Properties of Heat Treatment Alkaline Pulping Black Liquor with Aluminum Chloride

2012 ◽  
Vol 610-613 ◽  
pp. 2220-2223
Author(s):  
Lan Ge ◽  
Jie Lu ◽  
Rui Feng Yang ◽  
Yan Jun Liu
Keyword(s):  
Heat Treatment ◽  
Organic Matter ◽  
Aluminum Chloride ◽  
Structural Changes ◽  
Heating Temperature ◽  
Lignin Content ◽  
Black Liquor ◽  
Organic Matter Content ◽  
Toxic Substances ◽  
Alkaline Pulping

The black liquor contains a large amount of suspended solids, organic pollutants and toxic substances, the black liquor discharged directly into water bodies will lead to serious pollution. So we regards the alkaline pulping black liquor as a research object, using autoclave to heat the mixture of aluminum chloride and soda black liquor lignin. By changing the heating temperature and the pH before the heat treatment, we analyze the lignin and carbohydrates in the cooking liquid to study cleavage situation and the corresponding structural changes. The results show that the lignin content accompanied the increase in temperature, organic matter content decreased and part of the decomposition of organic matter. Without adjusting pH, the lignin content is small and ash (inorganic) content is higher.

Properties of Heat Treatment Alkaline Pulping Black Liquor

2012 ◽  
Vol 622-623 ◽  
pp. 1754-1758
Author(s):  
Cheng Hui Xie ◽  
Rui Feng Yang ◽  
Jie Lu ◽  
Yan Jun Liu
Keyword(s):  
Heat Treatment ◽  
Aluminum Chloride ◽  
Treatment Process ◽  
Black Liquor ◽  
Heat Treatment Process ◽  
Alkaline Pulping ◽  
High Temperature Heat Treatment ◽  
Temperature Heat ◽  
Solids Content ◽  
Temperature Heat Treatment

For a large-scale industrial separations and purifications of the lignin in the alkaline pulping, we use aluminum chloride as a catalyst to heat the alkaline pulping black liquor, in order to discuss effects in the nature of high temperature heat treatment process in the alkaline pulping black liquor and aluminum chloride on the nature of alkaline pulping black liquor. The results show that temperature increased and the lignin and carbohydrate content increased and the solids content and pH decreased in the high temperature heat treatment process. When joining the catalyst aluminum chloride, lignin, carbohydrates, solids content and pH value were increased, and increased with increasing amount of aluminum chloride. It proves that the Aluminum chloride plays a big role in the process of the alkaline pulping black liquor heat treatment. It will provide some theoretical basis of the heat treatment of alkaline pulping black liquor.

Heat Treatment Influence on the Corrosion Resistance of a Cu-Al-Fe-Mn Bronze

2018 ◽  
Vol 69 (5) ◽  
pp. 1055-1059 ◽  
Author(s):  
Mariana Ciurdas ◽  
Ioana Arina Gherghescu ◽  
Sorin Ciuca ◽  
Alina Daniela Necsulescu ◽  
Cosmin Cotrut ◽  
...  
Keyword(s):  
Heat Treatment ◽  
Corrosion Resistance ◽  
Structural Changes ◽  
Heating Temperature ◽  
Galvanic Corrosion ◽  
Cooling Water ◽  
Open Circuit ◽  
Water Quenching ◽  
Heat Treated ◽  
Different Temperatures

Aluminium bronzes are exhibiting good corrosion resistance in saline environments combined with high mechanical properties. Their corrosion resistance is obviously confered by the alloy chemical composition, but it can also be improved by heat treatment structural changes. In the present paper, five Cu-Al-Fe-Mn bronze samples were subjected to annealing heat treatments with furnace cooling, water quenching and water quenching followed by tempering at three different temperatures: 200, 400 and 550�C. The heating temperature on annealing and quenching was 900�C. The structure of the heat treated samples was studied by optical and scanning electron microscopy. Subsequently, the five samples were submitted to corrosion tests. The best resistance to galvanic corrosion was showed by the quenched sample, but it can be said that all samples are characterized by close values of open-circuit potentials and corrosion potentials. Concerning the susceptibility to other types of corrosion (selective leaching, pitting, crevice corrosion), the best corrosion resistant structure consists of a solid solution, g2 and k compounds, corresponding to the quenched and 550�C tempered sample.

scholarly journals THE INFLUENCE OF NITROGEN ON THE DECOMPOSITION OF CROP RESIDUES IN THE SOIL

1962 ◽  
Vol 42 (2) ◽  
pp. 276-288 ◽  
Author(s):  
H. Lueken ◽  
W. L. Hutcheon ◽  
E. A. Paul
Keyword(s):  
Organic Matter ◽  
Soil Organic Matter ◽  
Crop Residues ◽  
Lignin Content ◽  
Organic Matter Content ◽  
Organic Amendments ◽  
Matter Content ◽  
Structural Development ◽  
Residue Decomposition ◽  
Advanced Stages

Additions of mineral nitrogen accelerated the initial decomposition rate of incorporated wheat straw, alfalfa hay and glucose when added to two soils differing widely in organic matter content. However, in the more advanced stages of decomposition the reverse was true, and over the total incubation period larger amounts of carbon were maintained in soils supplemented with nitrogen.In contrast to all other residues used, nitrogen additions to cellulose effected a continuous and substantial increase in residue decomposition. This was the only residue for which the mineralization of soil organic matter did not supply nitrogen adequate for its decomposition within 120 days.The very slow rate of decomposition of sphagnum peat could be attributed to its high lignin content, rather than to the nitrogen levels.Sulphacetolysis analysis, which measures the non-humified carbon, indicated the feasibility of separating non-humified crop residues from the more complex soil organic matter. Addition of organic amendments thus resulted in a drop in the soil humification quotient. Nitrogen resulted in the retention of a significantly higher percentage of the added residue, without a drop in the humification quotient for the high organic matter Melfort soil.Residue applications to soils produced a significant improvement of structural development, especially in the low organic matter soil (Arborfield).

scholarly journals Effect of Alkaline Black Liquor Recycling on Alkali Combined with Ozone Pretreatment of Corn Stalk

Molecules ◽  
2019 ◽  
Vol 24 (15) ◽  
pp. 2836
Author(s):  
Xia Zhou ◽  
Mengya Wang ◽  
Shuo Fang ◽  
Xiao Liu ◽  
Ping Liu
Keyword(s):  
Structural Changes ◽  
Lignin Content ◽  
Early Stage ◽  
Black Liquor ◽  
Great Influence ◽  
Covalent Bond ◽  
Hydroxyl Group ◽  
Cellulose Content ◽  
Ozone Pretreatment ◽  
Pretreatment Conditions

In the early stage, the best conditions for alkali-bound ozone pretreatment were studied. But after treatment, the alkaline black liquor was directly discarded due to the large amount of organic matter, resulting in environmental pollution and waste of resources. In this paper, the alkaline black liquor was recycled under the optimal pretreatment conditions. The results showed that the number of alkaline black liquor cycles had little effect on hemicellulose content, and had a great influence on cellulose content and lignin content. Through structural characterization of corn stover, it was found that the pretreatment caused structural changes of lignin in straw. However, when the alkaline black liquor was recycled for the fourth time, the ether bond in the side chain of lignin and the covalent bond between the components were not sufficiently destroyed, and the damage to the phenolic hydroxyl group was also weakened. It was indicated that when the alkaline black liquor was recycled for the fourth time, the destruction effect of the alkaline black liquor on the straw was significantly inhibited. Therefore, the optimal circulation time of alkaline black liquor was three times, and the cellulolytic conversion rate was 81.53%.

scholarly journals Use of Fungal Laccases to Facilitate Biodethatching: A New Approach

HortScience ◽  
2012 ◽  
Vol 47 (10) ◽  
pp. 1536-1542 ◽  
Author(s):  
Sudeep S. Sidhu ◽  
Qingguo Huang ◽  
Robert N. Carrow ◽  
Paul L. Raymer
Keyword(s):  
Organic Matter ◽  
Layer Thickness ◽  
Lignin Content ◽  
Organic Matter Content ◽  
Ligninolytic Enzyme ◽  
Matter Content ◽  
Organic Layer ◽  
Putting Greens ◽  
Turf Quality ◽  
Application Rates

Accumulation of excessive organic matter as thatch restricts permeability of putting greens and is one of the most difficult problems in turfgrass management. A greenhouse experiment using potted bentgrass (Agrostis stolonifera L.) determined the efficacy of a ligninolytic enzyme, laccase, in reducing organic matter accumulation in the thatch-mat layer. Laccase was added biweekly at 0, 0.206, 2.06, and 20.6 units of activity/cm2 with and without guaiacol (2-methoxyphenol), a mediator of laccase, and sampling was performed after two and nine months. Parameters investigated included thickness of the organic layer, thatch layer and mat layer, organic matter content, saturated hydraulic conductivity, and lignin content. Organic matter and thatch layer increased between the two sampling dates in all treatments. Laccase was shown to be effective in slowing the rate of accumulation of organic matter and thatch layer. After two months, application of 20.6 units/cm2 of laccase reduced organic layer thickness by 8.7% and extractive-free total lignin content by 8.4% when compared with non-treated control. After nine months, laccase application rates of 2.06 units/cm2 reduced organic matter and thatch layer thickness by 15.6% and 45.0%, respectively, below levels observed in the non-treated control. Applications using 0.206 units/cm2 of laccase were ineffective. Laccase applications had no influence on turf quality. These positive responses suggest laccase treatments could be a non-disruptive option for thatch and/or mat control in bentgrass.

HEAVY METAL SPECIATION IN BOTTOM SEDIMENTS OF THE VYSHNEVOLOTSKY RESERVOIR

2018 ◽  
pp. 46-54
Author(s):  
O. A. Lipatnikova
Keyword(s):  
Heavy Metal ◽  
Organic Matter ◽  
Bottom Sediments ◽  
Metal Speciation ◽  
Organic Matter Content ◽  
Water Reservoir ◽  
Matter Content ◽  
Heavy Metal Speciation ◽  
Mobile Forms ◽  
Manganese Hydroxides

The study of heavy metal speciation in bottom sediments of the Vyshnevolotsky water reservoir is presented in this paper. Sequential selective procedure was used to determine the heavy metal speciation in bottom sediments and thermodynamic calculation — to determine ones in interstitial water. It has been shown that Mn are mainly presented in exchangeable and carbonate forms; for Fe, Zn, Pb и Co the forms are related to iron and manganese hydroxides is played an important role; and Cu and Ni are mainly associated with organic matter. In interstitial waters the main forms of heavy metal speciation are free ions for Zn, Ni, Co and Cd, carbonate complexes for Pb, fulvate complexes for Cu. Effects of particle size and organic matter content in sediments on distribution of mobile and potentially mobile forms of toxic elements have been revealed.

Physico-Chemical Properties of Soil Collected from Chandrabhaga River in Kalmeshwar, Nagpur, Maharashtra

2020 ◽  
Vol 07 (02) ◽  
pp. 1-3
Author(s):  
Amita M Watkar ◽  
Keyword(s):  
Organic Matter ◽  
Soil Quality ◽  
Agricultural Land ◽  
Organic Matter Content ◽  
Chemical Properties ◽  
Matter Content ◽  
Soil Attributes ◽  
Essential Components ◽  
Agricultural Land Management ◽  
Physical And Chemical

Soil, itself means Soul of Infinite Life. Soil is the naturally occurring unconsolidated or loose covering on the earth’s surface. Physical properties depend upon the amount, size, shape, arrangement, and mineral composition of soil particles. It also depends on the organic matter content and pore spaces. Chemical properties depend on the Inorganic and organic matter present in the soil. Soils are the essential components of the environment and foundation resources for nearly all types of land use, besides being the most important component of sustainable agriculture. Therefore, assessment of soil quality and its direction of change with time is an ideal and primary indicator of sustainable agricultural land management. Soil quality indicators refer to measurable soil attributes that influence the capacity of a soil to function, within the limits imposed by the ecosystem, to preserve biological productivity and environmental quality and promote plant, animal and human health. The present study is to assess these soil attributes such as physical and chemical properties season-wise.

Physical methods of research and monitoring

2019 ◽  
Vol 85 (1(I)) ◽  
pp. 35-44
Author(s):  
S. G. Sandomirski
Keyword(s):  
Heat Treatment ◽  
Coercive Force ◽  
Remanent Magnetization ◽  
Structural Changes ◽  
Mechanical Load ◽  
Magnetic Hysteresis ◽  
Steel Structures ◽  
Magnetic Characteristics ◽  
Magnetic Parameters ◽  
Saturation Intensity

The main magnetic parameters sensitive to the structure of steels are the parameters of their saturation loop of magnetic hysteresis: the coercive force Hcs and remanent magnetization Mrs. The saturation magnetization or saturation intensity Mr is most sensitive to the phase composition of steels. The variety of steel grades and modes of technological treatment (e.g., heat treatment, mechanical load) determined the use of magnetic structurescopy and magnetic characteristics — the coercive force Hc, remanent magnetization Mr , and specific hysteresis losses Wh on the subloops of the magnetic hysteresis of steels — as control parameters in diagnostics of the stressed and structural states of steel structures and pipelines. It has been shown that changes in Hc, Mr , and Wh are more sensitive to structural stresses and structures of steels than the parameters of the saturation hysteresis loop of magnetic hysteresis (Hcs, Mrs, and Mrs). The formulas for calculating Hc, Mr and Wh are presented to be used for estimation of changes in the parameters upon heat treatment of steels. Features of the structural sensitivity of the subloop characteristics and expediency of their use for magnetic structural and phase analyzes are determined. Thus, the range of changes in Ìr attributed to the structural changes in steels upon gradual Hm decrease is many times wider compared to the range of possible changes in Mrs under the same conditions. Conditions (relations between the magnetic parameters) and recommendations regarding the choice of the field strength Hm are given which provide the justified use of Hc, Mr and Wh parameters in magnetic structurescopy

The Issue of Plastic and Microplastic Pollution in Soil

2019 ◽  
Vol 56 (3) ◽  
pp. 484-487 ◽  
Author(s):  
Valentina Constanta Tudor ◽  
Dorina Nicoleta Mocuta ◽  
Ruxandra Florina Teodorescu ◽  
Dragos Ion Smedescu
Keyword(s):  
Water Pollution ◽  
Organic Matter ◽  
Soil Pollution ◽  
Aquatic Environment ◽  
Negative Impact ◽  
Plastic Material ◽  
Soil Biota ◽  
Toxic Substances

Soil pollution with plastics represents a great threat to plants, animals, but especially to humans, as a very small quantity of the plastic which is discarded daily is recycled or incinerated in waste facilities, much of it reaching landfills where their decomposition lasts up to 1000 years and during this time the toxic substances penetrate the soil and the water. If, initially, the pollution with plastics has been identified and recognized in the aquatic environment, recent studies show that plastics residues exist in huge quantities in the soil. The present study focuses on the analysis of factors that pollute soil, so the various studies that have been carried out claim that soil pollution with plastic is much higher and increases in an aggressive manner, being estimated to be 4 to 23 times higher than water pollution with plastics, and the accumulation of microplastics in the soil has a negative impact on soil biota. Thus, once the plastic material accumulates in the soil, it is assimilated to organic matter and the mineral substitutes of the soil and persists for several hundred years.

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