scholarly journals Influence of Nanoparticles on Thermal and Electrical Conductivity of Composites

Polymers ◽  
2020 ◽  
Vol 12 (4) ◽  
pp. 742 ◽  
Author(s):  
Divan Coetzee ◽  
Mohanapriya Venkataraman ◽  
Jiri Militky ◽  
Michal Petru

This review analyzes thermal and electrically conductive properties of composites and how they can be influenced by the addition of special nanoparticles. Composite functional characteristics—such as thermal and electrical conductivity, phase changes, dimensional stability, magnetization, and modulus increase—are tuned by selecting suitable nanoparticle filler material. The conductivity of composites can be related to the formation of conductive pathways as nanofiller materials form connections in the bulk of a composite matrix. With increasing use of nanomaterial containing composites and relatively little understanding of the toxicological effects thereof, adequate disposal and recyclability have become an increasing environmental concern.

Materials ◽  
2021 ◽  
Vol 14 (24) ◽  
pp. 7505
Author(s):  
Vít Černý ◽  
Grigory Yakovlev ◽  
Rostislav Drochytka ◽  
Šimon Baránek ◽  
Lenka Mészárosová ◽  
...  

Electroconductive cement-based composites are modern materials that are commonly used in many industries such as the construction industry, among others. For example, these materials can be used as sensors for monitoring changes in construction, grounding suspension, and resistance heating materials, etc. The aim of the research presented in this article is to monitor the impact of carbon particle character on cement-based electroconductive composites. Four types of graphite were analyzed. Natural and synthetic types of graphite, with different particle sizes and one with improved electrically conductive properties, were tested. For the analysis of the electrical conductivity of powder raw materials, a new methodology was developed based on the experience of working with these materials. Various types of graphite were tested in pure cement paste (80% cement, 20% graphite) as well as in a composite matrix, which consisted of cement (16.8%), a mixture of silica sand 0–4 mm (56.4%), graphite filler (20.0%) ground limestone (6.7%) and super plasticizers (0.1%). The resistivity and physical-mechanical properties of the composite material were determined. Furthermore, the resistivity of the test samples was measured with a gradual decrease in saturation. It may be concluded that graphite fillers featuring very fine particles and high specific surface are most suitable and most effective for creating electrically conductive silicate composites. The amount, shape and, in particular, the fineness of the graphite filler particles thus creates suitable conditions for the creation of an integrated internal electricity-conductive network. In the case of the use of a coarse type of graphite or purely non-conductive fillers, the presence of an electrolyte, for example, in the form of water, is necessary to achieve a low resistivity. Samples with fine types of graphite fillers achieved stable resistivity values when the sample humidity changed. The addition of graphite fillers caused a large decrease in the strength of the samples.


2021 ◽  
Vol 899 ◽  
pp. 720-725
Author(s):  
Muslim A. Mikitaev ◽  
V.A. Borisov ◽  
Ismel V. Musov ◽  
Azamat L. Slonov ◽  
Diana M. Khakulova

We have obtained polymer composites based on low-pressure polyethylene and carbon-containing fillers: carbon black, carbon nanotubes. The electrical properties of the obtained polymer composites have been investigated. Obtained polymer composites have electrically conductive properties. This article shows that the electrical properties significantly depend on the concentration, type of carbon-containing filler, as well as on temperature and voltage. It was found that containment of a certain amount of carbon-containing fillers leads to a formation of conductive paths composites, leading to the manifestation of a positive temperature coefficient in electrical resistance by the material.


2021 ◽  
Author(s):  
Zhanyu Jia ◽  
Guangyao Li ◽  
Juan Wang ◽  
shouhua Su ◽  
Jie Wen ◽  
...  

Conductivity, self-healing and moderate mechanical properties are necessary for multifunctional hydrogels which have great potential in health-monitor sensor application. However, the combination of electrical conductivity, self-healing and good mechanical properties...


Nanomaterials ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 1875
Author(s):  
Alexander Yu. Gerasimenko ◽  
Artem V. Kuksin ◽  
Yury P. Shaman ◽  
Evgeny P. Kitsyuk ◽  
Yulia O. Fedorova ◽  
...  

A technology for the formation of electrically conductive nanostructures from single-walled carbon nanotubes (SWCNT), multi-walled carbon nanotubes (MWCNT), and their hybrids with reduced graphene oxide (rGO) on Si substrate has been developed. Under the action of single pulses of laser irradiation, nanowelding of SWCNT and MWCNT nanotubes with graphene sheets was obtained. Dependences of electromagnetic wave absorption by films of short and long nanotubes with subnanometer and nanometer diameters on wavelength are calculated. It was determined from dependences that absorption maxima of various types of nanotubes are in the wavelength region of about 266 nm. It was found that contact between nanotube and graphene was formed in time up to 400 fs. Formation of networks of SWCNT/MWCNT and their hybrids with rGO at threshold energy densities of 0.3/0.5 J/cm2 is shown. With an increase in energy density above the threshold value, formation of amorphous carbon nanoinclusions on the surface of nanotubes was demonstrated. For all films, except the MWCNT film, an increase in defectiveness after laser irradiation was obtained, which is associated with appearance of C–C bonds with neighboring nanotubes or graphene sheets. CNTs played the role of bridges connecting graphene sheets. Laser-synthesized hybrid nanostructures demonstrated the highest hardness compared to pure nanotubes. Maximum hardness (52.7 GPa) was obtained for MWCNT/rGO topology. Regularity of an increase in electrical conductivity of nanostructures after laser irradiation has been established for films made of all nanomaterials. Hybrid structures of nanotubes and graphene sheets have the highest electrical conductivity compared to networks of pure nanotubes. Maximum electrical conductivity was obtained for MWCNT/rGO hybrid structure (~22.6 kS/m). Networks of nanotubes and CNT/rGO hybrids can be used to form strong electrically conductive interconnections in nanoelectronics, as well as to create components for flexible electronics and bioelectronics, including intelligent wearable devices (IWDs).


2021 ◽  
Vol 2 (1) ◽  
Author(s):  
Caroline O’Keeffe ◽  
Laura Rhian Pickard ◽  
Juan Cao ◽  
Giuliano Allegri ◽  
Ivana K. Partridge ◽  
...  

AbstractConventional carbon fibre laminates are known to be moderately electrically conductive in-plane, but have a poor through-thickness conductivity. This poses a problem for functionality aspects that are of increasing importance to industry, such as sensing, current collection, inductive/resistive heating, electromagnetic interference (EMI) shielding, etc. This restriction is of course more pronounced for non-conductive composite reinforcements such as glass, organic or natural fibres. Among various solutions to boost through-thickness electrical conductivity, tufting with hybrid micro-braided metal-carbon fibre yarns is one of the most promising. As a well-characterised method of through thickness reinforcement, tufting is easily implementable in a manufacturing environment. The hybridisation of materials in the braid promotes the resilience and integrity of yarns, while integrating metal wires opens up a wide range of multifunctional applications. Many configurations can be produced by varying braid patterns and the constituting yarns/wires. A predictive design tool is therefore necessary to select the right material configuration for the desired functional and structural performance. This paper suggests a fast and robust method for generating finite-element models of the braids, validates the prediction of micro-architecture and electrical conductivity, and demonstrates successful manufacturing of composites enhanced with braided tufts.


2019 ◽  
Vol 50 (3) ◽  
pp. 333-345 ◽  
Author(s):  
Danmei Sun ◽  
Meixuan Chen ◽  
Symon Podilchak ◽  
Apostolos Georgiadis ◽  
Qassim S Abdullahi ◽  
...  

Smart and interactive textiles have been attracted great attention in recent years. This research explored three different techniques and processes in developing textile-based conductive coils that are able to embed in a garment layer. Coils made through embroidery and screen printing have good dimensional stability, although the resistance of screen printed coil is too high due to the low conductivity of the print ink. Laser cut coil provided the best electrical conductivity; however, the disadvantage of this method is that it is very difficult to keep the completed coil to the predetermined shape and dimension. The tested results show that an electromagnetic field has been generated between the textile-based conductive coil and an external coil that is directly powered by electricity. The magnetic field and electric field worked simultaneously to complete the wireless charging process.


2008 ◽  
Vol 47-50 ◽  
pp. 714-717 ◽  
Author(s):  
Xin Lan ◽  
Jin Song Leng ◽  
Yan Ju Liu ◽  
Shan Yi Du

A new system of thermoset styrene-based shape-memory polymer (SMP) filled with carbon black (CB) is investigated. To realize the electroactive stimuli of SMP, the electrical conductivity of SMP filled with various amounts of CB is characterized. The percolation threshold of electrically conductive SMP filled with CB is about 3% (volume fraction of CB), which is much lower than many other electrically conductive polymers. When applying a voltage of 30V, the shape recovery process of SMP/CB(10 vol%) can be realized in about 100s. In addition, the thermomechanical properties are also characterized by differential scanning calorimetery (DSC).


2012 ◽  
Vol 182-183 ◽  
pp. 254-258
Author(s):  
Zhong Li Zhao ◽  
Zun Li Mo ◽  
Zhong Yu Chen

Cellulose/Ag/polyaniline conductive composite with rather excellent electrical conductivity was heterogeneously synthesized in this paper. The UV-Vis analysis indicated that homogeneous nanoAg particles deposited on the surface of cellulose in the form of globe particles. They offered some electrons to polyaniline chains. This behavior resulted to the facts that more polyaniline embedded on cellulose and an integrated electrically conductive network formed. Consequently, the high electrical conductivity of the composite was observed. The value was 3.48 S/cm, which was higher two magnitudes than the electrical conductivity of cellulose/polyaniline composite (2.15×10-2S/cm), and even was higher than the electrical conductivity of pure polyaniline (0.142 S/cm). This paper provided a facile method for the preparation of cellulose/Ag/ polyaniline composite with favorable electrical conductivity.


2021 ◽  
Vol 321 ◽  
pp. 171-176
Author(s):  
Jana Majerová ◽  
Rostislav Drochytka

The electrical conductivity of concrete can be achieved by adding steel wires or functional fillers. Commonly used fillers are nanotubes, carbon black, nickel powder and so on. These fillers are expensive, but there is a possibility to use waste materials. This is the subject of this experiment. The conductive properties of conductive sand, sludge from the wire drawing process, iron grinding dust waste and waste carbon were verified. From these fillers, waste carbon showed the best electrical properties (impedance). The impedance of the waste carbon was 0.31 Ω and the impedance of the cement composite containing 70% of the weight of waste carbon was less than 670 Ω.


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