scholarly journals Design and Preparation of PU/EP Blend Resin Grafted by Hydrophilic Molecular Segments

Coatings ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1345
Author(s):  
Gang Lu ◽  
Changgeng Shuai ◽  
Yinsong Liu ◽  
Xue Yang ◽  
Xiaoyang Hu
Keyword(s):  
Mechanical Properties ◽  
Essential Role ◽  
Functional Performance ◽  
Experimental Conditions ◽  
Plate Test ◽  
Antifouling Coating ◽  
Comprehensive Properties ◽  
Antifouling Coatings ◽  
Film Forming ◽  
Better Than

Film-forming resins, as carriers of antifouling coatings, play an essential role in the functional performance of coatings. With the gradual promotion of coatings in the field of marine antifouling, the preparation of film-forming resins containing hydrophilic chain segments is urgently needed to give full play to the functional and time-sensitive performance of antifouling coatings. In this paper, the single-ended isocyanate group (NCO) polyurethane (PU) prepolymer with hydrophilic chain segments was prepared and grafted onto an epoxy resin (EP) molecular chain to obtain the PU/EP grafted blend. Successful preparation of the PU/EP grafted blends was confirmed by infrared spectrum analysis. Simultaneously, the grafted blend was cured, and its hydrophilicity and mechanical properties were also tested. The results demonstrate that the grafted method can effectively improve the hydrophilicity of the film-forming resin while maintaining its mechanical properties. It can be concluded from the hydrophilic and mechanical properties of the materials that the comprehensive properties of PU/EP grafted blends are the best when the PU content is between 40% and 50%. The hanging plate test showed that the antifouling effect of the antifouling coating prepared by hydrophilic modified PU/EP film-forming resin was better than that of the traditional antifouling coating under the experimental conditions.

scholarly journals Imparting Strong Antifouling Properties to the Transparent PVB Coating through the Zwitterionic Compound Condensation

Coatings ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 1164
Author(s):  
Jianbin Zhang ◽  
Shangshang Bo ◽  
Haiyan Feng ◽  
Bo Yu ◽  
Qiangliang Yu ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Surface Roughness ◽  
Sulfonic Acid ◽  
Polyvinyl Butyral ◽  
Light Transmittance ◽  
High Transparency ◽  
Antifouling Coating ◽  
Comprehensive Properties ◽  
Ft Ir ◽  
Physical And Chemical

Fouling is a ubiquitous and longstanding challenge that causes both economic and environmental problems, especially for underwater detection equipment, as fouling directly limits the normal services and functions of such equipment. Therefore, it is necessary to develop coatings with high transparency and good antifouling performance. Herein, a novel zwitterion compound was synthesized, and an antifouling coating with excellent comprehensive properties was prepared by integrating 3-[[3-(triethoxysilyl)-propyl] amino] propane-1-sulfonic acid (TPAPS) into polyvinyl butyral (PVB) polymer, which possesses excellent mechanical properties and transparency. The physical and chemical, mechanical, and antifouling properties, and the light transmittance of the coating were characterized by the SEM, FT-IR, XPS, UV-VIS. The results show that the coating had good mechanical properties and adhesion to the substrate, and the strong hydration ability of TPAPS endowed the coating with excellent resistance to oil stains and biofouling. More importantly, the structure of the coating was homogenous and its surface roughness was very little, which imparted the coating with high transmittance. This research provides a facile approach for synthesizing high-transparency materials with excellent antifouling and mechanical properties.

Electron Microscopic Observation of the Longitudinal Organization of Poly (p-Phenylene Terephthalamide) Fibers

1982 ◽  
Vol 40 ◽  
pp. 680-681
Author(s):  
Li Li-Sheng ◽  
L.F. Allard ◽  
W.C. Bigelow
Keyword(s):  
Electron Microscopy ◽  
Mechanical Properties ◽  
Scanning Electron Microscopy ◽  
Microscopic Observation ◽  
Electron Microscopic Observation ◽  
Electron Microscopic ◽  
Aromatic Polyamides ◽  
Radial Arrangement ◽  
Scanning Electron ◽  
Better Than

The aromatic polyamides form a class of fibers having mechanical properties which are much better than those of aliphatic polyamides. Currently, the accepted morphology of these fibers as proposed by M.G. Dobb, et al. is a radial arrangement of pleated sheets, with the plane of the pleats parallel to the axis of the fiber. We have recently obtained evidence which supports a different morphology of this type of fiber, using ultramicrotomy and ion-thinning techniques to prepare specimens for transmission and scanning electron microscopy.

Green Synthesis and Enhanced CO2 Capture Performance of Perfluorinated Cerium-Based Metal-Organic Frameworks with UiO-66 and MIL-140 Topology

2018 ◽  
Author(s):  
Roberto D’Amato ◽  
Anna Donnadio ◽  
Mariolino Carta ◽  
Claudio Sangregorio ◽  
Riccardo Vivani ◽  
...  
Keyword(s):  
Photoelectron Spectroscopy ◽  
Metal Organic Frameworks ◽  
Isosteric Heat ◽  
Experimental Conditions ◽  
Cerium Ammonium Nitrate ◽  
Ideal Adsorbed Solution Theory ◽  
Metal Organic ◽  
Adsorbed Solution ◽  
Better Than ◽  
The Ideal

Reaction of cerium ammonium nitrate and tetrafluoroterephthalic acid in water afforded two new metal-organic frameworks with UiO-66 [F4_UiO-66(Ce)] and MIL-140 [F4_MIL-140A(Ce)] topologies. The two compounds can be obtained in the same experimental conditions, just by varying the amount of acetic acid used as crystallization modulator in the synthesis. Both F4_UiO-66(Ce) and F4_MIL-140A(Ce) feature pores with size < 8 Å, which classifies them as ultramicroporous. Combination of X-ray photoelectron spectroscopy and magnetic susceptibility measurements revealed that both compounds contain a small amount of Ce(III), which is preferentially accumulated near the surface of the crystallites. The CO<sub>2</sub> sorption properties of F4_UiO-66(Ce) and F4_MIL-140A(Ce) were investigated, finding that they perform better than their Zr-based analogues. F4_MIL-140A(Ce) displays an unusual S-shaped isotherm with steep uptake increase at pressure < 0.2 bar at 298 K. This makes F4_MIL-140A(Ce) exceptionally selective for CO<sub>2</sub> over N<sub>2</sub>: the calculated selectivity, according to the ideal adsorbed solution theory for a 0.15:0.85 mixture at 1 bar and 293 K, is higher than 1900, amongst the highest ever reported for metal-organic frameworks. The calculated isosteric heat of CO<sub>2 </sub>adsorption is in the range of 38-40 kJ mol<sup>-1</sup>, indicating a strong physisorptive character.

FERRIUM S53

Alloy Digest ◽  
2008 ◽  
Vol 57 (12) ◽  
Keyword(s):  
Mechanical Properties ◽  
Fracture Toughness ◽  
Corrosion Resistance ◽  
Heat Treating ◽  
Corrosion Resistant Steel ◽  
Resistant Steel ◽  
Corrosion Resistant ◽  
Aircraft Landing ◽  
Aircraft Landing Gear ◽  
Better Than

Abstract Ferrium S53 was developed for use as a structural corrosion resistant steel for aircraft landing gear. S53 has a corrosion resistance equivalent to 440C, strength equivalent to or better than 300M (AMS 6257A) and SAE 4340 (see Mechanical Properties), optimum microstructure features for maximum fatigue resistance, and a surface hardenability equal to or greater than 67 HRC for wear and fatigue. This datasheet is an update to Alloy Digest SS-942 and SS-1003. This datasheet provides information on composition, physical properties, hardness, and tensile properties as well as fracture toughness. It also includes information on corrosion resistance as well as heat treating and machining. Filing Code: SA-589. Producer or source: QuesTek Innovations, LLC.

Self-healing, Highly Elastic and Amphiphilic Silicone-based Polyurethane for Antifouling Coatings

2021 ◽  
Author(s):  
Xiaobin Lin ◽  
Qingyi Xie ◽  
Chunfeng Ma ◽  
Guangzhao Zhang
Keyword(s):  
Mechanical Properties ◽  
Silicone Elastomer ◽  
Self Healing ◽  
Fouling Resistance ◽  
The Poor ◽  
Antifouling Coatings ◽  
Fouling Release

Silicone elastomer coatings have attracted increasing attention owing to its eco-friendly nature, excellent fouling release ability and drag-reducing property. However, the poor mechanical properties and lack of fouling resistance limits...

Improvement of mechanical properties of chitosan-based films via physical treatment of film-forming solution

2015 ◽  
Vol 158 ◽  
pp. 66-72 ◽  
Author(s):  
Wasina Thakhiew ◽  
Manida Champahom ◽  
Sakamon Devahastin ◽  
Somchart Soponronnarit
Keyword(s):  
Mechanical Properties ◽  
Physical Treatment ◽  
Film Forming

scholarly journals Formation conditions and mechanical properties of aggregates produced in tephra–water–snow flows

2020 ◽  
Vol 72 (1) ◽  
Author(s):  
Hirofumi Niiya ◽  
Kenichi Oda ◽  
Daisuke Tsuji ◽  
Hiroaki Katsuragi
Keyword(s):  
Mechanical Properties ◽  
Mixing Time ◽  
Testing Machine ◽  
Small Scale ◽  
Scaling Analysis ◽  
Compression Tests ◽  
Ice Slurry ◽  
Experimental Conditions ◽  
Formation Conditions ◽  
Snow And Ice

Abstract The formation of aggregates consisting of snow, water, and tephra has been reported in small-scale experiments on three-phase flows containing tephra, water, and snow, representing lahars triggered by snowmelt. Such aggregates reduce the mobility of mud flow. However, the formation mechanism of such aggregates under various conditions has not been investigated. To elucidate the formation conditions and mechanical properties of the aggregates, we performed mixing experiments with materials on a rotating table and compression tests on the resulting aggregates with a universal testing machine in a low-temperature room at $$0\,^{\circ }\text {C}$$ 0 ∘ C . From experiments with varying component ratios of the mixture and tephra diameter, the following results were obtained: (i) the aggregate grew rapidly and reached maturity after a mixing time of 5 min; (ii) the mass of aggregates increased with snow concentration, exhibiting an approximately linear relationship; (iii) single aggregates with large mass formed at lower and higher tephra concentrations, whereas multiple aggregates with smaller mass were observed at intermediate concentrations; (iv) the shape of the aggregate satisfied the similarity law for an ellipsoid; (v) the compressive mechanical behavior could be modeled by an empirical nonlinear model. The obtained mechanical properties of the aggregates were independent of the experimental conditions; (vi) scaling analysis based on the Reynolds number and the strength of the aggregates showed that the aggregates cannot form in ice-slurry lahars. Our findings suggest that low-speed lahars containing snow and ice are likely to generate aggregates, but snow and ice in the ice-slurry lahars are dispersed without such aggregates.

scholarly journals The Infuence of Salicin on Rheological and Film-Forming Properties of Collagen

Molecules ◽  
2021 ◽  
Vol 26 (6) ◽  
pp. 1661
Author(s):  
Katarzyna Adamiak ◽  
Katarzyna Lewandowska ◽  
Alina Sionkowska
Keyword(s):  
Mechanical Properties ◽  
Atomic Force Microscopy ◽  
Infrared Spectroscopy ◽  
Rheological Properties ◽  
Silver Carp ◽  
Shear Tests ◽  
Force Microscopy ◽  
Atomic Force ◽  
Film Forming ◽  
Potential Applications

Collagen films are widely used as adhesives in medicine and cosmetology. However, its properties require modification. In this work, the influence of salicin on the properties of collagen solution and films was studied. Collagen was extracted from silver carp skin. The rheological properties of collagen solutions with and without salicin were characterized by steady shear tests. Thin collagen films were prepared by solvent evaporation. The structure of films was researched using infrared spectroscopy. The surface properties of films were investigated using Atomic Force Microscopy (AFM). Mechanical properties were measured as well. It was found that the addition of salicin modified the roughness of collagen films and their mechanical and rheological properties. The above-mentioned parameters are very important in potential applications of collagen films containing salicin.

Abrasive Waterjet Cutting of Aluminum Alloys: Workpiece Surface Roughness

2013 ◽  
Vol 404 ◽  
pp. 3-9 ◽  
Author(s):  
Nihat Tosun ◽  
Ihsan Dagtekin ◽  
Latif Ozler ◽  
Ahmet Deniz
Keyword(s):  
Mechanical Properties ◽  
Surface Roughness ◽  
Aluminum Alloys ◽  
Abrasive Waterjet ◽  
Traditional Methods ◽  
Workpiece Surface ◽  
Abrasive Waterjet Machining ◽  
Waterjet Machining ◽  
Area Of Application ◽  
Better Than

Abrasive waterjet machining is one of the non-traditional methods of the recent years which found itself a wide area of application in the industry for machining of different materials. In this paper, the surface roughness of 6061-T6 and 7075-T6 aluminum alloys are being cut with abrasive waterjet is examined experimentally. The experiments were conducted with different waterjet pressures and traverse speeds. It has been found that the surface roughness obtained by cutting material with high mechanical properties is better than that of obtained by cutting material with inferior mechanical properties.

Study on the Mechanical Properties and Frost Resistance of Recycled Concrete Prepared by Village Construction Wastes

2011 ◽  
Vol 418-420 ◽  
pp. 406-410
Author(s):  
Jun Liu ◽  
Yao Li ◽  
Dan Dan Hong ◽  
Yu Liu
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Frost Resistance ◽  
Cement Mortar ◽  
Strength Loss ◽  
Recycled Concrete ◽  
Recycled Aggregate ◽  
Replacement Rate ◽  
Concrete Mechanical Properties ◽  
Better Than

Abstract. Recycled aggregate—rural building material wastes pretreated by cement mortar—are applied into concrete with different replacement rates: 0, 25%, 50%, 75%, and 100%. Results from measurements of compressive strength, cleavage tensile strength, mass loss after fast freeze-thaw cycles, and compressive strength loss indicate that a different recycled aggregate replacement rate certainly influences concrete mechanical properties and frost resistance. Recycled aggregate replacement rates less than 75% performs better than common concrete. Data from the 100% replacement rate is worse than that of rates less than 75% but still satisfy the general demands of GB standard on C30 concrete.

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