scholarly journals High-Complexity WO3-Based Catalyst with Multi-Catalytic Species via 3D Printing

Catalysts ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 840 ◽  
Author(s):  
Xiaofeng Wang ◽  
Wei Guo ◽  
Raed Abu-Reziq ◽  
Shlomo Magdassi
Keyword(s):  
3D Printing ◽  
Heterogeneous Catalysts ◽  
Three Dimensional ◽  
Structural Constraints ◽  
High Complexity ◽  
Digital Light Processing ◽  
New Approach ◽  
Complex Shapes ◽  
Metallic Salts ◽  
3D Printed

Three-dimensional (3D) printing has recently been introduced into the field of chemistry as an enabling tool employed to perform reactions, but so far, its use has been limited due to material and structural constraints. We have developed a new approach for fabricating 3D catalysts with high-complexity features for chemical reactions via digital light processing printing (DLP). PtO2-WO3 heterogeneous catalysts with complex shapes were directly fabricated from a clear solution, composed of photo-curable organic monomers, photoinitiators, and metallic salts. The 3D-printed catalysts were tested for the hydrogenation of alkynes and nitrobenzene, and displayed excellent reactivity in these catalytic transformations. Furthermore, to demonstrate the versatility of this approach and prove the concept of multifunctional reactors, a tungsten oxide-based tube consisting of three orderly sections containing platinum, rhodium, and palladium was 3D printed.

scholarly journals 3D Printing of Thermo-Sensitive Drugs

Pharmaceutics ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1524
Author(s):  
Sadikalmahdi Abdella ◽  
Souha H. Youssef ◽  
Franklin Afinjuomo ◽  
Yunmei Song ◽  
Paris Fouladian ◽  
...  
Keyword(s):  
3D Printing ◽  
Three Dimensional ◽  
Fused Deposition Modelling ◽  
Future Directions ◽  
Digital Light Processing ◽  
Fused Deposition ◽  
Printing Technique ◽  
3D Printed ◽  
Semi Solid ◽  
Selection Of

Three-dimensional (3D) printing is among the rapidly evolving technologies with applications in many sectors. The pharmaceutical industry is no exception, and the approval of the first 3D-printed tablet (Spiratam®) marked a revolution in the field. Several studies reported the fabrication of different dosage forms using a range of 3D printing techniques. Thermosensitive drugs compose a considerable segment of available medications in the market requiring strict temperature control during processing to ensure their efficacy and safety. Heating involved in some of the 3D printing technologies raises concerns regarding the feasibility of the techniques for printing thermolabile drugs. Studies reported that semi-solid extrusion (SSE) is the commonly used printing technique to fabricate thermosensitive drugs. Digital light processing (DLP), binder jetting (BJ), and stereolithography (SLA) can also be used for the fabrication of thermosensitive drugs as they do not involve heating elements. Nonetheless, degradation of some drugs by light source used in the techniques was reported. Interestingly, fused deposition modelling (FDM) coupled with filling techniques offered protection against thermal degradation. Concepts such as selection of low melting point polymers, adjustment of printing parameters, and coupling of more than one printing technique were exploited in printing thermosensitive drugs. This systematic review presents challenges, 3DP procedures, and future directions of 3D printing of thermo-sensitive formulations.

Broadening the absorption bandwidth by novel series-parallel cross convex-concave structures

2021 ◽  
Author(s):  
Hui Mei ◽  
Dou Yang ◽  
Li Yao ◽  
Wenqiang Yang ◽  
Xing Zhao ◽  
...  
Keyword(s):  
3D Printing ◽  
Three Dimensional ◽  
Absorption Bandwidth ◽  
Polymer Derived Ceramics ◽  
Complex Shapes ◽  
New Type ◽  
3D Printed

As a new type of molding technology, three dimensional (3D) printing can realize the manufacturing of devices with complex shapes. In the current study, 3D printed polymer-derived ceramics (PDCs), whose...

scholarly journals Cytocompatibility of 3D printed dental materials for temporary restorations on fibroblasts

2020 ◽  
Author(s):  
Jung-Hyun Park ◽  
Hyun Lee ◽  
Jong-Woo Kim ◽  
Ji-Hwan Kim
Keyword(s):  
3D Printing ◽  
Laser Scanning ◽  
Dental Materials ◽  
Three Dimensional ◽  
Confocal Laser Scanning Microscope ◽  
Confocal Laser ◽  
Control Group ◽  
Digital Light Processing ◽  
3D Printed ◽  
Materials Used

Abstract Background Three-dimensional (3D) printing is widely used in the fabrication of dental prostheses; however, the influence of dental materials used for 3D printing on temporary restoration of fibroblasts in tissues is unclear. Thus, the influence of different dental materials on fibroblasts were investigated. Methods Digital light processing (DLP) type 3D printing was used. Specimens in the control group were fabricated by mixing liquid and powder self-curing resin restoration materials. The temporary resin materials used were Model, Castable, Clear-SG, Tray, and Temporary, and the self-curing resin materials used were Lang dental, Alike, Milky blue, TOKVSO CUREFAST, and UniFast III. Fibroblast cells were cultured on each specimen and subsequently post-treated for analysis. Morphology of the adhered cells were observed using a confocal laser scanning microscope (CLSM) and a scanning electron microscope (SEM). Results CLSM and SEM cell imaging revealed that the 3D printed material group presented better cell adhesion with well-distributed filopodia compared to that in the conventional resin material group. Cell proliferation was significantly higher in the 3D printing materials. Conclusion This indicates that using resins fabricated by 3D printing technology rather than the ones fabricated by self-curing technology is recommended for the fabrication of dental temporary restorations.

3D printing of metasurface-based dual-linear polarization converter

2021 ◽  
Author(s):  
Gyeongyeong Lee ◽  
Yeong-Hoon Noh ◽  
In-Gon Lee ◽  
Ic-Pyo Hong ◽  
Jong-Gwan Yook ◽  
...  
Keyword(s):  
3D Printing ◽  
Linear Polarization ◽  
Orthogonal Polarization ◽  
Polarization Conversion ◽  
Polarization Converter ◽  
Digital Light Processing ◽  
Conductive Materials ◽  
Complex Shapes ◽  
3D Printed ◽  
Materials Used

Abstract 3D printing using digital light processing (DLP) technology has been studied in various fields because of its ability to create complex shapes through a simple process. In this study, DLP 3D printing was employed in the implementation of the metasurface-based dual-linear polarization converter (DLPC). The unit cell of the metasurface-based DLPC for linear polarization conversion was designed consisting of the upper and lower dipole-pair antennas connected through vias and a shielding layer that electrically shields the antennas from each other, and its fabrication was based on the characterization results of the dielectric properties of the photocurable substrate materials and electrical properties of the conductive materials used for synthesizing the metasurface. The printability evaluation of dipole pairs, vias, and a shielding layer was carried out to implement the detailed structures of the DLPC in 3D printing. The electromagnetic wave transmission characteristics of the 3D-printed 8×8 array DLPC demonstrated an orthogonal polarization conversion, as predicted by the simulation results. This study confirmed that the DLP-based 3D printing technology can go beyond the existing functions of manufacturing objects and can be applied to the implementation of various electronics based on different meta-structures.

Development of fabrics by digital light processing three-dimensional printing technology and using a polyurethane acrylate photopolymer

2019 ◽  
Vol 90 (7-8) ◽  
pp. 847-856
Author(s):  
Seul Gi Kim ◽  
Ji Eun Song ◽  
Hye Rim Kim
Keyword(s):  
3D Printing ◽  
Layer Thickness ◽  
Three Dimensional ◽  
Curing Time ◽  
Printing Technology ◽  
Digital Light Processing ◽  
Three Dimensional Printing ◽  
3D Printing Technology ◽  
Polyurethane Acrylate ◽  
3D Printed

This study aimed to produce fabrics by the digital light processing (DLP) three-dimensional (3D) printing technology and using a polyurethane acrylate photopolymer as the printing material. The effect of the acrylate oligomer concentration on printing was evaluated. The DLP 3D printing conditions, such as the curing time and layer thickness, were controlled considering the physical properties, such as the tensile strength, elongation, and crease recovery of the 3D printed material. The optimal printing conditions were as follows: concentration of acrylate oligomer in the photopolymer: 10% (v/v); curing time per layer: 14 s; and layer thickness: 100 µm. These results are expected to guide further studies on the development of fabrics using DLP 3D printing technology.

3D printing: an emerging technology for sensor fabrication

Sensor Review ◽  
2016 ◽  
Vol 36 (4) ◽  
pp. 333-338 ◽  
Author(s):  
Robert Bogue
Keyword(s):  
3D Printing ◽  
Three Dimensional ◽  
Diverse Range ◽  
Content Type ◽  
Sensor Fabrication ◽  
Wide Range ◽  
Complex Shapes ◽  
Printed Sensors ◽  
3D Printed ◽  
Manufacturing Techniques

Purpose This study aims to provide a technical insight into sensors fabricated by three-dimensional (3D) printing methods. Design/methodology/approach Following an introduction to 3D printing, this article first discusses printed sensors for strain and allied variables, based on a diverse range of principles and materials. It then considers ultrasonic and acoustic sensor developments and provides details of a sensor based on 3D printed electronic components for monitoring food quality in real-time. Finally, brief concluding comments are drawn. Findings Several variants of the 3D printing technique have been used in the fabrication of a range of sensors based on many different operating principles. These exhibit good performance and sometimes unique characteristics. A key benefit is the ability to overcome the limitations of conventional manufacturing techniques by creating complex shapes from a wide range of sensing materials. Originality/value 3D printing is a new and potentially important sensor fabrication technology, and this article provides details of a range of recently reported developments.

scholarly journals Three-dimensional printing for heart diseases: clinical application review

2021 ◽  
Author(s):  
Yanyan Ma ◽  
Peng Ding ◽  
Lanlan Li ◽  
Yang Liu ◽  
Ping Jin ◽  
...  
Keyword(s):  
3D Printing ◽  
Clinical Application ◽  
Heart Diseases ◽  
Three Dimensional ◽  
Convincing Evidence ◽  
Surgical Interventions ◽  
Three Dimensional Printing ◽  
Complex Anatomy ◽  
Precise Understanding ◽  
3D Printed

AbstractHeart diseases remain the top threat to human health, and the treatment of heart diseases changes with each passing day. Convincing evidence shows that three-dimensional (3D) printing allows for a more precise understanding of the complex anatomy associated with various heart diseases. In addition, 3D-printed models of cardiac diseases may serve as effective educational tools and for hands-on simulation of surgical interventions. We introduce examples of the clinical applications of different types of 3D printing based on specific cases and clinical application scenarios of 3D printing in treating heart diseases. We also discuss the limitations and clinically unmet needs of 3D printing in this context.

scholarly journals Three-Dimensional Printing of Hydroxyapatite Composites for Biomedical Application

Crystals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 353
Author(s):  
Yanting Han ◽  
Qianqian Wei ◽  
Pengbo Chang ◽  
Kehui Hu ◽  
Oseweuba Valentine Okoro ◽  
...  
Keyword(s):  
Tissue Engineering ◽  
3D Printing ◽  
Biomedical Application ◽  
Three Dimensional ◽  
Antibacterial Properties ◽  
Natural Polymers ◽  
Three Dimensional Printing ◽  
3D Printed ◽  
Dental Applications ◽  
Hard Tissue Engineering

Hydroxyapatite (HA) and HA-based nanocomposites have been recognized as ideal biomaterials in hard tissue engineering because of their compositional similarity to bioapatite. However, the traditional HA-based nanocomposites fabrication techniques still limit the utilization of HA in bone, cartilage, dental, applications, and other fields. In recent years, three-dimensional (3D) printing has been shown to provide a fast, precise, controllable, and scalable fabrication approach for the synthesis of HA-based scaffolds. This review therefore explores available 3D printing technologies for the preparation of porous HA-based nanocomposites. In the present review, different 3D printed HA-based scaffolds composited with natural polymers and/or synthetic polymers are discussed. Furthermore, the desired properties of HA-based composites via 3D printing such as porosity, mechanical properties, biodegradability, and antibacterial properties are extensively explored. Lastly, the applications and the next generation of HA-based nanocomposites for tissue engineering are discussed.

scholarly journals Three-dimensionally printed polycaprolactone/multicomponent bioactive glass scaffolds for potential application in bone tissue engineering

2020 ◽  
Vol 6 (1) ◽  
pp. 57-69
Author(s):  
Amirhosein Fathi ◽  
Farzad Kermani ◽  
Aliasghar Behnamghader ◽  
Sara Banijamali ◽  
Masoud Mozafari ◽  
...  
Keyword(s):  
Tissue Engineering ◽  
3D Printing ◽  
Bone Tissue Engineering ◽  
Bone Tissue ◽  
Three Dimensional ◽  
Layer By Layer ◽  
Composite Scaffolds ◽  
3D Printed ◽  
Co Doped

AbstractOver the last years, three-dimensional (3D) printing has been successfully applied to produce suitable substitutes for treating bone defects. In this work, 3D printed composite scaffolds of polycaprolactone (PCL) and strontium (Sr)- and cobalt (Co)-doped multi-component melt-derived bioactive glasses (BGs) were prepared for bone tissue engineering strategies. For this purpose, 30% of as-prepared BG particles (size <38 μm) were incorporated into PCL, and then the obtained composite mix was introduced into a 3D printing machine to fabricate layer-by-layer porous structures with the size of 12 × 12 × 2 mm3.The scaffolds were fully characterized through a series of physico-chemical and biological assays. Adding the BGs to PCL led to an improvement in the compressive strength of the fabricated scaffolds and increased their hydrophilicity. Furthermore, the PCL/BG scaffolds showed apatite-forming ability (i.e., bioactivity behavior) after being immersed in simulated body fluid (SBF). The in vitro cellular examinations revealed the cytocompatibility of the scaffolds and confirmed them as suitable substrates for the adhesion and proliferation of MG-63 osteosarcoma cells. In conclusion, 3D printed composite scaffolds made of PCL and Sr- and Co-doped BGs might be potentially-beneficial bone replacements, and the achieved results motivate further research on these materials.

scholarly journals Dimensional Accuracy of Dental Models for Three-Unit Prostheses Fabricated by Various 3D Printing Technologies

Materials ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1550
Author(s):  
Soo-Yeon Yoo ◽  
Seong-Kyun Kim ◽  
Seong-Joo Heo ◽  
Jai-Young Koak ◽  
Joung-Gyu Kim
Keyword(s):  
Surface Roughness ◽  
Three Dimensional ◽  
Dimensional Accuracy ◽  
3D Analysis ◽  
Digital Light Processing ◽  
Test Models ◽  
Reference File ◽  
Significant Difference ◽  
Jet Printing ◽  
3D Printed

Previous studies on accuracy of three-dimensional (3D) printed model focused on full arch measurements at few points. The aim of this study was to examine the dimensional accuracy of 3D-printed models which were teeth-prepped for three-unit fixed prostheses, especially at margin and proximal contact areas. The prepped dental model was scanned with a desktop scanner. Using this reference file, test models were fabricated by digital light processing (DLP), Multi-Jet printing (MJP), and stereo-lithography apparatus (SLA) techniques. We calculated the accuracy (trueness and precision) of 3D-printed models on 3D planes, and deviations of each measured points at buccolingual and mesiodistal planes. We also analyzed the surface roughness of resin printed models. For overall 3D analysis, MJP showed significantly higher accuracy (trueness) than DLP and SLA techniques; however, there was not any statistically significant difference on precision. For deviations on margins of molar tooth and distance to proximal contact, MJP showed significantly accurate results; however, for a premolar tooth, there was no significant difference between the groups. 3D color maps of printed models showed contraction buccolingually, and surface roughness of the models fabricated by MJP technique was observed as the lowest. The accuracy of the 3D-printed resin models by DLP, MJP, and SLA techniques showed a clinically acceptable range to use as a working model for manufacturing dental prostheses

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