scholarly journals Imparting Strong Antifouling Properties to the Transparent PVB Coating through the Zwitterionic Compound Condensation

Coatings ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 1164
Author(s):  
Jianbin Zhang ◽  
Shangshang Bo ◽  
Haiyan Feng ◽  
Bo Yu ◽  
Qiangliang Yu ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Surface Roughness ◽  
Sulfonic Acid ◽  
Polyvinyl Butyral ◽  
Light Transmittance ◽  
High Transparency ◽  
Antifouling Coating ◽  
Comprehensive Properties ◽  
Ft Ir ◽  
Physical And Chemical

Fouling is a ubiquitous and longstanding challenge that causes both economic and environmental problems, especially for underwater detection equipment, as fouling directly limits the normal services and functions of such equipment. Therefore, it is necessary to develop coatings with high transparency and good antifouling performance. Herein, a novel zwitterion compound was synthesized, and an antifouling coating with excellent comprehensive properties was prepared by integrating 3-[[3-(triethoxysilyl)-propyl] amino] propane-1-sulfonic acid (TPAPS) into polyvinyl butyral (PVB) polymer, which possesses excellent mechanical properties and transparency. The physical and chemical, mechanical, and antifouling properties, and the light transmittance of the coating were characterized by the SEM, FT-IR, XPS, UV-VIS. The results show that the coating had good mechanical properties and adhesion to the substrate, and the strong hydration ability of TPAPS endowed the coating with excellent resistance to oil stains and biofouling. More importantly, the structure of the coating was homogenous and its surface roughness was very little, which imparted the coating with high transmittance. This research provides a facile approach for synthesizing high-transparency materials with excellent antifouling and mechanical properties.

Preparation of Transparent Water-Insoluble Silk Fibroin Films

2011 ◽  
Vol 175-176 ◽  
pp. 79-84
Author(s):  
Min Qing Luo ◽  
Cen Cen Zhang ◽  
Shen Zhou Lu
Keyword(s):  
Mechanical Properties ◽  
Silk Fibroin ◽  
Light Transmittance ◽  
Human Cornea ◽  
X Ray Diffraction ◽  
X Ray ◽  
Blend Films ◽  
Structure Surface ◽  
Ft Ir ◽  
Transparent Water

The transparent water-insoluble silk fibroin(SF) films were casted from the mixture solution of silk fibroin and xylitol/mannitol. The structure, surface morphology, solubility, mechanical properties and light transmittance of the blend films were measured. FT-IR, X-ray diffraction retuslts indicated that the films were mainly composed of Silk I structure. SEM showed the blend films with xylitol were miscible, whereas the blend films with mannitol had phase-separated structure. There were lots of nanopores in the blend films in the wet state. The insoluble SF /xylitol films had excellent mechanical properties while the SF / mannitol films were brittle. The mechanical property of SF/alcohol blend films were consistent with the human cornea in wet state.When the contents of xylitol were 10% and 20%, the blend films had high light transmittance which were similar to human cornea. In summary, the SF /xylitol film containing 10% xylitol provides a great potential to act as repairing materials for cornea.

scholarly journals Design and Preparation of PU/EP Blend Resin Grafted by Hydrophilic Molecular Segments

Coatings ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1345
Author(s):  
Gang Lu ◽  
Changgeng Shuai ◽  
Yinsong Liu ◽  
Xue Yang ◽  
Xiaoyang Hu
Keyword(s):  
Mechanical Properties ◽  
Essential Role ◽  
Functional Performance ◽  
Experimental Conditions ◽  
Plate Test ◽  
Antifouling Coating ◽  
Comprehensive Properties ◽  
Antifouling Coatings ◽  
Film Forming ◽  
Better Than

Film-forming resins, as carriers of antifouling coatings, play an essential role in the functional performance of coatings. With the gradual promotion of coatings in the field of marine antifouling, the preparation of film-forming resins containing hydrophilic chain segments is urgently needed to give full play to the functional and time-sensitive performance of antifouling coatings. In this paper, the single-ended isocyanate group (NCO) polyurethane (PU) prepolymer with hydrophilic chain segments was prepared and grafted onto an epoxy resin (EP) molecular chain to obtain the PU/EP grafted blend. Successful preparation of the PU/EP grafted blends was confirmed by infrared spectrum analysis. Simultaneously, the grafted blend was cured, and its hydrophilicity and mechanical properties were also tested. The results demonstrate that the grafted method can effectively improve the hydrophilicity of the film-forming resin while maintaining its mechanical properties. It can be concluded from the hydrophilic and mechanical properties of the materials that the comprehensive properties of PU/EP grafted blends are the best when the PU content is between 40% and 50%. The hanging plate test showed that the antifouling effect of the antifouling coating prepared by hydrophilic modified PU/EP film-forming resin was better than that of the traditional antifouling coating under the experimental conditions.

scholarly journals Preparation of Transparent and Thick CNF/Epoxy Composites by Controlling the Properties of Cellulose Nanofibrils

Nanomaterials ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 625 ◽  
Author(s):  
Shin Young Park ◽  
Simyub Yook ◽  
Sooim Goo ◽  
Wanhee Im ◽  
Hye Jung Youn
Keyword(s):  
Mechanical Properties ◽  
Epoxy Resin ◽  
Cellulose Nanofibrils ◽  
High Light ◽  
Epoxy Composites ◽  
Light Transmittance ◽  
High Transparency ◽  
Preparation Conditions ◽  
Optically Transparent ◽  
Optical And Mechanical Properties

Cellulose nanofibrils (CNFs) have been used as reinforcing elements in optically transparent composites by combination with polymer matrices. In this study, strong, optically transparent, and thick CNF/epoxy composites were prepared by immersing two or four layers of CNF sheets in epoxy resin. The morphology of the CNF, the preparation conditions of the CNF sheet, and the grammage and layer numbers of the CNF sheets were controlled. The solvent-exchanged CNF sheets resulted in the production of a composite with high transparency and low haze. The CNF with smaller width and less aggregated fibrils, which are achieved by carboxymethylation, and a high number of grinding passes are beneficial in the production of optically transparent CNF/epoxy composites. Both the grammage and number of stacked layers of sheets in a composite affected the optical and mechanical properties of the composite. A composite with a thickness of 450–800 μm was prepared by stacking two or four layers of CNF sheets in epoxy resin. As the number of stacked sheets increased, light transmittance was reduced and the haze increased. The CNF/epoxy composites with two layers of low grammage (20 g/m2) sheets exhibited high light transmittance (>90%) and low haze (<5%). In addition, the composites with the low grammage sheet had higher tensile strength and elastic modulus compared with neat epoxy and those with high grammage sheets.

INFLUENCE THE QUENCHING AND TEMPERING ON THE MICROSTRUCTURE, MECHANICAL PROPERTIES AND SURFACE ROUGHNESS, OF MEDIUM CARBON STEEL

2018 ◽  
Vol 18 (1) ◽  
pp. 125-135
Author(s):  
Sattar H A Alfatlawi
Keyword(s):  
Mechanical Properties ◽  
Heat Treatment ◽  
Surface Roughness ◽  
Carbon Steel ◽  
Cold Water ◽  
Medium Carbon Steel ◽  
Medium Carbon ◽  
Heating And Cooling ◽  
Treatment Processes ◽  
Quenching And Tempering

One of ways to improve properties of materials without changing the product shape toobtain the desired engineering applications is heating and cooling under effect of controlledsequence of heat treatment. The main aim of this study was to investigate the effect ofheating and cooling on the surface roughness, microstructure and some selected propertiessuch as the hardness and impact strength of Medium Carbon Steel which treated at differenttypes of heat treatment processes. Heat treatment achieved in this work was respectively,heating, quenching and tempering. The specimens were heated to 850°C and left for 45minutes inside the furnace as a holding time at that temperature, then quenching process wasperformed in four types of quenching media (still air, cold water (2°C), oil and polymersolution), respectively. Thereafter, the samples were tempered at 200°C, 400°C, and 600°Cwith one hour as a soaking time for each temperature, then were all cooled by still air. Whenthe heat treatment process was completed, the surface roughness, hardness, impact strengthand microstructure tests were performed. The results showed a change and clearimprovement of surface roughness, mechanical properties and microstructure afterquenching was achieved, as well as the change that took place due to the increasingtoughness and ductility by reducing of brittleness of samples.

Friction Force and Stresses Analysis for Contact of Assembled Details

2006 ◽  
Vol 113 ◽  
pp. 334-338
Author(s):  
Z. Dreija ◽  
O. Liniņš ◽  
Fr. Sudnieks ◽  
N. Mozga
Keyword(s):  
Mechanical Properties ◽  
Surface Roughness ◽  
Plastic Deformation ◽  
Friction Force ◽  
Sliding Friction ◽  
Friction Model ◽  
Contact Interface ◽  
Finite Element Program ◽  
Elastic Plastic ◽  
Element Program

The present work deals with the computation of surface stresses and deformation in the presence of friction. The evaluation of the elastic-plastic contact is analyzed revealing three distinct stages that range from fully elastic through elastic-plastic to fully plastic contact interface. Several factors of sliding friction model are discussed: surface roughness, mechanical properties and contact load and areas that have strong effect on the friction force. The critical interference that marks the transition from elastic to elastic- plastic and plastic deformation is found out and its connection with plasticity index. A finite element program for determination contact analysis of the assembled details and due to details of deformation that arose a normal and tangencial stress is used.

scholarly journals Coatings with recycled polyvinyl butyral on polyester and polyamide mono- and multifilament yarns

2021 ◽  
Author(s):  
Rike Brendgen ◽  
Carsten Graßmann ◽  
Thomas Grethe ◽  
Boris Mahltig ◽  
Anne Schwarz-Pfeiffer
Keyword(s):  
Mechanical Properties ◽  
Chemical Resistance ◽  
Crosslinking Agent ◽  
Polyvinyl Butyral ◽  
Polymer Dispersion ◽  
Safety Glass ◽  
Enhanced Properties ◽  
Multifilament Yarns ◽  
Textile Coating ◽  
Recycled Material

AbstractPolyvinyl butyral is used in safety glass interlayers, mainly in car windshields. Legislative regulations require a recycling of cars after their lifetime and therefore also their safety glass. This causes the availability of recycled polyvinyl butyrate (r-PVB) originated from safety glass interlayers. Due to deteriorated optical properties, such as the transparency, and unknown amounts of plasticizers, it is challenging to reuse the recycled material in new windshields. Therefore, it is of particular interest to find new fields of application for r-PVB, such as the usage as a textile coating. In this research, r-PVB was investigated as a material for yarn coating. Polyester and polyamide mono- and multifilament yarns were coated continuously with solely a polymer dispersion and with mixtures of crosslinking agent and polymer dispersion. Crosslinked r-PVB coatings showed enhanced properties toward abrasion and chemical resistance. Coatings without the crosslinking agent showed a diminished abrasion resistance and could be washed off with ethanol. Mechanical properties of the monofilaments were influenced by the r-PVB coating in general. However, varying concentrations of the crosslinking agent did not affect the mechanical properties.

scholarly journals Enhancement of Chloroprene/Natural/Butadiene Rubber Nanocomposite Properties Using Organoclays and Their Combination with Carbon Black as Fillers

Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1085
Author(s):  
Patricia Castaño-Rivera ◽  
Isabel Calle-Holguín ◽  
Johanna Castaño ◽  
Gustavo Cabrera-Barjas ◽  
Karen Galvez-Garrido ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Carbon Black ◽  
High Performance ◽  
Rubber Matrix ◽  
Butadiene Rubber ◽  
X Ray Diffraction ◽  
X Ray ◽  
Rubber Blends ◽  
Ft Ir ◽  
Chloroprene Rubber

Organoclay nanoparticles (Cloisite® C10A, Cloisite® C15) and their combination with carbon black (N330) were studied as fillers in chloroprene/natural/butadiene rubber blends to prepare nanocomposites. The effect of filler type and load on the physical mechanical properties of nanocomposites was determined and correlated with its structure, compatibility and cure properties using Fourier Transformed Infrared (FT-IR), X-ray Diffraction (XRD), Thermogravimetric Analysis (TGA) and rheometric analysis. Physical mechanical properties were improved by organoclays at 5–7 phr. Nanocomposites with organoclays exhibited a remarkable increase up to 46% in abrasion resistance. The improvement in properties was attributed to good organoclay dispersion in the rubber matrix and to the compatibility between them and the chloroprene rubber. Carbon black at a 40 phr load was not the optimal concentration to interact with organoclays. The present study confirmed that organoclays can be a reinforcing filler for high performance applications in rubber nanocomposites.

scholarly journals Effects of Various Types of Expandable Graphite and Blackcurrant Pomace on the Properties of Viscoelastic Polyurethane Foams

Materials ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1801
Author(s):  
Rafał Oliwa ◽  
Joanna Ryszkowska ◽  
Mariusz Oleksy ◽  
Monika Auguścik-Królikowska ◽  
Małgorzata Gzik ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Chemical Structure ◽  
Oxygen Index ◽  
Polyurethane Foams ◽  
Expandable Graphite ◽  
Ftir Analysis ◽  
Limiting Oxygen Index ◽  
Peak Heat Release Rate ◽  
Physical And Chemical ◽  
Scanning Electron

We investigated the effect of the type and amount of expandable graphite (EG) and blackcurrant pomace (BCP) on the flammability, thermal stability, mechanical properties, physical, and chemical structure of viscoelastic polyurethane foams (VEF). For this purpose, the polyurethane foams containing EG, BCP, and EG with BCP were obtained. The content of EG varied in the range of 3–15 per hundred polyols (php), while the BCP content was 30 php. Based on the obtained results, it was found that the additional introduction of BCPs into EG-containing composites allows for an additive effect in improving the functional properties of viscoelastic polyurethane foams. As a result, the composite containing 30 php of BCP and 15 php of EG with the largest particle size and expanded volume shows the largest change in the studied parameters (hardness (H) = 2.65 kPa (+16.2%), limiting oxygen index (LOI) = 26% (+44.4%), and peak heat release rate (pHRR) = 15.5 kW/m2 (−87.4%)). In addition, this composite was characterized by the highest char yield (m600 = 17.9% (+44.1%)). In turn, the change in mechanical properties is related to a change in the physical and chemical structure of the foams as indicated by scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) analysis.

scholarly journals Composite Material of PDMS with Interchangeable Transmittance: Study of Optical, Mechanical Properties and Wettability

2021 ◽  
Vol 5 (4) ◽  
pp. 110
Author(s):  
Flaminio Sales ◽  
Andrews Souza ◽  
Ronaldo Ariati ◽  
Verônica Noronha ◽  
Elder Giovanetti ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Experimental Study ◽  
Room Temperature ◽  
Casting Process ◽  
Optical Characteristics ◽  
Smart Devices ◽  
Superhydrophobic Coating ◽  
Gravity Casting ◽  
High Flexibility ◽  
Physical And Chemical

Polydimethylsiloxane (PDMS) is a polymer that has attracted the attention of researchers due to its unique properties such as transparency, biocompatibility, high flexibility, and physical and chemical stability. In addition, PDMS modification and combination with other materials can expand its range of applications. For instance, the ability to perform superhydrophobic coating allows for the manufacture of lenses. However, many of these processes are complex and expensive. One of the most promising modifications, which consists of the development of an interchangeable coating, capable of changing its optical characteristics according to some stimuli, has been underexplored. Thus, we report an experimental study of the mechanical and optical properties and wettability of pure PDMS and of two PDMS composites with the addition of 1% paraffin or beeswax using a gravity casting process. The composites’ tensile strength and hardness were lower when compared with pure PDMS. However, the contact angle was increased, reaching the highest values when using the paraffin additive. Additionally, these composites have shown interesting results for the spectrophotometry tests, i.e., the material changed its optical characteristics when heated, going from opaque at room temperature to transparent, with transmittance around 75%, at 70 °C. As a result, these materials have great potential for use in smart devices, such as sensors, due to its ability to change its transparency at high temperatures.

scholarly journals Influence of a Natural Plant Antioxidant on the Ageing Process of Ethylene-norbornene Copolymer (Topas)

2021 ◽  
Vol 22 (8) ◽  
pp. 4018
Author(s):  
Anna Masek ◽  
Angelika Plota
Keyword(s):  
Mechanical Properties ◽  
Food Packaging ◽  
Colour Change ◽  
Good Alternative ◽  
Plant Origin ◽  
Aging Behavior ◽  
Current State ◽  
Ft Ir ◽  
Potential Use

In the field of polymer technology, a variety of mainly synthetic additives are used to stabilize the materials during processing. However, natural compounds of plant origin can be a green alternative to chemicals such as synthetic polyphenols. An analysis of the effect of hesperidin on the aging behavior of ethylene-norbornene copolymer was performed. The evaluation of changes in the tested samples was possible by applying the following tests: determination of the surface energy and OIT values, mechanical properties analysis, colour change measurements, FT-IR and TGA analyses. The obtained results proved that hesperidin can be effectively used as natural stabilizer for polymers. Furthermore, as a result of this compound addition to Topas-silica composites, their surface and physico-mechanical properties have been improved and the resistance to aging significantly increased. Additionally, hesperidin can act as a dye or colour indicator and only few scientific reports describe a possibility of using flavonoids to detect changes in products during their service life, e.g., in food packaging. In the available literature, there is no information about the potential use of hesperidin as a stabilizer for cycloolefin copolymers. Therefore, this approach may contribute not only to the current state of knowledge, but also presents an eco-friendly solution that can be a good alternative to synthetic stabilizers.

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