Relationship between Heating Value and Proximate Analysis of Oil Shale

2012 ◽  
Vol 614-615 ◽  
pp. 69-72
Author(s):  
Qing Wang ◽  
Na Pei
Keyword(s):  
Oil Shale ◽  
Mining Area ◽  
Volatile Matter ◽  
Proximate Analysis ◽  
Fixed Carbon ◽  
Heating Value ◽  
Lower Heating Value ◽  
Value Measurement ◽  
Important Significance ◽  
Lower Heating

In this research, experimental samples were from Maoming, Huadian, Wangqing, Fushun and Longkou regions in different layers and different mining area. The experimental results of oil shale proximate analysis and heating value measurement show that there are certain relations between proximate analysis of moisture, ash, fixed carbon, volatile matter and lower heating value. The relations between oil shale lower heating value and proximate analysis have important significance to estimate the average characteristics of oil shale as received and oil shale combustion conditions in boiler.

scholarly journals The Investigation of Mercury Contents in Polish Coal Samples

2013 ◽  
Vol 39 (2) ◽  
pp. 141-150 ◽  
Author(s):  
Michał Wichliński ◽  
Rafał Kobyłecki ◽  
Zbigniew Bis
Keyword(s):  
Electricity Generation ◽  
Volatile Matter ◽  
Proximate Analysis ◽  
Mercury Content ◽  
Hard Coal ◽  
Fixed Carbon ◽  
Heating Value ◽  
High Heating Value ◽  
Enrichment Process

Abstract This paper presents the results of the investigation associated with the determination of mercury content in Polish hard coal and lignite samples. Those coals are major fuels used for electricity generation in Poland. The results indicated that the average content of mercury in the coal samples was roughly about 100 ng/g. Apart from the determination of the mercury contents a detailed ultimate and proximate analysis of the coal samples was also carried out. The relationships between the mercury content and ash, as well as fixed carbon, volatile matter, sulfur, and high heating value of the coal samples were also established. Furthermore, the effect of coal enrichment was also investigated, and it was found that the enrichment process enabled the removal of up to 75% of the coal mercury from the samples.

Compositional and experimental investigation of the effect of reactor temperature on softwood and hardwood pyrolysis

2018 ◽  
Vol 15 (1) ◽  
pp. 21-26
Author(s):  
Joseph Adewumi Oyebanji ◽  
Sunday Olayinka Oyedepo
Keyword(s):  
Design Methodology ◽  
Pyrolysis Temperature ◽  
Volatile Matter ◽  
Proximate Analysis ◽  
Initial Weight ◽  
Fixed Carbon ◽  
Heating Value ◽  
Content Type ◽  
Reactor Temperature ◽  
Temperature Levels

Purpose This study aims to investigate the effect of reactor temperature on softwood and hardwood pyrolysis. Experiments are performed at six temperature levels ranging from 300 to 800°C under N2 atmosphere. The weights of char, tar and gas yields produced were measured and recorded in percentage of initial weight of the pyrolyzed samples. Results of the study showed that hardwood produces maximum char, tar and gas yields of 41.02 per cent at 300°C,44.10 per cent at 300°C and 56.86 per cent at 800°C, respectively, whereas softwood produces maximum yields of 30.10 per cent at 300°C, 28.25 per cent at 300°C and 68.73 per cent at 800°C, respectively. Proximate analysis shows that volatile matter, fixed carbon, ash content and moisture content of hardwood are 74.83, 14.28, 2.81 and 8.08 per cent, respectively, and that of softwood are 79.76, 12.65, 0.98 and 6.61 per cent, respectively. Result of the elemental analysis results shows that the carbon, hydrogen, nitrogen, oxygen and sulphur contents for hardwood are 52.20, 6.45, 0.68, 39.64 and 1.03 per cent, respectively, and that of softwood are 45.95, 4.57, 0.56, 48.13 and 0.79 per cent, respectively. The higher heating value of hardwood and softwood are 21.76 and 16.50 kJ/g respectively. This study shows that char and tar yields decrease with increase pyrolysis temperature, whereas gas yield increases as pyrolysis temperature increases for the wood samples considered. At all temperatures considered in this study, gas yields are higher than tar and char yields for softwood, whereas for hardwood, tar yield decreases with increase in temperature with accompanying increase in gas yield. Design/methodology/approach Experiments are performed at six temperature levels ranging from 300 to 800°C under N2 atmosphere. Findings At all temperatures considered in this study, gas yields are higher than tar and char yields for softwood, whereas for hardwood, tar yield decreases with increase in temperature with accompanying increase in gas yield. Originality/value Results of the study showed that hardwood produces maximum char, tar and gas yields of 41.02 per cent at 300°C,44.10 per cent at 300°C and 56.86 per cent at 800°C, respectively, whereas softwood produces maximum yields of 30.10 per cent at 300°C, 28.25 per cent at 300°C and 68.73 per cent at 800°C, respectively.

Lower Heating Value Estimation of Coal Gangue through Proximate Analysis Data Based on GB/T 212-2008

2013 ◽  
Vol 726-731 ◽  
pp. 2699-2703
Author(s):  
Xiu Teng Wang ◽  
Bin Lu ◽  
Ling Xu ◽  
Chen Yi Li ◽  
Ling Lin ◽  
...  
Keyword(s):  
Thermal Power ◽  
Calorific Value ◽  
Analysis Data ◽  
Proximate Analysis ◽  
Coal Gangue ◽  
Important Indicator ◽  
Heating Value ◽  
Lower Heating Value ◽  
Value Estimation ◽  
Lower Heating

The calorific value of coal gangue is an important indicator to assess its quality for comprehensive utilizations. Although the heating values can be measured experimentally with a Bomb calorimeter, an easier and faster approach within an acceptable tolerance is in great demand. Herein, we use an alternative approach to estimate the heating value based on proximate analysis data, which are measured under the instruction of GB/T 212-2008. The lower heating values of coal gangue samples we collected range from 2307 to 8309 kJ/kg, which are key information for the use of coal gangue in principle. We conclude that the sample with calorific value of 8309 kJ/kg can be used as formal fossil fuel; another sample of 5799 kJ/kg can be used for thermal power generation, while the other four are not worth for fuel.

Comparison Proximate Analysis and Heating Value between Cassava Rhizome and Perennial Wood

2011 ◽  
Vol 415-417 ◽  
pp. 1693-1696
Author(s):  
Jarinee Jongpluempiti ◽  
Kiatfa Tangchaichit
Keyword(s):  
Moisture Content ◽  
Volatile Matter ◽  
Proximate Analysis ◽  
High Moisture Content ◽  
High Moisture ◽  
Fixed Carbon ◽  
Heating Value ◽  
Residue Biomass ◽  
Cassava Crop ◽  
Proximate Analyses

Cassava is one of the most important crops in Nakhon Ratchasima province which grows the most cassava in the Northeast of Thailand. Therefore, a large amount of cassava rhizome is left in the field after harvest. The objectives of this research were to study the potential of using residue biomass from the cassava crop i.e. cassava rhizomes. The physical properties and heating value of the cassava rhizomes were evaluated and compared with perennials. The analysis consisted of proximate analysis to measure moisture content, ash, volatile matter and fixed carbon. Heating values were measured using the IKA*C5003 automatic bomb calorimeter. The results were that for high moisture content of about 49-52% the cassava rhizomes had properties inferior to the perennials. When the moisture content of the rhizomes was reduced until around 12%, the properties were equivalent to those of wood samples that had about 2% moisture content. The proximate analyses gave ash 1.8-2.8%, volatile matter 72-75% and fixed carbon 9-13%. Moreover, its average heating values were around 17.08 MJ/kg, while the wood samples were around 17.78 MJ/kg. It appears that cassava rhizome has a high potential as an energy source. Using it to replace wood fuel is possible but it is necessary to reduce the moisture content to an appropriate level.

scholarly journals ELEMENTAL COMPOSITION OF BIODIESEL PRODUCED BY FAST PYROLYSIS OF EUCALYPTUS LEAVES

2021 ◽  
Author(s):  
Ashok Patel ◽  
◽  
Basant Agrawal ◽  
B R Rawal ◽  
◽  
...  
Keyword(s):  
Volatile Matter ◽  
Proximate Analysis ◽  
Ash Content ◽  
Gas Chromatography Mass Spectrometry ◽  
Composition Analysis ◽  
Analytical Pyrolysis ◽  
Fixed Carbon ◽  
Pyrolysis Gas ◽  
Heating Value ◽  
Eucalyptus Leaves

In this study, temperature studies were studied on the production of a product from selected eucalyptus leaving samples. The bio-diesel yield from these samples was further determined using non-model methods and analytical pyrolysis-gas chromatography / mass spectrometry (Py-GC / MS). The fresh eucalyptus leaves were obtained from nearby forest of Godhra (Gujarat), India. Results of the Proximate analysis of eucalyptus leaves powder sample study shows that volatile matter, fixed carbon, ash content and moisture content are 61.70 %, 26.37%, 8.36 % and 3.57%, The results of the basic analysis indicate that the carbon, hydrogen, nitrogen, oxygen, and sulfur content is 89.17%, 7.36%, 1.01%, 1.98% and 0.26%, respectively. The higher heating value (HHV) of the biodiesel obtained from the biomass samples is 32.81 MJ/kg. Chemical composition analysis of Eucalyptus Biodiesel carried out and compared with standards. The study revealed that pyro-fuel is not only used as fuel but also can be purified and used as a commodity in the chemical and processing industries.

scholarly journals Mass and energy balance of the carbonization of babassu nutshell as affected by temperature

2014 ◽  
Vol 49 (3) ◽  
pp. 189-196 ◽  
Author(s):  
Thiago de Paula Protásio ◽  
Paulo Fernando Trugilho ◽  
Alfredo Napoli ◽  
Marcela Gomes da Silva ◽  
Allan Motta Couto
Keyword(s):  
Energy Balance ◽  
Carbonization Temperature ◽  
Energy Losses ◽  
Charcoal Production ◽  
Fixed Carbon ◽  
Final Temperature ◽  
Heating Value ◽  
Eucalyptus Wood ◽  
Lower Heating Value ◽  
Lower Heating

The objective of this work was to evaluate the carbonization yield of babassu nutshell as affected by final temperature, as well as the energy losses involved in the process. Three layers constituting the babassu nut, that is, the epicarp, mesocarp and endocarp, were used together. The material was carbonized, considering the following final temperatures: 450, 550, 650, 750, and 850ºC. The following were evaluated: energy and charcoal yields, pyroligneous liquid, non-condensable gases, and fixed carbon. The use of babassu nutshell can be highly feasible for charcoal production. The yield of charcoal from babassu nutshell carbonization was higher than that reported in the literature for Eucalyptus wood carbonization, considering the final temperature of 450ºC. Charcoal and energy yields decreased more sharply at lower temperatures, with a tendency to stabilize at higher temperatures. The energy yields obtained can be considered satisfactory, with losses between 45 and 52% (based on higher heating value) and between 43 and 49% (based on lower heating value) at temperatures ranging from 450 to 850ºC, respectively. Yields in fixed carbon and pyroligneous liquid are not affected by the final carbonization temperature.

scholarly journals Willow Biomass as Energy Feedstock: The Effect of Habitat, Genotype and Harvest Rotation on Thermophysical Properties and Elemental Composition

Energies ◽  
2020 ◽  
Vol 13 (16) ◽  
pp. 4130
Author(s):  
Mariusz Jerzy Stolarski ◽  
Michał Krzyżaniak ◽  
Kazimierz Warmiński ◽  
Dariusz Załuski ◽  
Ewelina Olba-Zięty
Keyword(s):  
Moisture Content ◽  
Elemental Composition ◽  
Thermophysical Properties ◽  
Volatile Matter ◽  
Ash Content ◽  
Heating Value ◽  
The North ◽  
Lower Heating Value ◽  
Conversion Technologies ◽  
Lower Heating

Willow biomass is used as a bioenergy source in various conversion technologies. It is noteworthy that apart from the beneficial environmental impact of a willow plantation, the biomass quality is also very important as it has an impact on the effectiveness of its use and emissions produced in various bioenergy technologies. Therefore, this study analysed the thermophysical properties and elemental composition of 15 genotypes of willow biomass from two plantations situated in the north of Poland, harvested in two consecutive three-year rotations. The differences in the moisture content, ash content and the lower heating value were mainly determined by the genotype, i.e., by genetic factors. In contrast, the content of carbon, nitrogen, sulphur and hydrogen was determined by the location (environmental factors), but also by the genotype, and by a combination of these factors. The following were the mean levels of the willow biomass characteristics, regardless of the location, genotype and harvest rotation: 48.9% moisture content, 1.26% d.m. ash content, 19.4% d.m. fixed carbon, 79.4% d.m. volatile matter, 19.53 MJ kg−1 d.m. higher heating value, 8.20 MJ kg−1 lower heating value, 52.90% d.m. carbon, 6.23% d.m. hydrogen, 0.032% d.m. sulphur, 0.42% d.m. nitrogen. The present research has shown that the selection of the willow genotype is important for the quality of biomass as energy feedstock. However, plantation location, as well as successive harvest rotations, can have a significant impact on the biomass elemental composition.

scholarly journals Combustion Study of Polyoxymethylene Dimethyl Ethers and Diesel Blend Fuels on an Optical Engine

Energies ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4608
Author(s):  
Jingjing He ◽  
Hao Chen ◽  
Xin Su ◽  
Bin Xie ◽  
Quanwei Li
Keyword(s):  
Soot Formation ◽  
Comprehensive Evaluation ◽  
Chemical Properties ◽  
Heating Value ◽  
Optical Engine ◽  
Leading Role ◽  
Combustion Duration ◽  
Polyoxymethylene Dimethyl Ethers ◽  
Lower Heating Value ◽  
Lower Heating

Polyoxymethylene dimethyl ethers (PODE) are a newly appeared promising oxygenated alternative that can greatly reduce soot emissions of diesel engines. The combustion characteristics of the PODE and diesel blends (the blending ratios of PODE are 0%, 20%, 50% and 100% by volume, respectively) are investigated based on an optical engine under the injection timings of 6, 9, 12 and 15-degree crank angles before top dead center and injection pressures of 100 MPa, 120 MPa and 140 MPa in this study. The results show that both the ignition delay and combustion duration of the fuels decrease with the increasing of PODE ratio in the blends. However, in the case of the fuel supply of the optical engine being fixed, the heat release rate, cylinder pressure and temperature of the blend fuels decrease with the PODE addition due to the low lower heating value of PODE. The addition of PODE in diesel can significantly reduce the integrated natural flame luminosity and the soot formation under all injection conditions. When the proportion of the PODE addition is 50% and 100%, the chemical properties of the blends play a leading role in soot formation, while the change of the injection conditions have an inconspicuous effect on it. When the proportion of the PODE addition is 20%, the blend shows excellent characteristics in a comprehensive evaluation of combustion and soot reduction.

Evaluation of the higher heating value, volatile matter, fixed carbon and ash content of ground bamboo using near infrared spectroscopy

2017 ◽  
Vol 25 (5) ◽  
pp. 301-310 ◽  
Author(s):  
Jetsada Posom ◽  
Panmanas Sirisomboon
Keyword(s):  
Infrared Spectroscopy ◽  
Near Infrared Spectroscopy ◽  
Near Infrared ◽  
Model Development ◽  
Volatile Matter ◽  
Ash Content ◽  
Least Squares Regression ◽  
Fixed Carbon ◽  
Bomb Calorimetry ◽  
Heating Value

This research aimed to determine the higher heating value, volatile matter, fixed carbon and ash content of ground bamboo using Fourier transform near infrared spectroscopy as an alternative to bomb calorimetry and thermogravimetry. Bamboo culms used in this study had circumferences ranging from 16 to 40 cm. Model development was performed using partial least squares regression. The higher heating value, volatile matter, fixed carbon and ash content were predicted with coefficients of determination (r2) of 0.92, 0.82, 0.85 and 0.51; root mean square error of prediction (RMSEP) of 122 J g−1, 1.15%, 1.00% and 0.77%; ratio of the standard deviation to standard error of validation (RPD) of 3.66, 2.55, 2.62 and 1.44; and bias of 14.4 J g−1, −0.43%, 0.03% and −0.11%, respectively. This report shows that near infrared spectroscopy is quite successful in predicting the higher heating value, and is usable with screening for the determination of fixed carbon and volatile matter. For ash content, the method is not recommended. The models should be able to predict the properties of bamboo samples which are suitable for achieving higher efficiency for the biomass conversion process.

Biodiesel Effects on Influencing Parameters of Brake Fuel Conversion Efficiency in a Medium Duty Diesel Engine

2010 ◽  
Vol 132 (12) ◽  
Author(s):  
Joshua A. Bittle ◽  
Jesse K. Younger ◽  
Timothy J. Jacobs
Keyword(s):  
Conversion Efficiency ◽  
Energy Content ◽  
Combustion Efficiency ◽  
Operating Conditions ◽  
Biodiesel Fuel ◽  
Mass Energy ◽  
Fuel Conversion ◽  
Heating Value ◽  
Lower Heating Value ◽  
Lower Heating

Biodiesel remains an alternative fuel of interest for use in diesel engines. A common characteristic of biodiesel, relative to petroleum diesel, is a lowered heating value (or per mass energy content of the fuel). For same torque engine comparisons, the lower heating value translates into a higher brake specific fuel consumption (amount of fuel consumed per unit of power produced). The efficiency at which fuel energy converts into work energy, however, may remain unchanged. In this experimental study, evaluating nine unique engine operating conditions, the brake fuel conversion efficiency (an assessor of fuel energy to work energy efficiency) remains unchanged between 100% petroleum diesel fuel and 100% biodiesel fuel (palm olein) at all conditions, except for high load conditions. Several parameters may affect the brake fuel conversion efficiency, including heat loss, mixture properties, pumping work, friction, combustion efficiency, and combustion timing. This article describes a study that evaluates how the aforementioned parameters may change with the use of biodiesel and petroleum diesel, and how these parameters may result in differences in the brake fuel conversion efficiency.

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