results for the Iranian power plants show that in 2005 greenhouse gas intensity for steam power plants, gas turbines and combined cycle power plants were 617, 773, and 462 g CO2eq/kWh, respectively with the overall intensity of 610 g CO2eq/kWh for all thermal power plants. This GHG intensity is directly depend on efficiency of power plants. Whereas, in 2004 GHG intensity for electricity generation sector in Canada for different fuels were as follows: Coal 1010, refined petroleum products 640, and natural gas 523 g CO2eq/kWh, which are comparable with same data for Iran. For average GHG intensity in the whole electricity generation sector the difference is much higher: Canada 222 vs. Iran 610g CO2eq/kWh. The reason is that in Canada a considerable portion of electricity is generated by hydro-electric and nuclear power plants in which they do not emit significant amount of GHG emissions. The average GHG intensity in electricity generation sector in Iran between 1995 and 2005 experienced 13% reduction. While in Canada at the same period of time there was 21% increase. However, the results demonstrate that still there are great potentials for GHG emissions reduction in Iran’s electricity generation sector.

Strength Design and Reliability Evaluation of a Hybrid Ceramic Stator Vane for Industrial Gas Turbines

1995 ◽  
Vol 117 (2) ◽  
pp. 245-250 ◽  
Author(s):  
K. Nakakado ◽  
T. Machida ◽  
H. Miyata ◽  
T. Hisamatsu ◽  
N. Mori ◽  
...  
Keyword(s):  
Gas Turbine ◽  
Gas Turbines ◽  
Power Plants ◽  
Metal Structure ◽  
Reliability Evaluation ◽  
Combustion Gas ◽  
Strength Design ◽  
Stator Vane ◽  
Industrial Gas Turbines ◽  
Hybrid Ceramic

Employing ceramic materials for the critical components of industrial gas turbines is anticipated to improve the thermal efficiency of power plants. We developed a first-stage stator vane for a 1300°C class, 20-MW industrial gas turbine. This stator vane has a hybrid ceramic/metal structure, to increase the strength reliability of brittle ceramic parts, and to reduce the amount of cooling air needed for metal parts as well. The strength design results of a ceramic main part are described. Strength reliability evaluation results are also provided based on a cascade test using combustion gas under actual gas turbine running conditions.

scholarly journals Considerations regarding the anti-icing system for the ship propulsion plant with gas turbine

2021 ◽  
Vol 286 ◽  
pp. 04013
Author(s):  
George Iulian Balan ◽  
Octavian Narcis Volintiru ◽  
Ionut Cristian Scurtu ◽  
Florin Ioniță ◽  
Mirela Letitia Vasile ◽  
...  
Keyword(s):  
Power Plant ◽  
Gas Turbine ◽  
Energy Flow ◽  
Gas Turbines ◽  
Power Plants ◽  
Compressed Air ◽  
Ambient Temperatures ◽  
Foreign Objects ◽  
Technical Solutions ◽  
Gas Turbine Power Plant

Vessels that have navigation routes in areas with ambient temperatures that can drop below + 5 [°C], with a relative humidity of over 65%, will have implemented technical solutions for monitoring and combating ice accumulations in the intake routes of gas turbine power plants. Because gas turbines are not designed and built to allow the admission of foreign objects (in this case - ice), it is necessary to avoid the accumulation of ice through anti-icing systems and not to melt ice through defrost systems. Naval anti-icing systems may have as a source of energy flow compressed air, supersaturated steam, exhaust gases, electricity or a combination of those listed. The monitoring and optimization of the operation of the anti-icing system gives the gas turbine power plant an operation as close as possible to the normal regimes stipulated in the ship's construction or retrofit specification.

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