scholarly journals Gelatin-Based Film Integrated with Copper Sulfide Nanoparticles for Active Packaging Applications

2021 ◽  
Vol 11 (14) ◽  
pp. 6307
Author(s):  
Swarup Roy ◽  
Jong-Whan Rhim
Keyword(s):  
Antibacterial Activity ◽  
Copper Sulfide ◽  
Biomedical Applications ◽  
Food Packaging ◽  
Composite Films ◽  
Antibacterial Properties ◽  
Barrier Properties ◽  
Gelatin Film ◽  
E Coli ◽  
Water Vapor Barrier

Gelatin-based multifunctional composite films were prepared by reinforcing various amounts of copper sulfide nanoparticles (CuSNP, 0.0, 0.5, 1.0, and 2.0 wt %), and the effect of CuSNP on the film was evaluated by analyzing its physical and antibacterial properties. CuSNP makes a compatible film with gelatin. The inclusion of CuSNP significantly enhanced the UV blocking, mechanical strength, and water vapor barrier properties of the gelatin film. The inclusion of CuSNP of 1.0 wt % or less did not affect the transparency of the gelatin film. When 2.0 wt % of CuSNP was mixed, the hydrophilicity of the gelatin film did not change noticeably, but its thermal properties slightly increased. Moreover, the gelatin/CuSNP composite film presented effective antibacterial activity against E. coli and some activity against L. monocytogenes. Gelatin/CuSNP composite films with better functional and physical properties can be used for food packaging or biomedical applications.

scholarly journals Fabrication of Copper Sulfide Nanoparticles and Limonene Incorporated Pullulan/Carrageenan-Based Film with Improved Mechanical and Antibacterial Properties

Polymers ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 2665
Author(s):  
Swarup Roy ◽  
Jong-Whan Rhim
Keyword(s):  
Composite Film ◽  
Copper Sulfide ◽  
Food Packaging ◽  
Pathogenic Bacteria ◽  
Composite Films ◽  
Antibacterial Properties ◽  
Barrier Properties ◽  
Food Borne ◽  
Active Food Packaging ◽  
Thermal Stability Of

Edible biopolymer (pullulan/carrageenan) based functional composite films were fabricated by the addition of copper sulfide nanoparticles (CuSNP) and D-limonene (DL). The DL and CuSNP were compatible with the pullulan/carrageenan biopolymer matrix. The addition of CuSNP significantly increased the UV-blocking properties without substantially reducing the transparency of the film. The addition of CuSNP improved the film’s tensile strength by 10%; however, the DL addition did not significantly influence the strength, while the combined addition of CuSNP and DL increased the strength by 15%. The addition of the fillers did not significantly affect the thermal stability of the film, but the water vapor barrier property was slightly improved. There was no significant change in the moisture content and hydrophobicity of the composite film. Besides, the composite film showed some antimicrobial activity against food-borne pathogenic bacteria. The fabricated pullulan/carrageenan-based film with antimicrobial and UV-barrier properties is likely to be used in active food packaging applications.

scholarly journals Structures and Antibacterial Properties of PLA-based Ciprofloxacin Composite Films Deposited by Low-Electron Beam Dispersion

2020 ◽  
Vol 22 (1) ◽  
pp. 35 ◽  
Author(s):  
Beibei Li ◽  
Chun He ◽  
Xiaohong Jiang ◽  
M.A. Yarmolenko ◽  
D.G. Piliptsou ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Antibacterial Activity ◽  
Electron Beam ◽  
Agar Medium ◽  
Composite Films ◽  
Antibacterial Properties ◽  
Diffusion Method ◽  
Mass Ratio ◽  
E Coli ◽  
High Antibacterial Activity

Polylactic acid (PLA)-based ciprofloxacin (Cip) antibacterial films with mass ratio PLA:Cip=1:1 were prepared by low-electron beam dispersion (EBD). The molecular structure, chemical composition and morphology of PLA-based ciprofloxacin antibacterial films were investigated by XPS, FTIR, liquid NMR and SEM. The antibacterial activity of composite films was tested against E. coli ATCC 25922 and S. aureus ATCC 12600 using the agar diffusion method on the solid LB agar medium. XPS and FTIR analysis showed the presence of an antibacterial ingredient in the composite films. Using NMR, it has been shown that the molecular structure of a monolayer of ciprofloxacin is fully consistent with the molecular structure of the initial ciprofloxacin powders. High antibacterial activity of the composite films has been also established and the layers still possess antibacterial activity with regard to S. aureus even after 7 days of leaching in an isotonic solution. The thermal treatment indicates that the composite films can withstand temperatures of 180 °C and keep its structure unchanged.

scholarly journals Physical, Mechanical, and Water Vapor Barrier Properties of Starch/Cellulose Nanofiber/Thymol Bionanocomposite Films

Polymers ◽  
2021 ◽  
Vol 13 (23) ◽  
pp. 4060
Author(s):  
Siti Hajar Othman ◽  
Bilguisse Mamadou Wane ◽  
Norhazirah Nordin ◽  
Noor Zafira Noor Hasnan ◽  
Rosnita A. Talib ◽  
...  
Keyword(s):  
Water Vapor ◽  
Food Packaging ◽  
Cellulose Nanofibers ◽  
Antibacterial Properties ◽  
Barrier Properties ◽  
Packaging Materials ◽  
Water Vapor Barrier ◽  
Food Packaging Materials ◽  
Bionanocomposite Films ◽  
Starch Films

The application of starch films, such as food packaging materials, has been restricted due to poor mechanical and barrier properties. However, the addition of a reinforcing agent, cellulose nanofibers (CNF) and also thymol, into the films, may improve the properties of films. This work investigates the effects of incorporating different concentrations of thymol (3, 5, 7, and 10 wt.%) on physical, mechanical, water vapor barrier, and antibacterial properties of corn starch films, containing 1.5 wt.% CNF produced using the solvent casting method. The addition of thymol does not significantly affect the color and opacity of the films. It is found that the tensile strength and Young’s modulus of the films decreases from 10.6 to 6.3 MPa and from 436.9 to 209.8 MPa, respectively, and the elongation at break increased from 110.6% to 123.5% with the incorporation of 10 wt.% thymol into the films. Furthermore, the addition of thymol at higher concentrations (7 and 10 wt.%) improved the water vapor barrier of the films by approximately 60.0%, from 4.98 × 10—9 to 2.01 × 10—9 g/d.m.Pa. Starch/CNF/thymol bionanocomposite films are also found to exhibit antibacterial activity against Escherichia coli. In conclusion, the produced starch/CNF/thymol bionanocomposite films have the potential to be used as antibacterial food packaging materials.

Preparation of bioactive and antibacterial PMMA-based bone cement by modification with quaternary ammonium and alkoxysilane

2021 ◽  
pp. 088532822110044
Author(s):  
Haiyang Wang ◽  
Toshinari Maeda ◽  
Toshiki Miyazaki
Keyword(s):  
Antibacterial Activity ◽  
Methyl Methacrylate ◽  
Bone Cement ◽  
Setting Time ◽  
Antibacterial Properties ◽  
The Body ◽  
Apatite Formation ◽  
Gram Positive ◽  
E Coli ◽  
Gram Positive Bacteria

Bone cement based on poly(methyl methacrylate) (PMMA) powder and methyl methacrylate (MMA) liquid is a very popular biomaterial used for the fixation of artificial joints. However, there is a risk of this cement loosening from bone because of a lack of bone-bonding bioactivity. Apatite formation in the body environment is a prerequisite for cement bioactivity. Additionally, suppression of infection during implantation is required for bone cements to be successfully introduced into the human body. In this study, we modified PMMA cement with γ-methacryloxypropyltrimetoxysilane and calcium acetate to introduce bioactive properties and 2-( tert-butylamino)ethyl methacrylate (TBAEMA) to provide antibacterial properties. The long-term antibacterial activity is attributed to the copolymerization of TBAEMA and MMA. As the TBAEMA content increased, the setting time increased and the compressive strength decreased. After soaking in simulated body fluid, an apatite layer was detected within 7 days, irrespective of the TBAEMA content. The cement showed better antibacterial activity against Gram-negative E. Coli than Gram-positive bacteria; however, of the Gram-positive bacteria investigated, B. subtilis was more susceptible than S. aureus.

Mechanical and antibacterial properties of ZnO/chitosan bio-composite films

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Ayse Kalemtas ◽  
Hasan B. Kocer ◽  
Ahmet Aydin ◽  
Pinar Terzioglu ◽  
Gulsum Aydin
Keyword(s):  
Particle Size ◽  
Food Packaging ◽  
Mechanical Test ◽  
Composite Films ◽  
Antibacterial Properties ◽  
Chitosan Film ◽  
Antibacterial Activities ◽  
Diffusion Method ◽  
Zno Powders ◽  
Solution Casting Method

Abstract In the current study, ZnO/chitosan bio-composite films were produced via solution-casting method. Two different ZnO powders, micrometer (d50 ≅ 1.5 μm) and nanometer sized (d50 ≅ 100 nm), were used to investigate the effect of ZnO particle size and concentration (0, 2, and 8% w/w of chitosan) on the mechanical and antibacterial properties of the ZnO/chitosan bio-composite films. The incorporation of the ZnO powders into the chitosan film resulted in an increase in the tensile strength (TS) and a decrease in the elongation at break (EB) values. Mechanical test results revealed that TS and EB properties were considerably affected (p < 0.05) by the concentration and particle size of the ZnO reinforcement. Disc diffusion method demonstrated good antibacterial activities of bio-composite films containing high amount of ZnO (8% w/w of chitosan) against Escherichia coli, Staphylococcus aureus, Klebsiella pneumoniae, and Bacillus subtilis. The growth-limiting effect of the films was more pronounced for S. aureus and K. pneumoniae. Due to enhanced TS and imparted antibacterial activity of the produced ZnO/chitosan bio-composite films, these materials are promising candidates for applications such as food packaging, wound dressing, and antibacterial coatings for various surfaces.

scholarly journals Hybrid Biocomposites Based on Poly(Lactic Acid) and Silica Aerogel for Food Packaging Applications

Materials ◽  
2020 ◽  
Vol 13 (21) ◽  
pp. 4910 ◽  
Author(s):  
Alejandro Aragón-Gutierrez ◽  
Marina P. Arrieta ◽  
Mar López-González ◽  
Marta Fernández-García ◽  
Daniel López
Keyword(s):  
Thermal Stability ◽  
Lactic Acid ◽  
Silica Aerogel ◽  
Food Packaging ◽  
Mechanical Performance ◽  
Composite Films ◽  
Barrier Properties ◽  
Extrusion Process ◽  
Poly Lactic Acid ◽  
Barrier Performance

Bionanocomposites based on poly (lactic acid) (PLA) and silica aerogel (SiA) were developed by means of melt extrusion process. PLA-SiA composite films were plasticized with 15 wt.% of acetyl (tributyl citrate) (ATBC) to facilitate the PLA processability as well as to attain flexible polymeric formulations for films for food packaging purposes. Meanwhile, SiA was added in four different proportions (0.5, 1, 3 and 5 wt.%) to evaluate the ability of SiA to improve the thermal, mechanical, and barrier performance of the bionanocomposites. The mechanical performance, thermal stability as well as the barrier properties against different gases (carbon dioxide, nitrogen, and oxygen) of the bionanocomposites were evaluated. It was observed that the addition of 3 wt.% of SiA to the plasticized PLA-ATBC matrix showed simultaneously an improvement on the thermal stability as well as the mechanical and barrier performance of films. Finally, PLA-SiA film formulations were disintegrated in compost at the lab-scale level. The combination of ATBC and SiA sped up the disintegration of PLA matrix. Thus, the bionanocomposites produced here show great potential as sustainable polymeric formulations with interest in the food packaging sector.

scholarly journals Preparation and Characterization of Carboxymethyl Cellulose-Based Bioactive Composite Films Modified with Fungal Melanin and Carvacrol

Polymers ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 499
Author(s):  
Łukasz Łopusiewicz ◽  
Paweł Kwiatkowski ◽  
Emilia Drozłowska ◽  
Paulina Trocer ◽  
Mateusz Kostek ◽  
...  
Keyword(s):  
Water Vapour ◽  
Carboxymethyl Cellulose ◽  
Food Packaging ◽  
Antioxidant Activities ◽  
Antioxidant Properties ◽  
Composite Films ◽  
Barrier Properties ◽  
Good Potential ◽  
Fungal Melanin ◽  
Spectroscopy Studies

Preparation of biodegradable packaging materials and valorisation of food industry residues to achieve “zero waste” goals is still a major challenge. Herein, biopolymer-based (carboxymethyl cellulose—CMC) bioactive films were prepared by the addition, alone or in combination, of carvacrol and fungal melanin isolated from champignon mushroom (Agaricus bisporus) agro-industrial residues. The mechanical, optical, thermal, water vapour, and UV-Vis barrier properties were studied. Fourier-transform infrared (FT-IR) spectroscopy studies were carried out to analyse the chemical composition of the resulting films. Antibacterial, antifungal, and antioxidant activities were also determined. Both CMC/melanin and CMC/melanin/carvacrol films showed some antimicrobial activity against Escherichia coli, Staphylococcus aureus, and Candida albicans. The addition of melanin increased the UV-blocking, mechanical, water vapour barrier, and antioxidant properties without substantially reducing the transparency of the films. The addition of carvacrol caused loss of transparency, however, composite CMC/melanin/carvacrol films showed excellent antioxidant activity and enhanced mechanical strength. The developed bioactive biopolymer films have a good potential to be green bioactive alternatives to plastic films in food packaging applications.

scholarly journals Effect of chitosan addition in starch and poly(lactic acid) sheets produced by extrusion

2015 ◽  
Vol 6 (1) ◽  
pp. 80
Author(s):  
Matheus Luz Alberti ◽  
Sílvio José De Souza ◽  
Heliberto Gonçalves ◽  
Fabio Yamashita ◽  
Marianne Ayumi Shirai
Keyword(s):  
Lactic Acid ◽  
Water Vapor ◽  
Food Packaging ◽  
Water Vapor Permeability ◽  
Barrier Properties ◽  
Extrusion Process ◽  
Pilot Scale ◽  
Poly Lactic Acid ◽  
Vapor Permeability ◽  
Water Vapor Barrier

<p>The use of blends containing biodegradable polymers like starch and poly (lactic acid) (PLA) has gained considerable attention, especially for the food packaging production. Current research has also highlighted the use of chitosan because their antimicrobial activity, biodegradability and applicability in the production of active biodegradable food packaging. The objective of this work was to produce cassava starch and PLA sheets incorporated with chitosan by flat extrusion process (calendering-extrusion), and evaluate the mechanical, water vapor barrier and microstructural properties. In order to simplify the obtainment of the material reducing processing steps, all components of the blend were homogenized in one step extrusion The incorporation of chitosan in the starch/PLA sheets decreased significantly the tensile strength, Young's modulus, elongation at break and density. In addition, the scanning electron microscopy images showed the formation of non-homogeneous mixtures with the presence of pores between the blend compounds, and this fact affected the water vapor barrier properties increasing water vapor permeability, solubility and diffusion coefficients. It was possible to conclude that although the incorporation of chitosan to the starch/PLA sheets has not contributed to obtain materials with suitable properties, it was able to produce them by calendering-extrusion process in pilot scale. Studies about chitosan incorporation in starch and PLA sheets still needed.</p><p>&nbsp;</p><p>DOI: 10.14685/rebrapa.v6i1.208</p><p>&nbsp;</p>

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