scholarly journals Phase Formation andWear Resistance of Carbon-Doped TiZrN Nanocomposite Coatings by Laser Carburization

Metals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 590
Author(s):  
Seonghoon Kim ◽  
Taewoo Kim ◽  
Eunpyo Hong ◽  
Ilguk Jo ◽  
Jaeyoung Kim ◽  
...  

Carbon-doped TiZrN nanocomposite coatings were investigated for phase formation and wear behavior. They were prepared by laser carburization using carbon paste, and the thermal energy of the pulsed laser was limited to the range of 20 to 50%. X-ray photoelectron spectroscopy analysis revealed that the ratio of carbide (TiC, ZrC) increased as the thermal energy of the laser increased. The sp2/sp3 ratio increased by approximately 16% when the laser thermal energy was raised from 30 to 40%, and the formation of amorphous carbon was confirmed in the carbon-doped TiZrN coatings. As a result of microstructural analysis, the carbon-doped TiZrN nanocomposite was formed by an increase of hybrid bonds in expanded localized carbon clusters. Wear resistance was evaluated using a ball-on-disc tester, which showed that the friction coefficient decreased from 0.74 to 0.11 and the wear rate decreased from 7.63 × 10−6 mm3 (Nm)−1 to 1.26 × 10−6 mm3 (Nm)−1. In particular, the friction coefficient and wear rate improved by 71 and 66%, respectively, owing to the formation of carbon-doped TiZrN nanocomposite with amorphous carbon while the thermal energy was increased from 30 to 40%.

2020 ◽  
Vol 1002 ◽  
pp. 151-160 ◽  
Author(s):  
Anmar D. Mahdi ◽  
Saif S. Irhayyim ◽  
Salah F. Abduljabbar

Al7075 hybrid nanocomposites considered one of the most material utilized in modern engineering applications that required a combination of superior properties such as lightweight, high strength, excellent corrosion resistance, and high thermal conductivity. In the current study, Al7075 – 5 vol % graphite self-lubricating composite was reinforced by 0, 1.5, 2.5, 3.5, and 4.5 vol % WO3 nanoparticles in order to study the microstructural, mechanical, and wear characteristics. The classical powder metallurgy route was employed to fabricate the hybrid nanocomposites specimens. The microstructural analysis of the nanocomposites was characterized by utilizing a Field Emission Scanning Electron Microscope (FESEM) and Energy-Dispersive X-ray (EDX) analyses. Mechanical properties such as micro-hardness and diametral compressive strength were studied. Dry sliding wear test was performed under the various loads of 10, 15, 20, and 25 N at a sliding distance and sliding speed of 1810 m and 1.5 m/s, respectively. Results have revealed that the microhardness and diametral compressive strength considerably improved by increasing the WO3 content until 3.5 vol % and then slightly decreased. Besides, both the values of the wear rate and friction coefficient gradually reduced by increment the reinforcement content up to 3.5 vol % and then suddenly increases for all the applied loads. Nevertheless, the wear rate and friction coefficient were correlated positively with the applied loads. From the results obtained, graphite as solid lubricating material with WO3 nanoparticles was successfully combined into the Al7075 alloy matrix. The optimum mechanical and wear performance of the hybrid nanocomposite were revealed at 3.5 vol % content of WO3 nanoparticles.


2018 ◽  
Vol 55 (1) ◽  
pp. 102-110 ◽  
Author(s):  
Marian Bastiurea ◽  
Dumitru Dima ◽  
Gabriel Andrei

Graphene oxide and graphite filled polyester composites were prepared by using conventional melt-mixing methods in order to improve tribological performance of polyester. It was investigated friction stability, microhardness, friction coefficient, and specific wear rate of the composites in details. It was found that the presence of graphite and graphene oxide influenced friction coefficient and wear rate of the composites. Graphene oxide decreased wear rate with increasing of test speed and graphite decreased wear rate for composite for all speeds. Tribological performance of the polyester/graphene composites is mainly attributed to bigger thermal conductivity for graphene, which can easily dissipate the heat which appears during the friction process at bigger forces. The positive influence of graphite on coefficient of friction (COF) of the composites is the result of the clivage of graphite layers during the loadings due to van der Waals weak bonds between the graphite layers.


2016 ◽  
Vol 844 ◽  
pp. 133-140 ◽  
Author(s):  
Mariya R. Komissarova ◽  
Ilia G. Dyakov ◽  
Yurii P. Gladii

Microhardness, friction coefficient, and wear rate of carburized titanium alloy VT 20 are considered. An X-ray diffractometer, a scanning electron microscopy (SEM) used to characterize the phase composition of the modified layer and its surface morphology. A pin-on-disc tribometer was occupied to evaluate wear behavior of the treated titanium alloys. It is established that the friction coefficient decreases from 0.46 (untreated sample) to 0.15 for the sample carburized at 750 °C during 5 min. Therefore, the anode carburizing of titanium alloys results in the reducing of the wear rate by 2 orders.


2019 ◽  
Vol 142 (2) ◽  
Author(s):  
Kunal Ghosh ◽  
Subhrojyoti Mazumder ◽  
Bipin Kumar Singh ◽  
Harish Hirani ◽  
Poulomi Roy ◽  
...  

Abstract Three mol% yttria-stabilized tetragonal zirconia polycrystals (3Y-TZP) with 0.5 wt% of magnesium oxide (MgO) and 6 wt% of molybdenum (Mo) were prepared by the pressureless sintering process, and the friction and wear behavior of the ceramic composite were studied against the alumina disc. Tribological tests were carried out both at room temperature as well as at an elevated temperature (500 °C). The result revealed that a substantial reduction of ∼50% in the friction coefficient and ∼31% reduction in the wear rate were achieved while 6 wt% Mo was added into the 3Y-TZP matrix operational at 500 °C. No significant tribological influence was observed with the addition of Mo at the normal operating temperature. The minimum coefficient of friction and low specific wear rate were achieved because of the formation of MoO3 in between the mating surfaces at elevated temperature. The worn surfaces were characterized by means of field emission scanning electron microscopy (FESEM). The formation of MoO3 phases was identified by wear debris analysis which was performed with the help of X-ray photoelectron spectroscopy (XPS).


2020 ◽  
Vol 143 (2) ◽  
Author(s):  
Ashish Kumar Mishra ◽  
Ram Krishna Upadhyay ◽  
Arvind Kumar

Abstract Additive manufacturing (AM) has witnessed substantial growth in recent years due to its excellent manufacturing capabilities and innovative production methodologies. However, the mechanical suitability aspect in terms of material wear has not received much attention yet and needs rigorous assessment. This study investigates the wear anisotropy in an AlSi10Mg alloy sample fabricated by selective laser melting (SLM) technique. Different scanning strategies encompassing the island and the continuous scanning patterns were used in sample manufacturing. The effects of the scanning vector orientation, design pattern, and the island pattern size on the mechanical wear and wear anisotropy have been analyzed in detail. The study also focused upon a comparative investigation of the wear properties at the top and the side surfaces to understand the wear anisotropy in different directions. The samples are fabricated both by the fresh and the recycled powder and the role of powder state is described. The ball-on-disk test is performed to simulate the similar contact applications for marine/automotive components such as bearings. Bearing steel balls are used as a standard sliding counterpart material to investigate the wear properties. The wear microstructure is analyzed by scanning electron microscopy. Overall, the island strategy with 2 mm hatch style and 45 deg scan rotation have achieved better wear resistance and friction coefficient compared with the continuous hatch style. The wear behavior is found to be anisotropic. The Raman spectra validate the presence of silicon and carbon particles on the wear track, which have a significant effect on the tribological properties. The type of particles present in the sliding zone characterizes different wear stages. Wear mechanism is described by considering four parameters, namely, scan pattern, scan vector rotation, type of powder, and the wear measurement direction. Results show that the surface wear rate of samples made by the fresh powder is lower than the recycled powder. However, samples of the recycled powder have friction modifier characteristics. The best wear rate and friction coefficient values are obtained with the island strategy (2 mm hatch, 45 deg scan rotation) in the side plane and are 3.76 × 10−6 mm3/N m, 0.0781, respectively.


2011 ◽  
Vol 311-313 ◽  
pp. 92-95 ◽  
Author(s):  
Kui Chen ◽  
Tian Yun Zhang ◽  
Wei Wei

Polypropylene/organo-montmorillonite (PP/OMMT) composites were investigated by XRD. Friction and wear behaviors of this composites sliding against GCr15 stainless steel were examined on M-2000 text rig in a ring-on-block configuration. Worn surfaces of PP and its composites were analyzed by SEM. The result shows that PP macromolecule chains have intercalated into OMMT layers and form intercalated nanocomposites. With the increase of mass fraction of OMMT, both wear rate and friction coefficient of composites first decrease then rise. With the increase of load, from 150 N, 200 N to 250 N, wear rate of composites increases, while friction coefficient reduces. The wear mechanisms of composites are connected with the content of OMMT. Composites were dominated by adhesive wear, abrasive wear and adhesive wear accompanied by abrasive wear respectively with the increase of OMMT content.


2016 ◽  
Vol 35 (5) ◽  
pp. 487-492
Author(s):  
Ahmet Karaaslan ◽  
Alptekin Kısasöz ◽  
Ş. Hakan Atapek ◽  
Kerem Altuğ Güler

AbstractThe wear behavior of cast A7075 and A7075/SAF 2205 composite material fabricated by vacuum-assisted investment flask casting was investigated under dry sliding condition. The wear tests were carried out using a “ball-on-disc” type tribometer. In the wear tests, 100Cr6 and ZrO2 balls were used as counterparts and the load, total distance and rotating speed were selected as 10 N, 100 m and 100 rpm, respectively. The results were evaluated using the friction coefficient–distance diagram, weight loss and wear rate. All worn surfaces were examined by scanning electron microscope and wear characteristics of the materials were discussed as a function of the microstructural features. It was concluded that composite material had lower friction coefficient, less weight loss and slower wear rate than that of cast material.


2010 ◽  
Vol 431-432 ◽  
pp. 385-388 ◽  
Author(s):  
Jian Hua Zhang ◽  
Pei Qi Ge ◽  
Lei Zhang ◽  
Yang Yu ◽  
Hui Li

The grind-hardening technology utilizes the grinding heat to harden the surface of the workpiece. The friction and wear performance of the grind-hardened layer is one of the important parameters. In this paper, the friction and wear performance of the grind-hardened layer was studied by the friction and wear experiment. The wear rate and the friction coefficient of the grind-hardened steel were studied by comparing with conventional hardened steel and non-hardened steel. The surface worn morphology and the collected wear debris of the grind-hardened steel were observed during the experiment. The wear mechanism of the grind-hardened steel was analyzed under different friction conditions.


2010 ◽  
Vol 150-151 ◽  
pp. 1106-1109 ◽  
Author(s):  
Yong Kun Wang ◽  
Li Chen ◽  
Zhi Wei Xu

The glass fiber (GF) reinforced epoxy (EP) composites filled by nano-Al2O3, nano-TiO2, nano-SiO2 and multi-walled carbon nanotubes (MWCNTs) were prepared. The friction and wear behavior of composites under dry condition were evaluated with block-on-ring friction and wear tester. The morphologies of the worn surfaces of the composites were analyzed by scanning electric microscopy (SEM). The results show that 0.5 wt% MWCNTs and nano-TiO2 can significantly lower the friction coefficient and specific wear rate of composites, respectively, while 0.5 wt% nano-SiO2 and nano-Al2O3 can slightly lower the friction coefficient and specific wear rate of the composites.


2021 ◽  
Vol 1 (3) ◽  
pp. 127-134
Author(s):  
Hossein Aghajani ◽  
Mohammad Roostaei ◽  
Shaya Sharif Javaherian ◽  
Arvin Taghizadeh Tabrizi ◽  
Ali Abdoli Silabi ◽  
...  

In this paper, the copper-based nanocomposites with TiO2 nanoparticles were synthesized by the self-propagating high-temperature synthesis (SHS) process. The effect of the different amounts of excess copper, in comparison with the stoichiometric ratio (CuO:Ti ratios of 1:1, 2:1, and 3:1), on the phase formation of achieved samples was studied. A thermodynamical study showed that increasing the excess copper powder reduces the adiabatic temperature, which helps the phase formation. The maximum Brinell hardness (89) was obtained for the sample with the CuO:Ti ratio of 1:1. Finally, the wear behavior of the synthesized nanocomposites was evaluated by the pin on disk test, and the variation of friction coefficient and lost weight were measured. The friction coefficient decreased by the formation of phases and distribution of titanium oxide particles during the SHS process in the presence of the stoichiometric ratio of CuO:Ti. Therefore, the wear behavior was improved. The lowest depth of wear trace was measured 0.68 where the ratio of CuO: Ti was 1:1.


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