scholarly journals STUDY OF THE INFLUENCE OF TECHNOLOGICAL PARAMETERS ON THE GRANULOMETRIC CHARACTERISTICS OF SUBMICRON ALUMINUM OXIDE IN α-FORM

Author(s):  
M. Troubitsin ◽  
N. Volovicheva ◽  
L. Furda ◽  
N. Skrypnikov

Experimental studies of the influence of technological parameters of grinding alumina raw materials in a ball mill on the kinetics of the grinding process and the granulometric characteristics of activated alumina in the α-form have been carried out. It is found that the use of spherical grinding bodies leads to the formation of a specific four-modal granulometric composition with maxima: 0.5; 4.0; 50.0 and 400.0 microns, respectively. The disadvantage of using spherical grinding bodies is the uneven distribution of the introduced intensifier additive (PEG), which in turn causes adhesion of fine particles and the appearance of aggregates. This is especially pronounced at n = 100 rpm. When using grinding bodies of cylindrical shape, on the contrary, there is a tendency towards a bimodal nature of the distribution of particles with maxima in the regions of 0.4 and 4 μm, respectively, regardless of the rotation speed of the drum (n). The use of cylpebs does not provoke agglomeration of the fine particle fraction, which is observed in the case of spherical grinding bodies. When analyzing the kinetics of grinding alumina raw materials, two main stages of the process are identified. The first stage corresponds to the active fragmentation of large initial aggregates into constituent crystallites by the cleavage mechanism. The second stage corresponds to a change in the grinding mechanism from crushing to abrasion. It is found that carrying out the grinding process for 10 hours using cylindrical grinding bodies at n = 100 rpm and φ = 0.35 provides a high yield of the submicron fraction of the target product (1 μm) - up to 20 wt. %.

Author(s):  
O. Yu. Kichigina

At production of stainless steel expensive alloying elements, containing nickel, are used. To decrease the steel cost, substitution of nickel during steel alloying process by its oxides is an actual task. Results of analysis of thermodynamic and experimental studies of nickel reducing from its oxide presented, as well as methods of nickel oxide obtaining at manganese bearing complex raw materials enrichment and practice of its application during steel alloying. Technology of comprehensive processing of complex manganese-containing raw materials considered, including leaching and selective extraction out of the solution valuable components: manganese, nickel, iron, cobalt and copper. Based on theoretical and experiment studies, a possibility of substitution of metal nickel by concentrates, obtained as a result of hydrometallurgical enrichment, was confirmed. Optimal technological parameters, ensuring high degree of nickel recovery out of the initial raw materials were determined. It was established, that for direct steel alloying it is reasonable to add into the charge pellets, consisting of nickel concentrate and coke fines, that enables to reach the through nickel recovery at a level of 90%. The proposed method of alloying steel by nickel gives a possibility to decrease considerably steel cost at the expense of application of nickel concentrate, obtained out of tails of hydrometallurgical enrichment of manganese-bearing raw materials, which is much cheaper comparing with the metal nickel.


2020 ◽  
pp. 451-457
Author(s):  
Aleksandr Yur'yevich Vititnev ◽  
Yuriy Davydovich Alashkevich ◽  
Natal'ya Geral'dovna Chistova ◽  
Roman Aleksandrovich Marchenko ◽  
Venera Nurullovna Matygullina

This paper presents the results of experimental studies of the physical and mechanical properties of wood-fiber boards of the wet production method when regulating the design and technological parameters of the grinding process. This allowed us to determine the influence of the working clearance between the grinding discs and the concentration of fibre mass with the subject to of quality change wood fiber after defibrator using the developed construction of the disc fibrillation action on the physico-mechanical properties of boards. As a result of the experiment, regression models were obtained that adequately describe the studied grinding process and allow predicting the values of physical and mechanical properties of the finished product depending on the established  parameters process. A comparative analysis of the size and quality characteristics of the fiber semi-finished product and its fractional composition when using a developed construction the disc of refiner fibrillation action and a traditional design used in industry is carried out. The preferential efficiency of the grinding process under the fibrillating effect the disc of refiner in comparison with the traditional construction disc of refiner is established. As a result, there is a significant improvement in the quality indicators of the fiber semi-finished product and its composition due to the formation and predominance in the total mass of long and thin, respectively, flexible fibrillated fibers with high tile-forming properties, which allows to increase the strength properties of the product (by 20–25%), without using binding resins.


Author(s):  
Gennady Kochetov ◽  
DM Samchenko ◽  
BM Yemchura

Modern requirements to electroplating waste treatment necessitate development of technologies that would allow on-site recycle and reuse of both treated water and residuals of water processing. The most prospective option for introduction of recourse-saving wastewater purification is associated with application the method of ferritisation. In this connection, the paper presents an advanced ferritisation process for reduction of initial concentrations of heavy metals (HM) in exhausted nickel electroplating electrolytes from 100 mg/L to 0.3 mg/L. Effects of main technological parameters of such wastewater treatment at thermal and electromagnetic pulse methods of activation of the ferritisation process were determined experimentally. Kinetics of removal of nickel and iron ions from aqueous solutions was investigated. Phase compositions and properties of sediments from wastewater treated were studied. The sediments are predominantly characterised by crystalline nanostructures, ferromagnetic properties and chemical stability, supporting opportunities for their environmentally sound utilisation. Proposed comprehensive process for treatment of liquid industrial waste flows would prevent contamination by toxic effluents; ensure rational use of water, raw materials and energy inputs.


2019 ◽  
Vol 57 ◽  
pp. 159-164
Author(s):  
N. V. Isichenko ◽  
V. M. Litvin ◽  
G. I. Babayeva ◽  
B. T. Stegniy ◽  
O. V. Dmitriyeva ◽  
...  

The purpose of the research is to investigate the ability to heat the parthenogenesis of new breeds silkworm T–1, T–2, D–1 silkworm breeds and to establish the reproductive, biological and technological parameters of the T–1clone, T–2clone and D–1clone created on their basis. Materials and methods of research. The research was conducted on the basis of the laboratory of silkworm and technical entomology of the National Scientific Center "Institute of Experimental and Clinical Veterinary Medicine" during 2016–2018. For the study of the ability of new breeds of silkworm D–1, T–1, T–2 to the thermal parthenogenesis, the females of the aforementioned silkworms were used. Activation of the gravel to ameiotic parthenogenesis (complete thermal pathogenesis) was carried out using the method B. L. Astaurov The reproductive parameters of parthenoclon were studied: the ability to parthenogenesis (%), the total number of eggs (pieces), the weight of one egg (mg), the output of caterpillars from eggs (%). The economic-valuable and technological indicators of the created clones were investigated: viability of caterpillars (%), cocoon yields of 1 g of caterpillars (kg), silkworm cocoons (%), cocoon mass (g), length of filaments (m), length of continuous- unwound thread (m), raw silk output (%). The main results obtained. It is established that the new clones of silkworm silk created by the ability to parthenogenesis are at the control level. In terms of the viability of caterpillars in 2018, they are somewhat inferior to Ukr.28, but according to the results of three years of research, this indicator is at a level, and T–2clone even exceeds control by 4.84% (p < 0,05). Similar results are obtained on the basis of the weight of the cocoon. By the cocoon yield, the new Parthenoclon exceeds control in 2018 by an average of 0.44 kg and for three years of research – by 0.50 kg. The indicator of silk worminess of cocoons in T–1clones and D–1clones was at the level of the indicator Ukr.28clones, at T–2clone – was higher than the parameters of part-clones and control at 0.83–2.73%. The length of the thread, the length of the continuously unwound yarn and the output of raw silk is dominated by T–2clone – its values exceed the similar indicators of T–1clone and D–1clone, dominated by control indicators – Ukr.28clones. Thus, the new clones of silkworm, adapted to the changed climate in Ukraine, were introduced and evaluated. They can be components for the creation of new clone-breed hybrids with high biological and technological performance. The stands of silkworm hybrids will provide domestic branches of production of organic raw materials for the production of modern products. This will allow import substitution of organic goods for everyday use to our country's inhabitants. Domestic production of organic products in the form of clothing, medical and cosmetic products will provide the work of thousands of compatriots and reduce the cost of goods in comparison with imported ones. Prospects for further scientific research are the creation of new clone-breed hybrids with high biological and technological indices for Ukraine. Conclusions. 1. Three new high-yield silkworm clones with the optimal combination of silk productivity and ability to ameiotic parthenogenesis, characterized by the following biological indices, are derived: T–1clone – caterpillar livelihood 84.13%, cocoon yield 3.76 kg, cocoon mass 2.30 g, silkiness 21.62%; T–2clone – caterpillars' survivability 88.94%, cocoon yield 4.23 kg, cocoon mass 2.53 g, silicone 24.25%; D–1clone. – The viability of the caterpillars is 85.52%, the cocoons are 4.08 kg, the cocoon mass is 2.41 g, and the silicone content is 21.62%. The estimation of reproductive indices of created T–1clone, T–2clone and D–1clone clones was made and their ability to heat parthenogenesis was determined. The highest ability to ameiotic parthenogenesis has D–1clone – 72.73%. Parthenoclones T–1clone, T–2clone and D–1clone for reproductive characteristics are at the level of the control clone Ukr.28clones and are promising for clone- breed hybridization. The technological parameters of the new clones are established: the T–2clone is the leader in the length of the filament (1432m), the length of the continuous unwound yarn (734 m) and the output of raw silk (46.3%) – its parameters exceed the similar indicators in T–1clone and D–1clone at 2.5% and prevail over control indicators – Ukr.28clones – by 5.5%.


2021 ◽  
Vol 9 (16) ◽  
pp. 20-27
Author(s):  
Kulbaram Bayazitova ◽  
◽  
Sulu Zhumakhan ◽  
Aidana Abilda ◽  
Gulmaral Apsemet ◽  
...  

The subject of research. The subject of the research is the production of soft cheese from goat's milk, the features of the technology used for the said, including milk-clotting enzymes and bacterial starter cultures. The purpose of research is to analyze the quality factors and the suitability of the starter culture for the production of soft cheese from goat’s milk to ensure a high yield of finished products, to study the effect of pasteurization modes on the curdling process. Materials and methods. When conducting research on the technological parameters of the production of soft cheese, various amounts of yeast, rennet, and calcium salt were added. The goat’s milk, starter culture, enzyme and calcium chloride available on the market were used. When determining the quality parameters of milk and finished products, we used standard methods for studying sensorial characteristics, determining the content of fat, moisture and dry matter, the mass fraction of protein, density and titratable acidity. Results of research. When conducting research, the duration of cheese mass formation was 8-14 hours. As the amount of added additional raw materials increased in each cheese sample, a decrease in the duration of the formation of the curd mass and the formation of a clot of different consistency were observed. The article also presents the results of studies of sensorial, physical and chemical parameters of samples of the finished soft cheese, describes the technological processes of the production of soft cheese from goat’s milk and the results of studies of factors affecting the quality of products. In particular, the technological parameters of obtaining soft cheese from goat’s milk, the procedure for pasteurization of the milk were studied, the optimal amounts of bacterial yeast, rennet and calcium chloride necessary for the production of cheese mass were determined, the effective concentration values of the enzyme and yeast that improve the physical colloidal properties of the protein clot were determined, these reducing the yield of dry matter during processing, increasing the output of finished cheese, the data on their impact on product quality is also provided. The benefits of the soft cheese made from goat's milk are due to the efficient use of raw materials, proper nutritional value and high yield of finished products. Sensorial, physical and chemical characteristics of ready soft cheeses have been studied. According to the results of the study, a sample of soft cheese from goat's milk was selected that fully meets the regulatory documents, without cheese defects in terms of physical and chemical parameters, fat content, moisture content, salt content, as well as sensorial properties. Scope of research results. The results of the research will be used to improve the technology for the production of milk products, namely, soft cheese from goat’s milk, to improve the food safety and consumer properties of the specified product.


2018 ◽  
Vol 4 ◽  
pp. 21-28
Author(s):  
Gregoriy Deynichenko ◽  
Vasyl Guzenko ◽  
Dmytro Dmytrevskyi ◽  
Vitalii Chervonyi ◽  
Tatiana Kolisnichenko ◽  
...  

The aim of research is studying a new method for intensifying extraction of pectin substances during acid extraction of pectin-containing raw materials. The description of the experimental setup and the procedure for processing the results of the investigation of the application of a new method for intensifying the beet pulp extraction are described. The results of experimental studies on the application of a new combined mixing element for intensifying the extraction of pectin-containing raw materials (beet pulp) and its effect on quantitative and qualitative output characteristics are presented. Mathematical models are constructed on the basis of regression equations of the full factorial experiment with the use of a new method of intensifying the extraction process to select input technological parameters for the extraction of pectin substances from pectin-containing raw materials. The rational operating parameters of the process of extraction of pectin substances with the use of a new combinable stirring element are determined. Such working parameters are: the process duration is 1 ... 1.1, the temperature of the working medium is 60 ... 70 ºС, and the hydromodule is 8 ... 10. The research results can be used to study other technological parameters of the extraction process of pectin substances, as well as to develop a technological line for the production of pectin products.


Author(s):  
Valery T. Kazub ◽  
Maria K. Kosheleva ◽  
Stanislav P. Rudobashta

The influence of the degree of grinding of the particles of growing raw materials during electric discharge extraction on the quality of the obtained extracts was studied. Each discharge during electro-discharge extraction contributes to the grinding of a part of the raw material, which is confirmed by granulometric analysis. The particle size of the raw material should be controlled, since excessive grinding of the extracts results in cloudy, difficult to clarify and poorly filtered. The design of the extraction chamber is proposed, in which the grounded electrode is made in the form of a perforated plate, called a false bottom, with the optimal size of the holes and their density, which eliminates the over-grinding of the raw material particles, which leads to the production of turbid and difficult-to-filter extracts. Since the extraction of raw materials is carried out at a certain ratio of solid-liquid phases, the volume of the chamber from the sieve to the bottom does not significantly affect the kinetics of the extraction process itself, since it is intended for collecting the smallest particles of processed raw materials, the mass of which does not exceed 15-16% of the loaded mass of raw materials. The device of the extraction chamber, due to the high turbulence and intensive mixing of the suspension under the action of cavitation and shock waves initiated by the discharge in the liquid, allows you to remove small particles of raw materials less than 1 mm in size from the working area of the chamber. The results of the study show that the extraction of target components from various raw materials using a chamber with a false bottom can significantly reduce the content of the smallest particles of raw materials in the extract. It facilitates the filtration of the extract, reduces the filtration time, significantly reduces the likelihood of turbidity of the solution due to suspension, which improves the quality of the extract. Experimental studies of the developed electric discharge chamber with a false bottom, conducted with various types of plant raw materials, confirm the effectiveness of extraction in the chamber of the proposed design.


Author(s):  
D. Yelatontsev ◽  
O. Kharitonova

Today's level of integrated use of minerals and beneficiation wastes in Ukraine, in particular, at the Kryvbas GOK, is unsatisfactory, as it is generally allowing the production of additional types of construction products. The volume of mining is growing, but only a small percentage of the extracted volume is transferred to the finished product. The residue in the form of waste is returned to the environment, polluting it. The reason for this is the lack of technology for integrated mineral processing and waste disposal. The article presents the results of industrial tests of off-balance manganese ore processing technology of Ordzhonikidze GOK with a manganese content of 15–30%. It is shown that nitric acid leaching of manganese with subsequent precipitation of impurities with soda or alkali allows you to consistently purify manganese from transition and alkaline earth metals. The obtained manganese oxide has a high degree of purity, which allows obtaining pure compounds Mn (NO3)2∙6H2O, MnO2 and metallic manganese for chemical current sources. The use of columnar clarifiers with a fluidized bed with the application of pulsations allowed to eliminate time-consuming filtration processes. Concomitantly formed sodium nitrate serves as a raw material for mineral fertilizers. Experimental studies on the beneficiation of off-balance manganese ores allowed us to determine the main technological parameters of the extraction of components and to develop a technological scheme of beneficiation. According to the proposed technological scheme, it is possible to obtain high-quality concentrates of manganese (IV) oxide. The use of optimal technological parameters of enrichment allows up to 95% of Mn to be extracted from off-balance manganese raw materials. In the long run, this will reduce dependence on imports of manganese raw materials and significantly reduce the cost of domestic manganese products.


2020 ◽  
Vol 5 (443) ◽  
pp. 28-37
Author(s):  
Bisenov Kylyshbai Aldabergenovich, ◽  
◽  
Narmanova Roza Abdibekovna, ◽  
Appazov Nurbol Orynbassaruly, ◽  
◽  
...  

The article presents the results of gas chromatographic studies of the oil sludge hydrocarbon composition, physical and chemical and heat-producing properties, which enabled to assess the potential of oil sludge as raw materials, their assortment predisposition and possible manufacturability. It has been established that the main physical and chemical characteristics of the organic part from the averaged samples of oil sludge are similar in properties to raw materials for the production of kerosene-diesel fractions. The expediency of the use of oil sludge and weakly bloating clay materials in the production technology of the popular construction material – expanded clay is substantiated. The results of experimental studies on the development of light and porous heat insulating material by granulation method are presented herein. It is shown that oil sludge from a high viscous state is transferred to a loose conglomerate with a moisture content of 12–15% by co-mixing with finely dispersed sand dune, which ensures uniform distribution when mixed with the basic mass. The peculiarities of granules burning according to a specially developed mode without preliminary drying are considered. It has been established that the addition of oil sludge increases the organic content in the mixture, thereby intensifying the process of combustion, gas generation and bloating of the ceramic body, which will positively affect the technological parameters of obtaining а product. It is found that the proposed technology allows to obtain marketable products, which can be used efficiently. At the same time, the unconditional priority is given to waste-free technologies, as the most environmentally friendly.


2020 ◽  
Vol 63 (5) ◽  
pp. 344-350
Author(s):  
O. I. Nokhrina ◽  
I. D. Rozhikhina ◽  
A. I. Edil’baev ◽  
B. A. Edil’baev

Manganese ores of the vast majority of domestic deposits are of low quality: with low content of manganese (18 – 24 %) and high specific content of phosphorus (ratio P/Mn > 0.006). They have an increased content of iron and silicon and they are difficult to enrich. The main part of balance reserves of manganese ores – 98.5 million tons (64.2 %) is concentrated in large Usinskoye field in the Kemerovo region. In addition to Usinskoye, there are also deposits in this region Kaigadatskoye (32.7 million tons), Durnovskoye (300 thousand tons), Selezenskoye fields and the Chumay plot. For a comprehensive approach to solving the proposed problem it is needed to assess technical and economic feasibility of all stages (exploration, extraction and enrichment of manganese ores, their subsequent processing and consumption) of involvement of manganese ores from these deposits in production. Using developed technology of calcium-chloride enrichment, high-quality manganese concentrates are obtained from carbonate, including high-phosphorous ores of the Usinskoye field, poor oxide and ferromanganese ores of the Selezenskoye and the Durnovskoye fields. Extraction of manganese from manganese-containing raw materials into concentrate was at least 90 %. The resulting concentrate contains 58 – 64 % of manganese, less than 0.01 % of phosphorus, 0.02 – 0.05 % of iron oxide, 0.5 – 1.0 % of silica and sulfur. Thermodynamic calculations and experimental studies on the enrichment of polymetallic manganese-containing ores from the Chumay plot allowed us to determine the main technological parameters for extracting valuable components. The use of optimal technological parameters of enrichment allows extraction of up to 95 – 97 % of manganese and 98 – 99 % of nickel from raw materials.


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