Study of Thermal Stress in Nano Silver Bonded Silicon Substrates for High Temperature Applications

2019 ◽  
Vol 2019 (HiTen) ◽  
pp. 000052-000055
Author(s):  
G.D. Liu ◽  
C.H. Wang

Abstract The silver nanoparticle paste is a promising material for high temperature die-attach applications. In this paper, the finite element method is used to study the relationship between the thickness of the sintered silver layer and the thermal stress in the sintered silver joint. Silicon chips are bonded together with sintered silver layers of different thicknesses. In the experimental study, strain gauges are attached onto the surface of the upper silicon and used to estimate the effects of the nano silver die-attach layer. The results show that the average stress in the silver layer at the interface decreases with the increasing thickness of the silver layer, while the stress on the silicon surface increases with the increasing thickness of the silver layer.

2015 ◽  
Vol 2015 (HiTEN) ◽  
pp. 000037-000049
Author(s):  
Paul Croteau ◽  
Sayan Seal ◽  
Ryan Witherell ◽  
Michael Glover ◽  
Shashank Krishnamurthy ◽  
...  

The emergence of wide band gap devices has pushed the boundaries of power converter operations and high power density applications. It is desirable to operate a power inverter at high switching frequencies to reduce passive filter weight and at high temperature to reduce the cooling system requirement. Therefore, materials and components that are reliable at temperatures ranging from −55 to 200 °C, or higher, are needed. Sintered silver is receiving significant attention in the power electronic industry. The porous nature of sintered nano-silver paste with a reduced elastic modulus has the potential to provide strain relief between the die component and substrate while maintaining its relatively high melting point after sintering. The test results presented herein include tensile testing to rupture of sintered silver film to characterize stress strain behavior, as well as die shear and thermal cyclic tests of sintered silver bonded silicon die specimens to copper substrates to determine shear strength and reliability.


Author(s):  
Fei Qin ◽  
Shuai Zhao ◽  
Yanwei Dai ◽  
Lingyun Liu ◽  
Tong An ◽  
...  

Abstract Thermo-mechanical reliability assessment for sintered silver is a crucial issue as sintered silver is a promising candidate of die-attachment materials for power devices. In this paper, the nano-indentation tests are performed for sintered silver in typical die-attach interconnection under different thermal cycles. Based on thermal cycling test, the Young's modulus and hardness of sintered silver layer have been presented. It is found that the Young's modulus and hardness of sintered silver layer changes slightly although the microstructure of sintered silver also presents some variations. The stress and strain curves for different thermal cycling tests for sintered silver based on reverse analysis of nano-indentation are also given. The results show that the elastoplastic constitutive equations change significantly after thermal cycling tests, and the yielding stress decreases remarkably after 70 thermal cycles. The experimental investigation also show that the cracking behaviors of sintered silver depends on its geometry characteristics, which implies that the possible optimization of sintered silver layer could enhance its thermo-mechanical performance.


2016 ◽  
Vol 13 (1) ◽  
pp. 6-16 ◽  
Author(s):  
Paul Croteau ◽  
Sayan Seal ◽  
Ryan Witherell ◽  
Michael Glover ◽  
Shashank Krishnamurthy ◽  
...  

The emergence of wide band gap devices has pushed the boundaries of power converter operations and high power density applications. It is desirable to operate a power inverter at high switching frequencies to reduce passive filter weight and at high temperature to reduce the cooling system requirement. Therefore, materials and components that are reliable at temperatures ranging from −55°C to 200°C, or higher, are needed. Sintered silver is receiving significant attention in the power electronic industry. The porous nature of sintered nanosilver paste with a reduced elastic modulus has the potential to provide strain relief between the die component and substrate while maintaining its relatively high melting point after sintering. The test results presented herein include tensile testing to rupture of sintered silver film to characterize stress-strain behavior, as well as die shear and thermal cyclic tests of sintered silver-bonded silicon die specimens to copper substrates to determine shear strength and reliability.


2016 ◽  
Vol 37 (9) ◽  
pp. 1159-1165
Author(s):  
陈佳 CHEN Jia ◽  
李欣 LI Xin ◽  
孔亚飞 KONG Ya-fei ◽  
梅云辉 MEI Yun-hui ◽  
陆国权 LU Guo-quan

2017 ◽  
Vol 2017 (HiTEN) ◽  
pp. 000168-000176 ◽  
Author(s):  
Khalid Khtatba ◽  
Seyed Amir Paknejad ◽  
Ali Mansourian ◽  
Samjid H. Mannan

Abstract: The surface oxidation of internal pore surfaces of nano-scale sintered silver has increased stability for high temperature applications. After treatment, high temperature storage at 400 °C has resulted in no changes to microstructure. By contrast, it is known that the microstructure of untreated pressure-less sintered silver continuously evolves at temperatures above 200 °C. Grain and pore growth occur in this temperature range for conventional sintered silver resulting in coarsening of the microstructure and increased susceptibility to fatigue. However, oxidation treatment of the internal pore surfaces has the effect of freezing the microstructure when the contact metallization is also silver or chemically inert. Oxidation prevents mass transfer by shutting down the fastest atomic migration route along the internal pore surfaces. Samples exhibited no change in microstructure either through continuous observation through glass, or after cross sectioning. The tested specimens under high temperature storage resisted grain growth for the whole duration of the tests of more than 600 h at 300 °C. The only detectable changes in microstructure occurred in a sparse number of isolated grains (1 in 7000 grains), presumably due to non-penetration of oxidising treatment into these closed pore spaces. It is hypothesized that even these can be prevented by minor changes to the sintering paste to slightly increase initial porosity. The oxidising treatment can be performed via many different routes, such as exposure to steam, or even by dipping in water for 10 min.


2018 ◽  
Vol 2018 (1) ◽  
pp. 000602-000605
Author(s):  
Tomofumi Watanabe ◽  
Keisuke Tanaka ◽  
Masafumi Takesue

Abstract Microstructural and mechanical properties of a pressureless sintered silver material were measured. The Microstructure of the pressureless sintered silver material had pores of less than 1 μm in size and some silver matrices sintered with nanoparticles between each other. The pressureless sintered silver material could be bonded on bare copper without applying an external pressure. After subjecting the material to a high temperature exposure test at 250 °C and for 1000 h, it showed no substantial change in microstructure and showed a constant Young's modulus of 14 GPa. The pressureless sintered silver material in this work did not show any embrittlement or increase in pore size after the high temperature exposure test, which demonstrated that the material has reliable physical and mechanical properties at temperatures up to 250 °C.


2018 ◽  
Vol 2018 (1) ◽  
pp. 000167-000172
Author(s):  
Guangyu Fan ◽  
Christine Labarbera ◽  
Ning-Cheng Lee ◽  
Colin Clark

Abstract Ag sintering has been paid attention as an alternative to soldering in die attach for decades, especially for high temperature power electronics packages because of its high melting temperature, highly thermal and electrical conductivity of the sintered silver joints, and low process temperature less than 275°C. The coefficient of thermal expansion (CTE) of silver (19.1ppm/°C), however, is much higher than the silicon die (2.6ppm/°C) and the commonly used alumina substrate (7.2ppm/°C). CTE mismatch of the different materials in the various components in a power electronics package lead to the delamination at the interface between interconnection layer and chips or substrate, and/or cracking of the interconnection layer is one of the mostly common causes of failure of power electronics device during thermal cycling or high temperature operation. In recent years we have been developing a series of silver sinter pastes containing low CTE non-metal particles to reduce or adjust CTE of the sintered joints so as to extend the lifetime and reliability of power electronics device in high temperature applications. In the present paper, we will report a new set of silver sinter pastes containing micro scale non-metal particles, a sintering process, microstructural morphologies, thermo-mechanical reliability of the sintered joint and effect of the contents of non-metal particles on shear strength of the sintered silver joints bonding an Ag silicon die on Ni/Au DBC substrates. Shear tests on the sintered joints with and/or without the low CTE non-metal additives have been conducted at room temperature, 200, 250, and 300°C. Thermo-mechanical reliability of the sintered joints was evaluated by thermal cycling, thermal shock, high temperature storage tests (HTS), respectively. X-ray inspection and scanning electronic microscopy (SEM) were used to characterize void, crack and microstructure morphologies of the sintered joints with and/or without the additives.


2016 ◽  
Vol 2016 (1) ◽  
pp. 000338-000344 ◽  
Author(s):  
Zhenzhen Shen ◽  
Aleksey Reiderman

Abstract Silver nano-particle (AgNP) sintering has been extensively shown to be an excellent bonding method for use in the assembly of high-temperature multi-chip modules (MCM) rated above 200° C. Among the proven advantages of using this material in the assembly are the high mechanical strength of the attachment joints, resilience to thermal cycles, low resistivity, and high thermal conductivity. One of the concerns related to the reliability of sintered silver joints is silver migration. Another concern is the change in the joint's microstructure under thermal stress. Vapor-deposited high-temperature fluorinated parylene coating (Paralyne HT) may have the potential to mitigate those concerns because of its superior conformal and crevice-penetration properties. In this work, impact of Parylene HT on sintered silver joints has been evaluated from the perspective of mechanical strength. Test vehicles were subjected to thermal cycling and high-temperature aging. To understand the sintered silver joint's failure mechanisms, shear test analysis of the cross sections and fracture surfaces was performed. In addition, the effectiveness of Parylene HT as a coating to inhibit silver migration at high humidity was evaluated. Coated and uncoated sintered silver test patterns were stressed with an electrical field inside a high-humidity chamber. The silver migration progression was monitored and compared between coated and uncoated samples during the test. One of the findings was that the coating material penetrates the pores of the sintered silver joints, altering their mechanical performance under thermal stress. Analysis of the performance differences between coated and uncoated test vehicles is presented in the paper.


2019 ◽  
Vol 141 (3) ◽  
Author(s):  
Mei-Chien Lu

Thermal interface materials (TIMs) are crucial elements for packaging of power electronics. In particular, development of high-temperature lead-free die-attach TIMs for silicon carbide wide bandgap power electronics is a challenge. Among major options, sintered silver shows advantages in ease of applications. Cost, performance, reliability, and integration are concerns for technology implementation. The current study first discusses issues and status reported in literatures. Then it focuses on cost reduction and performance improvement of sintered silver using enhancement structures at micro- and nano-scales. A few design architectures are analyzed by finite element methods. The feasibility of strengthening edges and corners is also assessed. The downside of potential increase of unfavorable stresses to accelerate void coalescence would be optimized in conjunction with design concept of power electronics package modules for paths of solutions in the form of integrated systems. Demands of developing new high-temperature packaging materials to enable optimized package designs are also highlighted.


2015 ◽  
Vol 2015 (1) ◽  
pp. 000842-000847
Author(s):  
Hiroaki Tatsumi ◽  
Sho Kumada ◽  
Atsushi Fukuda ◽  
Hiroshi Yamaguchi ◽  
Yoshihiro Kashiba

Sintered silver bonding processes are expected to offer bonding solutions with high heat resistances for power modules using wide-bandgap semiconductors. This study reports the die-attach reliability of such a bonding process under thermal cycling tests, focusing on the metallurgical and mechanical properties of sintered silver nanoparticles. A nanocrystalline structure with a grain size of approximately 150 nm was observed in the as-sintered state, while a coarsened structure with a grain size of several microns and pore coalescence was observed after annealing at 623 K for 1 h. In addition, the increase of bonding pressure reduced the number of coarse pores. Observations with a transmission electron microscope showed favorable crystalline structure along the grain boundaries. Tensile tests at room and high temperature revealed that the sintered silver nanoparticles showed the inherent mechanical properties of nanocrystalline metals. Thermal cycling tests of die-attached specimens demonstrated the temperature dependence of crack propagation caused by plastic deformation at a constant temperature amplitude. Furthermore, pore coalescence and coarsening reduced bonding reliability. It can be inferred from the results that nanocrystalline structure and minute pore dispersion improves bonding reliability.


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