scholarly journals The Investigation of Mercury Contents in Polish Coal Samples

2013 ◽  
Vol 39 (2) ◽  
pp. 141-150 ◽  
Author(s):  
Michał Wichliński ◽  
Rafał Kobyłecki ◽  
Zbigniew Bis

Abstract This paper presents the results of the investigation associated with the determination of mercury content in Polish hard coal and lignite samples. Those coals are major fuels used for electricity generation in Poland. The results indicated that the average content of mercury in the coal samples was roughly about 100 ng/g. Apart from the determination of the mercury contents a detailed ultimate and proximate analysis of the coal samples was also carried out. The relationships between the mercury content and ash, as well as fixed carbon, volatile matter, sulfur, and high heating value of the coal samples were also established. Furthermore, the effect of coal enrichment was also investigated, and it was found that the enrichment process enabled the removal of up to 75% of the coal mercury from the samples.

2018 ◽  
Vol 37 (1) ◽  
pp. 544-557 ◽  
Author(s):  
Alejandra Saffe ◽  
Anabel Fernandez ◽  
Germán Mazza ◽  
Rosa Rodriguez

The use of energy from biomass is becoming more common worldwide. This energy source has several benefits that promote its acceptance; it is bio-renewable, non-toxic and biodegradable. To predict its behavior as a fuel during thermal treatment, its characterization is necessary. The experimental determination of ultimate analysis data requires special instrumentation, while proximate analysis data can be obtained easily by using common equipment but, the required time is high. In this work, a methodology is applied based on thermogravimetric analysis, curves deconvolution and empirical correlations for characterizing different regional agro-industrial wastes to determine the high heating value, the contents of moisture, volatiles matter, fixed carbon, ash, carbon, hydrogen, oxygen, lignin, cellulose and hemicellulose. The obtained results are similar to those using standard techniques, showing the accuracy of proposed method and its wide application range. This methodology allows to determine the main parameters required for industrial operation in only in one step, saving time.


2018 ◽  
Vol 15 (1) ◽  
pp. 21-26
Author(s):  
Joseph Adewumi Oyebanji ◽  
Sunday Olayinka Oyedepo

Purpose This study aims to investigate the effect of reactor temperature on softwood and hardwood pyrolysis. Experiments are performed at six temperature levels ranging from 300 to 800°C under N2 atmosphere. The weights of char, tar and gas yields produced were measured and recorded in percentage of initial weight of the pyrolyzed samples. Results of the study showed that hardwood produces maximum char, tar and gas yields of 41.02 per cent at 300°C,44.10 per cent at 300°C and 56.86 per cent at 800°C, respectively, whereas softwood produces maximum yields of 30.10 per cent at 300°C, 28.25 per cent at 300°C and 68.73 per cent at 800°C, respectively. Proximate analysis shows that volatile matter, fixed carbon, ash content and moisture content of hardwood are 74.83, 14.28, 2.81 and 8.08 per cent, respectively, and that of softwood are 79.76, 12.65, 0.98 and 6.61 per cent, respectively. Result of the elemental analysis results shows that the carbon, hydrogen, nitrogen, oxygen and sulphur contents for hardwood are 52.20, 6.45, 0.68, 39.64 and 1.03 per cent, respectively, and that of softwood are 45.95, 4.57, 0.56, 48.13 and 0.79 per cent, respectively. The higher heating value of hardwood and softwood are 21.76 and 16.50 kJ/g respectively. This study shows that char and tar yields decrease with increase pyrolysis temperature, whereas gas yield increases as pyrolysis temperature increases for the wood samples considered. At all temperatures considered in this study, gas yields are higher than tar and char yields for softwood, whereas for hardwood, tar yield decreases with increase in temperature with accompanying increase in gas yield. Design/methodology/approach Experiments are performed at six temperature levels ranging from 300 to 800°C under N2 atmosphere. Findings At all temperatures considered in this study, gas yields are higher than tar and char yields for softwood, whereas for hardwood, tar yield decreases with increase in temperature with accompanying increase in gas yield. Originality/value Results of the study showed that hardwood produces maximum char, tar and gas yields of 41.02 per cent at 300°C,44.10 per cent at 300°C and 56.86 per cent at 800°C, respectively, whereas softwood produces maximum yields of 30.10 per cent at 300°C, 28.25 per cent at 300°C and 68.73 per cent at 800°C, respectively.


2012 ◽  
Vol 614-615 ◽  
pp. 69-72
Author(s):  
Qing Wang ◽  
Na Pei

In this research, experimental samples were from Maoming, Huadian, Wangqing, Fushun and Longkou regions in different layers and different mining area. The experimental results of oil shale proximate analysis and heating value measurement show that there are certain relations between proximate analysis of moisture, ash, fixed carbon, volatile matter and lower heating value. The relations between oil shale lower heating value and proximate analysis have important significance to estimate the average characteristics of oil shale as received and oil shale combustion conditions in boiler.


2011 ◽  
Vol 415-417 ◽  
pp. 1693-1696
Author(s):  
Jarinee Jongpluempiti ◽  
Kiatfa Tangchaichit

Cassava is one of the most important crops in Nakhon Ratchasima province which grows the most cassava in the Northeast of Thailand. Therefore, a large amount of cassava rhizome is left in the field after harvest. The objectives of this research were to study the potential of using residue biomass from the cassava crop i.e. cassava rhizomes. The physical properties and heating value of the cassava rhizomes were evaluated and compared with perennials. The analysis consisted of proximate analysis to measure moisture content, ash, volatile matter and fixed carbon. Heating values were measured using the IKA*C5003 automatic bomb calorimeter. The results were that for high moisture content of about 49-52% the cassava rhizomes had properties inferior to the perennials. When the moisture content of the rhizomes was reduced until around 12%, the properties were equivalent to those of wood samples that had about 2% moisture content. The proximate analyses gave ash 1.8-2.8%, volatile matter 72-75% and fixed carbon 9-13%. Moreover, its average heating values were around 17.08 MJ/kg, while the wood samples were around 17.78 MJ/kg. It appears that cassava rhizome has a high potential as an energy source. Using it to replace wood fuel is possible but it is necessary to reduce the moisture content to an appropriate level.


Author(s):  
Ashok Patel ◽  
◽  
Basant Agrawal ◽  
B R Rawal ◽  
◽  
...  

In this study, temperature studies were studied on the production of a product from selected eucalyptus leaving samples. The bio-diesel yield from these samples was further determined using non-model methods and analytical pyrolysis-gas chromatography / mass spectrometry (Py-GC / MS). The fresh eucalyptus leaves were obtained from nearby forest of Godhra (Gujarat), India. Results of the Proximate analysis of eucalyptus leaves powder sample study shows that volatile matter, fixed carbon, ash content and moisture content are 61.70 %, 26.37%, 8.36 % and 3.57%, The results of the basic analysis indicate that the carbon, hydrogen, nitrogen, oxygen, and sulfur content is 89.17%, 7.36%, 1.01%, 1.98% and 0.26%, respectively. The higher heating value (HHV) of the biodiesel obtained from the biomass samples is 32.81 MJ/kg. Chemical composition analysis of Eucalyptus Biodiesel carried out and compared with standards. The study revealed that pyro-fuel is not only used as fuel but also can be purified and used as a commodity in the chemical and processing industries.


2021 ◽  
Author(s):  
Diego Aleixo Aleixo Silva ◽  
Natália Carvalho ◽  
Ariane Aparecida Felix Pires ◽  
Elias Ricardo Durango Padilla ◽  
Ana Larissa Santiago Hansted ◽  
...  

Abstract Measuring the energy characteristics of solid biofuels can help to determine the most suitable species for combustion. The objective of this study is to propose a new methodology for determining the ignition time and flaming duration in lignocellulosic biomass. A muffle furnace was used, instead of an epiradiador, to measure the variables. The optimal oven temperature was defined according to the average time-to-ignition of biomasses in the literature. Ten biomasses were analyzed to obtain their high heating value, volatile matter, fixed carbon content, ash content, time-to-ignition, and flaming duration. The results showed a high correlation between the biomass volatile content, time-to-ignition, and flaming duration. In the literature, it is described that high levels of volatile materials accelerate the ignition of the material. Thus, the association between the volatile matter and the variables analyzed justifies the use of the muffle furnace methodology. Furthermore, biomasses with high levels of volatile matter have longer flaming durations than other solid biofuels.


2019 ◽  
Vol 797 ◽  
pp. 309-318
Author(s):  
Ruwaida Abdul Rasid ◽  
Tai Xin Yee ◽  
Rahsya Nur Udzaifa Abdul Rahman ◽  
Mazni Ismail

Food waste is a potential source of renewable carbon that can be utilized as a feedstock for biofuel production. Instead of disposing it in the landfills, food waste can be processed through thermochemical process known as torrefaction, which is conducted between 200°C and 300°C under inert atmosphere, to produce energy-dense biochar. Due to high oil content in the food waste, wet rendering process is introduced as a pre-treatment step to remove the oil from food waste. In this study, the potential of food waste as a renewable energy source is studied, where the biochar produced from direct torrefaction (DT) is compared with the biochar produced from torrefaction process that is preceded with wet rendering (WR) process. Food waste was torrefied in the fixed bed reactor at temperatures 220°C, 240°C and 260°C, with various residence times (15 min, 30 min and 45 min). The produced biochars were characterized in terms of its elemental composition, High Heating Value (HHV) and proximate analysis which includes moisture content, fixed carbon, ash content and volatile matter. It was found that the torrefied food waste shows improved physical properties when compared to raw food waste. The moisture content showed significant reduction while the fixed carbon increased with increasing torrefaction and residence time. This effects were further improved with WR, especially HHV which indicates that the WR process followed by torrefaction may be able to further improve the produced biochar.


2018 ◽  
Vol 14 (4) ◽  
pp. 408-413
Author(s):  
Nur Syairah Mohamad Aziz ◽  
Adilah Shariff ◽  
Nurhayati Abdullah ◽  
Nurhidayah Mohamed Noor

The aim of this study is to investigate the potential of coconut frond as a feedstock for biochar production via slow pyrolysis process.  Proximate, elemental and thermogravimetric analysis were performed to evaluate the chemical and thermal properties of the coconut frond.  The percentage of its lignocellulosic component and high heating value were determined. Surface morphology of coconut frond was examined using field emission scanning electron microscope (FESEM). Coconut frond (CF) contains 78.03±3.91 d.b. wt% of volatile matter, 4.96±0.07 d.b. wt% of ash content and 17.01±3.86 d.b. wt% of fixed carbon. Elemental analysis revealed a sulfur content of 0.94±0.12 %, while the percentage of nitrogen is 0.46±0.33%. The composition of carbon and hydrogen are 34.0±6.22 % and 7.71±0.34 % respectively. The high heating value of CF is 17.77±0.40 MJ/kg. CF consists of 43.91±1.80 % cellulose, 31.58±1.20 % hemicellulose, and 18.15±0.60 % lignin. From thermogravimetric (TG) analysis, it is apparent that the weight loss of CF occurred prominently in the temperature range 200°C - 400°C.  The peaks of the DTG curve at 281.75±0.35 °C and 334.08±0.35°C indicate the weight loss of coconut frond sample due to the degradation of hemicellulose and cellulose, respectively. The FESEM images of CF show its fibrous strands are compact with a few large pores with diameters around 42.5 - 48.1 μm large pores in the center of the CF sample. The results of the analysis show that CF has a potential as a feedstock for biochar production via slow pyrolysis. CF also can be used in other application such as syngas and bio-oil production due to the low lignin percentage and high volatile percentage.


Nativa ◽  
2018 ◽  
Vol 6 (3) ◽  
pp. 300
Author(s):  
Thammi Queuri Gomes Da Cunha ◽  
Pedro Vilela Gondim Barbosa ◽  
Pedro Augusto Fonseca Lima ◽  
Thalles Santiago Pimentel ◽  
Lucas Lemes de Souza Peixoto ◽  
...  

O processamento dos painéis de MDF, para a fabricação de móveis, gera uma grande quantidade de resíduos que constituem passivo ambiental, podendo ser utilizados para geração de energia. O objetivo deste trabalho foi avaliar as características do resíduo de MDF e seu aproveitamento na produção de pellets, visando a aplicação energética. A caracterização energética do resíduo foi realizada por meio da química imediata (teores de cinzas, voláteis e carbono fixo) e do poder calorífico superior. Além disso, foram produzidos e avaliados pellets (características energéticas e físico-mecânicas). A avaliação das características do resíduo: poder calorífico superior (4427,8 kcal.kg-1) e química imediata (carbono fixo, materiais voláteis e cinzas foram 16,3; 82,3 e 1,4%, respectivamente) e dos pellets de MDF: densidade aparente (1,15 g.cm-3), a granel (0,61 g.cm-3), energética (2,6 a 5,5 Gcal.m-3) e durabilidade (99,87%) indicaram a viabilidade técnica do aproveitamento do material como fonte energética. As características energéticas e físico-mecânicas dos pellets de MDF atenderam as especificações de qualidade exigidas nas normas internacionais de comercialização, exceto para o diâmetro médio.Palavras-chave: materiais densificados, potencial energético, painéis. CHARACTERIZATION OF MDF RESIDUE AND ITS USE IN PELLET PRODUCTION ABSTRACT:The processing of MDF panels, for the manufacture of furniture, generates a large amount of residues that constitutes an environmental liability, and can be used for power generation. The objective of this work was to evaluate the characteristics of the MDF residue and its use in the production of pellets, aiming at the energetic application. The energetic characterization of the residue was carried out by means of the proximate analysis (ash, volatile and fixed carbon contents), calorific value. In addition, pellets were produced and evaluated (energy and physico-mechanical characteristics). The evaluation of the characteristics of the residue: high heating value  (4427.8 kcal kg-1) and proximate analysis (fixed carbon, volatile materials and ash were 16.3, 82.3 and 1.4%, respectively) and pellets: density (1.15 g cm -3), bulk density (0.61 g cm -3), energy density (2.6-5.5 Gcal m-3) and durability (99.87 %) indicated the technical feasibility of using the material as an energy source. The energy and physical-mechanical characteristics of MDF pellets met the quality specifications required by international marketing standards, except for the average diameter.Keywords: densified materials, energetic potential, panels. DOI:


2017 ◽  
Vol 25 (5) ◽  
pp. 301-310 ◽  
Author(s):  
Jetsada Posom ◽  
Panmanas Sirisomboon

This research aimed to determine the higher heating value, volatile matter, fixed carbon and ash content of ground bamboo using Fourier transform near infrared spectroscopy as an alternative to bomb calorimetry and thermogravimetry. Bamboo culms used in this study had circumferences ranging from 16 to 40 cm. Model development was performed using partial least squares regression. The higher heating value, volatile matter, fixed carbon and ash content were predicted with coefficients of determination (r2) of 0.92, 0.82, 0.85 and 0.51; root mean square error of prediction (RMSEP) of 122 J g−1, 1.15%, 1.00% and 0.77%; ratio of the standard deviation to standard error of validation (RPD) of 3.66, 2.55, 2.62 and 1.44; and bias of 14.4 J g−1, −0.43%, 0.03% and −0.11%, respectively. This report shows that near infrared spectroscopy is quite successful in predicting the higher heating value, and is usable with screening for the determination of fixed carbon and volatile matter. For ash content, the method is not recommended. The models should be able to predict the properties of bamboo samples which are suitable for achieving higher efficiency for the biomass conversion process.


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