Synthesis of Acrylic High-Oil Absorption Resins

2012 ◽  
Vol 502 ◽  
pp. 222-226 ◽  
Author(s):  
Xiao Hua Wang

Through suspension polymerization , the influences of different crosslinking agent, initiator, disperser and reaction temperature on oil absorption rate of cetane methacrylate highly oil absorptive resin were studied. The oil absorption ability of the resin for different oil was investigated. The results show the oil absorption capacity of synthesized resins was good with crosslinker divinylbenzene(DVB), initiator benzoyl peroxide(BPO) and disperser polyvinyl alcohol(PVA). Suitable process conditions were: crosslinker DVB 1.0%, initiator BPO 1.2%, disperser PVA 0.8%, reaction temperature 70°C, and oil absorptive power of obtained resin is about 36.6g.g-1 for CC14.

Foods ◽  
2020 ◽  
Vol 9 (12) ◽  
pp. 1754
Author(s):  
Davide De Angelis ◽  
Aleksei Kaleda ◽  
Antonella Pasqualone ◽  
Helen Vaikma ◽  
Martti Tamm ◽  
...  

Pea protein dry-fractionated (PDF), pea protein isolated (PIs), soy protein isolated (SIs) and oat protein (OP) were combined in four mixes (PDF_OP, PIs_OP, PDF_PIs_OP, SIs_OP) and extruded to produce meat analogues. The ingredients strongly influenced the process conditions and the use of PDF required higher specific mechanical energy and screw speed to create fibrous texture compared to PIs and SIs. PDF can be conveniently used to produce meat analogues with a protein content of 55 g 100 g−1, which is exploitable in meat-alternatives formulation. PDF-based meat analogues showed lower hardness (13.55–18.33 N) than those produced from PIs and SIs (nearly 27 N), probably due to a more porous structure given by the natural presence of carbohydrates in the dry-fractionated ingredient. PDF_OP and PIs_PDF_OP showed a significantly lower water absorption capacity than PIs OP and SIs_OP, whereas pea-based extrudates showed high oil absorption capacity, which could be convenient to facilitate the inclusion of oil and fat in the final formulation. The sensory evaluation highlighted an intense odor and taste profile of PDF_OP, whereas the extrudates produced by protein isolates had more neutral sensory characteristics. Overall, the use of dry-fractionated protein supports the strategies to efficiently produce clean-labeled and sustainable plant-based meat analogues.


2016 ◽  
Vol 848 ◽  
pp. 120-124
Author(s):  
Lei Chen ◽  
Yu Fei Tang ◽  
Xu Liu ◽  
Kang Zhao

PMMA-BMA oil absorption resin was prepared by dispersion polymerization. Oil absorption properties were adjusted by changing the monomer ratio, content of initiator and crosslinking agent. Absorption capacity of porous material, which PMMA-BMA oil absorption resin adhesive in the polyurethane surface, was also investigated. The experimental results show that the best oil absorption ratio of PMMA-BMA copolymer resin was obtained when the MMA/BMA mole ratio was1:1.5, and the initiator and crosslinking agent was 0.4% and 0.35% of the copolymer resin respectively. The porous material was fabricated using the porous polyurethane sponge dipped in the liquid copolymer resin. The porous material resin can be reused since its low oil retention rate, and it can be used as absorption container of oil vapor.


2017 ◽  
Vol 2017 ◽  
pp. 1-8 ◽  
Author(s):  
Hongliang Guan ◽  
Junbo Li ◽  
Biyu Zhang ◽  
Xunmin Yu

To improve the humidity resistance and water absorption capacity of the superabsorbent polymer (SAP), a biodegradable cellulose-containing polymer was successfully assembled through inverse suspension polymerization, using cellulose, acrylic acid, and acrylamide as monomers, Span-80 as dispersant, and potassium persulfate as initiator. The impact of conditions such as reaction temperature, ratio of oil to water, degree of neutralization, amount of cellulose, and cross-linking agents on the properties of the polymer were evaluated. The results showed that the as-prepared superabsorbent polymer exhibited the best water (859 g/g) and salt water (72.48 g/g) absorption rate, when the reaction temperature was 70°C, monomer ratio was 1 : 10, neutralization degree was 75%, and oil-water ratio was 3 : 1. Moreover, the humidity resistance of the polymer could be enhanced significantly by adding different cross-linking reagents such as epoxy chloropropane or diethylene glycol.


2020 ◽  
Vol 39 (1) ◽  
pp. 417-423
Author(s):  
Baochen Han ◽  
PeiPei Du ◽  
Yuzhu Zhang ◽  
Hongwei Xing ◽  
Guangsheng Wei ◽  
...  

AbstractThe development of an environmentally friendly binder can immensely benefit and promote the BF slag fiber industry. Accordingly, in this study, fiber insulation pipes were prepared using water glass, polyvinyl alcohol (PVA), and PVA–glutaraldehyde (GA); moreover, their bulk density, moisture absorption capacity, and thermal conductivity coefficient were measured and compared. The results demonstrated that the values of these three parameters depend on the binder concentration and dosage under certain fiber quality, pipe sizes, and manufacturing process conditions. The best binder composition was proven to be that of PVA–GA, prepared using 3 wt% PVA and 5 wt% GA herein, which facilitated reduction in the bulk density and improvement of the waterproof properties and insulation performance of the slag fiber pipes.


2012 ◽  
pp. 385-388 ◽  
Author(s):  
Azadeh Saadatmandi ◽  
Mohammad Elahi ◽  
Reza Farhoosh ◽  
Mahdi Karimi

The incorporation of sugar beet fiber (0–5%) to tortilla chips and the effects on the chemical and sensory properties were studied. Addition of sugar beet fiber (SBF) led to an increasing of water absorption capacity, ash content and darkness while lowering the protein content and oil absorption. Sensory evaluation showed that the overall acceptability of tortilla chips reduces if adding more than 2% SBF.


2020 ◽  
Vol 7 (04) ◽  
Author(s):  
SATYA NARAYAN SINGH ◽  
RAJESH G BURBADE ◽  
HITESH SANCHAVAT ◽  
P S PANDIT

The cereals of today are more nutritious and healthful than ever before. Cereals processing is one of the oldest and the most essential part of all food technologies. Pasta products and noodles have been staple foods since ancient times in many countries all over the world. In this study pasta formulation was substituted with blending sapota powder in different proportions (4 levels i.e. 0%, 10%, 20%, 30%) into semolina and maida flour separately. Pasta products were prepared using eight different formulations and adding water (approximately 31% of total weight) in DOLLY pasta extruder machine. All the samples were evaluated for physical properties: specific length (mm/g), bulk density (kg/m3), specific density (kg/m3) and porosity (%); functional properties: water absorption index (%), water solubility index (%) and oil absorption capacity (ml/g) and nutritional compositions: moisture (%), crude protein (%), fat (%) and carbohydrate (%). Highest specific length 36.20 mm/g was observed for T5 treatment, low bulk density 368.10 kg/m3 was observed for T5 and highest porosity 9.24% was found for T1 treatment. The maximum WAI, WSI values 325.83%, 17.33% respectively was observed for T1 treatment and minimum value of oil absorption capacity 1.06 ml/g for T8 treatment. The moisture content of dried pasta products was found in the range of 6 to 7%. The maximum value of crude protein 13.07% was found for T5 and minimum value 8.81% for T4 treatments. The fat contents were varied from 1.02% to 1.28 %. The maximum value of carbohydrate was 76.20% for T1 and minimum value 65.41% for T8.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Jiaqi Wang ◽  
Yan Chen ◽  
Qinyao Xu ◽  
Miaomiao Cai ◽  
Qian Shi ◽  
...  

AbstractSuperhydrophobic sponges have considerable potential for oil/water separation. Most of the methods used for superhydrophobic modification of sponges require toxic or harmful solvents, which have the drawbacks of hazardous to environment, expensive, and complex to utilize. Moreover, the hydrophobic layer on the surface of sponge is often easily destroyed. In this paper, a highly efficient superhydrophobic sponge with excellent reusability was developed by using a facile, simple and environmentally friendly dopamine biomimetic bonding method. Different types of sponges, such as melamine, polyethylene or polyurethane sponge wastes, were used as raw materials to prepare superhydrophobic sponges, which possess the advantages of inexpensive and abundant. The effects of different dopamine polymerization time and different hydrophobic agent dosage on the hydrophobicity and oil absorption capacity of melamine sponges were optimized. The study results showed that the water contact angle of the superhydrophobic sponge could reach 153° with excellent organic solvent absorption capacity of 165.9 g/g. Furthermore, the superhydrophobic sponge retained approximately 92.1% of its initial absorption capacity after 35 reutilization cycles. More importantly, the dopamine biomimetic bonding superhydrophobic modification method can be used for different types of sponges. Therefore, a universally applicable, facile, simple and environmentally friendly superhydrophobic modification method for sponges was developed.


Food Research ◽  
2021 ◽  
Vol 5 (4) ◽  
pp. 145-152
Author(s):  
M. Hasmadi ◽  
M. Merlynda ◽  
A.H. Mansoor ◽  
I. Salwa ◽  
M.K. Zainol ◽  
...  

This study aimed to determine the proximate compositions and functional properties of sweet potato flour from different varieties cultivated in Sabah, Malaysia, namely Jepun, Kairot and Kaladi. The results showed that the moisture content of all flour samples was below 14%. The fat and protein content of Jepun sweet potato variety were significantly different (p<0.05) as compared with Kairot and Kaladi sweet potato varieties. The ash and dietary fibre content of Kairot sweet potato flour were higher (p<0.05) compared to Jepun and Kaladi flours. In addition, Kaladi sweet potato had the highest carbohydrate content (82%). There were significant differences (p<0.05) in the values of L*, a* and b* for all sweet potato flours. The Jepun sweet potato flour had the highest foaming capacity, water absorption capacity, oil absorption capacity, swelling power and viscosity. Rapid Visco analyser revealed that significant differences were observed for pasting parameters such as peak viscosity, trough viscosity, breakdown viscosity, final viscosity and setback viscosity. The gelatinisation properties showed that Kairot sweet potato flour had the highest onset temperature, conclusion temperature and enthalpy while Kaladi sweet potato flour had the highest peak temperature.


Polymers ◽  
2021 ◽  
Vol 13 (16) ◽  
pp. 2782
Author(s):  
Yong-Rok Kwon ◽  
Jung-Soo Kim ◽  
Dong-Hyun Kim

A superabsorbent polymer (SAP) was synthesized by copolymerizing itaconic acid and vinyl sulfonic acid. The typically low absorbency of itaconic acid-based SAPs under mechanical loads was improved by introducing surface crosslinking. Fourier-transform infrared spectroscopy and X-ray photoelectron spectroscopy were used to characterize the synthesis and surface-crosslinking reactions in the SAP. Various conditions for surface-crosslinking reactions, such as the surface-crosslinking solution, content of surface-crosslinking agent, and reaction temperature, were explored and correlated with the gel strength and absorption characteristics of the resulting SAP particles. The distilled water content in the surface-crosslinking solution strongly influenced the absorption capacity of the SAP, but this sensitivity decreased when acetone was used as a co-solvent. Itaconic acid-based SAP that was crosslinked under optimal conditions exhibited centrifuge retention capacity and absorbency under a load of 31.1 and 20.2, respectively.


2021 ◽  
Vol 3 (1) ◽  
Author(s):  
Na Thi Ty Ngo ◽  
Fereidoon Shahidi

AbstractCamelina and flixweed (sophia) seed protein isolates were prepared using both the conventional extraction and ultrasonic-assisted extraction methods at 40 kHz for 20 min, and their functional properties investigated. SDS-PAGE showed that both ultrasound-assisted and conventional extractions resulted in a similar protein profile of the extract. The application of ultrasound significantly improved protein extraction/content and functional properties (water holding capacity, oil absorption capacity, emulsifying foaming properties, and protein solubility) of camelina protein isolate and sophia protein isolate. The water-holding and oil absorption capacities of sophia protein isolate were markedly higher than those of camelina protein isolate. These results suggest that camelina protein isolate and sophia protein isolate may serve as natural functional ingredients in the food industry. Graphical Abstract


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