scholarly journals Benzenesulfonic Acid - an Green Efficient Esterification Catalysts for Continuous Synthesis of n-propyl Acetate

2021 ◽  
Vol 72 (2) ◽  
pp. 94-101
Author(s):  
Zhijun Xia
Keyword(s):  
Sulfuric Acid ◽  
High Yield ◽  
Benzenesulfonic Acid ◽  
Propyl Acetate ◽  
Comparison System ◽  
Fast Evaluation ◽  
Green Catalyst ◽  
Continuous Synthesis ◽  
Continuous Rectification ◽  
The Stability

The esterification of acetic acid and n-propanol catalyzed by benzenesulfonic acid and its derivatives in the batch and continuous rectification tower was studied, in order to develop a new effective and green catalyst instead of the oxidative and corrosive sulfuric acid. A series of the comparison system with sulfuric acid was build for the targeted and fast evaluation of catalysts. The results showed that the catalytic esterification activity of p-phenolsulfonic acid and p-toluenesulfuric acid is very closed to sulfonic acid in the continuous rectification tower. Furthermore, the stability test for continuous esterification with p-toluenesulfuric acid presented that the high yield of n-propyl acetate could maintain 50 hours and stability. Therefore, p-phenolsulfonic acid and p-toluenesulfuric acid could be prospective substitutes for sulfuric acid for the continuous synthesis of n-propyl acetate in the rectification tower.

Synthesis and solvatochromic studies of 2- amino-3-phenolazo1-(4-sulfophenyl)-3-methyi-5-pyrozolone and use it for the determination of trace amount of Nickel (II) in blood samples

2016 ◽  
Vol 5 (10) ◽  
pp. 4920
Author(s):  
Amar M. Ali ◽  
Hussain. J. Mohammed*
Keyword(s):  
Stability Constant ◽  
Trace Amount ◽  
Benzenesulfonic Acid ◽  
Determination Method ◽  
Blood Samples ◽  
Determination Of Nickel ◽  
Normal Human ◽  
The Stability ◽  
Normal Human Blood

A new, simple, sensitive and rapid spectrophotometric method is proposed for the determination of trace amount of Nickel (II). The method is based on the formation of a 1:2 complex with 4-(4-((2-hydroxy-6-nitrophenyl) diazenyl) -3-methyl-5-oxo-2, 5-dihydro-1H-pyrazol-1-yl) benzenesulfonic acid (2-ANASP) as a new reagent is developed. The complex has a maximum absorption at 516 nm and εmax of 1. 84 X 105 L. mol-1. cm-1. A linear correlation (0. 25 – 4. 0μg. ml-1) was found between absorbance at λmax and concentration. The accuracy and reproducibility of the determination method for various known amounts of Nickel (II) were tested. The results obtained are both precise (RSD was 1. 2 %) and accurate (relative error was 0. 787 %). The effect of diverse ions on the determination of Nickel (II) to investigate the selectivity of the method were also studied. The stability constant of the product was 0. 399 X 106 L. mol-1. The proposed method was successfully applied to the analysis of diabetes blood and normal human blood. 

scholarly journals VARIABILTY AND STABILTY OF TUBER YIELD OF JERUSALEM ARTICHOKE (Helianthus tuberosus L.) / VARIABILIDAD Y ESTABILIDAD DEL RENDIMIENTO DE TUBERCULOS DEL TOPINAMBO / VARIABILITÉ ET STABILITÉ DU RENDEMENT DU TUBERCULE DE TOPINAMBUR

Helia ◽  
2001 ◽  
Vol 24 (35) ◽  
pp. 25-32 ◽  
Author(s):  
Janoš Berenji ◽  
Vladimir Sikora
Keyword(s):  
Tuber Yield ◽  
Jerusalem Artichoke ◽  
Tuber Size ◽  
Yield Stability ◽  
Tuber Number ◽  
High Yield ◽  
Helianthus Tuberosus ◽  
Variety Trial ◽  
Stable Performance ◽  
The Stability

SUMMARYThe objective of this paper was to estimate the genetic and ecological variation as well as the stability of tuber yield per plant, tuber number per plant and tuber size of Jerusalem artichoke based on the results of a variety trial carried out with 20 different Jerusalem artichoke varieties during the period of 1994-2000. Significant genetic as well as ecologycal variation was observed for all of the traits studied. The most promissing varieties showing high tuber yield combined with high yield stability were “BT-4”, “Violet Rennes” and “UKR 4/ 82”. It is encouraging that the highest yielding varieties exibited a rather stable performance over environments.

scholarly journals Stability of Wheat Genotypes by AMMI and Yield Evaluated under Peninsular Zone of India

2021 ◽  
Author(s):  
Ajay Verma ◽  
G.P. Singh
Keyword(s):  
Weighted Average ◽  
Principal Component ◽  
Efficient Estimation ◽  
High Yield ◽  
First Year ◽  
Wheat Genotypes ◽  
Stability Measure ◽  
Linear Behaviour ◽  
The Stability ◽  
Selection Of

Background: Efficient estimation of main and interaction effects under multi environment trials had been carried out by AMMI. Studies with low proportion of the variance explained by first interaction principal component IPCA1 under AMMI analysis had been reported biased interpretation for the stability of the genotypes.Methods: Weighted Average of Absolute scores (WAASB), quantitative stability measure had been recommended for selection of productive genotypes with broad adaptation. The selection of promising genotypes had been assisted by use of superiority index (WAASBY) that considered simultaneous use of yield and stability by allowing variable weighting mechanism for yield and stability.Result: Wheat GW509 and HI1633 genotypes had been identified by stability measure WAASB for the first year. While Superiority index considered stability and high yield settled for HI1633 and Raj4083 genotypes. Analytic measures of adaptability PRVG and MHPRVG observed suitability of HI1633 and Raj 4083. SI expressed positive linear behaviour with yield, MHPRVG and PRVG measures. While stability measure WAASB maintained moderate negative correlation with yield, SI, MHPRVG and PRVG. Wheat genotypes HI1633, HI1641 and HI1646 identified by stability measure for the next year of study. Superiority index selected HI1641, HI1633 and MACS6752 genotypes. SI expressed direct linear relation with yield, MHPRVG and PRVG. Stability measure exhibited indirect relationships with SI, MHPRVG, PRVG and yield Wheat genotypes HI1633, Raj 4083 for first year and HI1641, MACS6752 for the second year of study.

scholarly journals Catalytic condensation of phenol with formaldehyde into BPF on recyclable anchoring sulfuric acid

2020 ◽  
Vol 213 ◽  
pp. 01003
Author(s):  
Hui Li ◽  
Xi Cao ◽  
Huiting He ◽  
Jian Liu ◽  
Weijian Xiang ◽  
...  
Keyword(s):  
Sulfuric Acid ◽  
Solid Acid Catalyst ◽  
Acid Catalyst ◽  
Catalytic Performance ◽  
Significant Loss ◽  
High Yield ◽  
Element Analysis ◽  
Simple Filtration ◽  
Ft Ir ◽  
The Mind

A novel solid-acid catalyst (PVC-EDA-SO4H) based on polyvinyl chloride (PVC) were prepared after amination of Ethylenediamine (EDA) and anchorage of sulfuric acid. The as-prepared catalyst was characterized by FT-IR, Element analysis, Chemical titration and Thermal analysis, the results indicated that the sulfuric acid was successfully anchored on PVC. The PVC-EDA-SO4H showed excellent catalytic performance for the synthesis of bisphenol F, and achieved almost high yield and selectivity (94%) of BPF under the mind reaction conditions. Meanwhile, exhibited excellent reusability without the significant loss after six cycles via simple filtration.

scholarly journals Environmental impact of intensive farming in sloping areas

2018 ◽  
Vol 174 ◽  
pp. 01001
Author(s):  
Giovanni Bosco ◽  
Lucia Simeoni
Keyword(s):  
Pore Water Pressure ◽  
Water Pressure ◽  
Sprinkler Irrigation ◽  
High Yield ◽  
Qualitative And Quantitative ◽  
Intensive Farming ◽  
Yield Production ◽  
Large Water ◽  
The Stability ◽  
Irrigation Runoff

The increased demand for food causes intensive farming with high yield production and large water consumption to extend significantly. Depending on soil properties, seasonal rainfall, surface drainage and water resources, hence the consumption-infiltration balance, the ground water table might be raised or depleted; soils could be saturated or remain partly saturated with negative pore pressures. As a result sloping grounds may become prone to shallow slides, as mudflows, or deep seated movements, involving large volumes of soil, especially after rupture of major watering lines or after long uncontrolled irrigations. Within this framework the paper investigates the possible effects of replacing grassland with intensive apple farming on the stability conditions of slopes. Apples require frequent watering, especially during spring and summer to meet qualitative and quantitative productive standards. Also, sprinkler irrigation is often used to protect against hail. From the precipitation, irrigation, runoff, evaporation and plant transpiration balance, the evolution of the pore water pressure distribution within an average year is calculated. Then the modified shear strength of the unsaturated-saturated soils is determined and the factor of safety against sliding is calculated.

scholarly journals Dynamics Analysis and Biomass Productivity Optimisation of a Microbial Cultivation Process through Substrate Regulation

2016 ◽  
Vol 2016 ◽  
pp. 1-13
Author(s):  
Kaibiao Sun ◽  
Shan Liu ◽  
Andrzej Kasperski ◽  
Yuan Tian
Keyword(s):  
Periodic Solution ◽  
Substrate Concentration ◽  
Process Model ◽  
Biomass Productivity ◽  
High Yield ◽  
Dynamics Analysis ◽  
State Dependent ◽  
Cultivation Process ◽  
Microbial Cultivation ◽  
The Stability

A microbial cultivation process model with variable biomass yield, control of substrate concentration, and biomass recycle is formulated, where the biochemical kinetics follows an extension of the Monod and Contois models. Control of substrate concentration allows for indirect monitoring of biomass and dissolved oxygen concentrations and consequently obtaining high yield and productivity of biomass. Dynamics analysis of the proposed model is carried out and the existence of order-1 periodic solution is deduced with a formulation of the period, which provides a theoretical possibility to convert the state-dependent control to a periodic one while keeping the dynamics unchanged. Moreover, the stability of the order-1 periodic solution is verified by a geometric method. The stability ensures a certain robustness of the adopted control; that is, even with an inaccurately detected substrate concentration or a deviation, the system will be always stable at the order-1 periodic solution under the control. The simulations are carried out to complement the theoretical results and optimisation of the biomass productivity is presented.

scholarly journals Wastewater Minimization in Indirect Electrochemical Synthesis of Phenylacetaldehyde

2002 ◽  
Vol 2 ◽  
pp. 48-52 ◽  
Author(s):  
Zhirong Sun ◽  
Xiang Hu ◽  
Ding Zhou
Keyword(s):  
Sulfuric Acid ◽  
Current Efficiency ◽  
Electrochemical Oxidation ◽  
Acid Concentration ◽  
Electrochemical Synthesis ◽  
Chemical Process ◽  
Sulfuric Acid Concentration ◽  
High Yield ◽  
High Current ◽  
High Current Efficiency

Wastewater minimization in phenylacetaldehyde production by using indirect electrochemical oxidation of phenylethane instead of the seriously polluting traditional chemical process is described in this paper. Results show that high current efficiency of Mn(III) and high yield of phenylacetaldehyde can be obtained at the same sulfuric acid concentration (60%). The electrolytic mediator can be recycled and there will be no waste discharged.

scholarly journals A Fast, Highly Efficient, and Green Protocol for Synthesis of Biscoumarins Catalyzed by Silica Sulfuric Acid Nanoparticles as a Reusable Catalyst

2013 ◽  
Vol 2013 ◽  
pp. 1-5 ◽  
Author(s):  
Bahareh Sadeghi ◽  
Tayebe Ziya
Keyword(s):  
Sulfuric Acid ◽  
Aromatic Aldehyde ◽  
High Yield ◽  
Reusable Catalyst ◽  
Silica Sulfuric Acid ◽  
Green Protocol ◽  
Highly Efficient

Silica sulfuric acid nanoparticles have been prepared and shown to efficiently catalyse the reaction between an aromatic aldehyde or phenylglyoxal and a 4-hydroxycoumarin at reflux in EtOH to afford the biscoumarin derivatives in high yield.

Development of copper-on-alumina catalytic materials for the cleanup of flue gas and the disposal of diluted ammonium sulfate solutions

1995 ◽  
Vol 10 (3) ◽  
pp. 553-561 ◽  
Author(s):  
G. Centi ◽  
B.K. Hodnett ◽  
P. Jaeger ◽  
C. Macken ◽  
M. Marella ◽  
...  
Keyword(s):  
Sulfuric Acid ◽  
Ammonium Sulfate ◽  
Flue Gas ◽  
Industrial Development ◽  
Power Plants ◽  
Flow Sheet ◽  
Catalytic Materials ◽  
Sulfate Solutions ◽  
The Stability ◽  
The Relationship

Some aspects of the industrial development of copper-on-alumina catalytic materials for the combined removal of SO2 (DeSOx and NOx (DeNOx) from flue gas of power plants are discussed. Applications of these catalytic materials for the recovery of sulfuric acid from diluted aqueous solutions of ammonium sulfate are also outlined. In particular, the following specific topics are analyzed: (i) the relationship between textural and reactivity properties. (ii) the problem of the design of samples with improved DeSOx properties in relation to the stability of the samples over extended operations, and (iii) the optimization of the regeneration characteristics of the samples. Details on the flow sheet of the technology are also given.

The Electrical Conductivity Stability of Polyaniline Doped with Three Different Acids

2013 ◽  
Vol 774-776 ◽  
pp. 803-806
Author(s):  
Ren Chun Fu ◽  
Jun Du ◽  
Hui Huang ◽  
Zhong Cheng Guo
Keyword(s):  
Electrical Conductivity ◽  
Sulfuric Acid ◽  
Hydrochloric Acid ◽  
Temperature Dependence ◽  
Methanesulfonic Acid ◽  
Variable Range Hopping ◽  
As Doping ◽  
The Stability ◽  
Better Than

The doping acid will obviously effect on the properties of polyaniline. In order to investigate the industrial acids influence the electrical conductivity stability of polyaniline, the hydrochloric acid (HCl), sulfuric acid (SA) and methanesulfonic acid (MSA) in industrial degree were chosen as doping acids to synthesize polyaniline. The stability of electrical conductivity was measured by in situ temperature. The mechanism of temperature dependence of electrical conductivity was discussed. The results revealed that the stability of polyaniline doped by hydrochloric acid (HCl) was better than that of polyaniline doped by other acids. The variable-range hopping (VRH) model could explain the temperature dependence of electrical conductivity of polyaniline.

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