scholarly journals Selected Critical Raw Materials in Waste from Coal Gasification in Poland

Energies ◽  
2021 ◽  
Vol 14 (23) ◽  
pp. 8071
Author(s):  
Barbara Bielowicz

In an effort to identify new sources of critical raw materials (CRMs) possibility of recovering selected CRMs from Polish coals, chars, and ashes resulting from the combustion of coals and chars was investigated. The samples were collected from pilot fluidized bed gasification systems. The search for CRMs in coal gasification wastes has not been widely reported before. The study used 2 bituminous coal and 1 lignite sample; the concentration of individual critical raw materials (CRMs) was analyzed using the ICP-MS method. The obtained results were compared with Clarke values in coal ash and in the Earth’s crust, and with the adopted cut-off grade. As shown by the analysis, the highest concentrations of CRMs can be found in fly ash, mainly in samples from the eastern part of the Upper Silesian Coal Basin. This applies mostly to Be, Cs, or Sb due to the fact that their concentrations were found to be higher than the Clarke value in the Earth’s crust; the mentioned fly ashes could be used as potential sources of critical elements if appropriate recovery technologies are developed. In addition, the tested materials have elevated Se, Pb, Ni concentrations, but their recovery is currently not economically viable. Compared to the currently adopted cut-off grade levels, there are no critical elements in the analyzed coal gasification waste that could be recovered.

Resources ◽  
2020 ◽  
Vol 9 (9) ◽  
pp. 115
Author(s):  
Barbara Bielowicz

The chemical composition of coal ash and the content of the critical elements Ga, Sc, and V in coal and ash are examined herein. In this study, lignite and bituminous coal from Polish deposits were used. The coals were subjected to ultimate and proximate analysis; the petrographic composition was determined based on maceral groups. The chemical composition of ash and the content of critical elements were determined using ICP-MS. The obtained results were correlated and Pearson’s linear correlation coefficient was determined. Based on the correlation analysis, the relationship between the chemical composition of ash and the proximate and ultimate analyses was demonstrated. The content of selected critical elements in the tested deposits was lower than the Clarke value in coal. However, in some deposits these contents are much higher in coal ashes. The higher levels of Ga, V, and Sc in the ash are associated with Al2O3. Therefore, it can be stated that ashes can be a potential source of some raw materials. The highest concentrations of critical elements in coal and ash were recorded in the Lublin Coal Basin. Supra-Clarke contents of Ga, V, and Sc were recorded in the Bogdanka coal mine.


2017 ◽  
Vol 68 ◽  
pp. 534-546 ◽  
Author(s):  
Sandra R. Mueller ◽  
Patrick A. Wäger ◽  
David A. Turner ◽  
Peter J. Shaw ◽  
Ian D. Williams

Minerals ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 975
Author(s):  
Slobodan Radusinović ◽  
Argyrios Papadopoulos

Research for critical raw materials is of special interest, due to their increasing demand, opulence of applications and shortage of supply. Bauxites, or bauxite residue after alumina extraction can be sources of critical raw materials (CRMs) due to their content of rare earth elements and other critical elements. Montenegrin bauxites and bauxite residue (red mud) are investigated for their mineralogy and geochemistry. The study of the CRM’s potential of the Montenegrin bauxite residue after the application of Bayer process, is performed for the first time. Montenegrin bauxites, (Jurassic bauxites from the Vojnik-Maganik and Prekornica ore regions from the Early Jurassic, Middle Jurassic-Oxfordian and Late Triassic paleorelief) are promising for their REE’s content (around 1000 ppm of ΣREE’s). More specifically, they are especially enriched in LREEs compared to HREEs. Regarding other CRMs and other elements, Ti, V, Zr, Nb, Sr and Ga could also be promising. In bauxite residue, the contents of Zr, Sr, V, Sc, La, Ce, Y, Ti and Nb are higher than those in bauxites. However, raw bauxites and bauxite residue as a secondary raw material can be considered as possible sources of CRMs.


Materials ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1656
Author(s):  
Maria Luisa Grilli ◽  
Daniele Valerini ◽  
Anca Elena Slobozeanu ◽  
Bogdan O. Postolnyi ◽  
Sebastian Balos ◽  
...  

Several applications where extreme conditions occur require the use of alloys often containing many critical elements. Due to the ever increasing prices of critical raw materials (CRMs) linked to their high supply risk, and because of their fundamental and large utilization in high tech products and applications, it is extremely important to find viable solutions to save CRMs usage. Apart from increasing processes’ efficiency, substitution, and recycling, one of the alternatives to preserve an alloy and increase its operating lifetime, thus saving the CRMs needed for its manufacturing, is to protect it by a suitable coating or a surface treatment. This review presents the most recent trends in coatings for application in high temperature alloys for aerospace engines. CRMs’ current and future saving scenarios in the alloys and coatings for the aerospace engine are also discussed. The overarching aim of this paper is to raise awareness on the CRMs issue related to the alloys and coating for aerospace, suggesting some mitigation measures without having the ambition nor to give a complete overview of the topic nor a turnkey solution.


2020 ◽  
Vol 7 ◽  
pp. 22
Author(s):  
Silviya Boycheva ◽  
Denitza Zgureva ◽  
Hristina Lazarova ◽  
Katerina Lazarova ◽  
Cyril Popov ◽  
...  

High-grade zeolite nanocomposites are synthesized utilizing solid by-products from combustion of coal for energy production in Thermal Power Plants applying alkaline aging, hydrothermal and fusion-hydrothermal activation procedures. The obtained coal ash zeolites were studied with respect to their chemical and phase composition, morphology, surface parameters and thermal properties. It was found that they are distinguished in nanocrystalline morphology and significant content of iron oxide nanoparticles (γ-Fe2O3, α-Fe2O3, γ-Fe3O4) and doping elements (Cu, Co, Mn, V, W, etc.) transferred from the raw coal ash, and therefore they are assumed as nanocomposites. Coal fly ash zeolite nanocomposites are characterized by a mixed micro-mesoporous texture, significant concentration of acidic Brønsted centers due to their high surface insaturation, high chemical and thermal stabilty. This unique combination of compositional and textural properties predetermines the application of these materials as catalysts for thermal oxidation processes, anticorrosion barrier coatings, carbon capture adsorbents, matrices for hosting functional groups, detergents etc. Examples for coal fly ash zeolite applications for substitution of critical raw materials in practice are provided.


Mineralogia ◽  
2016 ◽  
Vol 47 (1-4) ◽  
pp. 15-28 ◽  
Author(s):  
Monika Kasina ◽  
Marek Michalik

Abstract The recovery of valuable metals from metallurgical slag disposals is a promising option to protect natural resources, limited due to technology development and increased consumption. The Ad-hoc Working Group on Defining Critical Raw Materials within the Raw Materials Supply Group has proposed a list of critical elements which have the greatest economic importance and meet the requirements of sustainable development in Europe. The goal of this study was to examine steelmaking- and blast-furnace slags from metallurgical processes to determine concentrations of elements of the greatest criticality for Poland, e.g. Nb, Ta and REE, and to discuss the viability of their recovery. Slag analyses indicate enrichment of REE relative to UCC, NASC and average chondrite compositions in blast-furnace slags and Nb and Ta in steelmaking slags. To make recovery of these critical elements reasonable and profitable, it is recommended that they be recovered together with other useful raw materials.


Minerals ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 814
Author(s):  
Thomas N. Kerestedjian

The raw materials obtained from the Earth’s crust (Geomaterials) are of fundamental importance for a wide range of industries [...]


2021 ◽  
Vol 82 (3) ◽  
pp. 153-155
Author(s):  
Valcana Stoyanova ◽  
Atanas Hikov ◽  
Elitsa Stefanova ◽  
Zlatka Milakovska ◽  
Tomasz Abramowski ◽  
...  

The renewed importance of polymetallic nodules in the context of forecasted increasing demands for metals are discussed. Based on the Interoceanmetal Joint Organization’s (IOM) site-specific data obtained during the exploration activity in the Clarion-Clipperton Fracture Zone, a total of 272.5 Mt of nodules were estimated as economically reasonable for future mining for Ni, Cu, Co, and Mn. Additionally, data for REE and other critical elements in nodules as potential by-products are presented.


Author(s):  
Fathi Habashi

Aluminum comprises 8% of the earth’s crust and is the most abundant structural metal. Its production has surpassed that of copper and approaches that of iron. This article is a review of all aspects of the production of aluminum including: the raw materials from which it derived, production of aluminum from bauxite, electrolytic reduction of aluminum oxide, purification and refining, and environmental aspects of production processes.


Author(s):  
G.V. Artemenko ◽  
◽  
L.V. Shumlyanskyy ◽  
S.A. Wilde ◽  
M.J. Whitehouse ◽  
...  

The U-Pb age of zircon populations from metadacite of the Huliaipole Suite was determined using the LA-ICP-MS method as 3085-2850 and 3700-3360 Ma. In addition, two crystals of zircon were discovered with an age of more than 3800 Ma. According to geological and geochronological data, the Huliaipole Block, 30 × 50 km in size, is composed of rocks and relicts of the Hadean, Archean, and Palaeoproterozoic eons. The oldest nucleus of the Azov Domain was probably formed from 3.97 to 3.3 Ga ago. In the Mesoarchean (3.2-3.0 Ga), it became a part of the Middle Dnieper-Azov-Kursk granite-greenstone terrane. Felsic and intermediate volcanics of the Huliaipole Suite could have formed due to the melting of the sialic crust, including rocks of the Hadean and Archean age, as a result of the underplating of basic melts during the formation of the Neoarchean to Paleoproterozoic rift structures.


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