scholarly journals Dielectric Properties of Upside-Down SrTiO3/Li2MoO4 Composites Fabricated at Room Temperature

2021 ◽  
Vol 8 ◽  
Author(s):  
Nina Kuzmić ◽  
Srečo Davor Škapin ◽  
Mikko Nelo ◽  
Heli Jantunen ◽  
Matjaž Spreitzer
Keyword(s):  
Room Temperature ◽  
High Ratio ◽  
Drying Time ◽  
Promising Alternative ◽  
Pressing Time ◽  
Energy Consuming ◽  
Two Phases ◽  
Time And Energy ◽  
Lithium Molybdate ◽  
Insight Into

In this paper, ceramic upside-down lithium molybdate-strontium titanate (LMO-ST) composites fabricated at room temperature are described. Room temperature fabrication (RTF) is a promising alternative to the time- and energy-consuming high-temperature sintering of electroceramics, which involves mixing of the initial phases, molding with a steel dye, pressing, and drying, while in the last two phases the action of densification takes place. The LMO-ST composites are based on a high ratio of filler ST, coupled with the corresponding LMO binder. Part of the binder is admixed to the ceramic particles and additional part is added as a saturated aqueous solution, which crystallizes during pressing and drying, leading to its deposition on the surface of the filler particles. As a result, sufficient binding with 76–84% relative density was achieved. The deeper insight into the method was provided by various processing aspects and corresponding microstructural investigations. The particle size distribution, pressure, pressing time, ultrasonic treatment, drying time and processing conditions were optimized to obtain improved functional properties of the LMO-ST composites. The results of this study with relative permittivity in the range of 65–78 and dielectric loss tangent values of 0.002–0.05 can attract considerable attention for the use of LMO-ST composites in the industry of electroceramics.

The Study of Computer Simulation on Vibratory Metal Machining with Low Frequency

2007 ◽  
Vol 10-12 ◽  
pp. 286-290
Author(s):  
J.L. Song ◽  
Guang Jun Chen
Keyword(s):  
Computer Simulation ◽  
Formation Process ◽  
Chip Formation ◽  
Metal Cutting ◽  
Low Frequency ◽  
Metal Machining ◽  
Energy Consuming ◽  
Time And Energy ◽  
Insight Into ◽  
Good Agreement

Vibratory cutting is one of the newly developed machining techniques and theories in recent years. Insight into the machining mechanism and the chip formation process in metal vibratory cutting has yet to be carried out for this technique to be used widely and efficiently. But with conventional investigation, it is much difficult, and time and energy consuming to analyze and study such principles quantitatively. A system of the computer simulation has been established and based on FEM the chip formation process was emulated. The cutting forces and temperature distribution were imitated under condition of a variety of vibratory frequencies and turning engagements. ANSYS is utilized for the quantitative analysis. Contrast and comparison experiments between vibratory and the conventional metal machining are done, revealing a good agreement between the simulation and the experiment and the inborn nature and the principles of the vibratory metal cutting.

Dynamic assessment and requesting: Assessing the development of Japanese EFL learners’ oral requesting performance interactively

2020 ◽  
Vol 17 (5) ◽  
pp. 545-575
Author(s):  
Allan Nicholas
Keyword(s):  
Conversation Analysis ◽  
Dynamic Assessment ◽  
Task Type ◽  
Efl Learners ◽  
Coding Scheme ◽  
Dynamic Methods ◽  
Two Phases ◽  
Japanese Learners ◽  
Development Analysis ◽  
Insight Into

AbstractThis study investigates the use of dynamically-administered strategic interaction scenarios (D-SIS) in identifying Japanese EFL participants’ difficulties with requesting-in-interaction, and tracking their development. Informed by conversation analysis research, six Japanese EFL learners at a university in Japan carried out D-SIS tasks in two phases, with the aim of both identifying specific aspects of requesting-in-interaction that were challenging, and learner development. Analysis focuses on three particular areas of difficulty that arose for participants during the dialogic interactions—connecting request turn utterance linguistic choices to social context; pre-request expansions of requesting talk, and pre-closing sequences. A coding scheme was applied that analyzed mediation sequences in terms of the efficiency with which participants oriented to and resolved problems, allowing ZPD movement to be quantified. In combination with close qualitative analysis of the transcript data, mediation sequences provided insights into the participants’ knowledge and understanding of these areas that would not have been gained through non-dynamic methods. Results therefore provide insight into areas of difficulty for Japanese learners with regards to requesting, and provide support for the use of the D-SIS task type as a diagnostic tool in regards to request-based talk-in-interaction.

scholarly journals Nonreciprocal charge transport up to room temperature in bulk Rashba semiconductor α-GeTe

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Yan Li ◽  
Yang Li ◽  
Peng Li ◽  
Bin Fang ◽  
Xu Yang ◽  
...  
Keyword(s):  
Charge Transport ◽  
Room Temperature ◽  
Theoretical Calculations ◽  
Ferromagnetic Layer ◽  
Spin Splitting ◽  
New Paradigm ◽  
Rashba Spin ◽  
Rashba Spin Splitting ◽  
Fundamental Insight ◽  
Insight Into

AbstractNonmagnetic Rashba systems with broken inversion symmetry are expected to exhibit nonreciprocal charge transport, a new paradigm of unidirectional magnetoresistance in the absence of ferromagnetic layer. So far, most work on nonreciprocal transport has been solely limited to cryogenic temperatures, which is a major obstacle for exploiting the room-temperature two-terminal devices based on such a nonreciprocal response. Here, we report a nonreciprocal charge transport behavior up to room temperature in semiconductor α-GeTe with coexisting the surface and bulk Rashba states. The combination of the band structure measurements and theoretical calculations strongly suggest that the nonreciprocal response is ascribed to the giant bulk Rashba spin splitting rather than the surface Rashba states. Remarkably, we find that the magnitude of the nonreciprocal response shows an unexpected non-monotonical dependence on temperature. The extended theoretical model based on the second-order spin–orbit coupled magnetotransport enables us to establish the correlation between the nonlinear magnetoresistance and the spin textures in the Rashba system. Our findings offer significant fundamental insight into the physics underlying the nonreciprocity and may pave a route for future rectification devices.

scholarly journals Concept for controlled adjustment of residual stress states in semi-finished products by gradation extrusion

2021 ◽  
Author(s):  
René Selbmann ◽  
Markus Baumann ◽  
Mateus Dobecki ◽  
Markus Bergmann ◽  
Verena Kräusel ◽  
...  
Keyword(s):  
Residual Stress ◽  
Stress Distribution ◽  
Experimental Tests ◽  
Residual Stress Distribution ◽  
Forming Process ◽  
Compressive Stresses ◽  
Energy Consuming ◽  
Stress States ◽  
Set Up ◽  
Time And Energy

AbstractThe residual stress distribution in extruded components and wires after a conventional forming process is frequently unfavourable for subsequent processes, such as bending operations. High tensile residual stresses typically occur near the surface of the wire and thus limit further processability of the material. Additional heat treatment operations or shot peening are often inserted to influence the residual stress distribution in the material after conventional manufacturing. This is time and energy consuming. The research presented in this paper contains an approach to influence the residual stress distribution by modifying the forming process for wire-like applications. The aim of this process is to lower the resulting tensile stress levels near the surface or even to generate compressive stresses. To achieve these residual compressive stresses, special forming elements are integrated in the dies. These modifications in the forming zone have a significant influence on process properties, such as degree of deformation and deformation direction, but typically have no influence on the diameter of the product geometry. In the present paper, the theoretical approach is described, as well as the model set-up, the FE-simulation and the results of the experimental tests. The characterization of the residual stress states in the specimen was carried out by X-ray diffraction using the sin2Ψ method.

scholarly journals Effect of Hot-Water Blanching Pretreatment on Drying Characteristics and Product Qualities for the Novel Integrated Freeze-Drying of Apple Slices

2018 ◽  
Vol 2018 ◽  
pp. 1-12 ◽  
Author(s):  
Hai-ou Wang ◽  
Qing-quan Fu ◽  
Shou-jiang Chen ◽  
Zhi-chao Hu ◽  
Huan-xiong Xie
Keyword(s):  
Electron Microscopy ◽  
Freeze Drying ◽  
Hot Water ◽  
The Novel ◽  
Rehydration Ratio ◽  
Drying Time ◽  
Drying Characteristics ◽  
Promising Alternative ◽  
Freeze Dried ◽  
Apple Slices

The effect of hot-water blanching (HWB) on drying characteristics and product qualities of dried apple slices with the novel integrated freeze-drying (NIFD) process was investigated by comparing with 3 different FD methods. Compared with the NIFD process without HWB pretreatment (VF-FD), the NIFD process with HWB pretreatment (HWB-VF-FD) resulted in a significantly higher mass loss and more sufficient freezing in vacuum-frozen samples, significantly higher rehydration ratio (RR), higher shrinkage ratio (SR), smaller Vitamin C (VC) content and lower hardness and better apparent shape in freeze-dried samples, and fewer change to the color of the dried or rehydrated samples (p<0.05). Compared with the conventional FD process with HWB pretreatment (HWB-PF-FD), HWB-VF-FD cost significantly less processing time and FD time and obtained significantly higher RR (p<0.05), almost the equivalent SR, VC content, and hardness, and similar appearance in dried samples. The microstructure of apple cell tissues was analyzed by transmission electron microscopy and scanning electron microscopy to interpret the above differences in drying characteristics and product qualities. The results suggested that the NIFD process of apple slices with HWB pretreatment was a promising alternative method to decrease drying time, achieve similar product quality, and simplify the process steps of the conventional FD technology.

scholarly journals Energy Efficient Dryer with Rice Husk Fuel for Agriculture Drying

2015 ◽  
Vol 4 (1) ◽  
pp. 20-24 ◽  
Author(s):  
M. Djaeni ◽  
N. Asiah ◽  
S Suherman ◽  
A. Sutanto ◽  
A. Nurhasanah
Keyword(s):  
Rice Husk ◽  
Energy Efficient ◽  
Pilot Scale ◽  
Drying Process ◽  
Energy Usage ◽  
Drying Time ◽  
Heat Efficiency ◽  
Operational Temperature ◽  
Time And Energy ◽  
Fossil Fuel Energy

Energy usage is crucial aspect on agriculture drying process. This step spends about 70% of total energy in post harvest treatment. The design of efficient dryer with renewable energy source is urgently required due to the limitation of fossil fuel energy. This work discusses the performance of air dehumidification using rice husk fuel as heat source for onion, and paddy drying. Unlike conventional dryer, the humidity of air during the drying was dehumidified by adsorbent. Hence, the driving force of drying can be  kept high.  As consequences, the drying time and energy usage can be reduced. Here, the research was conducted in two step: laboratory and pilot scale tests. Results showed that the lowering air humidity with rice husk fuel has improved the energy efficiency. At operational temperature 60oC, the heat efficiency of 75%  was achieved. 

scholarly journals Freeze-drying microscopy in mathematical modeling of a biomaterial freeze-drying

2012 ◽  
Vol 48 (2) ◽  
pp. 203-209 ◽  
Author(s):  
Camila Figueiredo Borgognoni ◽  
Joyce da Silva Bevilacqua ◽  
Ronaldo Nogueira de Moraes Pitombo
Keyword(s):  
Mathematical Modeling ◽  
Freeze Drying ◽  
Drying Process ◽  
Critical Temperatures ◽  
Fundamental Properties ◽  
Moving Interface ◽  
Energy Consuming ◽  
Sublimation Rates ◽  
Time And Energy

Transplantation brings hope for many patients. A multidisciplinary approach on this field aims at creating biologically functional tissues to be used as implants and prostheses. The freeze-drying process allows the fundamental properties of these materials to be preserved, making future manipulation and storage easier. Optimizing a freeze-drying cycle is of great importance since it aims at reducing process costs while increasing product quality of this time-and-energy-consuming process. Mathematical modeling comes as a tool to help a better understanding of the process variables behavior and consequently it helps optimization studies. Freeze-drying microscopy is a technique usually applied to determine critical temperatures of liquid formulations. It has been used in this work to determine the sublimation rates of a biological tissue freeze-drying. The sublimation rates were measured from the speed of the moving interface between the dried and the frozen layer under 21.33, 42.66 and 63.99 Pa. The studied variables were used in a theoretical model to simulate various temperature profiles of the freeze-drying process. Good agreement between the experimental and the simulated results was found.

scholarly journals Computational Insight into the Rope-Skipping Isomerization of Diarylether Cyclophanes

Symmetry ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 2127
Author(s):  
Thomas J. Summers ◽  
Hrishikesh Tupkar ◽  
Tyler M. Ozvat ◽  
Zoë Tregillus ◽  
Kenneth A. Miller ◽  
...  
Keyword(s):  
Asymmetric Catalysis ◽  
Room Temperature ◽  
Chemical Bonds ◽  
Chiral Molecules ◽  
Free Energies ◽  
Design And Synthesis ◽  
The Impact ◽  
Rope Skipping ◽  
Temperature Factors ◽  
Insight Into

The restricted rotation of chemical bonds may lead to the formation of stable, conformationally chiral molecules. While the asymmetry in chiral molecules is generally observed in the presence of one or more stereocenters, asymmetry exhibited by conformational chirality in compounds lacking stereocenters, called atropisomerism, depends on structural and temperature factors that are still not fully understood. This atropisomerism is observed in natural diarylether heptanoids where the length of the intramolecular tether constrains the compounds to isolable enantiomers at room temperature. In this work, we examine the impact tether length has on the activation free energies to isomerization of a diarylether cyclophane substructure with a tether ranging from 6 to 14 carbons. Racemization activation energies are observed to decay from 48 kcal/mol for a 7-carbon tether to 9.2 kcal/mol for a 14-carbon tether. Synthetic efforts to experimentally test these constraints are also presented. This work will likely guide the design and synthesis of novel asymmetric cyclophanes that will be of interest in the catalysis community given the importance of atropisomeric ligands in the field of asymmetric catalysis.

Data and model operations in computational sciences. The examples of computational embryology and epidemiology

2021 ◽  
pp. 1-47
Author(s):  
Fabricio Li Vigni
Keyword(s):  
Social Sciences ◽  
Theoretical Work ◽  
Political Decision ◽  
Computational Epidemiology ◽  
Computational Sciences ◽  
Energy Consuming ◽  
Using Data ◽  
The 1960S ◽  
Time And Energy ◽  
Political Decision Making

Abstract Computer models and simulations have become, since the 1960s, an essential instrument for scientific inquiry and political decision making in several fields, from climate to life and social sciences. Philosophical reflection has mainly focused on the ontological status of the computational modeling, on its epistemological validity and on the research practices it entails. But in computational sciences, the work on models and simulations are only two steps of a longer and richer process where operations on data are as important as, and even more time and energy-consuming than modeling itself. Drawing on two study cases – computational embryology and computational epidemiology –, this article contributes to fill the gap by focusing on the operations of producing and re-using data in computational sciences. The different phases of the scientific and artisanal work of modelers include data collection, aggregation, homogenization, assemblage, analysis and visualization. The article contributes to deconstruct the ideas that data are self-evident informational aggregates and that data-driven approaches are exempted from theoretical work. More importantly, the paper stresses the fact that data are constructed and theory-laden not only in their fabrication, but also in their reusing.

Highly Efficient and Thermally Stable Eu2+-Doped Ca9Nd(PO4)7 Phosphor for Near-Ultraviolet White-Emission LED Applications

2021 ◽  
Vol 21 (12) ◽  
pp. 5859-5866
Author(s):  
Jian Zhou ◽  
Si-Li Ren
Keyword(s):  
Room Temperature ◽  
Green Emission ◽  
Color Temperature ◽  
Multipole Interaction ◽  
Interaction Radius ◽  
Promising Alternative ◽  
Quenching Effect ◽  
Near Ultraviolet ◽  
Great Performance ◽  
Concentration Quenching Effect

Various Eu2+-based Ca9Nd(PO4)7 (CNP:xEu2+, with different x values) materials are prepared via facile solid-state reaction. Their crystal structures are investigated in detail by means of the Rietveld refinement. The structure of CNP:Eu2+ with a trigonal lattice is analogous to that of β-Ca3(PO4)2. Therefore, Eu2+ ions tend to incorporate calcium sites in the host. All the obtained samples can be excited using near ultraviolet (nUV) light to present blue-green emission. An optimal dopant concentration is verified at x = 0.8 with a large critical interaction radius (11.21 Å). The mechanism of the concentration quenching effect is assigned to the multipole-multipole interaction. CNP:xEu2+ possesses a short decay lifetime of ∼60 μs and can endure severe working conditions thanks to its great thermal stability. The relative photoluminescence (PL) intensity of CNP:0.8Eu2+ can retain 84.75% of the pristine intensity measured at room temperature, and the relative intensity remains as high as 69.97% at 423 K. The CNP:Eu2+ phosphors also show great performance in the WLED demonstration. The correlated color temperature (CCT) of the prototype device is 3404 K, with an extremely high Ra (97.6). Therefore, CNP:xEu2+ could be regarded as a promising alternative to blue green phosphors in nUV chip-based WLED applications.

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