Green Carbon Dots for Metal Sensing

2019 ◽  
Vol 962 ◽  
pp. 36-40
Author(s):  
Lan Ching Sim ◽  
Jia Min Khor ◽  
Kah Hon Leong ◽  
Pichiah Saravanan

In this work, carbon quantum dots (C-dots) was successfully synthesized by hydrothermal treatment using dried leaves as green precursor for metal sensing. The performance of C-dots when detecting metal ions in water will be evaluated by testing with different types of metal stock solutions. Quenching effect of fluorescence C-dots solution was observed in the presence of different metal ions. C-dots is more selective towards Fe3+ compared to other metal ions.

A green and simple synthesis of carbon quantum dots (CQDs) was derived from dried mint leaves by hydrothermal method. Crystalline structure of the synthesized CQDs was characterized with X-ray diffraction (XRD) method. The morphological properties of the CQDs were investigated with transmission electron microscopy (TEM). The optical behaviors of the CQDs were examined with fourier transfom infrared spectrophotometer (FT-IR), ultraviolet visible (UV-Vis) and photoluminescence spectrophotometer techniques. Crystalline structure of the CQDs was found as amorphous in nature and the average diameter of the CDs was calculated as 8.13 nm from TEM study. According to the fluorescence emission spectra of the samples, synthesized CQDs was sensitive to mainly Ag(I), Cr(III) and Fe(III) ions. Especially, Ag(I) was the most sensible compared to other metal ions. Quenching effect of the CQDs was also evaluated by using ascorbic acid to metal ions added CQDs samples. Ascorbic acid showed the quenching effect for all the metal ion added samples except Sn(II) ion.


2019 ◽  
Vol 11 (4) ◽  
pp. 490-506 ◽  
Author(s):  
K. Radhakrishnan ◽  
P. Panneerselvam ◽  
M. Marieeswaran

In this work, a green synthetic route was used to create a number of surface passivated fluorescent carbon quantum dots, which are explored as promising sensing probes, via facile one-pot hydrothermal methods.


2019 ◽  
Vol 11 (20) ◽  
pp. 2650-2657 ◽  
Author(s):  
Yifang Gao ◽  
Huilin Zhang ◽  
Shaomin Shuang ◽  
Hui Han ◽  
Chuan Dong

Novel nitrogen co-doped carbon dots (NCDs) were synthesized as a fluorescent “on–off–on” switch for the highly sensitive and selective sensing of Cu2+ and glutathione (GSH) by a straightforward pyrolysis route.


RSC Advances ◽  
2016 ◽  
Vol 6 (65) ◽  
pp. 59956-59960 ◽  
Author(s):  
Yalin Zhang ◽  
Lulu Hu ◽  
Yue Sun ◽  
Cheng Zhu ◽  
Rongsheng Li ◽  
...  

Chiral carbon quantum dots (l-carbon quantum dots, l-CQDs; and d-carbon quantum dots, d-CQDs) were synthesized through the facile hydrothermal treatment of carbonated citric acid and l-cysteine (or d-cysteine).


2019 ◽  
Vol 5 (2) ◽  
pp. 33 ◽  
Author(s):  
Fengming Lin ◽  
Yan-Wen Bao ◽  
Fu-Gen Wu

Carbon dots (or carbon quantum dots) are small (less than 10 nm) and luminescent carbon nanoparticles with some form of surface passivation. As an emerging class of nanomaterials, carbon dots have found wide applications in medicine, bioimaging, sensing, electronic devices, and catalysis. In this review, we focus on the recent advancements of carbon dots for sensing and killing microorganisms, including bacteria, fungi, and viruses. Synthesis, functionalization, and a toxicity profile of these carbon dots are presented. We also discuss the underlying mechanisms of carbon dot-based sensing and killing of microorganisms.


Nanomaterials ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 677 ◽  
Author(s):  
Chun-Chieh Fu ◽  
Chun-Yung Wu ◽  
Chih-Ching Chien ◽  
Tai-Hao Hsu ◽  
Shih-Fu Ou ◽  
...  

Photoluminescent nanomaterials have immense potential for use in biological systems due to their excellent fluorescent properties and small size. Traditional semiconductor quantum dots are heavy-metal-based and can be highly toxic to living organisms, besides their poor photostability and low biocompatibility. Nano-sized carbon quantum dots and their surface-modified counterparts have shown improved characteristics for imaging purposes. We used 1,3, 6-trinitropyrene (TNP) and polyethylene glycol6000 (PEG6000) in a hydrothermal method to prepare functional polyethylene glycol6000/carbon nanodots (PEG6000/CDs) and analyzed their potential in fluorescent staining of different types of bacteria. Our results demonstrated that PEG6000/CDs stained the cell pole and septa of gram-positive bacteria B. Subtilis and B. thuringiensis but not those of gram-negative bacteria. The optimal concentration of these composite nanodots was approximately 100 ppm and exposure times varied across different bacteria. The PEG6000/CD composite had better photostability and higher resistance to photobleaching than the commercially available FM4-64. They could emit two wavelengths (red and green) when exposed to two different wavelengths. Therefore, they may be applicable as bioimaging molecules. They can also be used for differentiating different types of bacteria owing to their ability to differentially stain gram-positive and gram-negative bacteria.


2019 ◽  
Vol 43 (14) ◽  
pp. 5488-5494 ◽  
Author(s):  
Xiaomin Luo ◽  
Pengxia Bai ◽  
Xuechuan Wang ◽  
Guohui Zhao ◽  
Jianyan Feng ◽  
...  

A facile synthetic method was used to prepare N-CQDs via the hydrothermal treatment of gelatin.


2019 ◽  
Vol 55 (30) ◽  
pp. 4419-4422 ◽  
Author(s):  
Haitao Li ◽  
Yadan Deng ◽  
Youdi Liu ◽  
Xin Zeng ◽  
Dianne Wiley ◽  
...  

We designed a photocatalyst of carbon dots and carbon layer double-protected Cu2O which exhibited excellent performance in CO2 conversion.


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