scholarly journals Compatibilization of Starch/Synthetic Biodegradable Polymer Blends for Packaging Applications: A Review

2021 ◽  
Vol 5 (11) ◽  
pp. 300
Author(s):  
O. H. P. Gunawardene ◽  
Chamila A. Gunathilake ◽  
A. P. S. M. Amaraweera ◽  
N. M. L. Fernando ◽  
W. M. D. B. Wanninayaka ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Polymer Blends ◽  
Biodegradable Polymer ◽  
Barrier Properties ◽  
Particle Sizes ◽  
Extensive Discussion ◽  
Hydrophobic Polymers ◽  
Plastic Materials ◽  
Homogeneous Structures ◽  
Water Resistivity

The health and environmental concerns of the usage of non-biodegradable plastics have driven efforts to explore replacing them with renewable polymers. Although starch is a vital renewable polymer, poor water resistivity and thermo-mechanical properties have limited its applications. Recently, starch/synthetic biodegradable polymer blends have captured greater attention to replace inert plastic materials; the question of ‘immiscibility’ arises during the blend preparation due to the mixing of hydrophilic starch with hydrophobic polymers. The immiscibility issue between starch and synthetic polymers impacts the water absorption, thermo-mechanical properties, and chemical stability demanded by various engineering applications. Numerous studies have been carried out to eliminate the immiscibility issues of the different components in the polymer blends while enhancing the thermo-mechanical properties. Incorporating compatibilizers into the blend mixtures has significantly reduced the particle sizes of the dispersed phase while improving the interfacial adhesion between the starch and synthetic biodegradable polymer, leading to fine and homogeneous structures. Thus, Significant improvements in thermo-mechanical and barrier properties and water resistance can be observed in the compatibilized blends. This review provides an extensive discussion on the compatibilization processes of starch and petroleum-based polymer blends.

scholarly journals Recycling of a Biodegradable Polymer Blend

Polymers ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 2297
Author(s):  
Francesco Paolo La Mantia ◽  
Luigi Botta ◽  
Maria Chiara Mistretta ◽  
Antonino Di Fiore ◽  
Vincenzo Titone
Keyword(s):  
Mechanical Properties ◽  
Thermal Properties ◽  
Biodegradable Polymer ◽  
Mechanical And Thermal Properties ◽  
Mechanical Recycling ◽  
Final Performance ◽  
Plastic Materials ◽  
Dry And Wet Conditions ◽  
Recycled Material

Mechanical recycling is one of the possible ways to enhance the value of postconsumer plastic materials. However, the final performance of the recycled material will strongly depend on the quality of the selection made on the recycled product and on the degradation of the properties. In this context, the present study examines the effect of reprocessing for five successive extrusion cycles on the rheological, mechanical and thermal properties of a poly(butylene adipate-co-terephthalate) (PBAT)-based blend on samples reprocessed in both dry and wet conditions. The results showed that when the sample was processed after drying, degradation of the material was less than when it was processed in wet conditions. However, the experimental results showed that the decrease of rheological and mechanical properties was not so dramatic, and therefore the material could be reused in both cases.

Enhancing the Mechanical Properties of Biodegradable Polymer Blends Using Tubular Nanoparticle Stitching of the Interfaces

2016 ◽  
Vol 8 (27) ◽  
pp. 17565-17573 ◽  
Author(s):  
Yichen Guo ◽  
Shan He ◽  
Kai Yang ◽  
Yuan Xue ◽  
Xianghao Zuo ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Polymer Blends ◽  
Biodegradable Polymer

Effects of particle sizes, wood to cement ratio and chemical additives on the properties of sesendok (Endospermum Diadenum) cement-bonded particleboard

2010 ◽  
Vol 7 (2) ◽  
pp. 57
Author(s):  
Jamaludin Kasim ◽  
Shaikh Abdul Karim Yamani ◽  
Ahmad Firdaus Mat Hedzir ◽  
Ahmad Syafiq Badrul Hisham ◽  
Mohd Arif Fikri Mohamad Adnan
Keyword(s):  
Mechanical Properties ◽  
Experimental Investigation ◽  
Cement Content ◽  
Particle Sizes ◽  
Thickness Swelling ◽  
Chemical Additives ◽  
Board Density ◽  
Cement Ratio ◽  
Aluminium Silicate ◽  
Cement Board

An experimental investigation was performed to evaluate the properties of cement-bonded particleboard made from Sesendok wood. The target board density was set at a standard 1200 kg m". The effect offarticle size, wood to cement ratio and the addition ofsodium silicate and aluminium silicate on the wood cement board properties has been evaluated. A change ofparticle size from 1.0 mm to 2.0 mm has a significant effect on the mechanical properties, however the physical properties deteriorate. Increasing the wood to cement ratio from 1:2.25 to 1:3 decreases the modulus ofrupture (MOR) by 11% and the addition ofsodium silicate improves valuesfurther by about 28% compared to the addition ofaluminum silicate. The modulus ofelasticity (MOE) in general increases with increasing cement content, but is not significantly affected by the addition ofsodium silicate or aluminium silicate, although the addition of their mixture (sodium silicate andaluminium silicate) consistentlyyields greater MOE values. Water absorption and thickness swelling is significantly affected by the inclusion ofadditives and better values are attained using higher wood to cement ratios.

Possibilities of using biodegradable polymeric materials in the agricultural sector

2020 ◽  
Vol 67 (2) ◽  
pp. 115-120
Author(s):  
Raisa A. Alekhina ◽  
Victoriya E. Slavkina ◽  
Yuliya A. Lopatina
Keyword(s):  
Mechanical Properties ◽  
Biodegradable Polymers ◽  
Biodegradable Polymer ◽  
Agricultural Sector ◽  
Polymeric Materials ◽  
Polymer Materials ◽  
Limiting Factors ◽  
Research Purpose ◽  
Biodegradable Materials ◽  
Advantages And Disadvantages

The article presents options for recycling polymers. The use of biodegradable materials is promising. This is a special class of polymers that can decompose under aerobic or anaerobic conditions under the action of microorganisms or enzymes forming natural products such as carbon dioxide, nitrogen, water, biomass, and inorganic salts. (Research purpose) The research purpose is in reviewing biodegradable materials that can be used for the manufacture of products used in agriculture. (Materials and methods) The study are based on open information sources containing information about biodegradable materials. Research methods are collecting, studying and comparative analysis of information. (Results and discussion) The article presents the advantages and disadvantages of biodegradable materials, mechanical properties of the main groups of biodegradable polymers. The article provides a summary list of agricultural products that can be made from biodegradable polymer materials. It was found that products from the general group are widely used in agriculture. Authors have found that products from a special group can only be made from biodegradable polymers with a controlled decomposition period in the soil, their use contributes to increasing the productivity of crops. (Conclusions) It was found that biodegradable polymer materials, along with environmental safety, have mechanical properties that allow them producing products that do not carry significant loads during operation. We have shown that the creation of responsible products (machine parts) from biodegradable polymers requires an increase in their strength properties, which is achievable by creating composites based on them. It was found that the technological complexity of their manufacture and high cost are the limiting factors for the widespread use of biodegradable polymers at this stage.

scholarly journals Experimental Analysis of the Mechanical Properties and Resistivity of Tectonic Coal Samples with Different Particle Sizes

Energies ◽  
2021 ◽  
Vol 14 (8) ◽  
pp. 2303
Author(s):  
Congyu Zhong ◽  
Liwen Cao ◽  
Jishi Geng ◽  
Zhihao Jiang ◽  
Shuai Zhang
Keyword(s):  
Mechanical Properties ◽  
Particle Size ◽  
Compressive Strength ◽  
Elastic Modulus ◽  
Uniaxial Compressive Strength ◽  
Coalbed Methane ◽  
Coal Sample ◽  
Fine Particles ◽  
Particle Sizes ◽  
Tectonic Coal

Because of its weak cementation and abundant pores and cracks, it is difficult to obtain suitable samples of tectonic coal to test its mechanical properties. Therefore, the research and development of coalbed methane drilling and mining technology are restricted. In this study, tectonic coal samples are remodeled with different particle sizes to test the mechanical parameters and loading resistivity. The research results show that the particle size and gradation of tectonic coal significantly impact its uniaxial compressive strength and elastic modulus and affect changes in resistivity. As the converted particle size increases, the uniaxial compressive strength and elastic modulus decrease first and then tend to remain unchanged. The strength of the single-particle gradation coal sample decreases from 0.867 to 0.433 MPa and the elastic modulus decreases from 59.28 to 41.63 MPa with increasing particle size. The change in resistivity of the coal sample increases with increasing particle size, and the degree of resistivity variation decreases during the coal sample failure stage. In composite-particle gradation, the proportion of fine particles in the tectonic coal sample increases from 33% to 80%. Its strength and elastic modulus increase from 0.996 to 1.31 MPa and 83.96 to 125.4 MPa, respectively, and the resistivity change degree decreases. The proportion of medium particles or coarse particles increases, and the sample strength, elastic modulus, and resistivity changes all decrease.

scholarly journals Controlling the Thermal Stability of Kyanite-Based Refractory Geopolymers

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2903
Author(s):  
Juvenal Giogetti Nemaleu Deutou ◽  
Rodrigue Cyriaque Kaze ◽  
Elie Kamseu ◽  
Vincenzo M. Sglavo
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
High Strength ◽  
Treatment Temperature ◽  
Strength Development ◽  
Particle Sizes ◽  
Cold Setting ◽  
Thermal Stability Of ◽  
Geopolymer Composites ◽  
Refractory Composites

The present project investigated the thermal stability of cold-setting refractory composites under high-temperature cycles. The proposed route dealt with the feasibility of using fillers with different particle sizes and studying their influence on the thermo-mechanical properties of refractory geopolymer composites. The volumetric shrinkage was studied with respect to particle sizes of fillers (80, 200 and 500 µm), treatment temperature (1050–1250 °C) and amount of fillers (70–85 wt.%). The results, combined with thermal analysis, indicated the efficiency of refractory-based kyanite aggregates for enhancing thermo-mechanical properties. At low temperatures, larger amounts of kyanite aggregates promoted mechanical strength development. Flexural strengths of 45, 42 and 40 MPa were obtained for geopolymer samples, respectively, at 1200 °C, made with filler particles sieved at 80, 200 and 500 µm. In addition, a sintering temperature equal to 1200 °C appeared beneficial for the promotion of densification as well as bonding between kyanite aggregates and the matrix, contributing to the reinforcement of the refractory geopolymer composites without any sign of vitrification. From the obtained properties of thermal stability, good densification and high strength, kyanite aggregates are efficient and promising candidates for the production of environmentally friendly, castable refractory composites.

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