Partition of Free Fatty Acids in Deacidification of Macaúba Pulp Oil by Liquid-Liquid Extraction Using Ethanol/Water as Solvent

2011 ◽  
Vol 312-315 ◽  
pp. 554-559 ◽  
Author(s):  
Renata Gomes Brito Mariano ◽  
Carolina Moura Da Silva ◽  
Sonia Couri ◽  
Regina Isabel Nogueira ◽  
Suely Pereira Freitas
Keyword(s):  
Fatty Acids ◽  
Free Fatty Acids ◽  
Water Content ◽  
Partition Coefficients ◽  
Liquid Extraction ◽  
Acid Oil ◽  
High Acid ◽  
Liquid Liquid Extraction ◽  
Water As Solvent ◽  
Acid Acid

Free fatty acids (FFA) is one of the most frequently determined quality indices in fats and oils industry because it has the economic impacts on production [1]. The FFA in macaúba pulp oil is usually very high (10 to 40%) due to enzymatic activity in the raw material [2]. In this case, alkali neutralization is not economically recommended due to neutral oil loss by occlusion in soapstock. The differential solubility of fatty acids and triacylglycerides (TAG) in various organic solvents has formed the basis of several processes for deacidification of crude oils by liquid–liquid extraction [3]. The aim of the present work was to evaluate the influence of raw oil acidity, ethanol/water ratio, water content in ethanol and temperature extraction on partition coefficients of FFA during macaúba oil deacidification. The macaúba crude oil presented high acid index, about 86  1.2 mg KOH/g. The extraction data for the system macaúba oil + free fatty acids + ethanol + water was determined for oil:solvent mass ratios 1:1. Alcoholic solutions containing 2 to 10 % (w/w) of water were used to FFA extraction and the partition coefficients were determined after 24 hours at room temperature (293 K). The phase’s separation was observed for water content in the mixture above 4%. After solvent evaporation, the FFA in oil phase was evaluated by AOCS standard method. Regarding the high acid oil, the single stage liquid-liquid extraction reduced the FFA in macaúba pulp oil in about 23 % while the three batch stages reduced up to 60%. At the selected parameters (ethanol 94oGL, solvent/substrate ratio = 2), the partition coefficients in the firs stage to FFA (KFFA) were 30.45, 12.00 and 1.95, respectively to high acid, acid and low acid macaúba oils and the partition coefficients to TAG (KTAG) were 7.07, 0.04 and 0.02, respectively to high acid, acid and low acid macaúba oils. These results show the potential of ethanol to vegetable oil deacidification. Besides reduced generation of environmental pollutants, this new approach could also lead to reduction in oil losses, especially for low acid oil.

Liquid–Liquid Extraction of Neutral Lipids and Free Fatty Acids from Microalgae Oil

2018 ◽  
Vol 63 (9) ◽  
pp. 3391-3399
Author(s):  
Tamires Teixeira Barcelos ◽  
Marcio Martins ◽  
Rita Sousa ◽  
Jane Selia dos Reis Coimbra
Keyword(s):  
Fatty Acids ◽  
Free Fatty Acids ◽  
Neutral Lipids ◽  
Liquid Extraction ◽  
Liquid Liquid Extraction ◽  
Microalgae Oil

scholarly journals EKSTRAKSI ASAM LEMAK BEBAS DARI MINYAK NABATI DENGAN METANOL KAJIAN PERPINDAHAN MASSA

2012 ◽  
Vol 16 (4) ◽  
pp. 173
Author(s):  
Wahyuningsih Wahyuningsih ◽  
Moh Endy Yulianto
Keyword(s):  
Fatty Acids ◽  
Mass Transfer ◽  
Free Fatty Acids ◽  
Vegetable Oils ◽  
Liquid Extraction ◽  
Feed Ratio ◽  
Transfer Coefficients ◽  
Mass Transfer Coefficients ◽  
Number Range ◽  
Liquid Liquid Extraction

Wahyuningsih, Moh Endy Yulianto, in this paper explain that extraction of free fatty acids from vegetable oils with methanol performed in batch stirred tank, in a variety of conditions. Variables experiments in liquid-liquid extraction including temperature, solvent ratio and rotational speed stirrer. This study aims to develop a correlation coefficient of mass transfer in extraction of free fatty acids from vegetable oils methanol. Rresearch was conducted in two phases. Was the first stage liquid-liquid extraction experiments in laboratory. Second step is the development of an empirical correlation for the mass transfer coefficients in the form of numbers not berdemensi results showed that the greater the temperature, turn the mixer speed and solvent-feed ratio of the mass transfer koffisien gained greater. Mass transfer coefficient expressed in Sherwood number and correlated against the Reynolds number, Schmitd, (dP / dT) and (L / S), the results obtained: Sh = 4,669 x 10-5 Re 0,462 Sc0,5 (dP/dT)0,308 (L/S)0,187 If used to calculate the mass transfer coefficients, have an average error of 8.79% for the regression line. This equation was developed in the Re number range 3169 to 11 750; numbers Sc 6321 to 9896, (dp / dT) from 0.0007 to 0.0013 and (L / S) of 0.333 to 1. Keywords: nabati oil extraction

scholarly journals Enzymatic Methods for the Manipulation and Valorization of Soapstock from Vegetable Oil Refining Processes

2021 ◽  
Vol 2 (1) ◽  
pp. 74-91
Author(s):  
Beatrice Casali ◽  
Elisabetta Brenna ◽  
Fabio Parmeggiani ◽  
Davide Tessaro ◽  
Francesca Tentori
Keyword(s):  
Fatty Acids ◽  
Free Fatty Acids ◽  
Vegetable Oil ◽  
Lipase Production ◽  
Oil Refining ◽  
Flow Mode ◽  
Acid Oil ◽  
Industrial Level ◽  
Vegetable Oil Refining ◽  
Hydrolysis Of

The review will discuss the methods that have been optimized so far for the enzymatic hydrolysis of soapstock into enriched mixtures of free fatty acids, in order to offer a sustainable alternative to the procedure which is currently employed at the industrial level for converting soapstock into the by-product known as acid oil (or olein, i.e., free fatty acids removed from raw vegetable oil, dissolved in residual triglycerides). The further biocatalyzed manipulation of soapstock or of the corresponding acid oil for the production of biodiesel and fine chemicals (surfactants, plasticizers, and additives) will be described, with specific attention given to processes performed in continuous flow mode. The valorization of soapstock as carbon source in industrial lipase production will be also considered.

Liquid–liquid extraction of thorium(IV) by fatty acids: a comparative study

2013 ◽  
Vol 299 (3) ◽  
pp. 1191-1198 ◽  
Author(s):  
Mohamed Amine Didi ◽  
Didier Villemin ◽  
Omar Abderrahim ◽  
Abdelkrim Azzouz
Keyword(s):  
Fatty Acids ◽  
Comparative Study ◽  
Liquid Extraction ◽  
Liquid Liquid Extraction

Catalyst-free microwave-assisted conversion of free fatty acids in triglyceride feedstocks with high acid content

2014 ◽  
Vol 68 ◽  
pp. 524-528 ◽  
Author(s):  
Jeroen Geuens ◽  
Sergey Sergeyev ◽  
Bert U.W. Maes ◽  
Serge M.F. Tavernier
Keyword(s):  
Fatty Acids ◽  
Free Fatty Acids ◽  
Acid Content ◽  
Microwave Assisted ◽  
High Acid ◽  
Catalyst Free

scholarly journals STUDI PENGARUH FAKTOR BUMBU, JENIS MINYAK DAN FREKUENSI PENGGORENGAN TERHADAP IMPURITIS MINYAK GORENG PASCA PENGGORENGAN TEMPE KEDELAI

Pro Food ◽  
2020 ◽  
Vol 6 (1) ◽  
pp. 591
Author(s):  
Cindhe Putri Larasati ◽  
Novian Wely Asmoro ◽  
Sri Hartati ◽  
Catur Budi Handayani
Keyword(s):  
Fatty Acids ◽  
Specific Gravity ◽  
Free Fatty Acids ◽  
Water Content ◽  
Oil Quality ◽  
Gravimetric Method ◽  
Physical Parameters ◽  
Bulk Oil ◽  
Cooking Oil ◽  
Randomized Design

ABSTRACT            The purpose of this study was to determine the effect of seasoning and type of oil on the weight of impurities and water content of oil after soybean tempeh frying, and to know the effect of frying frequency on quality of cooking oil after soybean tempeh frying with chemical and physical parameters. The experimental design used in this study was a factorial completely randomized design with two treatments No Seasoning and Seasoning. The second treatment is the frying frequency. The first factor had 18 treatments and the second factor was 12 treatments, each treatment was repeated 2x so that the first factor was obtained 18x2 = 36 units of the experiment, the second factor 12x2 = 24 units of the experiment. Data were analyzed statistically using F. If the test shows significantly different results, followed by HSD test. Stage I to measure water content (gravimetric method) and the weight of impurities cooking oil after frying soybean tempeh. The influence of seasoning / no seasoning and the type of oil which gives the water content and weight of impurities in the highest post-frying soybean frying oil used for stage II research. Phase II tests the water content, weight of impurities (gravimetry), specific gravity (pycnometer), free fatty acids (titration), color (chromameter). The results showed that cooking oil with no seasoning tempeh frying and no oil had a significant effect on water content, while the weight of impurities had a significant effect on tempeh results without Bulk oil seasoning (TC) 28.25% and Bulk oil-seasoned tempeh BC) 31.23%. The frying frequency does not significantly affect the water content and specific gravity, but it has a significant effect on the weight of impurities with results, the frequency of 1 time frying (P1X) 30.1%, free fatty acids with a frequency of 3 times frying (P3X) 0.40% and at a frequency of 4 times frying (P4X) 0.35% and color L * at a frequency of 1 frying time (P1X) 60.54, a * with a frequency of 1 time frying (P1X) -0.51 and a frequency of 2 times the frying (P2X) 2.54, b * 1 time frying frequency (P1X) 29.26.   Keywords: Frying frequency, Impurities, Oil, Oil quality   ABSTRAK            Tujuan dari penelitian ini adalah mengetahui pengaruh bumbu dan  jenis minyak terhadap berat impuritis dan kadar air minyak pasca penggorengan tempe kedelai, serta mengetahui pengaruh frekuensi penggorengan terhadap mutu minyak goreng pasca penggorengan tempe kedelai dengan parameter fisik dan kimia. Metode penelitian menggunakan Rancangan Acak Lengkap. Faktor pertama menggunakan tempe berbumbu/ tidak berbumbu serta jenis minyak dan faktor kedua frekuensi penggorengan. Faktor pertama mempunyai 18 perlakuan dan faktor kedua 12 perlakuan, masing-masing perlakuan diulang 2x sehingga diperoleh faktor pertama 18x2 = 36 unit percobaan, faktor kedua 12x2 = 24 unit percobaan. Data yang diperoleh dianalisis secara statistik menggunakan uji F. Apabila memperlihatkan hasil berbeda nyata, dilanjutkan dengan uji BNJ. Analisis pada tahap I yaitu kadar air (metode gravimetri) dan berat impuritis minyak goreng pasca penggorengan tempe kedelai. Tahap II menguji kadar air, berat impuritis (gravimetri), berat jenis (piknometer), asam lemak bebas (titrasi), warna (chromameter). Hasil penelitian menunjukkan bahwa minyak goreng pasca penggorengan tempe yang berbumbu/ tidak berbumbu dan jenis minyak tidak berpengaruh nyata terhadap kadar air, sedangkan terhadap berat impuritis berpengaruh nyata dengan hasil tempe tanpa bumbu minyak Curah (TC) 28,25% dan tempe berbumbu minyak Curah (BC) 31,23%. Pada frekuensi penggorengan tidak berpengaruh nyata terhadap kadar air dan berat jenis, namun berpengaruh nyata terhadap berat impuritis dengan hasil, frekuensi 1 kali penggorengan (P1X) 30,1%, asam lemak bebas dengan frekuensi 3 kali penggorengan (P3X) 0,40% dan pada frekuensi 4 kali penggorengan (P4X) 0,35% dan warna L* pada frekuensi 1 kali penggorengan (P1X) 60,54, a* dengan frekuensi 1 kali penggorengan (P1X) -0,51 dan frekuensi 2 kali penggorengan (P2X) 2,54, b* frekuensi 1 kali penggorengan (P1X) 29,26.   Kata kunci: Frekuensi penggorengan, Impuritis, Minyak, Mutu minyak

scholarly journals Pengaruh Kadar Air Pada Proses Pemucatan Minyak Kelapa Sawit

2019 ◽  
Vol 2 (1) ◽  
pp. 79-83
Author(s):  
Mayang Sari ◽  
Yusuf Ritonga ◽  
Sri Wahyuna Saragih
Keyword(s):  
Fatty Acids ◽  
Free Fatty Acids ◽  
Water Content ◽  
Palm Oil ◽  
Operating Temperature ◽  
Vacuum Pump ◽  
Bleaching Process ◽  
Effect Of Water ◽  
Dye Absorption ◽  
Oil Water

Secara alami air memang sudah ada pada minyak. Pada tahap penetralan untuk pemurnian minyak kelapa sawit, air juga terbentuk akibat reaksi antara kaustik soda dengan asam lemak bebas. Tujuan penelitian ini adalah untuk mengetahui pengaruh kadar air pada pada proses pemucatan minyak kelapa sawit terhadap warna minyak dan terhadap asam lemak bebas. Penelitian dilakukan pada temperature operasi 70 °C dengan menggunakan pompa vakum (30-40 cmHg). Bahan pemucat yang digunakan tanah bentonite sebanyak 1,5% dari berat total keseluruhan minyak. Dilakukan dengan bantuan pengaduk dalam membantu penyerapan zat warna selama 30 menit oleh tanah bentonite. Hasil penelitian menunjukkan bahwa Kandungan air dalam minyak sangat berpengaruh terhadap warna minyak yang dihasilkan pada proses pemucatan. Bertambahnya kadar air, maka sangat berpengaruh terhadap warna minyak . Pengaruh kadar air juga terlihat terhadap asam lemak bebas (bilangan asam). Semakin tinggi kadar air minyak maka semakin besar harga bilangan asam minyak .   Water naturally exists in oil. In the neutralization stage for refining palm oil, water is also formed due to the reaction between caustic soda and free fatty acids. The purpose of this study was to determine the effect of water content on the bleaching process of palm oil on the color of oil and on free fatty acids. This study was carried out at an operating temperature of 70°C using a vacuum pump (30 - 40 cmHg). The bleaching material used by bentonite soil was 1.5% of the total weight of the oil. It was carried out with the help of a stirrer to help the dye absorption for 30 minutes by bentonite soil. The results showed that the water content in the oil greatly affected the color of the oil produced in the bleaching process. The increase of the water content greatly affected the oil color. The effect of water content was also seen on free fatty acids (acid numbers). The higher the water content of the oil, the greater the number of oil acid.

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