scholarly journals Modelling Sessile Droplet Profile Using Asymmetrical Ellipses

Processes ◽  
2021 ◽  
Vol 9 (11) ◽  
pp. 2081
Author(s):  
Du Tuan Tran ◽  
Nhat-Khuong Nguyen ◽  
Pradip Singha ◽  
Nam-Trung Nguyen ◽  
Chin Hong Ooi
Keyword(s):  
Surface Tension ◽  
Contact Angle ◽  
Liquid Droplet ◽  
Contact Angles ◽  
Critical Parameters ◽  
Contact Radius ◽  
Simulation Environment ◽  
Sessile Droplet ◽  
Elliptic Model ◽  
Modelling Approach

Modelling the profile of a liquid droplet has been a mainstream technique for researchers to study the physical properties of a liquid. This study proposes a facile modelling approach using an elliptic model to generate the profile of sessile droplets, with MATLAB as the simulation environment. The concept of the elliptic method is simple and easy to use. Only three specific points on the droplet are needed to generate the complete theoretical droplet profile along with its critical parameters such as volume, surface area, height, and contact radius. In addition, we introduced fitting coefficients to accurately determine the contact angle and surface tension of a droplet. Droplet volumes ranging from 1 to 300 µL were chosen for this investigation, with contact angles ranging from 90° to 180°. Our proposed method was also applied to images of actual water droplets with good results. This study demonstrates that the elliptic method is in excellent agreement with the Young–Laplace equation and can be used for rapid and accurate approximation of liquid droplet profiles to determine the surface tension and contact angle.

Ring-Shaped Sessile Droplet

2011 ◽  
Author(s):  
Svyatoslav S. Chugunov ◽  
Douglas L. Schulz ◽  
Iskander S. Akhatov
Keyword(s):  
Contact Angle ◽  
Liquid Droplet ◽  
Liquid Structure ◽  
Solid Substrate ◽  
Contact Angles ◽  
Equilibrium Contact Angle ◽  
Sessile Droplet ◽  
System Equilibrium ◽  
Energy Consideration ◽  
External Forces

It is recognized that small liquid droplet placed on the solid substrate forms equilibrium contact angle that can be obtained from well-known Young’s law. Previously, deviations from Young’s law were demonstrated for the droplets exposed to external fields (gravity, electric, etc) and for the droplets on non-homogeneous substrates. This work reveals that the Young’s equilibrium contact angle can be altered by geometrical reasons only. We consider a ring-shaped droplet on a solid substrate as a test structure for our discussion. We use the global energy consideration for analysis of system equilibrium for the case of freely deposited liquid with no external forces applied. The theoretical analysis shows that steady ring-shaped liquid structure on a solid substrate does exist with contact angles on both contact lines to be different from the Young’s equilibrium contact angle.

scholarly journals Dependency of Contact Angles on Three-Phase Contact Line: A Review

2021 ◽  
Vol 5 (1) ◽  
pp. 8
Author(s):  
H. Yildirim Erbil
Keyword(s):  
Contact Angle ◽  
Contact Line ◽  
Contact Angle Hysteresis ◽  
Contact Angles ◽  
Contact Radius ◽  
Phase Contact ◽  
Sessile Droplet ◽  
Line Energy ◽  
Three Phase ◽  
Tension Term

The wetted area of a sessile droplet on a practical substrate is limited by the three-phase contact line and characterized by contact angle, contact radius and drop height. Although, contact angles of droplets have been studied for more than two hundred years, there are still some unanswered questions. In the last two decades, it was experimentally proven that the advancing and receding contact angles, and the contact angle hysteresis of rough and chemically heterogeneous surfaces, are determined by interactions of the liquid and the solid at the three-phase contact line alone, and the interfacial area within the contact perimeter is irrelevant. However, confusion and misunderstanding still exist in this field regarding the relationship between contact angle and surface roughness and chemical heterogeneity. An extensive review was published on the debate for the dependence of apparent contact angles on drop contact area or the three-phase contact line in 2014. Following this old review, several new articles were published on the same subject. This article presents a review of the novel articles (mostly published after 2014 to present) on the dependency of contact angles on the three-phase contact line, after a short summary is given for this long-lasting debate. Recently, some improvements have been made; for example, a relationship of the apparent contact angle with the properties of the three-phase line was obtained by replacing the solid–vapor interfacial tension term, γSV, with a string tension term containing the edge energy, γSLV, and curvature of the triple contact line, km, terms. In addition, a novel Gibbsian thermodynamics composite system was developed for a liquid drop resting on a heterogeneous multiphase and also on a homogeneous rough solid substrate at equilibrium conditions, and this approach led to the same conclusions given above. Moreover, some publications on the line energy concept along the three-phase contact line, and on the “modified” Cassie equations were also examined in this review.

scholarly journals Influence of moisture content on the contact angle and surface tension measured on birch wood surfaces

2021 ◽  
Author(s):  
Rami Benkreif ◽  
Fatima Zohra Brahmia ◽  
Csilla Csiha
Keyword(s):  
Surface Tension ◽  
Contact Angle ◽  
Moisture Content ◽  
Solid Wood ◽  
Contact Angles ◽  
Surface Moisture ◽  
Wood Coatings ◽  
The Relationship ◽  
Wood Surfaces

AbstractSurface tension of solid wood surfaces affects the wettability and thus the adhesion of various adhesives and wood coatings. By measuring the contact angle of the wood, the surface tension can be calculated based on the Young-Dupré equation. Several publications have reported on contact angle measured with different test liquids, under different conditions. Results can only be compared if the test conditions are similar. While the roles of the drop volume, image shooting time etc., are widely recognized, the role of the wood surface moisture content (MC) is not evaluated in detail. In this study, the effect of wood moisture content on contact angle values, measured with distilled water and diiodomethane, on sanded birch (Betula pendula) surfaces was investigated, in order to find the relationship between them. With increasing MC from approximately 6% to 30%, increasing contact angle (decreasing surface tension) values were measured according to a logarithmic function. The function makes possible the calculation of contact angles that correspond to different MCs.

scholarly journals Experimental Investigation of Coal Dust Wettability Based on Surface Contact Angle

2016 ◽  
Vol 2016 ◽  
pp. 1-8 ◽  
Author(s):  
Gang Zhou ◽  
Han Qiu ◽  
Qi Zhang ◽  
Mao Xu ◽  
Jiayuan Wang ◽  
...  
Keyword(s):  
Surface Tension ◽  
Contact Angle ◽  
Specific Surface ◽  
Coal Dust ◽  
Single Point ◽  
Contact Angles ◽  
Critical Surface ◽  
Volume Percentage ◽  
Surface Areas ◽  
Specific Surface Areas

Wettability is one of the key chemical properties of coal dust, which is very important to dedusting. In this paper, the theory of liquid wetting solid was presented firstly; then, taking the gas coal of Xinglongzhuang coal mine in China as an example, by determination of critical surface tension of coal piece, it can be concluded that only when the surface tension of surfactant solution is less than 45 mN/m can the coal sample be fully wetted. Due to the effect of particle dispersity, compared with the contact angle of milled coal particle, not all the contact angles of screened coal powder with different sizes have a tendency to increase. Furthermore, by the experiments of coal samples’ specific surface areas and porosities, it can be achieved that the volume of single-point total pore decreases with the gradual decreasing of coal’s porosity, while the ultramicropores’ dispersities and multipoint BET specific surface areas increase. Besides, by a series of contact angle experiments with different surfactants, it can be found that with the increasing of porosity and the decreasing of volume percentage of ultramicropore, the contact angle tends to reduce gradually and the coal dust is much easier to get wetted.

scholarly journals Molecular Dynamics Simulation of Wetting Behavior: Contact Angle Dependency on Water Potential Models

2021 ◽  
Vol 1 (1) ◽  
pp. 10
Author(s):  
Lukman Hakim ◽  
Irsandi Dwi Oka Kurniawan ◽  
Ellya Indahyanti ◽  
Irwansyah Putra Pradana
Keyword(s):  
Molecular Dynamics ◽  
Contact Angle ◽  
Liquid Droplet ◽  
Center Of Mass ◽  
Contact Angles ◽  
Surface Wettability ◽  
Dynamics Simulation ◽  
Potential Models ◽  
Surface Hydrophilicity ◽  
Dynamics Simulations

The underlying principle of surface wettability has obtained great attentions for the development of novel functional surfaces. Molecular dynamics simulations has been widely utilized to obtain molecular-level details of surface wettability that is commonly quantified in term of contact angle of a liquid droplet on the surface. In this work, the sensitivity of contact angle calculation at various degrees of surface hydrophilicity to the adopted potential models of water: SPC/E, TIP4P, and TIP5P, is investigated. The simulation cell consists of a water droplet on a structureless surface whose hydrophilicity is modified by introducing a scaling factor to the water-surface interaction parameter. The simulation shows that the differences in contact angle described by the potential models are systematic and become more visible with the increase of the surface hydrophilicity. An alternative method to compute a contact angle based on the height of center-of-mass of the droplet is also evaluated, and the resulting contact angles are generally larger than those determined from the liquid-gas interfacial line.

Determining Micro Droplet Profile Using Internal Reflection Interference Fringes

2020 ◽  
Author(s):  
Iltai Isaac Kim ◽  
Yang Li ◽  
Jaesung Park
Keyword(s):  
Contact Angle ◽  
Liquid Droplet ◽  
Surface Profile ◽  
Morphological Features ◽  
Internal Reflection ◽  
Sessile Droplet ◽  
Spherical Droplet ◽  
Interference Fringes ◽  
The One ◽  
Air Liquid Interface

Abstract We introduce an optical diagnostics to determine the morphological features of liquid droplet such as the thickness, the contact angle, and the dual profile using internal reflection interferometry. A coherent laser beam is internally reflected on the air/liquid interface of a sessile droplet placed on a prism-based substrate to produce an interference fringe on a screen far from the substrate. The reflected laser rays consist of the reflection from the center spherical droplet profile and the one from the lower hyperbola-like droplet profile. The reflected rays are interfered each other to form the interference fringes. Ray tracing simulation is conducted using a custom-designed computer program. The simulation shows that the interfering rays reflected near the inflection point produce the outer-most fringes of the concentric interference pattern on the screen, and the reflected rays from the apex of the spherical profile and the contact line of the lower hyperbola-like profile construct the fringes at the center of the interference patterns. The simulated results are compared with the experimental observation to show a good agreement in the number and the location of the fringes and the radius of the outer-most-fringe where the number of the fringes is dependent on the droplet thickness and the radius of the fringe depends on the contact angle of the droplet. This result provides a new measurement technique to determine the morphological features of very small microdroplet such as the thickness (< a few micron thickness), the contact angle (< a few degree), and the dual-surface profile.

Investigation of Pool Boiling Critical Heat Flux Enhancement on a Modified Surface Through the Dynamic Wetting of Water Droplets

2012 ◽  
Vol 134 (7) ◽  
Author(s):  
Ho Seon Ahn ◽  
Joonwon Kim ◽  
Moo Hwan Kim
Keyword(s):  
Surface Tension ◽  
Heat Flux ◽  
Contact Angle ◽  
Critical Heat Flux ◽  
Pool Boiling ◽  
Water Layer ◽  
Contact Angles ◽  
Water Droplets ◽  
Dynamic Wetting ◽  
Modified Surface

Dynamic wetting behaviors of water droplet on the modified surface were investigated experimentally. Dynamic contact angles were measured as a characterization method to explain the extraordinary pool boiling critical heat flux (CHF) enhancement on the zirconium surface by anodic oxidation modification. The sample surface is rectangular zirconium alloy plates (20 × 25 × 0.7 mm), and 12 μl of deionized water droplets were fallen from 40 mm of height over the surface. Dynamic wetting movement of water on the surface showed different characteristics depending on static contact angle (49.3 deg–0 deg) and surface temperature (120 °C–280 °C). Compared with bare surface, wettable and spreading surface had no-receding contact angle jump and seemed stable evaporating meniscus of liquid droplet in dynamic wetting condition on hot surface. This phenomenon could be explained by the interaction between the evaporation recoil and the surface tension forces. The surface tension force increased by micro/nanostructure of the modified zirconium surface suppresses the vapor recoil force by evaporation which makes the water layer unstable on the heated surface. Thus, such increased surface force could sustain the water layer stable in pool boiling CHF condition so that the extraordinary CHF enhancement could be possible.

scholarly journals Surface, Volumetric, and Wetting Properties of Oleic, Linoleic, and Linolenic Acids with Regards to Application of Canola Oil in Diesel Engines

2019 ◽  
Vol 9 (17) ◽  
pp. 3445 ◽  
Author(s):  
Anna Zdziennicka ◽  
Katarzyna Szymczyk ◽  
Bronisław Jańczuk ◽  
Rafał Longwic ◽  
Przemysław Sander
Keyword(s):  
Surface Tension ◽  
Contact Angle ◽  
Diesel Engines ◽  
Canola Oil ◽  
Contact Angles ◽  
Physiochemical Properties ◽  
Engine Valve ◽  
Wetting Properties ◽  
Main Components ◽  
Adhesion Work

Oleic, linoleic, and linolenic acids are the main components of canola oil and their physiochemical properties decide on the use of canola oil as fuel for diesel engines. Therefore, the measurements of the surface tension of oleic, linoleic, and linolenic acids being the components of the canola oil, as well as their contact angles on the polytetrafluoroethylene (PTFE), poly(methyl methacrylate) (PMMA), and engine valve, were made. Additionally, the surface tension and contact angle on PTFE, PMMA, and the engine valve of the oleic acid and n-hexane mixtures were measured. On the basis of the obtained results, the components and parameters of oleic, linoleic, and linolenic acids’ surface tension were determined and compared to those of the canola oil. Next, applying the components and parameters of these acids, their adhesion work to PTFE, PMMA, and the engine valve was calculated by means of various methods.

scholarly journals Amphiphobic Nanostructured Coatings for Industrial Applications

Materials ◽  
2019 ◽  
Vol 12 (5) ◽  
pp. 787 ◽  
Author(s):  
Federico Veronesi ◽  
Giulio Boveri ◽  
Mariarosa Raimondo
Keyword(s):  
Surface Tension ◽  
Contact Angle ◽  
Photoelectron Spectroscopy ◽  
Contact Angle Hysteresis ◽  
Contact Angles ◽  
Friction Reduction ◽  
Hybrid Coatings ◽  
Wetting Behavior ◽  
Wide Range ◽  
Solid Liquid

The search for surfaces with non-wetting behavior towards water and low-surface tension liquids affects a wide range of industries. Surface wetting is regulated by morphological and chemical features interacting with liquid phases under different ambient conditions. Most of the approaches to the fabrication of liquid-repellent surfaces are inspired by living organisms and require the fabrication of hierarchically organized structures, coupled with low surface energy chemical composition. This paper deals with the design of amphiphobic metals (AM) and alloys by deposition of nano-oxides suspensions in alcoholic or aqueous media, coupled with perfluorinated compounds and optional infused lubricant liquids resulting in, respectively, solid–liquid–air and solid–liquid–liquid working interfaces. Nanostructured organic/inorganic hybrid coatings with contact angles against water above 170°, contact angle with n-hexadecane (surface tension γ = 27 mN/m at 20 °C) in the 140–150° range and contact angle hysteresis lower than 5° have been produced. A full characterization of surface chemistry has been undertaken by X-ray photoelectron spectroscopy (XPS) analyses, while field-emission scanning electron microscope (FE-SEM) observations allowed the estimation of coatings thicknesses (300–400 nm) and their morphological features. The durability of fabricated amphiphobic surfaces was also assessed with a wide range of tests that showed their remarkable resistance to chemically aggressive environments, mechanical stresses and ultraviolet (UV) radiation. Moreover, this work analyzes the behavior of amphiphobic surfaces in terms of anti-soiling, snow-repellent and friction-reduction properties—all originated from their non-wetting behavior. The achieved results make AM materials viable solutions to be applied in different sectors answering several and pressing technical needs.

Spreading-Droplet Simulation With Surface Tension Model Using Inter-Particle Force in Particle Method

2013 ◽  
Author(s):  
Eiji Ishii ◽  
Taisuke Sugii
Keyword(s):  
Surface Tension ◽  
Contact Angle ◽  
Dynamic Contact Angle ◽  
Particle Method ◽  
Dynamic Contact ◽  
Contact Angles ◽  
Particle Methods ◽  
Static Contact ◽  
Particle Force ◽  
Surface Tension Model

Predicting the spreading behavior of droplets on a wall is important for designing micro/nano devices used for reagent dispensation in micro-electro-mechanical systems, printing processes of ink-jet printers, and condensation of droplets on a wall during spray forming in atomizers. Particle methods are useful for simulating the behavior of many droplets generated by micro/nano devices in practical computational time; the motion of each droplet is simulated using a group of particles, and no particles are assigned in the gas region if interactions between the droplets and gas are weak. Furthermore, liquid-gas interfaces obtained from the particle method remain sharp by using the Lagrangian description. However, conventional surface tension models used in the particle methods are used for predicting the static contact angle at a three-phase interface, not for predicting the dynamic contact angle. The dynamic contact angle defines the shape of a spreading droplet on a wall. We previously developed a surface tension model using inter-particle force in the particle method; the static contact angle of droplets on the wall was verified at various contact angles, and the heights of droplets agreed well with those obtained theoretically. In this study, we applied our surface tension model to the simulation of a spreading droplet on a wall. The simulated dynamic contact angles for some Weber numbers were compared with those measured by Šikalo et al, and they agreed well. Our surface tension model was useful for simulating droplet motion under static and dynamic conditions.

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