scholarly journals Developed Method for Treatment of Industrial Wastewater from Edible Oil Industry using Membrane Technology

2020 ◽  
Vol 9 (3) ◽  
pp. 3034-3038
Keyword(s):  
Surface Water ◽  
Removal Efficiency ◽  
Membrane Filtration ◽  
Negative Impact ◽  
Edible Oil ◽  
Tween 20 ◽  
Market Demand ◽  
Permeate Flux ◽  
Industrial Sectors ◽  
Ro Membrane

Microorganisms and algae growth on surface water are stimulated in surface water in the presence of effluent wastewater from edible oil industries. This leads to depletion of dissolved oxygen (DO) by eutrophication process result in negative impact on aquatic environment. The new regulation in environment agency and increasing market demand are forcing the industrial sectors to consider finding new solutions and sustainable techniques of the wastewater treatment. In this study, reverse osmosis (RO) membrane filtration has been applied to assess the removal performance of emulsified oil from wastewater. Polysorbate 20 (Tween 20) was used as an oil/water emulsifier. Effect of oil concentrations in terms of chemical oxygen demand (COD) and activated carbon unit on removal efficiency and permeate flux have been studied in details. The results elucidated significant improvement in removal efficiency reached to "98%". The obtained results show promising application of RO membrane (polyamide membrane) at flux "17 L/m2 hr-1". The experiments showed that membrane filtration of wastewater from edible oil is a convenient technique for a possible removal of high concentration of oil (up to 6000 mg/L) with "98%" removal efficiency at permeate flux "17 L/m2 hr-1 "and low fouling rate.

scholarly journals Oily Wastewater Treatment Using Polyamide Thin Film Composite Membrane Technology

Membranes ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 84 ◽  
Author(s):  
Sarah Elhady ◽  
Mohamed Bassyouni ◽  
Ramadan A. Mansour ◽  
Medhat H. Elzahar ◽  
Shereen Abdel-Hamid ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Membrane Filtration ◽  
Edible Oil ◽  
Oily Wastewater ◽  
Permeate Flux ◽  
Treatment Unit ◽  
Thin Film Composite ◽  
Ro Membrane ◽  
Pre Treatment ◽  
Oil Wastewater

In this study, polyamide (PA) thin film composite (TFC) reverse osmosis (RO) membrane filtration was used in edible oil wastewater emulsion treatment. The PA-TFC membrane was characterized using mechanical, thermal, chemical, and physical tests. Surface morphology and cross-sections of TFCs were characterized using SEM. The effects of edible oil concentrations, average droplets size, and contact angle on separation efficiency and flux were studied in detail. Purification performance was enhanced using activated carbon as a pre-treatment unit. The performance of the RO unit was assessed by chemical oxygen demand (COD) removal and permeate flux. Oil concentration in wastewater varied between 3000 mg/L and 6000 mg/L. Oily wastewater showed a higher contact angle (62.9°) than de-ionized water (33°). Experimental results showed that the presence of activated carbon increases the permeation COD removal from 94% to 99%. The RO membrane filtration coupled with an activated carbon unit of oily wastewater is a convenient hybrid technique for removal of high-concentration edible oil wastewater emulsion up to 99%. Using activated carbon as an adsorption pre-treatment unit improved the permeate flux from 34 L/m2hr to 75 L/m2hr.

scholarly journals Performance of a novel recycling magnetic flocculation membrane filtration process for tetracycline-polluted surface water treatment

2017 ◽  
Vol 76 (2) ◽  
pp. 490-500 ◽  
Author(s):  
Yufei Wang ◽  
Hui Jia ◽  
Hongwei Zhang ◽  
Jie Wang ◽  
Wenjin Liu
Keyword(s):  
Surface Water ◽  
Membrane Fouling ◽  
Membrane Filtration ◽  
Average Particle Size ◽  
Quality Parameters ◽  
Average Particle ◽  
Permeate Flux ◽  
Personal Care Product ◽  
Surface Water Treatment ◽  
Scale Experiment

A recycling magnetic flocculation membrane filtration (RMFMF) process integrating circulating coagulation, magnetic enhanced flocculation and membrane filtration was investigated for the treatment of surface water micro-polluted by tetracycline, a typical pharmaceutical and personal care product. A bench-scale experiment was conducted and several water quality parameters including turbidity, ultraviolet absorbance at 254 nm (UV254), total organic carbon and tetracycline concentration were evaluated, taking coagulation membrane filtration and magnetic flocculation membrane filtration processes as reference treatments. The experimental results showed that at the optimum doses of 20 mg·L−1 ferric chloride (FeCl3), 4 mg·L−1 magnetite (Fe3O4) and 6 mg·L−1 reclaimed magnetic flocs in RMFMF processes, removal efficiencies of above evaluated parameters ranged from 55.8% to 92.9%, which performed best. Simultaneously, the largest average particle size of 484.71 μm and the highest fractal dimension of 1.37 of flocs were achieved, which did not only present the best coagulation effect helpful in enhancing the performance of removing multiple contaminants, but also lead to the generation of loose and porous cake layers favouring reduced permeate flux decline and membrane fouling.

Application of MIEX® pre-treatment for ultrafiltration membrane process for NOM removal and fouling reduction

2005 ◽  
Vol 5 (5) ◽  
pp. 15-24 ◽  
Author(s):  
H.J. Son ◽  
Y.D. Hwang ◽  
J.S. Roh ◽  
K.W. Ji ◽  
P.S. Sin ◽  
...  
Keyword(s):  
Organic Matter ◽  
Removal Efficiency ◽  
Membrane Fouling ◽  
Membrane Filtration ◽  
Reduction Rate ◽  
Chemical Characteristics ◽  
Permeate Flux ◽  
Physical Chemical ◽  
Sample Water ◽  
Original Water

In this study, pretreatment of organic matters with MIEX® was evaluated using bench-scale experimental procedures on three organic matters to determine its effect on subsequent UF or MF membrane filtration. For comparison, a coagulation process was also used as a pretreatment of UF or MF membrane filtration. Moreover, the membrane fouling potential was identified using different fractions and molecular weights (MW) of organic matter. From the removal property of MW organic matter by the coagulation process for the sample water NOM and AOM, the removal efficiencies of high MW organic matter were much higher than those of low MW organic matter. It was shown that the removal efficiency of high MW organic matter (more than 10 kDa) was lower than that of low MW organic matter for the MIEX® process. For the change of permeate flux by the pretreatment process, the MIEX®-UF process showed high removal efficiency of organic matter compared with the coagulation-UF processes, but a high reduction rate of permeate flux was presented through the reduction of removal efficiency of high MW organic matter. From sequential filtration test results to examine the effect of MW of organic matter on membrane fouling, we found that the membrane fouling occurred with high MW organic matter, and the DOC of organic matter less than 0.5 mg/L was acting as the membrane foulant. In sample water composed of low MW organic matter (less than 10 kDa), because the low MW organic matter of less than 10 kDa has a high removal efficiency by MIEX®, a low reduction rate of permeate flux is obtained compared with the coagulation-UF processes. In summary, research on the physical/chemical characteristics of original water is needed before a membrane pretreatment process is selected, and a pertinent pretreatment process should be used based on the physical/chemical characteristics of the original water.

Evaluation of a MF membrane system composed of pre coagulation-sedimentation and chlorination for water reuse

2006 ◽  
Vol 54 (10) ◽  
pp. 115-121 ◽  
Author(s):  
S.H. Lee ◽  
B.C. Lee ◽  
S.Y. Moon ◽  
Y.S. Choi ◽  
N.Y. Jang ◽  
...  
Keyword(s):  
Water Quality ◽  
Surface Water ◽  
River Water ◽  
Removal Efficiency ◽  
Membrane Filtration ◽  
Transmembrane Pressure ◽  
Stable Operation ◽  
Feed Water ◽  
Promising Alternative ◽  
Sedimentation Process

In this research, we investigated the variation of transmembrane pressure and permeate water quality in pre-coagulation and sedimentation with iron based coagulant, and chlorination of feed water for PVDF (Polyvinylidene fluoride) based MF membrane filtration. NaClO was fed to the membrane module at a dosage of 0.5 mg/L and maintained during filtration. To observe the effect of raw water, three types of raw and processed waters, including river surface water, coagulated water and coagulated-settled water, were employed. In the case of river surface water, the transmembrane pressure increased abruptly in 500 hours operation. On the contrary, no significant increase in transmembrane pressure was observed for coagulated water and coagulated-settled water for 1200 hours operation. The turbidity of permeate was lower than the detection limit for all applied waters. The removal efficiency for humic substances in coagulated water and coagulated-settled water was approximately ten times higher than that in surface river water. And, the removal efficiency for TOC and DOC was approximately two times higher than that in surface river water. From the results of the operation, it can be observed that it is possible to maintain stable operation at 0.9 m3/m2-day filtration flux through a combination of pre-coagulation and pre-chlorination. However, the water quality of permeate was the best when the pre-coagulation-sedimentation process was combined with pre-chlorination. With respect to fouling reduction and operation efficiency increase in membrane filtration, the pre-coagulation/sedimentation process is a promising alternative.

scholarly journals Performance of a Micro-Scale Membrane Reactor for Greywater Treatment at Household Level

Membranes ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 63
Author(s):  
Vasileios Diamantis
Keyword(s):  
Removal Efficiency ◽  
Water Conservation ◽  
Water Reuse ◽  
Membrane Reactor ◽  
Membrane Filtration ◽  
Iron Hydroxide ◽  
Permeate Flux ◽  
Household Level ◽  
Capital Costs ◽  
Working Volume

An aerated membrane reactor (25 L working volume) equipped with 1.5 m2 hollow-fiber module was designed and operated using synthetic greywater for household water reuse. Activated sludge (MBR), activated carbon (PAC), zeolite (ZEO) and iron hydroxide (GEH) were added in separate experiments to optimize membrane hydraulic performance and removal efficiency of organics. The use of additives improved permeate quality (in terms of Chemical Oxygen Demand—COD) compared to the direct membrane filtration mode of operation. GEH and MBR were efficient for phosphorus removal, which was not the case for PAC and ZEO. No significant improvement of membrane flux was recorded when PAC, ZEO or GEH were added inside the membrane tank. The MBR system displayed optimum performance during medium-term operation, with COD removal efficiency 85% and permeate flux between 40 and 25 L m−2 h−1. The capital costs of the proposed technology were around 300 € and the operational costs below 80 € yr−1, rendering the process feasible at household level. Greywater treatment systems for household applications are still on their infancy; however, this trend is expected to change due public perception towards circular economy, water conservation and reuse.

scholarly journals Impact of Advanced Oxidation Products on Nanofiltration Efficiency

Water ◽  
2019 ◽  
Vol 11 (3) ◽  
pp. 541 ◽  
Author(s):  
Renata Żyłła ◽  
Rafał Milala ◽  
Irena Kamińska ◽  
Marcin Kudzin ◽  
Marta Gmurek ◽  
...  
Keyword(s):  
Salicylic Acid ◽  
Membrane Filtration ◽  
Main Product ◽  
Membrane Separation ◽  
Negative Impact ◽  
Microscopic Analysis ◽  
Contact Angles ◽  
Oxidation Products ◽  
Acid Oxidation ◽  
Dihydroxybenzoic Acid

The aim of the work was to determine the influence of salicylic acid (SA) oxidation products on the effectiveness of their further removal in the membrane filtration process. Two commercial polyamide-based polymer membranes, HL (GE Osmonics) and TS80 (TriSepTM), were used and characterized by SEM microscopic analysis, contact angles, and free surface energy. The products of salicylic acid oxidation, 2,3- and 2,5-dihydroxybenzoic acid and catechol, were determined and their impact on the removal of unreacted salicylic acid in the nanofiltration process was investigated. It was also checked to what extent and why they were retained or not by the membranes. The results of the research have shown that the main product of salicylic acid oxidation, 2,3-dihydroxybenzoic acid, has a negative impact on the retention of salicylic acid in the nanofiltration stage, while the other product, catechol, improves SA retention. The determined values of contact angles correlate well with solubility (S) of the tested compounds, which increases in the following order SSA < S2,3-DHBA < SCAT, while the contact angle of the membrane decreases. Nevertheless, it has been shown that some oxidation products can penetrate the environment due to poorer membrane separation properties of these products.

Concentration and Desalination of Protein Derived from Tuna Cooking Juice by Nanofiltration

2013 ◽  
Vol 65 (4) ◽  
Author(s):  
Muhammadameen Hajihama ◽  
Wirote Youravong
Keyword(s):  
Membrane Filtration ◽  
Protein Concentration ◽  
Protein Hydrolysate ◽  
Salt Content ◽  
Cross Flow ◽  
Transmembrane Pressure ◽  
Permeate Flux ◽  
Batch Mode ◽  
Additional Process ◽  
Canning Industry

Tuna cooking juice is a co-product of tuna canning industry. It riches in protein, currently used for production of feed meal as well as protein hydrolysate. The finish products are usually in the form of concentrate, produced by evaporation process. However, evaporation is energy consumable process and the salt content level of the concentrate is often over the standard, thus required additional process for lowering salt content e.g. crystallization. The use of membrane technology, therefore, is of interest, since it required less energy and footprint compared with evaporation and is also able to reduce salt content of the concentrate. The aim of this study were to employ and select the membrane filtration process, and optimize the operating condition for protein concentration and desalination of tuna cooking juice. The results indicated that nanofiltration (NF) was more suitable than the ultrafiltration (UF) process, regarding the ability in protein recovery and desalination. The NF performance was evaluated in terms of permeation flux and protein and salt retentions. The protein and salt rejections of NF were 96 % and 5 %, respectively. The permeate flux(J) increased as transmembrane pressure (TMP) or cross flow rate (CFR) increased and the highest flux was obtained at TMP of 10 bar and CFR of 800 L/h. Operating with batch mode, the permeate flux was found to decrease as protein concentration increased, and at volume concentration factor about 4, the protein concentration  about 10% while salt removal was aproximately 70 % of the initial value. This work clearly showed that NF was successfully employed for concentration and desalination of protein derived from tuna cooking juice.

Treatment of highly-colored surface water by a hybrid microfiltration membrane system incorporating ion-exchange

2018 ◽  
Vol 19 (3) ◽  
pp. 855-863 ◽  
Author(s):  
T. Miyoshi ◽  
Y. Takahashi ◽  
T. Suzuki ◽  
R. Nitisoravut ◽  
C. Polprasert
Keyword(s):  
Surface Water ◽  
Hybrid System ◽  
Membrane Fouling ◽  
Membrane Filtration ◽  
Membrane System ◽  
Pilot Scale ◽  
Manganese Concentration ◽  
Moderate Increase ◽  
Coagulant Dosage ◽  
Filtration System

Abstract This study investigated the performance of a hybrid membrane filtration system to produce industrial water from highly-colored surface water. The system consists of a membrane filtration process with appropriate pretreatments, including coagulation, pre-chlorination, and anion exchange (IE) process. The results of the pilot-scale experiments revealed that the hybrid system can produce treated water with color of around 5 Pt-Co, dissolved manganese concentration of no more than 0.05 mg/L, and a silt density index (SDI) of no more than 5 when sufficient coagulant and sodium hypochlorite were dosed. Although the IE process effectively reduced the color of the water, a moderate increase in the color of the IE effluent was observed when there was a significant increase in the color of the raw water. This resulted in a severe membrane fouling, which was likely to be attributed to the excess production of inorganic sludge associated with the increased coagulant dosage required to achieve sufficient reduction of color. Such severe membrane fouling can be controlled by optimising the backwashing and relaxation frequencies during the membrane filtration. These results indicate that the hybrid system proposed is a suitable technology for treating highly-colored surface water.

scholarly journals The role of wastewater treatment plants in surface water contamination by plastic pollutants

2018 ◽  
Vol 45 ◽  
pp. 00054 ◽  
Author(s):  
Bozena Mrowiec
Keyword(s):  
Wastewater Treatment ◽  
Surface Water ◽  
Water Contamination ◽  
Membrane Filtration ◽  
Municipal Wastewater ◽  
Wastewater Treatment Plants ◽  
Point Sources ◽  
Municipal Sewage ◽  
Municipal Wastewater Treatment ◽  
Surface Water Contamination

The aim of this paper was to review the literature data regarding the physico-chemical characteristic of plastic pollutants discharged with municipal sewage, the practical possibility of removing microplastic particles from wastewater during different treatment steps in WWTPs and the problem of surface water contamination within them. Microplastics (the size range of 1 nm to < 5 mm), have been recognized as an emerging threat, as well as an ecotoxicological and ecological risk for water ecosystems. Municipal wastewater treatment plants (WWTPs) are mentioned as the main point sources of microplastics in an aquatic environment. Microplastic particles can be effectively removed in the primary treatment zones via solids skimming and sludge settling processes. Different tertiary treatment processes such as: gravity sand filtration, discfilter, air flotation and membrane filtration provide substantial additional removal of microplastics, and the efficiency of wastewater treatment process can be at a removal level of 99.9%. Nevertheless, given the large volumes of effluent constantly discharged to receivers, even tertiary level WWTPs may constitute a considerable source of microplastics in the surface water.

Removal Mechanisms for Pharmaceuticals and Personal Care Products (PPCPs) in Water by NF/RO Membranes

2013 ◽  
Vol 726-731 ◽  
pp. 2502-2505
Author(s):  
Zhong Hua Huang ◽  
Zheng Li Liu ◽  
Li Jun Zhu ◽  
Guli Mira Akbar
Keyword(s):  
Human Health ◽  
Removal Efficiency ◽  
Aquatic Environment ◽  
Membrane Filtration ◽  
Personal Care Products ◽  
Separation Method ◽  
Ecological Environment ◽  
Personal Care ◽  
Removal Mechanisms ◽  
Micro Pollutants

Pharmaceuticals and personal care products (PPCPs) have been widely detected in aquatic environment in recent years; as emerging micro-pollutants, their influence on human health and ecological environment safety are of increasing concern. Membrane filtration is considered as the suitable separation method for PPCPs removal due to different removal mechanisms. This paper reviews the removal efficiency and removal mechanisms for PPCPs by NF/RO membranes.

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