scholarly journals Statistical Evaluation of Mechanical Properties of Slag Based Alkali-Activated Material

2019 ◽  
Vol 11 (21) ◽  
pp. 5935 ◽  
Author(s):  
Martin Sisol ◽  
Dušan Kudelas ◽  
Michal Marcin ◽  
Tomáš Holub ◽  
Peter Varga

Slag is one of the by-products of the energy industry, which is suitable for secondary industrial processing. Although slag has been successfully used in industrial production for several decades, its use does not achieve the level of its potential. Today, to achieve a sustainable construction industry, alternative types of cement have been extensively investigated. Geopolymer is a kind of material which is obtained from the alkaline activator and it can be produced from the industrial wastes or by-products. In this study, SiO2/Na2O ratio and the amount of Na2O in activation solution parameters of alkali-activated materials were tested how they affect the strengths of hardened geopolymers from ground granulated blast furnace slag (GGBFS). Compressive and flexural strength tests were conducted, and the results were analyzed by analysis of variance (ANOVA). Strengths were tested after 7, 28, and 90 days.

2021 ◽  
Vol 11 (13) ◽  
pp. 5887
Author(s):  
Thandiwe Sithole ◽  
Nelson Tsotetsi ◽  
Tebogo Mashifana

Utilisation of industrial waste-based material to develop a novel binding material as an alternative to Ordinary Portland Cement (OPC) has attracted growing attention recently to reduce or eliminate the environmental footprint associated with OPC. This paper presents an experimental study on the synthesis and evaluation of alkali activated Ground granulated blast furnace slag (GGBFS) composite using a NaOH solution as an alkaline activator without addition of silicate solution. Different NaOH concentrations were used to produce varied GGBFS based alkali activated composites that were evaluated for Uncofined Compressive Strength (UCS), durability, leachability, and microstructural performance. Alkali activated GGBFS composite prepared with 15 M NaOH solution at 15% L/S ratio achieved a UCS of 61.43 MPa cured for 90 days at ambient temperatures. The microstructural results revealed the formation of zeolites, with dense and non-porous morphology. Alkali activated GGBFS based composites can be synthesized using a sole alkaline activator with potential to reduce CO2 emission. The metal leaching tests revealed that there are no potential environmental pollution threats posed by the synthesized alkali activated GGBFS composites for long-term use.


2020 ◽  
Author(s):  
Naim Sedira ◽  
João Castro-Gomes

This study determines the effect of ground granulated blast furnace slag (GGBFS) and metakaolin (MK) on the microstructural properties of the tungsten mining waste-based alkali-activated binder (TMWM). During this investigation, TMWM was partially replaced with 10 wt.% GGBFS and 10 wt.% MK to improve the microstructure of the binder. In order to understand the effect of the substitutions on the microstructure, two pastes were produced to make a comparative study between the sample contain 100% TMWM and the ternary precursors. Both precursors were activated using a combination of alkaline activator solutions (sodium silicate and sodium hydroxide) with the ratio of 1:3 (66.6 wt.% sodium silicate combined with 33.33 wt.% of NaOH 8M). The alkali-activated mixes were cured in oven at temperature of 60 °C in the first day and at room temperature for the next 27 days. The reaction products N-A-S-H gel and (N,M)-A-S-H gel resulted from the alkaline activation reaction process. In addition, a formation of natrite (Na2CO3) with needles shape occurred as a reaction product of the fluorescence phenomena. However, a dense matrix resulted from the alkline activation of the ternary precursors containg different gels such as N-A-S-H, C-A-S-H and (N,M)-C-A-S-H gel, these results were obtained through SEM-EDS analyses, as well FTIR tests. Keywords: Mining Waste, Alkali-activated, Microstructure, Slag, Metakaolin


2017 ◽  
Vol 7 (4) ◽  
pp. 413-425 ◽  
Author(s):  
Khalid Al-Gahtani ◽  
Ibrahim Alsulaihi ◽  
Mohamed Ali ◽  
Mohamed Marzouk

Purpose The purpose of this paper is to highlight the sustainability benefits of using demolition and industrial wastes as a replacement for aggregates and cement in traditional concrete mixes. Design/methodology/approach Crushed concrete from demolition sites served as a replacement for fine and coarse aggregate in some of the mixes at various ratios. In addition, ground granulated blast furnace slag, metakaolin, silica fume, and fly ash each served as a cement replacement for cement content in the mixes tested in this research at various rates. Compression strength tests, permeability, and thermal expansion tests were performed on various mixes to compare their performance to that of traditional mixes with natural aggregate, and with no cement replacement. Findings The compressive strength results indicated the suitability of using such demolition wastes as replacements in producing green concrete (GC) without hindering its mechanical characteristics significantly. In addition, the results indicated an enhancement in the mechanical characteristics of GC when replacing cement with pozzolanic industrial wastes and byproducts. Originality/value The research assesses the utilization of sustainable GC using recycled waste aggregate and byproducts.


2011 ◽  
Vol 287-290 ◽  
pp. 916-921
Author(s):  
Kyung Taek Koh ◽  
Gum Sung Ryu ◽  
Si Hwan Kim ◽  
Jang Hwa Lee

This paper examines the effects of the mixture ratio of fly ash/slag, the type of alkaline activators and curing conditions on the workability, compressive strength and microstructure of cementless alkali-activated mortar. The investigation showed that the mixture ratio of fly ash/slag and the type of alkaline activator have significant influence on the workability and strength, whereas the curing temperature has relatively poor effect. An alkali-activated mortar using a binder composed of 50% of fly ash and 50% of granulated blast furnace slag and alkaline activator made of 9M NaOH and sodium silicate in proportion of 1:1 is seen to be able to develop a compressive strength of 65 MPa at age of 28 days even when cured at ambient temperature of 20°C.


2019 ◽  
Vol 27 (1) ◽  
pp. 32-38
Author(s):  
Seshu D. Rama ◽  
R. Shankaraiah ◽  
Srinivas B. Sesha

Abstract Geopolymer concrete (GPC) is an environmentally friendly material in the sense that it uses industrial by-products such as ground granulated blast furnace slag (GGBS) and fly ash (FA), which are activated by an alkaline solution. This paper presents an experimental investigation concerning the strength of the GPC and its relation to a new parameter called the ‘Binder Index (BI)’. The parameters considered in the investigation include GGBS to fly ash ratios (0.25 0.43, 0.67, 1.0, 1.5, and 2.3) and the molarity of the alkaline activator (6, 8, 10, and 12). The binder index combines the effect of the GGBS to the fly ash ratio and the molarity of the alkaline activator. The results have shown that the strength of the GPC is significantly influenced by varying the binder index. The results indicate that a nonlinear relation exists between the binder index and the compressive strength of the GPC and the binder index and the modulus of rupture.


2021 ◽  
Vol 1205 (1) ◽  
pp. 012016
Author(s):  
V Iliushchenko ◽  
V Bilek Jr. ◽  
L Kalina ◽  
P Hruby ◽  
T Opravil ◽  
...  

Abstract The rheological properties of alkali-activated systems are significantly affected by the nature of the alkaline activator. Hydroxide-activated systems’ workability is typically lower than that of alkali-activated systems but can be improved by lignosulfonate plasticizer. However, the lignosulfonate plasticizer’s effectivity depends on the dosage of lignosulfonate, the nature of hydroxide and pH of their solutions. Therefore, in this study, the effectiveness of lignosulfonate plasticizer with respect to alkali ion type (Na+, K+, Li+) in alkali hydroxide-activated systems based on ground granulated blast furnace slag was evaluated. The concentration of the alkaline activator (NaOH, KOH and LiOH) was the same in all cases of 4M. The superplasticizer dosage was 0%, 0.5% and 1.0% of dry matter of lignosulfonate plasticizer to the slag weight. Rheological properties were determined using a rotational rheometer equipped with vane in-cup geometry working in oscillation amplitude sweep mode, from which critical strain and corresponding viscoelastic variables were obtained.


2018 ◽  
Vol 195 ◽  
pp. 01013 ◽  
Author(s):  
Apriany Saludung ◽  
Yuko Ogawa ◽  
Kenji Kawai

This study presents the microstructure and mechanical properties of geopolymer paste made from low-calcium fly ash (FA) and ground granulated blast-furnace slag (GGBS) through alkalination. The use of GGBS and FA is not only for sustainable construction but also for reducing the emission of CO2 due to the use of Portland cement. Different replacement ratios of GGBS to FA were used to determine the effect of GGBS presented to the compressive strength of geopolymer specimens. The alkaline activator solution used is a combination of sodium hydroxide (NaOH) 14 M and sodium silicate (Na2SiO3). A compressive strength test on cylindrical specimens (50 mm x 100 mm) at the ages of 7, 14, and 28 days was carried out. The results showed that the compressive strength increased with the increase of GGBS in the mixes (up to 100 MPa). Moreover, SEM-EDS, XRD, and TG-DTA characterization methods were conducted to investigate the microstructure, phase composition, and thermal stability of the geopolymer specimens respectively.


2013 ◽  
Vol 723 ◽  
pp. 580-587
Author(s):  
Wen Huan Zhong ◽  
Tung Hsuan Lu ◽  
Wei Hsing Huang

Electric arc furnace (EAF) reducing slag is the by-product of EAF steel-making. Currently, reducing slag is considered a waste material by the industry in Taiwan. Since the chemical content of reducing slag is similar to blast furnace slag (BFS), it is expected that reducing slag exhibits a similar pozzolanic effect as the BFS. This study used alkaline activator consisting of sodium silicate and sodium hydroxide to improve the activity of reductive slag so as to replace Portland cement as binder in concrete. Some BFS was used to blend with the reducing slag to enhance the binding quality of alkali-activated mixes. The results show that a blend of 50% BFS and 50% reducing slag can be activated successively with alkali. Also, the sulfate resistance of concrete made with alkali-activated EAF reducing slag is found to be better than that of concrete made with portland cement, while the drying shrinkage of alkali-activated EAF reducing slag concrete is greater than that of portland cement concrete.


2018 ◽  
Vol 230 ◽  
pp. 03016 ◽  
Author(s):  
Raisa Runova ◽  
Volodymyr Gots ◽  
Igor Rudenko ◽  
Oleksandr Konstantynovskyi ◽  
Oles’ Lastivka

Functionality of mortar and concrete mixes is regulated by surfactants, which act as plasticizers. The molecular structure of these admixtures can be changed during hydration of alkali-activated cements (AAC). The objective was to determine the chemical nature of plasticizers effective for property modification of mortars and concretes based on AACs with changing content of granulated blast furnace slag from 0 to 100 %. The admixtures without ester links become more effective than polyesters when content of alkaline component increase. The admixtures effective in high alkaline medium were used in dry mixes for anchoring (consistency of mortar 150 mm by Vicat cone; 1 d tensile strength in bending / compressive strength of mortar 6.6 /30.6 MPa) and in ready-mixed concretes (consistency class changed from S1 to S3, S4 with consistency safety during 60 min; 3 d compressive strength of modified concrete was not less than the reference one without admixtures).


2020 ◽  
Vol 11 (2) ◽  
pp. 221-246
Author(s):  
Ghasem Pachideh ◽  
Majid Gholhaki

Purpose With respect to the studies conducted so far and lack of researches on the post-heat behavior of cement mortars containing pozzolanic materials, the purpose of this paper is to investigate the post-heat mechanical characteristics (i.e. compressive, tensile and flexural strength) of cement mortars containing granulated blast-furnace slag (GBFS) and silica fume (SF). In doing so, selected temperatures include 25, 100, 250, 500, 700 and 9000c. Last, the X-ray diffraction test was conducted to study the microstructure of mixtures and subsequently, the results were presented as power-one mathematical relations. Design/methodology/approach Totally, 378 specimens were built to conduct flexural, compressive and tensile strength tests. Accordingly, these specimens include cubic and prismatic specimens with dimensions of 5 × 5 × 5 cm and 16 × 4 × 4 cm, respectively, to conduct compressive and flexural strength tests together with briquette specimen used for tensile strength test in which cement was replaced by 7, 14 and 21 per cent of SF and GBFS. To study the effect of temperature, the specimens were heated. In this respect, they were heated with a rate of 5°C/min and exposed to temperatures of 25 (ordinary temperature), 100, 250, 500, 700 and 900°C. Findings On the basis of the results, the most profound effect of using GBFS and SF, respectively, takes place in low (up to 250°C) and high (500°C and greater degrees) temperatures. Quantitatively, the compressive, tensile and flexural strengths were enhanced by 73 and 180 per cent, 45 and 100 per cent, 106 and 112 per cent, respectively, in low and high temperatures. In addition, as the temperature elevates, the particles of specimens containing SF and GBFS shrink less in size compared to the reference specimen. Originality/value The specimens were cured according to ASTMC192 after 28 days placement in the water basin. First, in compliance with what has been specified by the mix design, the mortar, including pozzolanic materials and superplasticizer, was prepared and then, the sampling procedure was conducted on cubic specimens with dimension of 5 × 5 × 5 mm for compressive strength test, prismatic specimens with dimensions of 16 × 4 × 4 mm for flexural strength test and last, briquette specimens were provided to conduct tensile strength tests (for each temperature and every test, three specimens were built).


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