Synthesis of Zero-Birefringence Polymers Based on Positive and Negative Birefringence Polymer

2010 ◽  
Vol 428-429 ◽  
pp. 111-116
Author(s):  
Wen Jun Yang ◽  
Guo Zhu Liu ◽  
Ji Min Wang ◽  
Du Ling Xia

Birefringence of a polymer is caused by polymer chain orientation during an injection-molding, extrusion processing or heat drawing. Birefringence of polymers degrades the performance of optical devices that require focusing by lenses or maintaining the polarization state of incident light. Optical polymers which exhibit no birefringence with any orientation of polymer chains are desirable to realize high performance optical devices that handle polarized light. In this study we demonstrate the random copolymerization method for synthesizing the zero-birefringence polymers in which positive and negative birefringence homopolymer are blended. We synthesize a polymer that exhibits no orientational birefringence with any orientation degree in a system that is composed of Methyl methacrylate/Styrene/Benzyl methacrylate.

2003 ◽  
Vol 771 ◽  
Author(s):  
Hisanori Ohkita ◽  
Masaki Mukoh ◽  
Akihiro Tagaya ◽  
Yasuhiro Koike

AbstractBirefringence induced by the orientation of polymer main chains during an injectionmolding or extrusion processing restricts the application of optical polymers to optical devices that require maintaining the polarization state of incident light. We propose the “birefringent crystal dopant method” to compensate the birefringence of polymers by homogeneous doping with an opposite birefringent needle-like crystal. Strontium carbonate (SrCO3) was selected for this method and synthesized, with particle lengths of 50-200nm and aspect ratios of 2-5. SrCO3 was doped into poly(MMA/BzMA= 78/22(wt./wt.)) film. The film was uniaxially drawn at 130°C and 4mm/min. For the first time, the positive birefringence of the drawn copolymer film at a wavelength of 633nm was compensated by doping with 0.3wt.% of SrCO3 without losing transparency and thermostability.


2004 ◽  
Vol 99-100 ◽  
pp. 143-148
Author(s):  
H. Ohkita ◽  
A. Tagaya ◽  
Y. Koike

Birefringence induced by the orientation of polymer main chains during injectionmoulding or extrusion processing restricts the application of optical polymers to optical devices that require the polarization state of incident light to be maintained. To compensate this birefringence of polymers we propose using the “birefringent crystal dopant method” - homogeneous doping with an opposite birefringent needle-like crystal. Strontium carbonate (SrCO3) was selected for this purpose and synthesized, with a length of about 200nm and a width of about 20nm. SrCO3 was doped into poly(MMA/BzMA= 78/22(wt./wt.)) film. The film was uniaxially drawn at 130°C and 4mm/min. For the first time, the positive birefringence of the drawn copolymer film at a wavelength of 633nm was compensated by doping with 0.3wt.% of SrCO3 without loss of transparency and thermostability.


2011 ◽  
Vol 201-203 ◽  
pp. 1590-1595
Author(s):  
Mu Zhun Zhou ◽  
Yan Ru Chen ◽  
Qi Zhao ◽  
Yu Xin

Principle of polarization encoding based on electro-optic effect of LiNbO3 crystal is analyzed, effact on polarization encoding optical field effects is studied when the incident light direction changes. Theoretical calculations show that, with the angle between the direction of incident laser beam and the main axis of LiNbO3 crystal increases, rotation angle of polarization ellipse remain unchanged,but ellipticity changes at any other position except in the center of the encoder,at the top and bottom of encoder,polarization state changes from circularly polarized to elliptically polarized,at other position of the encoder, polarization states are still elliptically polarized light but with different ellipticity angle. Experiment measurement results are in accord with ones of the calculation.


2021 ◽  
Vol 9 ◽  
Author(s):  
Yongkang Song ◽  
Weici Liu ◽  
Xiaolei Wang ◽  
Faqiang Wang ◽  
Zhongchao Wei ◽  
...  

Metasurfaces have powerful light field manipulation capabilities, which have been extensively studied in the past few years and have developed rapidly in various fields. At present, the focus of metasurface research has shifted to the tunable functionality. In this paper, a temperature-controllable multifunctional metasurface lens based on phase transition material is designed. First of all, by controlling the temperature of the desired working area and the polarization of the incident light, switching among multiple focus, single focus, and no focus at any position can be achieved, and the intensity and helicity of the output light can be adjusted. In addition, a polarization-sensitive intensity-tunable metalens based on the P-B phase principle is designed, when the incident light is linearly polarized light, left-handed circularly polarized light, or right-handed circularly polarized light, it has the same focal point but with different light field intensities. Therefore, the focused intensity can be tunable by the polarization state of the incident light.


Materials ◽  
2021 ◽  
Vol 14 (2) ◽  
pp. 326
Author(s):  
Cong Chen ◽  
Jiajia Mi ◽  
Panpan Chen ◽  
Xiang Du ◽  
Jianxin Xi ◽  
...  

With the rapid development of on-chip optics, integrated optical devices with better performance are desirable. Waveguide couplers are the typical integrated optical devices, allowing for the fast transmission and conversion of optical signals in a broad working band. However, traditional waveguide couplers are limited by the narrow operation band to couple the spatial light into the chip and the fixed unidirectional transmission of light flow. Furthermore, most of the couplers only realize unidirectional transmission under the illumination of the linear polarized light. In this work, a broadband polarization directional coupler based on a metallic catenary antenna integrated on a silicon-on-insulator (SOI) waveguide has been designed and demonstrated under the illumination of the circularly polarized light. By applying the genetic algorithm to optimize the multiple widths of the metallic catenary antenna, the numerical simulation results show that the extinction ratio of the coupler can be maintained larger than 18 dB in a wide operation band of 300 nm (from 1400 to 1700 nm). Moreover, the coupler can couple the spatial beam into the plane and transmit in the opposite direction by modulating the rotation direction of the incident light. The broadband polarization directional coupler might have great potential in integrated optoelectronic devices and on-chip optical devices.


Nanomaterials ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 3436
Author(s):  
Shaobo Ge ◽  
Weiguo Liu ◽  
Xueping Sun ◽  
Jin Zhang ◽  
Pengfei Yang ◽  
...  

In this paper, comprehensively utilizing the diffraction theory and electromagnetic resonance effect is creatively employed to design a multifunctional metasurface zone plate (MMZP) and achieve the control of polarization states, while maintaining a broadband achromatic converging property in a near-IR region. The MMZP consists of several rings with fixed width and varying heights; each ring has a number of nanofins (usually called meta-atoms). The numerical simulation method is used to analyze the intensity distribution and polarization state of the emergent light, and the results show that the designed MMZP can realize the polarization manipulation while keeping the broadband in focus. For a specific design wavelength (0.7μm), the incident light can be converted from left circularly polarized light to right circularly polarized light after passing through the MMZP, and the focusing efficiency reaches above 35%, which is more than twice as much as reported in the literature. Moreover, the achromatic broadband focusing property of the MMZP is independent with the polarization state of the incident light. This approach broadens degrees of freedom in micro-nano optical design, and is expected to find applications in multifunctional focusing devices and polarization imaging.


2020 ◽  
Vol 2020 (2) ◽  
pp. 100-1-100-6
Author(s):  
Takuya Omura ◽  
Hayato Watanabe ◽  
Naoto Okaichi ◽  
Hisayuki Sasaki ◽  
Masahiro Kawakita

We enhanced the resolution characteristics of a threedimensional (3D) image using time-division multiplexing methods in a full-parallax multi-view 3D display. A time-division light-ray shifting (TDLS) method is proposed that uses two polarization gratings (PGs). As PG changes the diffraction direction of light rays according to the polarization state of the incident light, this method can shift light rays approximately 7 mm in a diagonal direction by switching the polarization state of incident light and adjusting the distance between the PGs. We verified the effect on the characteristics of 3D images based on the extent of the shift. As a result, the resolution of a 3D image with depth is improved by shifting half a pitch of a multi-view image using the TDLS method, and the resolution of the image displayed near the screen is improved by shifting half a pixel of each viewpoint image with a wobbling method. These methods can easily enhance 3D characteristics with a small number of projectors.


Nanophotonics ◽  
2020 ◽  
Vol 9 (16) ◽  
pp. 4719-4728
Author(s):  
Tao Deng ◽  
Shasha Li ◽  
Yuning Li ◽  
Yang Zhang ◽  
Jingye Sun ◽  
...  

AbstractThe molybdenum disulfide (MoS2)-based photodetectors are facing two challenges: the insensitivity to polarized light and the low photoresponsivity. Herein, three-dimensional (3D) field-effect transistors (FETs) based on monolayer MoS2 were fabricated by applying a self–rolled-up technique. The unique microtubular structure makes 3D MoS2 FETs become polarization sensitive. Moreover, the microtubular structure not only offers a natural resonant microcavity to enhance the optical field inside but also increases the light-MoS2 interaction area, resulting in a higher photoresponsivity. Photoresponsivities as high as 23.8 and 2.9 A/W at 395 and 660 nm, respectively, and a comparable polarization ratio of 1.64 were obtained. The fabrication technique of the 3D MoS2 FET could be transferred to other two-dimensional materials, which is very promising for high-performance polarization-sensitive optical and optoelectronic applications.


Molecules ◽  
2021 ◽  
Vol 26 (10) ◽  
pp. 2942
Author(s):  
Bhausaheb V. Tawade ◽  
Ikeoluwa E. Apata ◽  
Nihar Pradhan ◽  
Alamgir Karim ◽  
Dharmaraj Raghavan

The synthesis of polymer-grafted nanoparticles (PGNPs) or hairy nanoparticles (HNPs) by tethering of polymer chains to the surface of nanoparticles is an important technique to obtain nanostructured hybrid materials that have been widely used in the formulation of advanced polymer nanocomposites. Ceramic-based polymer nanocomposites integrate key attributes of polymer and ceramic nanomaterial to improve the dielectric properties such as breakdown strength, energy density and dielectric loss. This review describes the ”grafting from” and ”grafting to” approaches commonly adopted to graft polymer chains on NPs pertaining to nano-dielectrics. The article also covers various surface initiated controlled radical polymerization techniques, along with templated approaches for grafting of polymer chains onto SiO2, TiO2, BaTiO3, and Al2O3 nanomaterials. As a look towards applications, an outlook on high-performance polymer nanocomposite capacitors for the design of high energy density pulsed power thin-film capacitors is also presented.


Crystals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 267
Author(s):  
Minyu Bai ◽  
Zhuoman Wang ◽  
Jijie Zhao ◽  
Shuai Wen ◽  
Peiru Zhang ◽  
...  

Weak absorption remains a vital factor that limits the application of two-dimensional (2D) materials due to the atomic thickness of those materials. In this work, a direct chemical vapor deposition (CVD) process was applied to achieve 2D MoS2 encapsulation onto the silicon nanopillar array substrate (NPAS). Single-layer 2D MoS2 monocrystal sheets were obtained, and the percentage of the encapsulated surface of NPAS was up to 80%. The reflection and transmittance of incident light of our 2D MoS2-encapsulated silicon substrate within visible to shortwave infrared were significantly reduced compared with the counterpart planar silicon substrate, leading to effective light trapping in NPAS. The proposed method provides a method of conformal deposition upon NPAS that combines the advantages of both 2D MoS2 and its substrate. Furthermore, the method is feasible and low-cost, providing a promising process for high-performance optoelectronic device development.


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