Diffusion of a Corroding Electrolyte through Defective Electroplated Ceria Based Coatings

2009 ◽  
Vol 289-292 ◽  
pp. 235-242 ◽  
Author(s):  
S. Poupard ◽  
F. Pedraza ◽  
J. Creus
Keyword(s):  
Cross Sections ◽  
Energy Dispersive Spectrometry ◽  
Electrochemical Impedance ◽  
Electrochemical Techniques ◽  
Metallic Surface ◽  
Outward Diffusion ◽  
Metallic Substrates ◽  
Polarisation Resistance ◽  
Corrosion Mechanisms ◽  
Scanning Electron

Among the new environmentally friendly alternatives to improve the corrosion resistance of metallic substrates, cerium oxide based electrodeposited layers have raised particular attention. In this work, various electrodeposited layers on zinc substrate have been elaborated at different conditions to produce tailored compositions, microstructures and different degrees of porosity. The use of electrochemical techniques (polarisation resistance measurements, electrochemical impedance spectroscopy) has allowed to ascertain the porosity, which coupled to Scanning Electron Microscopy (FEG-SEM) and Energy Dispersive Spectrometry (EDS) studies along the cross sections have revealed the inward and/or outward diffusion of the different elements through the film till the metallic surface. The resulting corrosion mechanisms of these coatings immersed in 3% NaCl are finally discussed.

scholarly journals Corrosion Performance of AISI-309 Exposed to Molten Salts V2O5-Na2SO4at 700°C Applying EIS andRpElectrochemical Techniques

2015 ◽  
Vol 2015 ◽  
pp. 1-12 ◽  
Author(s):  
E. F. Diaz ◽  
C. Cuevas-Arteaga ◽  
N. Flores-García ◽  
S. Mejía Sintillo ◽  
O. Sotelo-Mazón
Keyword(s):  
Molten Salts ◽  
Electrochemical Impedance ◽  
Electrochemical Techniques ◽  
Metallic Surface ◽  
Corrosion Performance ◽  
Potentiodynamic Polarization Curve ◽  
Linear Polarization Resistance ◽  
Second Stage ◽  
Tafel Slopes ◽  
Bode Plots

The corrosion performance of AISI-309 exposed 5 days to molten salts 50 mol% V2O5-50 mol% Na2SO4at 700°C is reported in this paper. Such evaluation was made using three electrochemical techniques: potentiodynamic polarization curve (PC), electrochemical impedance spectroscopy (EIS), and linear polarization resistance (Rp). FromPC, the Tafel slopes,Icorr, andEcorrwere obtained. From Nyquist and Bode plots, it was possible to determine two different stages; the first one showed just one loop, which indicated the initial formation of Cr2O3layer over the metallic surface; after that, the dissolution of Cr2O3formed a porous layer, which became part of the corrosion products; at the same time a NiO layer combined with sulfur was forming, which was suggested as the second stage, represented by two capacitive loops. EIS plots were in agreement with the physical characterization made from SEM and EDS analyses. Fitting of EIS experimental data allowed us to propose two electrical circuits, being in concordance with the corrosion stages. Parameters obtained from the simulation of EIS data are also reported. From the results, it was stated that AISI-309 suffered intergranular corrosion due to the presence of sulfur, which diffused to the metallic surface through a porous Cr2O3layer.

scholarly journals Green Corrosion Inhibitors for Copper in HCl and H2SO4 Solution - A Review

2021 ◽  
Vol 9 (VI) ◽  
pp. 353-361
Author(s):  
R. T. Vashi
Keyword(s):  
Weight Loss ◽  
Electrochemical Impedance ◽  
Electrochemical Techniques ◽  
Energy Dispersive ◽  
Effect Of Temperature ◽  
Metallic Surface ◽  
Electrochemical Impedance Spectra ◽  
X Ray ◽  
Surface Corrosion ◽  
Chemical Attack

Corrosion is the deterioration of metal by chemical attack or reaction with its environment. It is a constant and continuous problem, often difficult to eliminate completely. Prevention would be more practical and achievable than complete elimination. Recently, a huge interested for the use of naturally occurring inhibitors extracted from plants have been emerged. Most of the natural products are non-toxic, biodegradable and readily available due to environmental concerns. The inhibitor is chemically adsorbed on the surface of the metal and forms a protective thin film with inhibitor effect or by combination between inhibitor ions and metallic surface. Corrosion of copper and its inhibition was analyzed by weight loss (Gravimetric), effect of temperature and time of immersion methods. Electrochemical methods such as, Potentiodynamic polarization and Electrochemical Impedance Spectra (EIS) were employed. The protective films formed on metal surface have been analyzed by various techniques such as Scanning Electron Microscope (SEM), Energy dispersive X-ray spectrometry (EDS) and. Atomic Force Microscopy (AFM), Fourier transform infrared spectroscopy (FT-IR), UV-Visible spectra, X-ray Diffraction spectroscopy (XRD), Energy Dispersive X-ray Spectroscopy (EDX), electrochemical frequency modulation (EFM) techniques. The results obtained from weight loss and electrochemical techniques were in good agreement. In this review paper, research works produced over the past background on the corrosion of copper in various medium and their corrosion inhibition by using a various green inhibitors were presented.

Evaluation of Polymeric Coatings in CO2 Containing Environment

2019 ◽  
Vol 965 ◽  
pp. 133-141
Author(s):  
Rayane Z.C. Demoner ◽  
Alexandre R.P. Castro ◽  
Adriana L. Barros ◽  
J.P. Quintela ◽  
Jefferson R. de Oliveira ◽  
...  
Keyword(s):  
Electrochemical Impedance ◽  
Electrochemical Techniques ◽  
Polymeric Coating ◽  
Metallic Surface ◽  
Polymeric Coatings ◽  
X Ray Diffraction ◽  
X Ray ◽  
Linear Polarization Resistance ◽  
Weight Loss Method ◽  
Loss Method

Two types of polymeric coating were applied on an AISI 1020 steel, where one of them was reinforced by carbon nanotubes, with the objective of protection against corrosion in a medium containing saline solution, NaCl 3% wt satured with CO2, at 75 bar and tested at 50oC and 75oC for 360 hours. Electrochemical techniques, such as Linear Polarization Resistance, (LPR), Electrochemical Impedance Spectroscopy (EIS), Tafel curves and weight loss method, were used for coating evaluation performance. Scanning Electron Microscopy (SEM), X-ray diffraction (XRD) and energy dispersive spectroscopy (EDS) were used to determine both the morphology and chemical composition of the layer formed on the analyzed surfaces. The coating adhesion to metallic surface was evaluated using pull-off test according to ASTM D4541-09. For the studied conditions, the results obtained showed that there was no adequate coating protection, occurring failures and indicating that both coatings may not be used in the tested conditions.

The Electrodeposition of Ni-Fe-Cr Alloy Coatings on Mild Steel Surfaces and Evaluation of Corrosion Resistance

2013 ◽  
Vol 785-786 ◽  
pp. 948-952 ◽  
Author(s):  
Qi Jun Zhong ◽  
Li Bin Yu ◽  
Yi Xiao ◽  
Jian Feng Gu ◽  
Qing Dong Zhong ◽  
...  
Keyword(s):  
Mild Steel ◽  
Electrochemical Impedance ◽  
Trivalent Chromium ◽  
Equivalent Circuits ◽  
Polarisation Resistance ◽  
Heat Treated ◽  
Steel Surfaces ◽  
Eis Measurements ◽  
Scanning Electron ◽  
Electrodeposited Alloy

The electrodeposition of Ni-Fe-Cr alloys was investigated in a trivalent chromium electrolyte on the surface of mild steel over a range of current density. Scanning Electron Microscopy (SEM), Tafel plot and Electrochemical Impedance Spectroscopy (EIS) measurements were used to compare plated alloy coatings and heat-treated electrodeposited alloy coatings. The heat-treated alloy coatings showed a relatively large impedance values and corrosion inhibiting efficiency. Moreover, the polarisation resistance, Rp, was obtained by EIS modeling using equivalent circuits.

Comparison of Electrochemical Behavior of Cu-10Ni-10Zn Alloy and Cu in Aqueous Solutions

2015 ◽  
Vol 229 (3) ◽  
Author(s):  
Waheed A. Badawy ◽  
Mohamed M. El-Rabiei ◽  
Hashem M. Nady ◽  
Mohammed A. Samy
Keyword(s):  
Electrochemical Behavior ◽  
Electrochemical Impedance ◽  
Electrochemical Techniques ◽  
Pure Copper ◽  
Open Circuit ◽  
Chloride Ions ◽  
Alloy Surface ◽  
Metallic Surface ◽  
Copper Dissolution ◽  
Basic Solutions

AbstractThe electrochemical behavior of Cu-10Ni-10Zn alloy and Cu was investigated in acidic, neutral and basic solutions. The effect of chloride ions in neutral solutions was also studied. Conventional electrochemical techniques and electrochemical impedance spectroscopy were used. The corrosion rate of these materials in acidic solutions is relatively high compared to that in neutral or basic solutions. The open-circuit potential of the alloy is nearly the same as that of pure copper in the different media, indicating that the processes which occur on the alloy surface are mainly governed by copper dissolution. In chloride solutions the rate of Cu corrosion is remarkably high. In the alloy, the copper dissolution was suppressed by the presence of nickel and zinc, due to the formation of complex oxide layers. The impedance data were fitted to equivalent circuit models that explain the different electrochemical processes occurring at the electrode/electrolyte interface. SEM and EDAX have shown that the alloy surface is enriched with Ni. In neutral solutions the chloride ions are penetrating the metallic surface.

New Materials on the Renaissance Artists' Palette

2004 ◽  
Vol 852 ◽  
Author(s):  
Barbara H. Berrie ◽  
Louisa C. Matthew
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Sixteenth Century ◽  
Cross Sections ◽  
Energy Dispersive Spectrometry ◽  
Energy Dispersive ◽  
Lead Silicate ◽  
New Materials ◽  
Lead Antimonate ◽  
Scanning Electron

ABSTRACTIn the light of new documentary information regarding the range of materials available to sixteenth century artists, cross sections from paintings were re-examined using scanning electron microscopy - energy dispersive spectrometry. Among a variety of new materials, colored glassy pigments were found including diverse yellow glassy particles, specifically lead silicate and a glass colored by lead antimonate. These are the “yellow smalts” described in Renaissance writings on artists’ materials.

Corrosion Evaluation of Rust Converter and Microcrystalline Wax on Cannon Balls from San Juan de Ulua Fortress

2014 ◽  
Vol 1618 ◽  
pp. 227-232
Author(s):  
R. Orozco-Cruz ◽  
M. Ambros-Peralta ◽  
R. Galvan-Martinez ◽  
J. Reyes-Trujeque
Keyword(s):  
Electrochemical Impedance ◽  
Electrochemical Techniques ◽  
Metallic Surface ◽  
Marine Atmosphere ◽  
Efficient Tool ◽  
Corrosion Evaluation ◽  
Historical Heritage ◽  
New Compounds ◽  
Metallic Artifacts

ABSTRACTOne of the main problems encountered by curators and conservators in charge of metallic collections from Historical Heritage is related to their long-term conservation, since metallic artifacts undergo corrosion phenomena, which are the result of the interaction between the metal and its environment. The use of rust converters and microcrystalline waxes can be an ecological alternative to the traditional and more aggressive conservation techniques. Although the mechanism of action of these compounds is not clear, it is assumed that they react with iron oxides and generate new compounds that may have a passivation effect on the metallic surface. This paper proposes to show how simple electrochemical techniques can be used as an efficient tool to contribute to the diagnosis of the conservation state of cannon balls and to monitor the restoration treatment. The objective of the present work is to evaluate the effectiveness of a rust converter based on tannins and phosphoric acid, and one microcrystalline wax applied on cannon balls samples exposed to a marine atmosphere. The protection properties of the oxide or conversion layer are evaluated by electrochemical impedance spectroscopy (EIS) technique. The results obtained suggest that the use of the rust converter and microcrystalline wax protects the cannon balls, even though its effect is less evident when the deterioration degree is larger.

Characterization of the Stainless Steel Corrosion Kinetic By EIS

2012 ◽  
Vol 1372 ◽  
Author(s):  
R. Galvan-Martinez ◽  
M. Flores-Cocuyo ◽  
R. Orozco-Cruz ◽  
A. Contreras
Keyword(s):  
Stainless Steel ◽  
Exposure Time ◽  
Electrochemical Impedance ◽  
Saturated Calomel Electrode ◽  
Electrochemical Techniques ◽  
Steel Corrosion ◽  
Localized Corrosion ◽  
Metallic Surface ◽  
Natural Seawater ◽  
Corrosion Morphology

ABSTRACTAn electrochemical study was carried out in order to obtain the effects of the turbulent flow condition on the stainless steel corrosion immersed in natural seawater using an electrochemical corrosion technique like electrochemical impedance spectroscopy (EIS). A three-electrode electrochemical glass cell was used to obtain the electrochemical measures, where a cylinder of the AISI 410 stainless steel was used as working electrode, a saturated calomel electrode as reference electrode and a synthesised graphite rod as auxiliary electrode. 24 hours was the total exposure time. In order to control the hydrodynamic conditions a rotating cylinder electrode (RCE) was used and, a scanning electron microscope (SEM) was used in order to obtain the superficial analyses of the metallic surface after tests. The results of the electrochemical techniques shown that at 1000 rpm of the rotation speed, the corrosion rate (CR) increased as the exposure time also increased. In additions, in the other rotations speed (2000, 3000 and 5000 rpm), the CR was affected by the corrosion products formed on metallic surface. t is important to point out that the corrosion morphology found in the steel sample was localized corrosion.

scholarly journals Beneficial Effects of Vanadium Additions on the Corrosion of Ti6AlxV Alloys in Chloride Solutions

Metals ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 264 ◽  
Author(s):  
El-Sayed M. Sherif ◽  
Hany S. Abdo ◽  
Nabeel H. Alharthi
Keyword(s):  
Electron Microscopy ◽  
Immersion Time ◽  
Electrochemical Impedance ◽  
Electrochemical Techniques ◽  
Test Medium ◽  
X Ray ◽  
Beneficial Effects ◽  
Cyclic Potentiodynamic Polarization ◽  
Scanning Electron

The beneficial effects of V addition on the corrosion of a newly manufactured Ti6AlxV (x = 2 wt %, 4 wt %, 6 wt %, and 8 wt %) alloys after various exposure periods in 3.5% NaCl solutions were reported. The Ti6AlxV were produced from their raw powders using mechanical alloying. Several electrochemical techniques such as electrochemical impedance spectroscopy, cyclic potentiodynamic polarization, and potentiodynamic current versus time at 300 mV experiments were conducted. The surface morphology and the elemental analysis were performed using scanning electron microscopy and energy dispersive X-ray analyses. All results were consistent with each other revealing that the increase of V content increases the resistance of the alloys against corrosion. The increase of corrosion resistance was achieved by the role of V in decreasing the rate of corrosion as a result of the formation of oxide films on the surface of the alloys. This effect was found to increase with prolonging the immersion time of the Ti6AlxV alloys in the test medium from 1 h to 24 h and further to 48 h.

scholarly journals The mixture of dicyclohexilamine and oleylamine as corrosion inhibitor for mild steel in NaCl solution saturated with CO2 under both continual immersion and top of the line corrosion

2012 ◽  
Vol 77 (8) ◽  
pp. 1047-1061 ◽  
Author(s):  
Ivana Jevremovic ◽  
Aleksandra Debeljkovic ◽  
Marc Singer ◽  
Mohsen Achour ◽  
Srdjan Nesic ◽  
...  
Keyword(s):  
Weight Loss ◽  
Corrosion Rate ◽  
Mild Steel ◽  
Corrosion Inhibitor ◽  
Vapor Phase ◽  
Electrical Resistance ◽  
Electrochemical Impedance ◽  
Electrochemical Techniques ◽  
Electrical Resistance Measurements ◽  
Scanning Electron

This paper presents a comprehensive method to evaluate the mixture of dicyclohexilamine and oleylamine (DCHA+OA) as corrosion inhibitor for mild steel in CO2 environment in liquid and vapor phase. Corrosion inhibitor volatile properties were investigated in order to determine if DCHA+OA can be used to control the severity of the top of the line (TLC) corrosion attack. Corrosion measurements were performed using electrochemical impedance spectroscopy, linear polarization resistance, potentiodynamic sweep measurements, as well as the electrical resistance measurements and weight loss measurements, in order to determine the inhibitive performances of dicyclohexilamine and oleylamine. In order to define surface morphological characteristics scanning electron microscopy technique was applied. The electrochemical study and weight loss measurements indicated that DCHA+OA significantly decreased the corrosion rate in liquid phase when 50 ppm of DCHA+OA was added. Scanning electron microphotographs indicated protective inhibitor film has formed on the steel surface and revealed that good protection was achieved, along with the decrease in the corrosion rate determined by weight loss and electrochemical techniques. Using electrical resistance measurements in vapor phase it was shown that concentration of 1000 ppm DCHA+OA significantly decreased the corrosion rate at the top of the line, only when it was carried there within its own foam and not due its volatility.

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