Different Chemical Oxidant of Benzene Series Pollution Site Repair Effect

2014 ◽  
Vol 989-994 ◽  
pp. 564-567
Author(s):  
Ding Long Li ◽  
Xin Lei Fang ◽  
Min Da Yu ◽  
Hao Lv ◽  
Yan Yang
Keyword(s):  
Hydrogen Peroxide ◽  
Contaminated Soil ◽  
Removal Rate ◽  
Antioxidant Effect ◽  
Soil Bioremediation ◽  
Sodium Persulfate ◽  
Combined Pollution ◽  
Fenton Reagent ◽  
Experiment Research ◽  
Benzene Series

this study intends to compare through the experiment research of potassium permanganate, Fenton reagent, sodium persulfate, hydrogen peroxide, four kinds of commonly used oxidant chlorobenzene in contaminated soil, the removal effect of O-O-dichlorobenzene;, selected a typical ground soil bioremediation is the best antioxidant effect. Research under the condition of different on the dose, 4 kinds of oxidants to chlorobenzene and O-O-dichlorobenzene; removal effect. Combined pollution ground soil properties screen of chlorobenzene in contaminated soil, the highest removal rate of dichlorobenzene oxidant and best delivery dosage, to apply typical ground soil bioremediation, the results show that the effect is the best Kmno4.

Experimental Research on the Treatment of Printing and Dyeing Wastewater Using Ultrasound Combined with Fenton Reagent

2015 ◽  
Vol 713-715 ◽  
pp. 2703-2705
Author(s):  
Ying Gang Wang ◽  
Lin Lin ◽  
Teng Fei Liu ◽  
Jin Meng Zhang
Keyword(s):  
Hydrogen Peroxide ◽  
Experimental Research ◽  
Removal Rate ◽  
Orthogonal Test ◽  
Experimental Results ◽  
Ultrasonic Power ◽  
Dyeing Wastewater ◽  
Fenton Reagent ◽  
Reaction Conditions ◽  
Printing And Dyeing Wastewater

Experimental research on the treatment of printing and dyeing wastewater has been carried out. The method of ultrasonic combined Fenton has been used.Separately by using ultrasonic and Fenton oxidation method to treat printing and dyeing wastewater, the hydrogen peroxide dosage, FeSO4•7H2O dosage, shaking time, pH value, ultrasonic time, ultrasonic power and other factors are investigated.The COD and chromaticity removal effect of printing and dyeing wastewater are calculated. The experimental results show that the above factors have a certain impact on the treatment effect. Based on these results, the orthogonal test method is used in this experiment, the optimal conditions of ultrasound combined with Fenton reagent for dealing printing and dyeing wastewater has been determined.The orthogonal experimental results show that the optimal reaction conditions of orthogonal test are below:pH value is 3, the best time for the experiment is 1.5h, hydrogen peroxide dosage is 5mL, seven water ferrous sulfate dosage is 0.7grams, ultrasonic power is 142.5W. Experiments are conducted in accordance with the best reaction conditions. On the optimal process conditions, the removal rate of COD reaches 94.6% and the chroma removal rate reaches 87.5%. The effect of using ultrasonic combined with Fenton reagent to treat printing and dyeing wastewater is better than the use of single method.

scholarly journals Chemical Oxidants for Remediation of Contaminated Soil and Water. A Review

2009 ◽  
Vol 3 (1) ◽  
pp. 41-45 ◽  
Author(s):  
Olexandr Karpenko ◽  
◽  
Vira Lubenets ◽  
Elena Karpenko ◽  
Volodymyr Novikov ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Contaminated Soil ◽  
Organic Contaminants ◽  
Chemical Oxidation ◽  
Oil Products ◽  
Ex Situ ◽  
Sodium Persulfate ◽  
Chemical Oxidants ◽  
Soil And Water

This review covers the main agents used for in situ and ex situ chemical oxidation of organic contaminants particularly oil products, in soil and water environments. Among them there are hydrogen peroxide, permanganate salts, ozone and sodium persulfate. The fields of application, as well as benefits and disadvantages of the mentioned agents use were described.

Study on Demulsification-Fenton to Deal with High Concentrations of Waster Emulsion

2013 ◽  
Vol 726-731 ◽  
pp. 2300-2304
Author(s):  
Hai Shan Dong ◽  
Jing Jing Liu ◽  
Peng Yan ◽  
Rong Yang
Keyword(s):  
Hydrogen Peroxide ◽  
Influencing Factors ◽  
Removal Efficiency ◽  
Removal Rate ◽  
Cod Removal ◽  
Fenton Oxidation ◽  
Experimental Results ◽  
Fenton Reagent ◽  
Cod Removal Rate ◽  
High Concentrations

This topic used the method of demulsification-Fenton oxidation to deal with the waste emulsion, and analyzed the influencing factors of COD removal efficiency . Experimental results show that when the dosage of demulsifier is 10g/L ,optimum aeration for 1h , dosage of Fe2+ is 500mg/L, the dosage of hydrogen peroxide is 50ml/L, After Fenton reagent has oxided for 1.5 h, the COD removal rate can up to 93.4%.

Heterogeneous Fenton Catalytic Removal of Organic Pollutant in Aqueous Solution by using Coal Gangue as a Catalyst

2019 ◽  
Vol 12 (4) ◽  
pp. 312-325
Author(s):  
Jiwei Zhang ◽  
Jingjing Xu ◽  
Shuaixia Liu ◽  
Baoxiang Gu ◽  
Feng Chen ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Hydrogen Peroxide ◽  
Hydroxyl Radical ◽  
Removal Rate ◽  
Organic Pollutant ◽  
Coal Gangue ◽  
Ion Leakage ◽  
Heterogeneous Fenton ◽  
Solution Ph ◽  
X Ray

Background: Coal gangue was used as a catalyst in heterogeneous Fenton process for the degradation of azo dye and phenol. The influencing factors, such as solution pH gangue concentration and hydrogen peroxide dosage were investigated, and the reaction mechanism between coal gangue and hydrogen peroxide was also discussed. Methods: Experimental results showed that coal gangue has the ability to activate hydrogen peroxide to degrade environmental pollutants in aqueous solution. Under optimal conditions, after 60 minutes of treatment, more than 90.57% of reactive red dye was removed, and the removal efficiency of Chemical Oxygen Demand (COD) up to 72.83%. Results: Both hydroxyl radical and superoxide radical anion participated in the degradation of organic pollutant but hydroxyl radical predominated. Stability tests for coal gangue were also carried out via the continuous degradation experiment and ion leakage analysis. After five times continuous degradation, dye removal rate decreased slightly and the leached Fe was still at very low level (2.24-3.02 mg L-1). The results of Scanning Electron Microscope (SEM), energy dispersive X-Ray Spectrometer (EDS) and X-Ray Powder Diffraction (XRD) indicated that coal gangue catalyst is stable after five times continuous reuse. Conclusion: The progress in this research suggested that coal gangue is a potential nature catalyst for the efficient degradation of organic pollutant in water and wastewater via the Fenton reaction.

Microbial Properties and Degradation of Polycyclic Aromatic Hydrocarbons in the Contaminated Farmland Soil with Bioremediation

2014 ◽  
Vol 665 ◽  
pp. 534-537
Author(s):  
Hong Wang ◽  
Hai Bo Li ◽  
Xin Wang ◽  
Ji Fu Ma
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Aromatic Hydrocarbons ◽  
Contaminated Soil ◽  
Significant Positive Correlation ◽  
Removal Rate ◽  
Microbial Properties ◽  
Total Pahs ◽  
Farmland Soil ◽  
Polycyclic Aromatic ◽  
Microbial Agent

Degradation of polycyclic aromatic hydrocarbons (PAHs) and microbial quantity were investigated in aged PAHs-contaminated soil in a pot experiment with regrass and alfalfa. After 60 days germination the concentration of total PAHs in soil decreased by 37.57% and 38.41% with the treatment of ryegrass-microbe agent and alfalfa-microbe agent. The processes of ryegrass and alfalfa were 18.72% and 19.34%. The root system promoted the quantity of microbe and the microbial agent was benefit for the PAHs degrading microbe. And there was significant positive correlation between the number of PAHs degrading microorganisms and the removal rate of PAHs in the soil.

Research of 6-Nitry Industrial Wastewater Treatment by Coagulation-Fenton Oxidation

2012 ◽  
Vol 518-523 ◽  
pp. 2745-2748
Author(s):  
Ling Yan Ren ◽  
Gang Xu
Keyword(s):  
Treatment Effect ◽  
Industrial Wastewater ◽  
Removal Rate ◽  
Sulfate Solution ◽  
Cod Removal ◽  
Fenton Oxidation ◽  
Fenton Reagent ◽  
Oxidation Treatment ◽  
Cod Removal Rate ◽  
Solution Acidity

The paper adopted Coagulation-Fenton Oxidation Method on treating the wastewater of 6-nitro-1,2 diazonium oxygroup naphthalene-4-sulfoacid production process (i.e. 6-nitry wastewater), introduced the treatment effect of the combined technology used on 6-nitry wastewater, and studied the factors influencing the treatment effect, to determine the reasonable parameters of the technology on treating 6-nitry wastewater. The results showed that Using polyaluminium chloride (mass fraction 2%) as flocculant for treating 6-nitry wastewater, the COD removal rate reached up to 48.7%; Making Fenton reagent oxidation treatment on coagulation yielding water, under the best conditions for solution acidity controlled at pH3 or so, in the 100 mL wastewater, 30% hydrogen peroxide was 5.0 mL, 0.5 mol/L ferrous sulfate solution was 4.0 mL, reaction time was 60 min, the COD removal rate could reach 98% or more.

scholarly journals Biodegradation of Used Motor Oil in Soil Using Organic Waste Amendments

2012 ◽  
Vol 2012 ◽  
pp. 1-8 ◽  
Author(s):  
O. P. Abioye ◽  
P. Agamuthu ◽  
A. R. Abdul Aziz
Keyword(s):  
Contaminated Soil ◽  
Oil Pollution ◽  
Green Technology ◽  
Lubricating Oil ◽  
Soil Bioremediation ◽  
Order Kinetic ◽  
Human Beings ◽  
Mushroom Compost ◽  
Oil Biodegradation ◽  
Used Lubricating Oil

Soil and surface water contamination by used lubricating oil is a common occurrence in most developing countries. This has been shown to have harmful effects on the environment and human beings at large. Bioremediation can be an alternative green technology for remediation of such hydrocarbon-contaminated soil. Bioremediation of soil contaminated with 5% and 15% (w/w) used lubricating oil and amended with 10% brewery spent grain (BSG), banana skin (BS), and spent mushroom compost (SMC) was studied for a period of 84 days, under laboratory condition. At the end of 84 days, the highest percentage of oil biodegradation (92%) was recorded in soil contaminated with 5% used lubricating oil and amended with BSG, while only 55% of oil biodegradation was recorded in soil contaminated with 15% used lubricating oil and amended with BSG. Results of first-order kinetic model to determine the rate of biodegradation of used lubricating oil revealed that soil amended with BSG recorded the highest rate of oil biodegradation (0.4361 day−1) in 5% oil pollution, while BS amended soil recorded the highest rate of oil biodegradation (0.0556 day−1) in 15% oil pollution. The results of this study demonstrated the potential of BSG as a good substrate for enhanced remediation of hydrocarbon contaminated soil at low pollution concentration.

scholarly journals Killing of Bacillus Spores by Aqueous Dissolved Oxygen, Ascorbic Acid, and Copper Ions

2003 ◽  
Vol 69 (4) ◽  
pp. 2245-2252 ◽  
Author(s):  
J. B. Cross ◽  
R. P. Currier ◽  
D. J. Torraco ◽  
L. A. Vanderberg ◽  
G. L. Wagner ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Ascorbic Acid ◽  
Dissolved Oxygen ◽  
Hydroxyl Radicals ◽  
Fenton Reaction ◽  
Copper Ions ◽  
Transition Metal Ions ◽  
Fenton Reagent ◽  
Bacillus Spores ◽  
Modified Fenton

ABSTRACT An approach to decontamination of biological endospores is discussed. Specifically, the performance of an aqueous modified Fenton reagent is examined. A modified Fenton reagent formulation of cupric chloride, ascorbic acid, and sodium chloride is shown to be an effective sporicide under aerobic conditions. The traditional Fenton reaction involves the conversion of hydrogen peroxide to hydroxyl radical by aqueous ionic catalysts such as the transition metal ions. Our modified Fenton reaction involves the conversion of aqueous dissolved oxygen to hydrogen peroxide by an ionic catalyst (Cu2+) and then subsequent conversion to hydroxyl radicals. Results are given for the modified Fenton reagent deactivating spores of Bacillus globigii. A biocidal mechanism is proposed that is consistent with our experimental results and independently derived information found in the literature. This mechanism requires diffusion of relatively benign species into the interior of the spore, where dissolved O2 is then converted through a series of reactions which ultimately produce hydroxyl radicals that perform the killing action.

Lead (II) Removal from Contaminated Soils by Electrokinetic Remediation Coupled with Modified Eggshell Waste

2018 ◽  
Vol 777 ◽  
pp. 256-261 ◽  
Author(s):  
André Ribeiro ◽  
André Mota ◽  
Margarida Soares ◽  
Carlos Castro ◽  
Jorge Araújo ◽  
...  
Keyword(s):  
Contaminated Soil ◽  
Contaminated Soils ◽  
Removal Rate ◽  
Electrokinetic Remediation ◽  
Permeable Reactive Barrier ◽  
Inorganic Contaminants ◽  
Reactive Barrier ◽  
Eggshell Waste ◽  
Inorganic Fraction ◽  
Maximum Removal

Electrokinetic remediation deserves particular attention in soil treatment due to its peculiar advantages, including the capability of treating fine and low permeability materials, and achieving consolidation, dewatering and removal of salts and inorganic contaminants like heavy metals in a single stage. In this study, the remediation of artificially lead (II) contaminated soil by electrokinetic process, coupled with Eggshell Inorganic Fraction Powder (EGGIF) permeable reactive barrier (PRB), was investigated. An electric field of 2 V cm-1was applied and was used an EGGIF/soil ratio of 30 g kg-1 of contaminated soil for the preparation of the permeable reactive barrier (PRB) in each test. It was obtained high removal rates of lead in both experiments, especially near the cathode. In the normalized distance to cathode of 0.2 it was achieved a maximum removal rate of lead (II) of 68, 78 and 83% in initial lead (II) concentration of 500 mg-1, 200 mg-1 and 100 mg-1, respectively. EGGIF (Eggshell Inorganic Fraction) proved that can be used as permeable reactive barrier (PRB) since in all the performed tests were achieved adsorptions yields higher than 90%.

Impacts of Changing Operational Parameters of In Situ Chemical Oxidation (ISCO) on Removal of Aged PAHs from Soil

2012 ◽  
Vol 15 (2) ◽  
Author(s):  
Paula Cajal-Mariñosa ◽  
Ruth G. de la Calle ◽  
F. Javier Rivas ◽  
Tuula Tuhkanen
Keyword(s):  
Hydrogen Peroxide ◽  
Removal Efficiency ◽  
Contaminated Soil ◽  
Chemical Oxidation ◽  
Contaminant Removal ◽  
Operational Parameters ◽  
In Situ Chemical Oxidation ◽  
Different Types ◽  
Wood Impregnation

AbstractThe removal efficiency of two different types of peroxide addition, catalyzed hydrogen peroxide (CHP) and sodium percarbonate (SPC) were compared on a highly PAH-contaminated soil from a wood impregnation site. In an attempt to simulate real in situ reagents delivery, experiments have been carried out in acrylic columns. The main parameters affecting contaminant removal were the reagent’s temperature and the total addition of peroxide (g

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