The Effects of a Compatibilizer for Improving Mechanical Properties on Polymer Matrix Composites

2021 ◽  
Vol 877 ◽  
pp. 3-8
Author(s):  
Prathumrat Nuyang ◽  
Atiwat Wiriya-Amornchai ◽  
Watthanaphon Cheewawuttipong

The effect of compatibilizer agent was studied when adding Aluminum fine powder (Al) to reinforce in Polypropylene (PP) by compared between polymer matrix composites (PMCs) and PMCs added Polypropylene graft maleic anhydride (PP-g-MAH).The average particle size of the aluminum fine powder was around 75 μm filled in polypropylene with different proportions of 2.5, 5, 7.5 and 10wt%. PMCs were prepared using the internal mixer. The results found that when the amount of aluminum fine powder increased, the mechanical properties had changed, i.e., tensile strength, and Young’s Modulus increased, while the impact strength and elongation at break decreased. But, when adding compatibilizer 1wt% it was found that the trend of tensile strength, and Young’s Modulus increased that compared with non-compatibilizer, but the impact strength and elongation at break decreased. The part of the morphology of PMCs with non-compatibilizer was found that the particle of aluminum fine powder dispersed in the matrix phase, but there were many microvoids between filler and matrix. But, PMCs with compatibilizer caused the microvoids between filler and matrix to be reduced.

2013 ◽  
Vol 575-576 ◽  
pp. 203-208
Author(s):  
Hong Xing Xu ◽  
Xin Hua Yuan ◽  
En Bo Zhu ◽  
Shuang Lian Li ◽  
Ling Chen ◽  
...  

The polytetrafluoroethylene (PTFE) matrix composites which filled with polyphenylene sulfide (PPS) fiber, poly-p-phenelenferephthalamide (PPTA) fibre or glass fiber (GF)) and graphite at various mass fractions were prepared by the processes of mechanical blending, compression molding and sintering. The mechanical properties of the composites, such as tensile strength, impact strength and hardness were investigated. The results show that tensile strength and elongation at break markedly decrease but elasticity increases by filling with fibers. Impact strength decreases by filling with PPS and GF, and the composite displays brittle characteristic. However, the impact strength rapidly increases by filling with PPTA fiber. Hardness increases with the fibers content increases, and decreases with graphite content increases. Filling graphite into PTFE has light effect on the impact and tensile strength of composites. The tribological properties of the composites were investigated on M-2000 wear tester at dry friction condition. The wear mechanism was also discussed and the wear surfaces were examined by SEM. The result indicates that fibers which diffused in PTFE matrix wind with PTFE molecule chain, and then form grid structure. The load-bearing capacity of composites can be obviously enhanced and the trend of block fragmentations slide is inhibited, so that the tribological properties are improved markedly.


Polymers ◽  
2021 ◽  
Vol 13 (17) ◽  
pp. 2951
Author(s):  
Vijay Tambrallimath ◽  
R. Keshavamurthy ◽  
Saravana D. Bavan ◽  
Arun Y Patil ◽  
T. M. Yunus Khan ◽  
...  

This experimental study investigates the mechanical properties of polymer matrix composites containing nanofiller developed by fused deposition modelling (FDM). A novel polymer nanocomposite was developed by amalgamating polycarbonate-acrylonitrile butadiene styrene (PC-ABS) by blending with graphene nanoparticles in the following proportions: 0.2, 0.4, 0.6, and 0.8 wt %. The composite filaments were developed using a twin-screw extrusion method. The mechanical properties such as tensile strength, low-velocity impact strength, and surface roughness of pure PC-ABS and PC-ABS + graphene were compared. It was observed that with the addition of graphene, tensile strength and impact strength improved, and a reduction in surface roughness was observed along the build direction. These properties were analyzed to understand the dispersion of graphene in the PC-ABS matrix and its effects on the parameters of the study. With the 0.8 wt % addition of graphene to PC-ABS, the tensile strength increased by 57%, and the impact resistance increased by 87%. A reduction in surface roughness was noted for every incremental addition of graphene to PC-ABS. The highest decrement was seen for the 0.8 wt % addition of graphene reinforcement that amounted to 40% compared to PC-ABS.


2020 ◽  
Vol 845 ◽  
pp. 39-44
Author(s):  
Woraporn Kiwjaroun ◽  
Saowaroj Chuayjuljit ◽  
Phasawat Chaiwutthinan ◽  
Anyaporn Boonmahitthisud

The aim of this study is to prepare green composites from poly (lactic acid) (PLA) and in-house epoxidized natural rubber (ENR) with coir fibers (CFs). In-house ENR with medium epoxidation degree (about 35 mole% epoxidation) was first prepared via ‘in situ’ epoxidation of natural rubber latex. PLA was melt-mixed with three loadings (10, 20 and 30 wt%) of ENR on a twin-screw extruder, followed by injection molding to observe their mechanical properties (impact strength, tensile strength, Young’s modulus and elongation at break) and thermal stability. The results showed that the addition of the ENR enhanced the impact strength and elongation at break, but deteriorated tensile strength, Young’s modulus and thermal stability of the blends. From mechanical properties consideration, the 90/10 PLA/ENR blend was selected for preparing green composites with different amounts of CFs (5, 10 and 20 phr). It was found that the incorporation of CFs improved tensile strength and Young’s modulus. However, the impact strength, elongation at break and thermal stability of the green composites decreased as compared to those of the neat 90/10 PLA/ENR blend.


2020 ◽  
pp. 089270572096352
Author(s):  
Yousef Ahmad Mubarak

In this study, the effects of two different biodegradable plastic additives on the thermal and mechanical properties of isotactic polypropylene were investigated, analyzed, and presented. Biosphere biodegradable plastic additive and another oxidative biodegradable plastic additive, D2W, were used in 0.25, 0.5, 1.0, 1.5, and 2.0 wt% to prepare two sets of isotactic polypropylene composites. Differential scanning calorimeter and optical polarized light microscope were used to analyze the obtained composites thermally while the mechanical properties of these composites were studied by conducting tensile and impact testing. The morphological results reveal that only monoclinic α spherulites were obtained when the polypropylene crystallizes isothermally from the melt, it was found that both biodegradable plastic additives used decreases the size of the spherulites and increases their densities per unit volume. The incorporation of the Biosphere within the polypropylene matrix raises the crystallization temperature while the existence of D2W within the matrix delays the crystallization process. The addition of 2 wt% of Biosphere allows polypropylene to crystallize at about 13°C higher than neat polypropylene. It has been found that the addition of the biosphere increases Young’s modulus, while decreases the yield strength, the elongation at break, and the impact strength. On the other hand, D2W as an oxidative biodegradable plastic additive increases the elongation at break and the impact strength while decreases the yield strength and Young’s modulus.


2021 ◽  
Vol 11 (12) ◽  
pp. 5317
Author(s):  
Rafał Malinowski ◽  
Aneta Raszkowska-Kaczor ◽  
Krzysztof Moraczewski ◽  
Wojciech Głuszewski ◽  
Volodymyr Krasinskyi ◽  
...  

The need for the development of new biodegradable materials and modification of the properties the current ones possess has essentially increased in recent years. The aim of this study was the comparison of changes occurring in poly(ε-caprolactone) (PCL) due to its modification by high-energy electron beam derived from a linear electron accelerator, as well as the addition of natural fibers in the form of cut hemp fibers. Changes to the fibers structure in the obtained composites and the geometrical surface structure of sample fractures with the use of scanning electron microscopy were investigated. Moreover, the mechanical properties were examined, including tensile strength, elongation at break, flexural modulus and impact strength of the modified PCL. It was found that PCL, modified with hemp fibers and/or electron radiation, exhibited enhanced flexural modulus but the elongation at break and impact strength decreased. Depending on the electron radiation dose and the hemp fibers content, tensile strength decreased or increased. It was also found that hemp fibers caused greater changes to the mechanical properties of PCL than electron radiation. The prepared composites exhibited uniform distribution of the dispersed phase in the polymer matrix and adequate adhesion at the interface between the two components.


2012 ◽  
Vol 3 (1) ◽  
pp. 13-26
Author(s):  
Myrtha Karina ◽  
Lucia Indrarti ◽  
Rike Yudianti ◽  
Indriyati

The effect of castor oil on the physical and mechanical properties of bacterial cellulose is described. Bacterial cellulose (BC) was impregnated with 0.5–2% (w/v) castor oil (CO) in acetone–water, providing BCCO films. Scanning electron micrographs revealed that the castor oil penetrated the pores of the bacterial cellulose, resulting in a smoother morphology and enhanced hydrophilicity. Castor oil caused a slight change in crystallinity indices and resulted in reduced tensile strength and Young's modulus but increased elongation at break. A significant reduction in tensile strength and Young's modulus was achieved in BCCO films with 2% castor oil, and there was an improvement in elongation at break and hydrophilicity. Impregnation with castor oil, a biodegradable and safe plasticiser, resulted in less rigid and more ductile composites.


2013 ◽  
Vol 706-708 ◽  
pp. 95-98
Author(s):  
Mi Dan Li ◽  
Dong Mei Liu ◽  
Lu Lu Feng ◽  
Huan Niu ◽  
Yao Lu

Polymer matrix composites made from phenolic resin are filled with natural graphite powders. They are fabricated by compression molding technique. The density, electrical conductivity and flexural strength of composite are analyzed to determine the influences of mould pressure and mould pressing time on the physical, electrical and mechanical properties of composite. It is found that the density, electrical conductivity and flexural strength of composites increased with increasing mould pressure. Under pressure of 40 MPa for 60 min, the density, electrical conductivity and flexural strength of composites were 1.85 g/cm3, 4.35  103 S/cm and 70 MPa, respectively. The decreased gaps could be the main reason for the increasing of density, electrical conductivity and flexural strength as mould pressure increases. The results also show that the density of composites increased with increasing mould pressing time.


Polymers ◽  
2020 ◽  
Vol 13 (1) ◽  
pp. 117
Author(s):  
Le Thuy Hang ◽  
Do Quoc Viet ◽  
Nguyen Pham Duy Linh ◽  
Vu Anh Doan ◽  
Hai-Linh Thi Dang ◽  
...  

In this study, we present the fabrication of nitrile butadiene rubber/waste leather fiber (NBR/WLF) composites with different weight percentages of WLF and NBR (0/100, 20/80, 30/70, 40/60, 50/50, 60/40 wt/wt). WLF was prepared by cutting the scrap leathers from the waste product of the Vietnamese leather industry. Subsequently, in order to make the short fibers, it was mixed by a hammer mill. The characteristics of WLF/NBR composites such as mechanical properties (tensile strength, tear strength, hardness), dynamic mechanical properties, toluene absorption, and morphology were carefully evaluated. As a result, the tensile strength and tear strength become larger with increasing WLF content from 0 to 50 wt% and they decrease when further increasing WLF content. The highest tensile strength of 12.5 MPa and tear strength of 72.47 N/mm were achieved with the WLF/NBR ratio of 50/50 wt%. Both hardness and resistance of the developed materials with toluene increased with increasing WLF content. The SEM results showed a good adhesion of NBR matrix and the WLF. The increasing of storage modulus (E’) in comparison with raw NBR showed good compatibility between WLF and NBR matrix. This research showed that the recycled material from waste leather and NBR was successfully prepared and has great potential for manufacturing products such as floor covering courts and playgrounds, etc.


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