scholarly journals Chemical and Isotopic Tracers for Characterization of the Groundwater in the Heterogeneous System: Case from Chichaoua-Imin’tanout (Morocco)

Water ◽  
2021 ◽  
Vol 14 (1) ◽  
pp. 9
Author(s):  
Rim Tijani ◽  
Abdennebi El Mandour ◽  
Driss Chafouq ◽  
Malak Elmeknassi ◽  
Fatima Ezzahra El Ghazali ◽  
...  

The geological and hydrogeological approach of the structure of the basin OuladBouSbaâ led to the definition of the geometry of the main aquifers. In general, the profiles show the complexity of the geological configuration. The filling of the depression of OuladBouSbaâ is from the Eo-Cretacian. At this level, the aquifer is recharged by direct water infiltration. The quaternary, Eocene, and Cenomanian-Turonian formations constitute the main aquifers. Horizontal as well as vertical heterogeneity lead to a higher diversification of aquifer characteristics. To define the origins and understand the groundwater flows in this complex zone, we used a multi-tracer approach with the analysis of major elements and the isotopes of δ2H and δ18O. The chemical composition is mainly governed by the interaction with the rock with low electrical conductivity except in areas around domestic landfills. Geochemical results analyzing groundwater in the Piper diagram show two distinct chemical facies: the sulfated calcium and magnesium, and the hyper-chloride calcium. The levels of δ18O range from −7.60 to −4.25 while those of δ2H vary between −53.07 and −27.03. Analyses of signature isotopes differentiate two groups. The first contains high levels of heavy isotopes (highest levels of δ2H and δ18O) having therefore been submitted to evaporation. The second with lower levels of δ2H and δ18O did not undergo evaporation. The first one belongs to the unconfined free aquifer while the second corresponds to the captive aquifer.

2021 ◽  
Vol 314 ◽  
pp. 07002
Author(s):  
Rabia El Fakir ◽  
El Mostafa Mili ◽  
Ali Essahlaoui ◽  
Mohammed El Hafyani ◽  
Zakaria Ammari

This paper aims to determine the hydrogeochemical characteristics of the Fez-Meknes free water table thought the monitoring of the physicochemical analyses of nine samples during the year of 2013, 2016, and 2019. This water table, which circulates in the plio-quaternary formations, is generally supplied by rainfall infiltration, irrigation water returns and also the lateral inflow of the unconfined liasic water table of the Middle Atlas Tabular. Analyses were performed for electrical conductivity (EC), potential hydrogen (pH), temperature and major elements: Cl-, NO3-, SO42-, Na+, Mg2+, Ca2+, HCO3⁻, K+. The results of the projection of the samples on the Piper diagram for the three companies showed a hydrochemical carbonate, calcic and magnesian facies for the majority of the samples with the exception of samples 1161/15 and 352/21 for the year 2013. Then, to understand the origin of the mineralization, as well as the processes related to the dissolution of the carbonate country rock, a principal component analysis (PCA) was performed.


Author(s):  
Oryslava Korkuna ◽  
Ivan Korkuna ◽  
Oleh Tsilnyk

Development of a territorial community requires efficient use of its capacity taking into account all possible aspects in the course of elaboration and implementation of the development strategy and other local legal and regulative documents. The approach is directly related to maintaining the living activity of a territorial community and should correspond to the interests of population and European standards of state regional policy. In addition to the definition of a community provided by the Law of Ukraine “On Local Governance in Ukraine”, there are also some other. For example, some authors understand territorial community as a single natural and social entity that operates in spatial boundaries of a state and realizes daily needs and interests of population. The paper aims to analyze legal and regulative foundation of the development of territorial communities in conditions of decentralization. The authors analyze current condition of legal and regulative maintenance of local governance reforming in Ukraine in conditions of decentralization of authorities. The paper argues that the major elements of management strategy in CTCs in Ukraine are independence, efficiency, management innovations, quicker and more substantiated decision-making and everything to meet the needs of community’s residents. Management of this sector is grounded on the principles of the provisions of European Charter of Local Self-Government that provides for decentralization of authorities and transfer of resources and responsibilities to local governments. Liabilities of local governments (of consolidated territorial communities) and the mayors are analyzed. The authors prove that in general legal provision of decentralization of local governance corresponds to European requirements and creates reliable ground for practical stage of the reform. The list of issues that require further legal regulation is outlined.


Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2313
Author(s):  
Maria Luisa Beconcini ◽  
Pietro Croce ◽  
Paolo Formichi ◽  
Filippo Landi ◽  
Benedetta Puccini

The evaluation of the shear behavior of masonry walls is a first fundamental step for the assessment of existing masonry structures in seismic zones. However, due to the complexity of modelling experimental behavior and the wide variety of masonry types characterizing historical structures, the definition of masonry’s mechanical behavior is still a critical issue. Since the possibility to perform in situ tests is very limited and often conflicting with the needs of preservation, the characterization of shear masonry behavior is generally based on reference values of mechanical properties provided in modern structural codes for recurrent masonry categories. In the paper, a combined test procedure for the experimental characterization of masonry mechanical parameters and the assessment of the shear behavior of masonry walls is presented together with the experimental results obtained on three stone masonry walls. The procedure consists of a combination of three different in situ tests to be performed on the investigated wall. First, a single flat jack test is executed to derive the normal compressive stress acting on the wall. Then a double flat jack test is carried out to estimate the elastic modulus. Finally, the proposed shear test is performed to derive the capacity curve and to estimate the shear modulus and the shear strength. The first results obtained in the experimental campaign carried out by the authors confirm the capability of the proposed methodology to assess the masonry mechanical parameters, reducing the uncertainty affecting the definition of capacity curves of walls and consequently the evaluation of seismic vulnerability of the investigated buildings.


2021 ◽  
pp. 1-10
Author(s):  
Narjes Firouzkouhi ◽  
Abbas Amini ◽  
Chun Cheng ◽  
Mehdi Soleymani ◽  
Bijan Davvaz

Inspired by fuzzy hyperalgebras and fuzzy polynomial function (term function), some homomorphism properties of fundamental relation on fuzzy hyperalgebras are conveyed. The obtained relations of fuzzy hyperalgebra are utilized for certain applications, i.e., biological phenomena and genetics along with some elucidatory examples presenting various aspects of fuzzy hyperalgebras. Then, by considering the definition of identities (weak and strong) as a class of fuzzy polynomial function, the smallest equivalence relation (fundamental relation) is obtained which is an important tool for fuzzy hyperalgebraic systems. Through the characterization of these equivalence relations of a fuzzy hyperalgebra, we assign the smallest equivalence relation α i 1 i 2 ∗ on a fuzzy hyperalgebra via identities where the factor hyperalgebra is a universal algebra. We extend and improve the identities on fuzzy hyperalgebras and characterize the smallest equivalence relation α J ∗ on the set of strong identities.


2021 ◽  
Vol 22 (9) ◽  
pp. 4707
Author(s):  
Mariana Lopes ◽  
Sandra Louzada ◽  
Margarida Gama-Carvalho ◽  
Raquel Chaves

(Peri)centromeric repetitive sequences and, more specifically, satellite DNA (satDNA) sequences, constitute a major human genomic component. SatDNA sequences can vary on a large number of features, including nucleotide composition, complexity, and abundance. Several satDNA families have been identified and characterized in the human genome through time, albeit at different speeds. Human satDNA families present a high degree of sub-variability, leading to the definition of various subfamilies with different organization and clustered localization. Evolution of satDNA analysis has enabled the progressive characterization of satDNA features. Despite recent advances in the sequencing of centromeric arrays, comprehensive genomic studies to assess their variability are still required to provide accurate and proportional representation of satDNA (peri)centromeric/acrocentric short arm sequences. Approaches combining multiple techniques have been successfully applied and seem to be the path to follow for generating integrated knowledge in the promising field of human satDNA biology.


Author(s):  
M. Ferrara ◽  
M. Trombetti

AbstractLet G be an abelian group. The aim of this short paper is to describe a way to identify pure subgroups H of G by looking only at how the subgroup lattice $$\mathcal {L}(H)$$ L ( H ) embeds in $$\mathcal {L}(G)$$ L ( G ) . It is worth noticing that all results are carried out in a local nilpotent context for a general definition of purity.


2020 ◽  
Vol 849 ◽  
pp. 113-118
Author(s):  
Yayat Iman Supriyatna ◽  
Slamet Sumardi ◽  
Widi Astuti ◽  
Athessia N. Nainggolan ◽  
Ajeng W. Ismail ◽  
...  

The purpose of this study is to characterize Lampung iron sand and to conduct preliminary experiments on the TiO2 synthesis which can be used for the manufacturing of functional food packaging. The iron sand from South Lampung Regency, Lampung Province that will be utilized as raw material. The experiment was initiated by sieving the iron sand on 80, 100, 150, 200 and 325 mesh sieves. Analysis using X-Ray Fluorescence (XRF) to determine the element content and X-Ray Diffraction (XRD) to observe the mineralization of the iron sand was conducted. The experiment was carried out through the stages of leaching, precipitation, and calcination. Roasting was applied firstly by putting the iron sand into the muffle furnace for 5 hours at a temperature of 700°C. Followed by leaching using HCl for 48 hours and heated at 105°C with a stirring speed of 300 rpm. The leaching solution was filtered with filtrate and solid residue as products. The solid residue was then leached using 10% H2O2 solution. The leached filtrate was heated at 105°C for 40 minutes resulting TiO2 precipitates (powder). Further, the powder was calcined and characterized. Characterization of raw material using XRF shows the major elements of Fe, Ti, Mg, Si, Al and Ca. The highest Ti content is found in mesh 200 with 9.6%, while iron content is about 80.7%. While from the XRD analysis, it shows five mineral types namely magnetite (Fe3O4), Rhodonite (Mn, Fe, Mg, Ca) SiO3, Quart (SiO2), Ilmenite (FeOTiO2) and Rutile (TiO2). The preliminary experiment showed that the Ti content in the synthesized TiO2 powder is 21.2%. The purity of TiO2 is low due to the presence of Fe metal which is dissolved during leaching, so that prior to precipitation purification is needed to remove impurities such as iron and other metals.


2012 ◽  
Vol 730-732 ◽  
pp. 569-574
Author(s):  
Marta Cabral ◽  
Fernanda Margarido ◽  
Carlos A. Nogueira

Spent Ni-MH batteries are not considered too dangerous for the environment, but they have a considerable economical value due to the chemical composition of electrodes which are highly concentrated in metals. The present work aimed at the physical and chemical characterisation of spent cylindrical and thin prismatic Ni-MH batteries, contributing for a better definition of the recycling process of these spent products. The electrode materials correspond to more than 50% of the batteries weight and contain essentially nickel and rare earths (RE), and other secondary elements (Co, Mn, Al). The remaining components are the steel parts from the external case and supporting grids (near 30%) containing Fe and Ni, and the plastic components (<10%). Elemental quantitative analysis showed that the electrodes are highly concentrated in metals. Phase identification by X-ray powder diffraction combined with chemical analysis and leaching experiments allowed advancing the electrode materials composition. The cathode is essentially constituted by 6% metallic Ni, 66% Ni(OH)2, 4.3% Co(OH)2 and the anode consists mainly in 62% RENi5 and 17% of substitutes and/or additives such as Co, Mn and Al.


2021 ◽  
Vol 13 (6) ◽  
pp. 3272
Author(s):  
Paúl Carrión-Mero ◽  
Maribel Aguilar-Aguilar ◽  
Fernando Morante-Carballo ◽  
María José Domínguez-Cuesta ◽  
Cristhian Sánchez-Padilla ◽  
...  

In the last decade, in the mining district of Zaruma-Portovelo, there has been significant land subsidence related to uncontrolled mining activity. The purpose of this work was to carry out a surface and underground geomechanical characterization of a mining sector north of the city of Zaruma that allows the definition of potentially unstable areas susceptible to the mass movement. The methodology used consists of the following stages: (i) compilation of previous studies; (ii) surface and underground characterization of rocky material to establish its susceptibility to mass movement; (iii) interpretation of results; and (iv) proposal of action measures. Among the most relevant results, it stands out that 26.1% of the 23 stations characterized on the surface present conditions that vary from potentially unstable to unstable. In underground galleries, the studied mean values of the 17 stations indicate that the rock has a medium to good quality, representing a medium susceptibility to gallery destabilization. The results obtained for the surface areas (depths up to 50 m, where altered materials predominate) and the underground areas (depths > 50 m, where the alterations are specific) can be used to identify the areas with a more significant potential for instability. For both cases, it has been possible to define specific monitoring, control, and planning actions for sensitive areas.


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