Thermal Properties of Si Mechanically Alloyed with FeSi2 and CrSi2
Thermal properties of Si mechanically alloyed with FeSi2 and CrSi2 were characterized for the samples with different volume fraction of the disilicides. An anomalously low thermal conductivity observed in the FeSi2-doped samples was ascribed to an enhanced porosity of the samples which triggered the size effect on the lattice thermal conductivity reported previously for nanomeshed and “holey” silicon structures. It was also found that alloying of Si with FeSi2 led to a reduction of thermal conductivity as compared to the reference sample of pure Si prepared under the same conditions. On the other hand, alloying of Si with CrSi2 resulted in an increase in the thermal conductivity as compared to the reference sample of pure Si. The observed trends in the thermal conductivity were ascribed to the formation of impurity levels in the band gap.