Study of Detoxifying Ability of Oxidized Humic Substances under the Conditions of Oil Pollution of Soils

2021 ◽  
Vol 625 (3) ◽  
pp. 53-56
Author(s):  
N. A. Likhacheva ◽  
◽  
E. A. Zaharova ◽  
Keyword(s):  
Chemical Modification ◽  
Humic Substances ◽  
Brown Coal ◽  
Contaminated Soil ◽  
Petroleum Hydrocarbons ◽  
Oil Pollution ◽  
Oxidative Modification ◽  
Noticeable Increase ◽  
Bioassay Method

The article presents the results of research on the oxidative modification of humic substances of brown coal of the Tyulgan deposit. The detoxifying effect of the obtained substances in relation to petroleum hydrocarbons was studied using the bioassay method. During the evaluation, a noticeable increase in the detoxifying ability was found in the result of chemical modification of humic substances. The greatest detoxifying effect in relation to oil pollution of the soil was observed for humic substances modified by oxidation and amounted to 19 and 42% at doses of 0.01 and 0.1% by weight. accordingly. The detoxifying effect of native humic substances is significantly lower: 9 and 2 % at doses of 0.01% and 0.1% by weight. accordingly. Thus, the prospects of using oxidized humic substances as sorbents-detoxicants during phytoremediation of oil-contaminated soil are shown.

Metal storage capacity evaluation of humic and himatomelanic acids hydroxymethyl derivatives obtained from brown coal

2021 ◽  
Author(s):  
I.A. Potapova ◽  
E.V. Nielina ◽  
N.V. Prokhorova
Keyword(s):  
Heavy Metals ◽  
Chemical Modification ◽  
Humic Substances ◽  
Brown Coal ◽  
Copper Ions ◽  
Phenol Formaldehyde ◽  
Humus Substances ◽  
Capacity Evaluation ◽  
Methyl Derivatives ◽  
Himatomelanic Acids

Humic substances represent the most extensive and reactive class of natural compounds. A more nature-saving way is to obtain humus substances from solid combustible minerals and waste from their processing. The ability of these compounds to form stable complexes with heavy metals, which increases with their directed chemical modification, has been experimentally confirmed. The effectiveness of the phenol-formaldehyde condensation method for the modification of initial humus substances has been confirmed. The interaction of humic and himatomelanic acids with formaldehyde leads to an increase in sorption activity in comparison with the initial humic acids with respect to heavy metals. This aspect has been studied and confirmed in model experiments with copper ions. Key words: humic substances, brown coal, humic and himatomelanic acids, directed chemical modification, hydroxymethyl (methyl) derivatives, heavy metals, copper ions, complex formation.

"PARAMETERS’ INFLUENCE OF CRUSHING BROWN COAL TO THE EXTRACTION OF HUMIC SUBSTANCES "

2017 ◽  
Vol 17 (6) ◽  
pp. 204-209
Author(s):  
K.S. Votolin ◽  
◽  
S.I. Zherebtsov ◽  
M.Y. Klimovich ◽  
O.V. Smotrina ◽  
...  
Keyword(s):  
Humic Substances ◽  
Brown Coal

Remediation of Hydrocarbon-Contaminated Soil by Washing with Novel Chemically Modified Humic Substances

2015 ◽  
Vol 44 (6) ◽  
pp. 1764-1771 ◽  
Author(s):  
César García-Díaz ◽  
Antonio Nebbioso ◽  
Alessandro Piccolo ◽  
Josefina Barrera-Cortés ◽  
Rafael Martínez-Palou
Keyword(s):  
Humic Substances ◽  
Contaminated Soil ◽  
Chemically Modified

scholarly journals Biodegradation of Used Motor Oil in Soil Using Organic Waste Amendments

2012 ◽  
Vol 2012 ◽  
pp. 1-8 ◽  
Author(s):  
O. P. Abioye ◽  
P. Agamuthu ◽  
A. R. Abdul Aziz
Keyword(s):  
Contaminated Soil ◽  
Oil Pollution ◽  
Green Technology ◽  
Lubricating Oil ◽  
Soil Bioremediation ◽  
Order Kinetic ◽  
Human Beings ◽  
Mushroom Compost ◽  
Oil Biodegradation ◽  
Used Lubricating Oil

Soil and surface water contamination by used lubricating oil is a common occurrence in most developing countries. This has been shown to have harmful effects on the environment and human beings at large. Bioremediation can be an alternative green technology for remediation of such hydrocarbon-contaminated soil. Bioremediation of soil contaminated with 5% and 15% (w/w) used lubricating oil and amended with 10% brewery spent grain (BSG), banana skin (BS), and spent mushroom compost (SMC) was studied for a period of 84 days, under laboratory condition. At the end of 84 days, the highest percentage of oil biodegradation (92%) was recorded in soil contaminated with 5% used lubricating oil and amended with BSG, while only 55% of oil biodegradation was recorded in soil contaminated with 15% used lubricating oil and amended with BSG. Results of first-order kinetic model to determine the rate of biodegradation of used lubricating oil revealed that soil amended with BSG recorded the highest rate of oil biodegradation (0.4361 day−1) in 5% oil pollution, while BS amended soil recorded the highest rate of oil biodegradation (0.0556 day−1) in 15% oil pollution. The results of this study demonstrated the potential of BSG as a good substrate for enhanced remediation of hydrocarbon contaminated soil at low pollution concentration.

RHEOLOGICAL PROPERTIES OF HUMIC SUBSTANCES OF PEAT AND BROWN COAL

2021 ◽  
pp. 169-174
Author(s):  
Ivan I. Lishtvan ◽  
Vera N. Aleinikova
Keyword(s):  
Rheological Properties ◽  
Humic Substances ◽  
Structure Formation ◽  
Humic Substance ◽  
Brown Coal ◽  
Oil Wells ◽  
Alkaline Media ◽  
Rheological Parameters ◽  
Acid Media ◽  
Brown Coals

Knowledge about structure and rheological peculiarities of drilling solutions and reagents applied for the proceeding of oil wells has significant value for the forecasting of oil wells drilling. The research results of the structure of the humic substances of peat and brown coals precipitated in different pH ranges from the standpoint of their ability to structure formation on the base of the rheological curves obtaining of the flow of their dispersions and determining of their rheological parameters in terms of their application in drilling practice are given in the article. It is established that during transition from fraction, beset into alkaline media (12.0–8.5) to fraction beset into acid media (5.0–2.0) the decrease of the rheological indicators of caustobiolate humic substance is occurred. Rheological curves of the flow of the disperse of caustobiolate humic substances of the fraction 1 and 2 are characterized for strong fossil structures, disperses of humic substances of the fraction 3 is for less strong coagulation structures. Less structured are humic substances of brown coal so that their use is preferable for the regulation of the structure and rheological peculiarities of drilling solutions.

Effect of compost in phytoremediation of diesel-contaminated soils

2001 ◽  
Vol 43 (2) ◽  
pp. 291-295 ◽  
Author(s):  
J. Vouillamoz ◽  
M. W. Milke
Keyword(s):  
Moisture Content ◽  
Contaminated Soil ◽  
Contaminated Soils ◽  
Petroleum Hydrocarbons ◽  
Dilution Effect ◽  
Screening Tests ◽  
Total Petroleum Hydrocarbons ◽  
Controlled Environment ◽  
Grass Growth ◽  
The Impact

The effect of compost on phytoremediation of diesel-contaminated soils was investigated using 130 small (200 g) containers in two screening tests. The experiments were conducted in a controlled environment using ryegrass from seed. Containers were destructively sampled at various times and analyzed for plant mass and total petroleum hydrocarbons. The results indicate that the presence of diesel reduces grass growth, and that compost helps reduced the impact of diesel on grass growth. The addition of compost helps increase diesel loss from the soils both with and without grass, though the addition of grass leads to lower diesel levels compared with controls. A second set of experiments indicates that the compost helps in phytoremediation of diesel-contaminated soil independent of the dilution effect that compost addition has. The results indicate that the compost addition allowed diesel loss down to 200 mg TPH/kg even though the compost would be expected to hold the diesel more tightly in the soil/compost mixture. The simplicity of the screening tests led to difficulties in controlling moisture content and germination rates. The conclusion of the research is that the tilling of compost into soils combined with grass seeding appears to be a valuable option for treating petroleum-contaminated soils.

scholarly journals MIKROORGANISME PENDEGRADASI TPH (TOTAL PETROLEUM HYDROCARBON) SEBAGAI AGEN BIOREMEDIASI TANAH TERCEMAR MINYAK BUMI (Review Article)

2018 ◽  
Vol 2 (2) ◽  
pp. 35
Author(s):  
Prasetyo Handrianto
Keyword(s):  
Petroleum Hydrocarbons ◽  
Soil Chemistry ◽  
Petroleum Hydrocarbon ◽  
Oil Spills ◽  
Oil Pollution ◽  
Review Article ◽  
Total Petroleum Hydrocarbon ◽  
Soil Conditions ◽  
Petroleum Pollution ◽  
Ph Optimization

Exploitation and exploration activities will produce sewage sludge and crude oil spills that cause pollution to the environment and upgrading to the environment, biology and soil chemistry. Monitoring of oil pollution conditions on the soil can be done by detection of all hydrocarbon components, or what is called the total petroleum hydrocarbon (TPH). According to its components, this total petroleum hydrocarbon (TPH) can be classified into 3 points, aliphatic, alicyclic, and aromatic. One of the biological efforts that can be used to overcome petroleum pollution is by using bioremediation technology. There are several methods in bioremediation, one of which is the biostimulation method, where the growth of the original hydrocarbon decomposers is stimulated by adding nutrients, oxygen, pH optimization and temperature. Hydrocarbonoclastic microorganisms have characteristic not possessed by other microorganisms, namely their ability to excrete hydroxylase enzymes, which are hydrocarbon oxidizing enzymes, so that these bacteria can degrade petroleum hydrocarbons. Biodegradation can be formed if there is a structural transformation so that cahnges in molecular integrity occur. This process is a series of enzymatic or biochemical reaction that require ideal environmental conditions with the growth and proliferation of microorganisms. Something that need to be known before remediation are pollutants (organic or inorganic), degraded/ not, dangerous/ not, how many pollutants pollute the soil, the ratio of carbon (C), Nitrogen (N), and phophorus (P), soil type, soil conditions (wet dry), and how long pollutants have been deposited in these locations

scholarly journals Soil Microcosms for Bioaugmentation With Fungal Isolates to Remediate Petroleum Hydrocarbon-contaminated Soil

2021 ◽  
Author(s):  
Dalel Daâssi ◽  
Fatimah Qabil Almaghribi
Keyword(s):  
Contaminated Soil ◽  
Petroleum Hydrocarbons ◽  
Fungal Growth ◽  
Total Petroleum Hydrocarbons ◽  
Fungal Culture ◽  
Soil Microcosms ◽  
Fungal Isolates ◽  
Petroleum Contaminated Soil ◽  
Decaying Wood ◽  
Native Strains

Abstract The aim of this work was to isolate indigenous PAH degrading-fungi from petroleum contaminated soil and exogenous ligninolytic strains from decaying-wood, with the ability to secrete diverse enzyme activity. A total of ten ligninolytic fungal isolates and two native strains, has been successfully isolated, screened and identified. The phylogenetic analysis revealed that the indigenous fungi (KBR1 and KB8) belong to the genus Aspergillus niger and tubingensis. While the ligninolytic exogenous PAH-degrading strains namely KBR1-1, KB4, KB2 and LB3 were affiliated to different genera like Syncephalastrum sp, Paecilomyces formosus, Fusarium chlamydosporum, and Coniochaeta sp., respectively. Basis on the taxonomic analysis, enzymatic activities and the hydrocarbons removal rates, single fungal culture employing the strain LB3, KB4, KBR1 and the mixed culture (LB3+KB4) were selected to be used in soil microcosms treatments. The Total petroleum hydrocarbons (TPH), fungal growth rates, BOD5/COD ratios and GC-MS analysis, were determined in all soil microcosmos treatments (SMT) and compared with those of the control (SMU). After 60 days of culture incubation, the highest rate of TPH degradation was recorded in SMT[KB4] by approximately 92±2.35% followed by SMT[KBR1] then SMT[LB3+KB4] with 86.66±1.83% and 85.14±2.21%, respectively.

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