scholarly journals Treatment of Post-Hydrothermal Liquefaction Wastewater (PHWW) for Heavy Metals, Nutrients, and Indicator Pathogens

Water ◽  
2019 ◽  
Vol 11 (4) ◽  
pp. 854 ◽  
Author(s):  
Samuel D. Jesse ◽  
Paul C. Davidson
Keyword(s):  
Heavy Metals ◽  
Environmental Protection Agency ◽  
Water Reuse ◽  
Crop Production ◽  
Hydrothermal Liquefaction ◽  
Total N ◽  
Treatment Methods ◽  
Attractive Option ◽  
Us Epa ◽  
Cadmium Lead

Recycling post-hydrothermal liquefaction wastewater (PHWW) may allow the use of nutrients in the aqueous phase that may otherwise go unused. PHWW is an attractive option for use as fertilizer in systems like crop production. However, there are potential contaminants in the PHWW that may inhibit crop growth or pose a food safety risk. This study investigated the concentrations of heavy metals and nutrients in the PHWW, as well as the presence of indicator pathogens. In addition, four different water treatment methods were used: (1) dilution of raw PHWW, (2) sand filtration after dilution, (3) sand and carbon filtration after dilution, and (4) reverse osmosis after dilution. Our results indicate that the concentrations of cadmium, lead, and arsenic in raw PHWW were well below the maximum recommended concentrations set by the US Environmental Protection Agency (US EPA) for Water Reuse. In addition, the treatment methods in this study achieved percent removals ranging from 82–100% for cadmium, 99–100% for mercury, 75–99.5% for lead, and 71–99% for arsenic. Nitrogen in raw PHWW was predominantly in the total N form, preventing it from being accessible to plants. After nitrification was induced, the concentration of NO3 + NO2 increased by 1.75 mg/L in the untreated 5% PHWW mixture, but remained unchanged or decreased for all other treatments and mixtures. There were no E. coli or coliform colonies detected in the raw PHWW, or in any PHWW mixtures. All PHWW mixtures with and without treatment are within US EPA guidelines for metals for irrigation water reuse. However, fertilizer supplementation may be required for PHWW to be suitable for crop production, as the low concentrations of NO3 + NO2 may prove challenging for growing crops.

Water reclamation and reuse criteria in the U.S.

1996 ◽  
Vol 33 (10-11) ◽  
pp. 451-462 ◽  
Author(s):  
James Crook ◽  
Rao Y. Surampalli
Keyword(s):  
Surface Waters ◽  
Water Reuse ◽  
Reclaimed Water ◽  
Water Reclamation ◽  
Water Supplies ◽  
The Us ◽  
Attractive Option ◽  
Us Epa ◽  
The Individual ◽  
The U.S

Increasing demands on water resources for domestic, commercial, industrial, and agricultural purposes have made water reclamation and reuse an attractive option for conserving and extending available water supplies. Also, many water reuse projects are implemented to eliminate a source of contamination in surface waters or as a least-cost alternative to meeting stringent discharge requirements. Reclaimed water applications range from pasture irrigation to augmentation of potable water supplies. Water reclamation and reuse criteria are principally directed at health protection. There are no federal regulations governing water reuse in the U.S.; hence, the regulatory burden rests with the individual states. This has resulted in differing standards among states that have developed criteria. This paper summarizes and compares the criteria from some states that have developed comprehensive regulations. Guidelines published by the US. EPA and the rationale behind them are presented for numerous types of reclaimed water applications.

scholarly journals A COMPARATIVE STUDY ON TREATMENT TECHNOLOGIES FOR SEWAGE RECLAMATION: A FOCUS ON THE DISINFECTION PROCESS

2020 ◽  
Vol 21 (2) ◽  
pp. 80-99
Author(s):  
Noorini Izzati Mohamad Mazuki ◽  
Yeit Haan Teow ◽  
Abdul Wahab Mohammad
Keyword(s):  
Environmental Protection Agency ◽  
Water Reuse ◽  
Oxygen Demand ◽  
Ammonia Nitrogen ◽  
Wastewater Reclamation ◽  
Potable Reuse ◽  
Us Epa ◽  
Multi Media ◽  
Pre Treatment ◽  
Almost All

Selection of suitable disinfection technology is necessary with regards to wastewater reclamation goals. In this work, the performance of various disinfection technologies - single disinfection units and integrated disinfection systems - on local sewage was studied for non-potable reuse. Disinfection units used as stand-alone units include ultraviolet (UV) disinfection, chlorination, microfiltration (MF), and ultrafiltration (UF). The integrated disinfection system consists of UV or chlorination as the primary disinfection unit incorporated with either MF, UF, multi-media or granular activated carbon as pre-treatment. The performance of these disinfection units and integrated processes were evaluated based on the percentage of removal of biochemical oxygen demand, chemical oxygen demand, total suspended solids, ammonia nitrogen, nitrate nitrogen, phosphorus, Escherichia coli, and trihalomethane in bench-scale disinfection systems. The single unit of PES20kDa membrane and the integrated disinfection system of UF-Cl showed the most effective treatment among single disinfection units and integrated systems, respectively. The results showed that almost all disinfection units and integrated disinfection processes were useable for restricted and unrestricted area non-potable applications according to United State Environmental Protection Agency (US EPA) water reuse guidelines and managed to fulfil Singapore grey water quality for recycling. ABSTRAK: Pemilihan teknologi penyahjangkitan kuman yang sesuai adalah perlu selaras dengan matlamat pemulihgunaan air buangan. Kajian ini adalah tentang prestasi pelbagai teknologi penyahjangkitan kuman - unit tunggal penyahjangkitan kuman dan sistem penyahjangkitan kuman bersepadu pada air sisa kumbahan tempatan dikaji bagi penggunaan semula air minuman. Unit  tunggal penyahjangkitan kuman yang digunakan mempunyai penyahjangkitan kuman ultraungu (UV), pengklorinan, mikro penurasan (MF), dan ultra penurasan (UF). Manakala, sistem penyahjangkitan kuman bersepadu terdiri daripada UV atau pengklorinan sebagai unit penyahjangkitan kuman utama yang digabungkan bersama samada dengan MF, UF, multi-media atau karbon teraktif berbutir sebagai proses pra-rawatan. Prestasi unit tunggal penyahjangkitan kuman dan proses-proses bersepadu dinilai berdasarkan pada peratus penyingkiran keperluan oksigen biokimia, permintaan oksigen kimia, jumlah pepejal terampai, nitrogen ammonia, nitrogen nitrat, fosforus, coli Escherichia, dan trihalometana dalam sistem penyahjangkitan kuman berskala-makmal. Unit tunggal penurasan ultra membran PES20kDa dan sistem penyahjangkitan kuman bersepadu UF-Cl menunjukkan masing-masing paling efektif dalam rawatan unit tunggal dan sistem penyahjangkitan kuman bersepadu. Keputusan menunjukkan bahawa hampir semua unit tunggal penyahjangkitan kuman dan proses penyahjangkitan kuman bersepadu boleh diguna pakai bagi aplikasi terhad dan tidak terhad  mengikut garis panduan penggunaan semula air sisa rawatan yang ditetapkan oleh Agensi Pelindungan Alam Sekitar Amerika Syarikat (US EPA) dan kualiti kitar semula air sisa Singapura.

scholarly journals Assessment of the Heavy Metals Pollution and Ecological Risk in Sediments of Mediterranean Sea Drain Estuaries in Egypt and Phytoremediation Potential of Two Emergent Plants

2021 ◽  
Vol 13 (21) ◽  
pp. 12244
Author(s):  
Yasser A. El-Amier ◽  
Armel Zacharie Ekoa Bessa ◽  
Ashraf Elsayed ◽  
Mohamed A. El-Esawi ◽  
Mohammad S. AL-Harbi ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Ecological Risk ◽  
Environmental Protection Agency ◽  
Industrial Development ◽  
Nile Delta ◽  
Risk Index ◽  
Population Expansion ◽  
Mediterranean Coast ◽  
Ecological Effect ◽  
Us Epa

Environmental pollution and its eco-toxicological impacts have become a large and interesting concern worldwide as a result of fast urbanization, population expansion, sewage discharge, and heavy industrial development. Nine heavy metals (Pb, Cd, Fe, Mn, Zn, Ni, Cu, Cr, and Co) were evaluated in 20 sediment samples from the estuaries of four major drains along the Mediterranean shoreline (Nile Delta coast) to determine the possible ecological effect of high heavy metal concentrations as well as roots and shoots of two common macrophytes (Cyperus alopecuroides and Persicaria salicifolia). For sediment, single- and multi-elemental standard indices were used to measure ecological risk. Data revealed high contents of heavy metals, for which the mean values of heavy metals in sediment followed a direction of Fe > Mn > Co > Zn > Cu > Ni > Cr > Pb > Cd, Fe > Mn > Co > Ni > Zn > Cu > Cr > Pb > Cd and Fe > Mn > Zn > Co > Cu > Ni > Cr > Pb > Cd for drains stream, estuaries, and Mediterranean coast, respectively. Mn, Cr, Zn, and Pb were found to be within Canadian Soil Quality Guidelines (CSQGD) and U.S. Environmental Protection Agency Guidelines (US-EPA) limitations, except for Zn and Pb in drain streams, which were above the US-EPA limits, whereas Cd, Co, Cu, and Ni indicated a high ecological risk index. This high quantity of contaminants might be linked to unabated manufacturing operations, which can bio-accumulate in food systems and create significant health issues in people. C. alopecuroides root demonstrated a more efficient accumulation of all metals than the shoot system. For most heavy metals, C. alopecuroides had the highest root BAF levels with the exception of Ni and Pb in P. salicifolia. As a result, C. alopecuroides might be employed as a possible phytoextractor of these dangerous metals, while P. salicifolia could be used as a hyper-accumulator of Ni and Pb. The policymaker must consider strict rules and restrictions against uncontrolled industrial operations, particularly in the Nile Delta near water streams.

scholarly journals Hydroponic Lettuce Production Using Treated Post-Hydrothermal Liquefaction Wastewater (PHW)

2019 ◽  
Vol 11 (13) ◽  
pp. 3605 ◽  
Author(s):  
Samuel D. Jesse ◽  
Yuanhui Zhang ◽  
Andrew J. Margenot ◽  
Paul C. Davidson
Keyword(s):  
Crop Production ◽  
Maximum Level ◽  
Additional Treatment ◽  
Hydrothermal Liquefaction ◽  
Fecal Coliforms ◽  
Source Water ◽  
Sand Filtration ◽  
Department Of Agriculture ◽  
Lettuce Yield ◽  
Cadmium Lead

Post-hydrothermal liquefaction wastewater (PHW) is a byproduct of the hydrothermal liquefaction (HTL) process. Previous research indicates that PHW is free of pathogens and contains nutrients needed for crop growth, but may contain metal(loid)s. This study evaluated the ability of differentially treated PHW for effective and safe hydroponic lettuce production. Water containing only hydroponic fertilizer (Source Water 1) had the highest total dry yield of all five treatments; 3.1 times higher than Source Water 2 (diluted PHW with sand filtration), 3.5 times higher than Source Water 3 (diluted PHW with sand + carbon filtration), 2.6 times higher than Source Water 4 (diluted and nitrified PHW with sand filtration), and 1.3 times higher than Source Water 5 (diluted PHW supplemented with hydroponic fertilizer). Findings also indicated that while PHW was below the US Department of Agriculture Foreign Agriculture Service maximum levels for cadmium, lead, and mercury in food, the concentration of arsenic was 1.6, 2.4, and 2.0 times higher than the maximum level for Source Waters 2, 3, and 4, respectively. There was no detectable E. coli or fecal coliforms in any of the treated PHW. While nitrogen was present in the raw PHW, only 0.03% was NO3-N and NO2-N. Diluted PHW supplemented with hydroponic fertilizer had lower lettuce yield than hydroponic fertilizer alone, indicating a potential non-nutrient inhibition of plant growth by PHW. Therefore, this research demonstrates that treated PHW does not pose a biological contamination risk for lettuce, but may entail levels of arsenic in edible leaf tissues that are in excess of safe levels. Additional treatment of PHW can benefit crop production by allowing crop utilization of a greater fraction of total nitrogen in the raw PHW.

scholarly journals Formation and Transformation of Typical Pollutant from MSW by Hydrothermal Carbonization towards Biofuel Hydrochar Production

2020 ◽  
Author(s):  
Wentao Jiao ◽  
Nana Peng ◽  
Zhengang Liu
Keyword(s):  
Heavy Metals ◽  
Environmental Protection Agency ◽  
Hydrothermal Carbonization ◽  
The United States ◽  
Waste To Energy ◽  
Increase Carbon Content ◽  
Hydrothermal Temperature ◽  
Polycyclic Aromatic ◽  
Us Epa ◽  
Increasing Temperature

An unprecedented increase in municipal solid waste (MSW) is increasingly attractive in response to waste-to-energy. MSW pretreatment is an essential step due to the inherent properties of MSW. Hydrothermal carbonization (HTC) offers an efficient approach for converting MSW into carbonaceous hydrochars. In this chapter, the formation and transformation of heavy metals and polycyclic aromatic hydrocarbons (PAHs) during HTC of MSW were determined. The results indicated that HTC can homogenize the density and size of MSW and also increase carbon content. Moreover, the concentrations of heavy metals in the leachates of the hydrochars were lower than the United States Environmental Protection Agency (US EPA) maximum limits. Compared to MSW, the concentrations of Cr, Cd, Hg, and Zn in the hydrochars were low and the concentrations of Pb, As, Ni, and Cu were high. The concentrations of PAHs in the hydrochars increased with increasing temperature in the range of 1298.71–177698.20 μg/kg, which were much higher than that in MSW, except for H-160. The dominant PAH rings in MSW and the hydrochars were four-ring PAHs and three-ring PAHs, respectively. These findings suggest that 180°C is an appropriate hydrothermal temperature to reduce heavy metals and the toxicity PAHs of MSW.

INFLUENCE OF THE ECOLOGICAL STATE OF THE SEREPOK RIVER (VIETNAM) ON ACCUMULATION OF HEAVY METALS IN ORGANS OF FISH

2017 ◽  
pp. 98-105
Author(s):  
Ngo The Cuong ◽  
Tran Hoan Quoc ◽  
Svetlana Vasilievna Zolotokopova
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
River Water ◽  
Bottom Sediments ◽  
Heavy Metal Concentration ◽  
Industrial Areas ◽  
Industrial Regions ◽  
Cadmium Lead ◽  
Sarotherodon Galilaeus ◽  
Water Bottom

The article focuses on the study of change of containing heavy metals (zinc, copper, iron, cadmium, lead, arsenic) in the abiotic and biotic components of the Serepok river (Vietman) influenced by wastewater discharge from industrial areas. Heavy metal content was determined in the river water and bottom sediments in the four zones: above and within the boundaries of industrial regions Xoa Phu and Tam Thang and in two water reservoirs situated below the boundaries of those industrial areas. Tilapia Galilean ( Sarotherodon galilaeus ), Hemibagrus ( Hemibagrus ), and sazan ( Cyprinus carpio ) caught in these areas were the hydrobionts under study in which liver, gills, skeleton and muscles accumulation of heavy metals was detected. In the organs of fish caught in the river within industrial region, heavy metals concentration was 3-7 times higher. The greatest concentration of heavy metals was found in the liver and gills of fish caught in the boundaries of industrial regions, the least concentration was in the muscles. In most cases, significant correlation between heavy metal concentration in organs of fishes and in river water, bottom sediments has been revealed.

Impact of Nitrogen Management Practices on Total Nitrogen in the Fruits of High Productive Hamlin Orange Trees

HortScience ◽  
1998 ◽  
Vol 33 (3) ◽  
pp. 498e-498
Author(s):  
S. Paramasivam ◽  
A.K. Alva
Keyword(s):  
Crop Production ◽  
Management Practices ◽  
Fine Sand ◽  
Fruit Production ◽  
Perennial Crop ◽  
Total N ◽  
N Removal ◽  
Leaf N Concentration ◽  
N Rates ◽  
Orange Trees

For perennial crop production conditions, major portion of nutrient removal from the soil-tree system is that in harvested fruits. Nitrogen in the fruits was calculated for 22-year-old `Hamlin' orange (Citrus sinensis) trees on Cleopatra mandarin (Citrus reticulata) rootstock, grown in a Tavares fine sand (hyperthermic, uncoated, Typic Quartzipsamments) that received various N rates (112, 168, 224, and 280 kg N/ha per year) as either i) broadcast of dry granular form (DGF; four applications/year), or ii) fertigation (FRT; 15 applications/year). Total N in the fruits (mean across 4 years) varied from 82 to 110 and 89 to 111 kg N/ha per year for the DGF and FRT sources, respectively. Proportion of N in the fruits in relation to N applied decreased from 74% to 39% for the DGF and from 80% to 40% for the FRT treatments. High percentage of N removal in the fruits in relation to total N applied at low N rates indicate that trees may be depleting the tree reserve for maintaining fruit production. This was evident, to some extent, by the low leaf N concentration at the low N treatments. Furthermore, canopy density was also lower in the low N trees compared to those that received higher N rates.

Health risk assessment of occupational exposure to heavy metals in a steel casting unit of a steelmaking plant using Monte–Carlo simulation technique

2021 ◽  
pp. 074823372110195
Author(s):  
Fatemeh Dehghani ◽  
Fariborz Omidi ◽  
Reza Ali Fallahzadeh ◽  
Bahman Pourhassan
Keyword(s):  
Heavy Metals ◽  
Occupational Exposure ◽  
Environmental Protection Agency ◽  
Steel Casting ◽  
Occupational Safety ◽  
The United States ◽  
Control Measures ◽  
Monte Carlo Simulation Technique ◽  
Safety And Health ◽  
Casting Unit

The present work aimed to evaluate the health risks of occupational exposure to heavy metals in a steel casting unit of a steel plant. To determine occupational exposure to heavy metals, personal air samples were taken from the workers’ breathing zones using the National Institute for Occupational Safety and Health method. Noncancer and cancer risks due to the measured metals were calculated according to the United States Environmental Protection Agency procedures. The results indicated that the noncancer risks owing to occupational exposure to lead (Pb) and manganese were higher than the recommended value in most of the workstations. The estimated cancer risk of Pb was also higher than the allowable value. Moreover, the results of sensitivity analysis indicated that the concentration, inhalation rate, and exposure duration were the most influencing variables contributing to the calculated risks. It was thus concluded that the present control measures were not adequate and further improvements were required for reducing the exposure levels.

scholarly journals An Assessment of Heavy Metal Contamination in the Nakdong River Around the Weir

Water ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 684
Author(s):  
Hee Won Son ◽  
Sun Hee Shim ◽  
Haeseong Oh ◽  
Jung Hyun Choi
Keyword(s):  
Heavy Metals ◽  
Sequential Extraction ◽  
Environmental Protection Agency ◽  
Heavy Metal Contamination ◽  
Environmental Research ◽  
Residual Fraction ◽  
Nakdong River ◽  
Risk Assessment Code ◽  
The Nakdong River ◽  
Reducible Fraction

In this study, the concentrations and characteristics of copper (Cu), zinc (Zn), and lead (Pb) contamination in sediment samples were investigated using aqua regia extraction and Tessier’s five-step sequential extraction. Based on the concentration of metals, the influence of the Hapcheon-Changnyeong weir on sediments in the Nakdong River was assessed. The origins of the contaminants, their bioavailability, and their mobility were determined using sequential extraction. Greater concentrations of heavy metals were found in samples collected closer to the weir. The largest proportion of Cu was identified in the residual fraction based on sequential extraction, whereas Zn was predominantly found in the reducible fraction. Iron-manganese in the reducible fraction of Zn has the potential to leach back to the water body. In addition, the combined concentration of fractions 1 and 2 of Cu comprised more than 20% of total amount that still has potential to affect the water quality. The results of this study were compared with existing sediment standards set out by the NIER (National Institute of Environmental Research), Canada, and US EPA (United States Environmental Protection Agency) guidelines, as well as the risk assessment code (RAC). The concentrations of heavy metals exceeded the standards set by the Canadian guideline by up to four times in particular samples, highlighting the need for continual monitoring.

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