Influence of Composite Nano-Coating of Ni-Co-SiC Obtained by Electrodeposition on the Corrosion Resistance of API 5L X80 Steel

2017 ◽  
Vol 899 ◽  
pp. 317-322 ◽  
Author(s):  
Roseana Florentino da Costa Pereira ◽  
Edkarlla Sousa Dantas de Oliveira ◽  
Diogo Lins Alves e Silva ◽  
Andrêssa Souza Ribeiro ◽  
Oscar Olimpio de Araújo Filho ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Open Circuit Potential ◽  
Electrochemical Impedance ◽  
Open Circuit ◽  
Nano Particles ◽  
Micro Hardness ◽  
X Ray ◽  
Hardness Tests ◽  
Nano Coating ◽  
X80 Steel

Corrosion problems are frequent and occur in various sectors of industries, resulting consequences of economic order and serious accidents involving human lives and contaminating the environment. The electrodeposition is one of the most popular methods for preventing corrosion, where the Ni-Co metal matrix has been widely applied. The incorporation of SiC nano-particles in electrochemical baths produces nanocomposite coatings to synergistic properties with potential application in anti-corrosion protection. The objective of this work was to develop the Ni-Co-SiC nano-coating electrodeposited on API 5L X80 steel and evaluate the corrosion resistance. Open circuit potential (OCP), electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization (PP) measurements were performed in 3.5% NaCl solution. To correlate with corrosion behavior, scanning electron microscopy (SEM), energy-dispersive X-ray spectrum (EDXS) and Vickers micro-hardness tests on the nano-coating were performed.

Corrosion Behavior of Surfaced AM50 Magnesium Alloys under Stress Conditions

2010 ◽  
Vol 95 ◽  
pp. 79-83
Author(s):  
Amir Eliezer
Keyword(s):  
Corrosion Resistance ◽  
Magnesium Alloys ◽  
Open Circuit Potential ◽  
Electrochemical Impedance ◽  
Spinel Phase ◽  
Ceramic Coatings ◽  
Open Circuit ◽  
Stress Conditions ◽  
X Ray Diffraction ◽  
X Ray

Micro-arc oxidization of AM50 magnesium alloys was studied. The influence of micro-arc oxidization process was investigated; phase structure were analyzed using X-ray diffraction (XRD). Open circuit potential (OCP) and electrochemical impedance spectroscopy (EIS) were used to evaluate the corrosion resistance of ceramic coatings formed on magnesium alloys under stress conditions. XRD analyses indicate that the ceramic coatings fabricated on the surface of magnesium alloys by micro-arc oxidization are composed of spinel phase MgAl2O4 The corrosion resistance of ceramic coatings is improved compared with magnesium alloy substrate.

scholarly journals Χαρακτηρισμός πολυμερικών επιστρώσεων με νανοπερίεκτες σε μέταλλα για την προστασία τους από διάβρωση σε θαλάσσιο περιβάλλον

2012 ◽  
Author(s):  
Ανδρόνικος Μπαλάσκας
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Open Circuit Potential ◽  
Electrochemical Impedance ◽  
Open Circuit ◽  
X Ray Diffraction ◽  
X Ray ◽  
Organically Modified Silicates ◽  
Organically Modified ◽  
Ft Ir ◽  
Scanningelectron Microscopy

Υβριδικές επιστρώσεις οργανικά τροποποιημένων πυριτικών ενώσεων και εποξειδικώνρητινών (Organically Modified Silicates, ORMOSILs – epoxy) εφαρμόστηκαν στο κράμααργιλίου 2024-Τ3 και σε γαλβανισμένο χάλυβα σε υψηλές θερμοκρασίες (Hot Dip GalvanizedSteel, HDGS) προκειμένου αυτές να προστατεύσουν τα υποστρώματα από τη διάβρωση. Για τηνβελτίωση της αντοχής των επιστρώσεων στην διάβρωση ενσωματώθηκαν στην πολυμερικήμήτρα νανοπεριέκτες από μολυβδαινικό δημήτριο (CeMo) και οξείδιο του τιτανίου (TiO2),καθώς και pH-ευαίσθητα οργανικά νανοδοχεία πληρωμένα με τους αναστολείς διάβρωσης 2-μερκαπτοβενζοθειαζόλιο, 8-υδροξυκινολίνη, 1H-βενζοτριαζολο-4-σουλφονικό οξύ καιεξαφλουοροτιτανικό οξύ.Οι υβριδικές επιστρώσεις εφαρμόστηκαν στο υπόστρωμα με τη διαδικασία εμβάπτισης.Η μορφολογία των επιστρώσεων εξετάστηκε με ηλεκτρονική μικροσκοπία σάρωσης (ScanningElectron Microscopy (SEM)). Η σύνθεση και η δομή τους μελετήθηκε με υπέρυθρηΦασματοσκοπία μετασχηματισμού Fourier (FT-IR) και με μικροανάλυση με φθορισμομετρίαακτίνων Χ (Energy Dispersive X-Ray Analysis (EDX)). H ηλεκτροχημική φασματοσκοπίασύνθετης αντίστασης (Electrochemical Impedance Spectroscopy, EIS), η dc-πόλωση (dcpolarization)και η μέτριση ανοικτού δυναμικού (open circuit potential, OCP) χρησιμοποιήθηκανγια την αξιολόγηση των αντι-διαβρωτικών ιδιοτήτων των επιστρώσεων. Τα αποτελέσματαέδειξαν ότι οι επιστρώσεις με πληρωμένα νανοδοχεία έχουν αυξημένες αντιδιαβρωτικέςιδιότητες συγκριτικά με τις υπόλοιπες επιστρώσεις εμφανίζοντας και ιδιότητες αυτο-θεραπείας.Τέλος, συντέθηκαν νανόσφαιρες οξειδίου του χαλκού (Cu2O), οι οποίεςχαρακτηρίστηκαν με SEM, ηλεκτρονική μικροσκοπία διερχόμενης δέσμης (ΤransmissionΕlectron Μicroscopy (TEM)) και περίθλαση ακτίνων Χ (X ray Diffraction (XRD)). Οινανόσφαιρες στη συνέχεια πληρώθηκαν με ουσίες που δρουν ως βιοκτόνα και ενσωματώθηκανσε βαφές εμπορίου και σε επιστρώσεις βασισμένες σε εποξειδικές ενώσεις και μελετήθηκε ηδράση τους ως αντιαποθετικά αντιδραστήρια. Τα αποτελέσματα έδειξαν ότι οι επιστρώσεις μεπληρωμένες νανόσφαιρες Cu2O είχαν μεγαλύτερη αποτελεσματικότητα σε σύγκριση με τιςβαφές εμπορίου με βιοκτόνα μετά από έκθεση σε θαλάσσιο περιβάλλον.

Electrochemical Determination of the Corrosion Resistance of Ag-Pd Dental Alloys

2008 ◽  
Vol 59 (9) ◽  
Author(s):  
Daniel Mareci ◽  
Igor Cretescu ◽  
Neculai Aelenei ◽  
Julia Claudia Mirza Rosca
Keyword(s):  
Corrosion Resistance ◽  
Open Circuit Potential ◽  
Electrochemical Impedance ◽  
Corrosion Behaviour ◽  
Artificial Saliva ◽  
Surface Film ◽  
Electrochemical Determination ◽  
Open Circuit ◽  
Electrochemical Characteristics

The electrochemical behavior of a three Ag-Pd alloys used in dental prosthetics construction for crowns and bridges was studied in artificial saliva using the polarization curves and electrochemical impedance spectroscopy (EIS). The corrosion resistance was evaluated by means of the corrosion currents value and by coulometric analysis. The open circuit potential of Ag-Pd are attributed to dealloying followed by surface enrichment with Ag and the possible formation of an insoluble AgCl surface film on the respective alloy surfaces. Our results have shown that these alloys have a somewhat good corrosion resistance in artificial saliva. When increasing the content of Cu, corrosion resistance decreases. The passivation of all samples occurred spontaneously at the open circuit potential. The electrochemical properties of the spontaneously passivated electrodes at the open circuit potential were studied by EIS. The polarization resistance (Rp) and the electrode capacitance (Cdl) were determined. The polarisation resistance of all the samples increases with the immersion time. The polarization resistances are largest and decrease when increasing the content of Cu. Cu reduces the Ag-Pd alloy corrosion resistance. The present study, thought limited, has shown that electrochemical characteristics can be use to identify such alloys. Knowledge of the in vitro corrosion behaviour of these alloys may lead to better understanding of any biologically adverse effects in vitro.

Preparation and Salt Spray Corrosion Resistance of Ni/BN and NiCrAl/BN Coatings

2013 ◽  
Vol 537 ◽  
pp. 67-70
Author(s):  
Feng Zhang ◽  
Chuan Bing Huang ◽  
Wei Liu ◽  
Kui Zhou ◽  
Wen Ting Zhang ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Test ◽  
Open Circuit Potential ◽  
Salt Spray ◽  
Open Circuit ◽  
X Ray Diffraction ◽  
Salt Spray Corrosion ◽  
X Ray ◽  
Corrosion Behaviors ◽  
Scanning Electron

Ni/BN and NiCrAl/BN abradable sealing coatings used in turbo engines were prepared by plasma spray technology. The phases and the microstructures of the coatings were characterized with X-ray diffraction (XRD) and scanning electron microscopy (SEM). Corrosion behaviors of these coatings were investigated with open-circuit potential (OCP) and salt spray corrosion test. The results showed that the NiCrAl/BN possess better corrosion resistance as compared with Ni/BN.

scholarly journals Influence of Ultrasonic Excitation Sealing on the Corrosion Resistance of HVOF-Sprayed Nanostructured WC-CoCr Coatings under Different Corrosive Environments

Coatings ◽  
2019 ◽  
Vol 9 (11) ◽  
pp. 724 ◽  
Author(s):  
Zhang ◽  
Hong ◽  
Lin ◽  
Zheng
Keyword(s):  
Corrosion Resistance ◽  
Atmospheric Pressure ◽  
Room Temperature ◽  
Open Circuit Potential ◽  
Electrochemical Impedance ◽  
Corrosion Current ◽  
Aluminum Phosphate ◽  
Open Circuit ◽  
Corrosive Environments ◽  
Oxygen Fuel

The corrosion behavior of unsealed and sealed high-velocity oxygen-fuel (HVOF)-sprayed nanostructured WC-CoCr cermet coatings under different corrosive environments was investigated using scanning electron microscopy (SEM), open circuit potential (OCP), potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). Ultrasonic excitation sealing with aluminum phosphate was performed in an external ultrasonic bath with the frequency of 40 kHz at atmospheric pressure and room temperature. SEM micrographs revealed that the exposed area of the coating was effectively reduced by the coverage of aluminum phosphate sealant on the majority of pores. Electrochemical measurements demonstrated that the sealant with the help of ultrasonic energy could shift the corrosion potential to a more noble direction, reduce the corrosion current density, increase the resistance of charge transfer, and effectively improve the corrosion resistance of the coating in both 3.5 wt % NaCl and 1 mol·L−1 HCl solutions.

scholarly journals Effect of Cu Addition on the Electrochemical Corrosion Performance of Ni3Al in 1.0 M H2SO4

2015 ◽  
Vol 2015 ◽  
pp. 1-18 ◽  
Author(s):  
J. Porcayo-Calderon ◽  
R. A. Rodriguez-Diaz ◽  
E. Porcayo-Palafox ◽  
J. Colin ◽  
A. Molina-Ocampo ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Open Circuit Potential ◽  
Electrochemical Impedance ◽  
Electrochemical Corrosion ◽  
Open Circuit ◽  
Intermetallic Alloy ◽  
Intermetallic Alloys ◽  
Corrosion Performance ◽  
Linear Polarization Resistance ◽  
Electrochemical Corrosion Behavior

The effect of Cu addition on the electrochemical corrosion behavior of Ni3Al intermetallic alloy was investigated by potentiodynamic polarization, open-circuit potential, linear polarization resistance, and electrochemical impedance spectroscopy in 1.0 M H2SO4solution. Performance of the pure elements (Cu, Ni, and Al) was also evaluated. In general, Cu addition improved the corrosion resistance of Ni3Al. Electrochemical measurements show that corrosion resistance of Ni3Al-1Cu alloy is lower than that of other intermetallic alloys and pure elements (Ni, Cu, and Al) in 1.0 M H2SO4solution at 25°C. Surface analysis showed that the Ni3Al alloys are attacked mainly through the dendritic phases, and Cu addition suppresses the density of dendritic phases.

The Corrosion Characteristics of AlSi1MgMn

2015 ◽  
Vol 818 ◽  
pp. 125-128
Author(s):  
Petra Lacková ◽  
Mária Mihaliková ◽  
Jana Cervová ◽  
Anna Lišková
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Rate ◽  
Exposure Time ◽  
Polarization Resistance ◽  
Open Circuit Potential ◽  
Corrosion Potential ◽  
Open Circuit ◽  
Atmospheric Conditions ◽  
X Ray ◽  
Industrial Atmosphere

The paper presents the evaluation of corrosion resistance of aluminium alloy AlSi1MgMn. This alloy is used above all in any atmospheric conditions. The corrosion resistance of the alloy was evaluated by determining the open circuit potential (OCP) in solution SARS (this solution simulates the industrial atmosphere) after the 10 months of exposure time. The surface of aluminum alloys were analyzed by using energy dispersive X-ray analysis after the exposure time. The basic of corrosion characteristics (corrosion potential Ecorr, corrosion rate icorr and polarization resistance Rp) were determined by potenciodynamic measurements according to Tafel’s and Stern’s methods.

Hydrothermal Surface Treatments with Cerium and Glycol Molecules on the AA 2024-T3 Clad Alloy

2016 ◽  
Vol 710 ◽  
pp. 216-221 ◽  
Author(s):  
Wagner Izaltino Alves Dos Santos ◽  
Isolda Costa ◽  
Célia Regina Tomachuk
Keyword(s):  
Corrosion Resistance ◽  
Electrochemical Impedance ◽  
Salt Spray ◽  
Electrochemical Techniques ◽  
Open Circuit ◽  
Self Healing ◽  
X Ray ◽  
Aa 2024 ◽  
New Treatment ◽  
New Treatments

New treatments for replacement of chromate require lower toxicity and corrosion protection. This study aims to investigate the influence of the combination of a Ce conversion coating (CCCe) with glycol molecules on the corrosion resistance of the AA2024-T3 clad (AA1230). The corrosion resistance of surface treated and untreated samples was evaluated by electrochemical techniques (electrochemical impedance spectroscopy, polarization tests and open circuit potential). These tests were complemented by salt spray tests to accelerate the corrosive effects of weathering. The surfaces were analyzed after corrosion tests by scanning electron microscopy with X-ray energy dispersive detector (SEM - EDX). The results of the CCCe samples in combination with glycol were compared with that of the surface with chromate layer and the results showed that the CCCe treatment is a candidate for replacement of chromating with the advantage that it does not generate toxic residues. The self-healing capacity of the new treatment tested was indicated by the increased formation of corrosion products deposition on top of Fe rich intermetallis in the AA1230 clad with time of exposure to the electrolyte.

scholarly journals Effect of Iron Content on Corrosion Properties of Pure Titanium as Grain Refiner

Materials ◽  
2021 ◽  
Vol 14 (23) ◽  
pp. 7193
Author(s):  
Bosung Seo ◽  
Hyeon-Tae Im ◽  
Ki-Beom Park ◽  
Kwangsuk Park ◽  
Hyung-Ki Park
Keyword(s):  
Corrosion Resistance ◽  
Open Circuit Potential ◽  
Electrochemical Impedance ◽  
Pure Titanium ◽  
Open Circuit ◽  
Tio2 Layer ◽  
Grain Refiner ◽  
Corrosion Properties ◽  
Acid Environment ◽  
Titanium Cathode

Microstructures and corrosion properties of pure titanium were characterized when iron was used as a grain refiner. The added Fe element acted as a strong grain refiner for pure titanium by forming β Ti phase at grain boundaries, and 0.15 wt% Fe was revealed to be a sufficient amount to make the grain size of pure titanium below 20 μm, which was the requirement for the desired titanium cathode. However, corrosion resistance was decreased with the Fe amount added. From the open circuit potential (OCP) results, it was obvious that the TiO2 stability against the reducing acid environment was deteriorated with the Fe amount, which seemed to be the main reason for the decreased corrosion resistance. Electrochemical impedance spectroscopy (EIS) results showed that both the decrease in the compact oxide film’s resistance (Rb) and the appearance of the outer porous film occurred as a result of the dissolution of the TiO2 layer, whose phenomena became more apparent as more Fe was added.

Corrosion Resistance of Modified Silane Films Formed on AZ31 Magnesium Alloys

2011 ◽  
Vol 686 ◽  
pp. 21-25
Author(s):  
Xian Long Cao ◽  
Fu Sheng Pan ◽  
Hong Da Deng ◽  
Wei Cai
Keyword(s):  
Corrosion Resistance ◽  
Magnesium Alloy ◽  
Corrosion Behavior ◽  
Open Circuit Potential ◽  
Electrochemical Impedance ◽  
Open Circuit ◽  
Chloride Ions ◽  
Cerium Nitrate ◽  
Az31 Magnesium Alloy ◽  
Sodium Chloride Solutions

This present work investigated the corrosion behavior of AZ31 magnesium alloy substrates pre-treated with bis-[triethoxysilylpropyl] tetrasulfide silane modified with cerium nitrate. The corrosion behavior of the pre-treated substrates in 0.005M sodium chloride solutions was assessed by potentiodynamic polarization, open circuit potential and electrochemical impedance spectroscopy (EIS). The results showed that the silane pre-treatments improved the corrosion resistance of the AZ31 magnesium alloy substrates in the presence of chloride ions. Especially the addition of cerium nitrate played an important role in reducing the corrosion activity.

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