Ionic liquid-plasticised composites of chitosan and hybrid 1D and 2D nanofillers

The focus of this research was to study the effect of combining nanofillers with different geometry and surface chemistry on the structure and properties of biopolymers as an alternative to traditional plastics. How the inclusion of 2D graphene oxide (GO) or reduced GO (rGO) combined with 1D sepiolite (SPT) or cellulose nanocrystals (CNCs) affect the structure and properties of chitosan and chitosan/carboxymethyl cellulose (CMC) materials was investigated. A 3D interconnected microstructure formed, composed of GO and SPT due to the strong interactions between these hydrophilic nanofillers. The chitosan/CMC/GO/SPT composite had the highest tensile strength (77.5 ± 1.2 MPa) and Young’s modulus (1925.9 ± 120.7 MPa). For the un-plasticised matrices, hydrophobic rGO nanosheets generally hindered the interaction of SPT or CNCs with the polysaccharides (chitosan and CMC) and consequently, composite properties were mainly determined by the rGO. However, for the chitosan matrix plasticised by 1-ethyl-3-methylimidazolium acetate ([C2mim][OAc]), rGO + CNCs or rGO + SPT disrupted polymer chain interactions more effectively than the nanofillers when added alone and resulted in the chitosan being more plasticised, as shown by increased chain mobility, ductility, and surface hydrophilicity. For the [C2mim][OAc]-plasticised chitosan/CMC matrix, the advantages of including hybrid fillers, rGO + CNCs or rGO + SPT, were also obtained, resulting in higher thermal stability and surface hydrophobicity. Graphical Abstract

The journey of polycarbonate-based composites towards suppressing electromagnetic radiation

Electronic devices’ widespread usage has led to a new form of pollution, known as electromagnetic (EM) pollution, causing serious problems like equipment malfunctioning and affecting its reliability. This review article presents a comprehensive literature survey on the various polycarbonate (PC)-based materials for electromagnetic interference (EMI) shielding applications comprising of PC-based composites, blend composites, foams, and more recently, multilayered architectures. Following the state-of-the-art literature available from the previous decade, it is apparent that the properties (conductivity, permittivity and permeability) of nanofiller/fillers and nanocomposite processing/fabrication techniques control the EMI shielding properties in PC-based materials. Researchers have explored a variety of fillers, but high aspect ratio carbonaceous nanofillers have gained significant attention. Through morphological modifications of PC composites, one can obtain a percolation threshold as low as 0.021 wt% of carbon nanotubes (CNTs). However, higher connectivity of conductive filler need not necessarily lead to high EMI shielding performance. Thus, detailed insight into the shielding mechanism is also highlighted. This review article will help researchers design PC-based materials with superior EMI shielding performance coupled with good mechanical stability. Graphical abstract

Effects of curing on emulsion cold mix asphalts and their extracted binder

This paper focuses on the physicochemical changes that happen in cold mix asphalts during curing, and more specifically, while and after transitioning to different simulated seasons. Several tests were carried out in order to better grasp the influence of the weather (temperature and humidity) on the curing of such materials. The mechanical behaviour of the mix was assessed using oedometer tests. The physicochemical evolutions of extracted binders, such as oxidation and rheology, were evaluated. The results show stiffening of the mix and ageing of the binder linked to a higher temperature and a lower humidity. A low temperature and high moisture seem to slow down these evolutions. However the binder behaviour does not explain the whole mix behaviour as the kinetics between them are not always similar. Thus other mechanisms are yet to be found and taken into account to fully understand cold mix asphalts behaviour.

Investigation of the effect of tufts contribution on the in-plane mechanical properties of flax fibre reinforced green biocomposite

Traditional laminated composites have fibres oriented only in the in-plane of the laminate due to their manufacturing process, and are therefore very susceptible to transverse cracking and delamination from out-of-plane actions. Delamination can considerably reduce the load bearing capacity of a structure hence several reinforcement solutions, based on the principle to add out-of-plane reinforcement to the 2D fabric, have been explored to enhance the delamination resistance. However, the usual textile technologies for Z-reinforcement such as weaving, knitting, stitching, z-pinning, and tufting generates perturbations that may alter the in-plane mechanical properties. Although tufting is a single needle and single thread based one side stitching (OSS) technique which can incorporate almost tension free through the thickness reinforcement in a material, various types of microstructural defects may be created during the manufacturing process and lead to a degradation of the in-plane properties of the composite. Moreover, due to awareness in environmental concerns, the development and use of eco-friendly biocomposites to replace synthetic ones has been increasing.This research work investigates the effect on in plane mechanical properties of adding through the thickness reinforcement (TTR) by tufting in a flax based composite laminate to improve the transversal strength. The glass fibre tufted laminates of 550 g/m2 flax fibre were moulded using a 38% biobased thermoset resin by vacuum bag resin transfer moulding (VBRTM). The tufted and un-tufted in-plane mechanical properties of green biocomposite were determined in tension, compression and shear in accordance with ASTM 3039, ASTM D7137 and EN ISO 14130, using universal INSTRON 1186 and MTS 20 M testing machines. The quantification of the in-plane mechanical properties established a reduction of the in plane tensile mechanical properties, due to tufting, whereas the reduction effects are marginal in compression. As expected, the glass fibre tufts strength the connection between core and skin of the composite so that the interlaminar shear strength, deduced from flexural tests with small span-to-thickness ratio, is increased. Thanks to Digital Image Correlation (DIC) performed during shear tests, an increase in interlaminar shear modulus is highlighted.

Surface functionalization of thermoset composite for infrared hybrid welding

Fusion assembly is a highly promising technique for joining thermoplastic composite to thermoset composites, enabling the use of both the most affordable composite material and process for each substructure. However, some major challenges need to be addressed such as functionalizing the thermoset composite surface through co-curing with an appropriate thermoplastic interlayer or realizing a fast and robust welding process that meets all quality and mechanical requirements. In this paper, we investigated the potential of polyetheretherketone (PEEK) and its amorphous (PEEK A) and semicristalline (PEEK SC) states as interlayer materials, co-cured onto thermoset composites. A surface preparation involving the atmospheric plasma process demonstrated that both PEEK state materials can be used as interlayer with favorable adhesion properties. The influence of the plasma treatment on surface properties and morphology was also experimentally characterized.

Impact of solar radiation on chemical structure and micromechanical properties of cellulose-based humidity-sensing material Cottonid

Renewable and environmentally responsive materials are an energy- and resource-efficient approach in terms of civil engineering applications, e.g. as so-called smart building skins. To evaluate the influence of different environmental stimuli, like humidity or solar radiation, on the long-term actuation behavior and mechanical robustness of these materials, it is necessary to precisely characterize the magnitude and range of stimuli that trigger reactions and the resulting kinetics of a material, respectively, with suitable testing equipment and techniques. The overall aim is to correlate actuation potential and mechanical properties with process- or application-oriented parameters in terms of demand-oriented stimuli-responsive element production. In this study, the impact of solar radiation as environmental trigger on the cellulose-based humidity-sensing material Cottonid, which is a promising candidate for adaptive and autonomously moving elements, was investigated. For simulating solar radiation in the lab, specimens were exposed to short-wavelength blue light as well as a standardized artificial solar irradiation (CIE Solar ID65) in long-term aging experiments. Photodegradation behavior was analyzed by Fourier-transform infrared as well as electron paramagnetic resonance spectroscopy measurements to assess changes in Cottonid’s chemical composition. Subsequently, changes in micromechanical properties on the respective specimens’ surface were investigated with roughness measurements and ultra-micro-hardness tests to characterize variations in stiffness distribution in comparison to the initial condition. Also, thermal effects during long-term aging were considered and contrasted to pure radiative effects. In addition, to investigate the influence of process-related parameters on Cottonid’s humidity-driven deformation behavior, actuation tests were performed in an alternating climate chamber using a customized specimen holder, instrumented with digital image correlation (DIC). DIC was used for precise actuation strain measurements to comparatively evaluate different influences on the material’s sorption behavior. The infrared absorbance spectra of different aging states of irradiated Cottonid indicate oxidative stress on the surface compared to unaged samples. These findings differ under pure thermal loads. EPR spectra could corroborate these findings as radicals were detected, which were attributed to oxidation processes. Instrumented actuation experiments revealed the influence of processing-related parameters on the sorption behavior of the tested and structurally optimized Cottonid variant. Experimental data supports the definition of an optimal process window for stimuli-responsive element production. Based on these results, tailor-made functional materials shall be generated in the future where stimuli-responsiveness can be adjusted through the manufacturing process.

3D printing of graphene-based polymeric nanocomposites for biomedical applications

Additive manufacturing techniques established a new paradigm in the manufacture of composite materials providing a simple solution to build complex, custom designed shapes. In the biomedical field, 3D printing enabled the production of scaffolds with patient-specific requirements, controlling product architecture and microstructure, and have been proposed to regenerate a variety of tissues such as bone, cartilage, or the nervous system. Polymers reinforced with graphene or graphene derivatives have demonstrated potential interest for applications that require electrical and mechanical properties as well as enhanced cell response, presenting increasing interest for applications in the biomedical field. The present review focuses on graphene-based polymer nanocomposites developed for additive manufacturing fabrication, provides an overview of the manufacturing techniques available to reach the different biomedical applications, and summarizes relevant results obtained with 3D printed graphene/polymer scaffolds and biosensors.

The impact of molded pulp product process on the mechanical properties of molded Bleached Chemi-Thermo-Mechanical Pulp

This study was carried out using bleached softwood Chemi-Thermo-Mechanical Pulp to evaluate the influence of Molded Pulp Products’ manufacturing process parameters on the finished products’ mechanical and hygroscopic properties. A Taguchi table was done to make 8 tests with specific process parameters such as moulds temperature, pulping time, drying time, and pressing time. The results of these tests were used to obtain an optimized manufacturing process with improved mechanical properties and a lower water uptake after sorption analysis and water immersion. The optimized process parameters allowed us to improve the Young’ Modulus after 30h immersion of 58% and a water uptake reduction of 78% with the first 8 tests done.