On genesis of massive sulfide polymetallic ore deposits of Rudny Altai

2021 ◽  
pp. 3-16
Author(s):  
B. DIYACHKOV ◽  
M. MIZERNAYA ◽  
A. PYATKOVA ◽  
A. BISATOVA ◽  
A. MIROSHNIKOVA ◽  
...  

Many geologists assign most of large- and medium-sized massive sulfide polymetallic ore deposits of Eastern Kazakhstan to the VMS type. These ore deposits formed in the Devonian, under conditions of rifting and active basalt-andesite-rhyolite volcanism. Ore bodies of these deposits are noted to be clearly confined to formations of several geochronologic levels (D1e to D3fm). Hydrothermal-sedimentary syngenetic and hydrothermal-metasomatic ores are distinguished. High concentrations of base metals in the ores (above 10 % sum metals) and their rather simple mineral composition (chalcopyrite, pyrite, galena, and sphalerite) are a characteristic feature of all the massive sulfide polymetallic ore deposits of Rudny Altai. The ores are noted to be multicomponental, with elevated contents of the admixtures of precious metals and rare elements (Cd, Se, Bi, Te, Ta, W, etc.). Mineralogical investigations of the ores have demonstrated an intricate relationships of the major ore minerals (chalcopyrite, pyrite, sphalerite, galena) that exhibit several generations and different geochemical specialization. Minerals of Au, Ag, Te, Bi, and other elements are encountered as individual grains or microscopic inclusions and stringers in minerals of Cu, Pb, and Zn. A significant vertical range of the ore mineralization (more than 100 m), the complexity and long duration of the ore-forming processes, the clearly defined confinement of the ore mineralization to certain geochronologic levels, – all these allow us to suppose a possibility of discovery of new ore lodes or individual ore deposits within the already known ore fields of the Kazakhstan segment of Rudny Altai

Minerals ◽  
2019 ◽  
Vol 9 (11) ◽  
pp. 657 ◽  
Author(s):  
Nan Ju ◽  
Sen Zhang ◽  
Lin-Lin Kou ◽  
Hai-Po Wang ◽  
Di Zhang ◽  
...  

The Shulan area in Jilin Province is a part of the Lesser Xing’an–Zhangguangcai Range polymetallic ore belt, which is an important Cu–Mo ore region of northeast China. The discovery of three large Mo ore deposits (Fu’anbu, Chang’anbu, and Jidetun) highlights its potential for porphyry Mo ore deposits. Here we investigated the tectonic setting and mineralization of Mo ore deposits in the Shulan area, based on comparative study of the Fu’anbu, Chang’anbu, and Jidetun deposits. The ore-controlling structures are NE–SW- and NW–SE-trending faults. The main ore mineral in all three deposits is molybdenite. The ore bodies are all hosted in granites, have a stratiform or lenticular shape, and have strongly altered wall rocks. These observations indicate the Mo deposits in the Shulan area are typical porphyry Mo deposits. All were formed during the early Yanshanian (199.6–133.9 Ma). Biotite adamellites from the Chang’anbu deposit yield a U–Pb age of 182.10 ± 1.20 Ma. Molybdenites from the Fu’anbu and Jidetun deposits have Re–Os isochron ages of 166.9 ± 6.7 and 169.1 ± 1.8 Ma, respectively. Quartz and ore minerals were analysed for H–O and S–Pb isotopes, respectively. The results suggest the ore-forming materials were predominantly of upper-mantle origin, with secondary contributions from the lower crust. The ore-hosting granites have high concentrations of SiO2 (66.67–75.43 wt.%) and Al2O3 (12.91–16.44 wt.%), low concentrations of MgO (0.09–1.54 wt.%), and Ritman index (σ = K2O + Na2O)2/(SiO2 − 43)) ratios of 2.09–2.57. The granites are enriched in large-ion lithophile elements and depleted in high-field-strength elements, and have negative Eu anomalies. The ore-hosting rocks are geochemically similar to granites in northeastern China that were generated in a collisional orogeny. We conclude that early Yanshanian (199.6–133.9 Ma) mantle–crust-derived magmatism caused by the subduction of the Palaeo-Pacific Plate was the main source of Mo deposits in the Shulan area.


2018 ◽  
Vol 82 (S1) ◽  
pp. S5-S41 ◽  
Author(s):  
J. R. S. Carvalho ◽  
J. M. R. S. Relvas ◽  
A. M. M. Pinto ◽  
M. Frenzel ◽  
J. Krause ◽  
...  

ABSTRACTHigh concentrations of indium (In) and selenium (Se) have been reported in the Neves-Corvo volcanic-hosted massive sulfide deposit, Portugal. The distribution of these ore metals in the deposit is complex as a result of the combined effects of early ore-forming processes and late tectonometamorphic remobilization. The In and Se contents are higher in Cu-rich ore types, and lower in Zn-rich ore types. At the deposit scale, both In and Se correlate positively with Cu, whereas their correlations with Zn are close to zero. This argues for a genetic connection between Cu, In and Se in terms of metal sourcing and precipitation. However, re-distribution and re-concentration of In and Se associated with tectonometamorphic deformation are also processes of major importance for the actual distribution of these metals throughout the whole deposit. Although minor roquesite and other In-bearing phases were recognized, it is clear that most In within the deposit is found incorporated within sphalerite and chalcopyrite. When chalcopyrite and sphalerite coexist, the In content in sphalerite (avg. 1400 ppm) is, on average, 2–3 times higher than in chalcopyrite (avg. 660 ppm). The In content in stannite (avg. 1.3 wt.%) is even higher than in sphalerite, but the overall abundance of stannite is subordinate to either sphalerite or chalcopyrite. Selenium is dispersed widely between many different ore minerals, but galena is the main Se-carrier. On average, the Se content in galena is ~50 times greater than in either chalcopyrite (avg. 610 ppm) or sphalerite (avg. 590 ppm). The copper concentrate produced at Neves-Corvo contains very significant In (+Se) content, well above economic values if the copper smelters recovered it. Moreover, the high In content of sphalerite from some Cu-Zn ores, or associated with shear structures, could possibly justify, in the future, a selective exploitation strategy for the production of an In-rich zinc concentrate.


2021 ◽  
Vol 29 (1) ◽  
pp. 90-107
Author(s):  
Zdeněk Dolníček ◽  
Jana Ulmanová ◽  
Karel Malý ◽  
Jaroslav Havlíček ◽  
Jiří Sejkora

In the Pohled quarry near Havlíčkův Brod town (central part of Czech Republic), texturally and mineralogically simple contaminated anatectic pegmatites form dikes or irregular bodies cementing breccia of host metamorphic rocks (paragneisses, amphibolites) belonging to the Monotonous (Ostrong) Group of the Moldanubicum of the Bohemian Massif. They exhibit signs of intense hydrothermal overprint and also the presence of abundant disseminations, nests and veinlets of ore minerals. A detailed mineralogical study revealed the presence of an extraordinary rich ore assemblage (20 species in total, including one unnamed phase). The oldest minerals are sphalerite (rich in Fe), löllingite, Fe-Co-Ni sulphoarsenides (cobaltite, glaucodot, arsenopyrite, gersdorffite), pyrrhotite, galena and chalcopyrite, in later portion accompanied by inclusions of Bi-minerals (native bismuth, bismuthinite, joséite-A, joséite-B, ikunolite and a Pb-Bi sulphosalt). The composition of the Pb-Bi sulphosalt is equal to Ag,Fe-substituted eclarite; its identity was confirmed also by Raman spectrum. Pyrite is very abundant phase, present probably in several generations. The Fe-Co-Ni thiospinels disseminated in younger chlorite, and represented by siegenite, violarite, grimmite and an unnamed NiFe2S4 phase, are the youngest ore minerals. The mineral association as well as chemical composition of most ore minerals are well comparable to those of local polymetallic ore veins and Alpine-type veins, which give evidence for identical origin of all these ore mineralizations. The formation of pegmatite-hosted ore assemblage was long-lasting multiphase process, which took place at temperatures between ca. 350 and <120 °C during changing fugacities of sulphur, tellurium and oxygen. A distinct enrichment in cobalt and nickel of ore mineralization hosted by pegmatites (in comparison with hydrothermal veins) is explained in terms of pronounced interactions of fluids with amphibolites and serpentinites.


2021 ◽  
pp. 36-47
Author(s):  
Tatyana SERAVINA ◽  
Svetlana KUZNETSOVA ◽  
Ludmila FILATOVA

The article describes composition of the host rocks and ores of the Lazursky and Maslyansky polymetallic volcanogenic massive sulfide deposits of the Lazursky ore field located within the Zmeinogorsk ore region of the Rudny Altai minerogenic zone. The ore field is composed of various facies of the Devonian (Late Givetian – Frasnian) ore-bearing siliceous-terrigenous basalt-rhyolite formation containing horizons of synvolcanic metasomatites. All rocks of the ore field were subjected to folding and schistosity with zones of tectonic brecciation. Hydrothermal alterations are represented by carbonatization and chloritization. The ore bodies exposed at the Lazursky and Maslyansky ore deposits are represented by copper-pyrite, copper, and zinc-copper-pyrite massive sulfide ores and other varieties. The major ore minerals of the deposits are chalcopyrite, pyrite, sphalerite, marcasite, and pyrrhotite.


Mineralogia ◽  
2012 ◽  
Vol 43 (3-4) ◽  
pp. 155-178 ◽  
Author(s):  
Ksenia Mochnacka ◽  
Teresa Oberc-Dziedzic ◽  
Wojciech Mayer ◽  
Adam Pieczka

AbstractThe Miedzianka mining district has been known for ages as a site of polymetallic ore deposits with copper and, later, uranium as the main commodities. Although recently uneconomic and hardly accessible, the Miedzianka ores attract Earth scientists due to the interesting and still controversial details of their ore structure, mineralogy and origin. Our examination of the ore mineralization from the Miedzianka district was based exclusively on samples collected from old mining dumps located in the vicinity of Miedzianka and Ciechanowice, and on samples from the only available outcrop in Przybkowice. In samples from the Miedzianka field, chalcopyrite, pyrite, galena, bornite, chalcocite, digenite, arsenopyrite, magnetite, sphalerite, tetrahedrite-tennantite, bornite, hematite, martite, pyrrhotite, ilmenite, cassiterite and covellite are hosted in quartz-mica schists and in coarse-grained quartz with chlorite. In the Ciechanowice field, the ore mineralization occurs mainly in strongly chloritized amphibolites occasionally intergrown with quartz and, rarely, with carbonates. Other host-rocks are quartz-chlorite schist and quartzites. Microscopic examination revealed the presence of chalcopyrite, pyrite, sphalerite, galena, tetrahedrite-tennantite, bismuthinite, native Bi, arsenopyrite, löllingite, cassiterite, cobaltite, gersdorffite, chalcocite, cassiterite, bornite, covellite, marcasite and pyrrhotite. Moreover, mawsonite and wittichenite were identified for the first time in the district. In barite veins cross-cutting the greenstones and greenschists in Przybkowice, we found previously-known chalcopyrite, chalcocite and galena. The composition of the hydrothermal fluids is suggested to evolved through a series of consecutive systems characterized, in turn, by Ti-Fe-Sn, Fe- As-S, Fe-Co-As-S, Cu-Zn-S and, finally, Cu-Pb-Sb-As-Bi compositions.


2017 ◽  
Vol 743 ◽  
pp. 417-421 ◽  
Author(s):  
Vasilii Ivanovich Leontev ◽  
Yackov Yur’evich Bushuev

The Podgolechnoe deposit, which belongs to the alkalic-type (A-type) epithermal gold-ore deposits, lies in the Central Aldan ore district (Russia). Gold-ore mineralization is associated with a volcano-plutonic complex made of rocks of the monzonite-syenite formation (J3–K1). The ore bodies are localized in the crushing zones developed after crystalline schists, gneisses, and granites of the crystalline basement complexes (Ar–Pr). Metasomatic alterations in host rocks have potassic specialization. Vein ore minerals are adular, fluorite, roscoelite, sericite, and carbonate. Ore minerals are pyrite, galena, sphalerite, cinnabar, brannerite, monazite, bismuth telluride, stutzite, hessite, petzite, montbraite, and native gold. The deposit has been explored as a gold-ore deposit, however, due to complex composition of ores there is a need to reveal the possibilities of the integrated development of this deposit. This could provide for a reserve increment and an increase in the gross recoverable value of ores due to the extraction of associated components.


2021 ◽  
Vol 82 (3) ◽  
pp. 147-149
Author(s):  
Ralica Sabeva

The Pishtene ore occurrence is situated north-northeast from the Pishtene paleovolcanic center in the western part of the Srednogorie zone. The occurrence is hosted by altered basaltic trachyandesites. The styles of alteration are advance argillic, argillic, sericitic and propylitic. Ore mineralization is in quartz-sericite zone and is represented by quartz-pyrite and quartz-polymetallic. The ore minerals are pyrite, chalcopyrite and sphalerite. Pyrite from quartz-polymetallic stage is with high concentrations of Cu, Se and Co. Au with low contents is also detected.


KURVATEK ◽  
2019 ◽  
Vol 4 (1) ◽  
pp. 25-33
Author(s):  
Fatimah Fatimah

Tulakan Subdistrict, Pacitan Regency, East Java Province. This area is part of the Southern Mountain Zone of East Java, which is the Sunda-Banda magmatic arc of Oligo-Miocene age, where there are alterations and indications of valuable ore minerals. Field magnetic data is taken in an area of 1 x 1 km, with the looping method on the grid trajectory within 200 x 100 m. Then, magnetic data correction and data processing were carried out with Oasis Montaj. From the magnetic anomaly map, the value of high magnetic intensity in the southern part is fresh (intrusive) andesit-dasitic rock as host rock which causes alteration, in the middle has a low magnetic intensity value which is in the direction of the relatively NE-SW river direction, whereas in the north with high intensity is fresh andesite lava. From the image data, it can be seen that the straightness pattern of the geological structure which is dominated by the extensional structure with the direction of NE-SW and E-W is the main trap of epithermal veins carrying ore mineralization mainly Cu, Pb in the study area.


Author(s):  
O. Hrinchenko ◽  
S. Bondarenko ◽  
T. Mironchuk

Composition of granites, genetically associated pegmatites and superimposed metasomatites distributed within Shpoliano-Tashlyk ore area (Ingul megablock) is considered. It is established, that on the basis of similarity in their petrographic and petrochemical features granitoids of the area can be related to single complex. Features of ore mineralization are defined by both composition of granitoids (Sgranites) after which rare-metal pegmatites are formed and intensity of superimposed metasomatic alterations. Main minerals-concentrators of Ta and Nb mineralization in granitic pegmatites and metasomatites are represented by minerals of three isomorphic series – columbite-tantalite (Fe,Mn)(Nb,Ta,Ti)2O6, ilmenorutile-struverite (Ti,Nb,Ta)O2 and pyrochlore-microlite (Ca,Na)2Ta2O6(O,B,OH,F). Depending on geological setting such ore minerals as tapiolite, ixiolite, cassiterite, uraninite, nigerite, gahnite are commonly found in association with these minerals. Chemical composion of tantalo-niobates sampled from ore-bearing pegmatites and metasomatites is investigated by microprobe analysis. Most minerals of columbite-tantalite series are characterized by distinct and rhythmic internal zonality and contrasting mosaic structure which are related to considerable heterogeneities of their chemical composition. Within one aggregate mineral phases with wide range of values – from 9,80 to 71,0 % for Ta2O5 and from 10,6 to 70,1 % for Nb2O5 – are established. Among minerals ferruginous varieties which composition relates to Fe-columbite-tantalites (Nb2O5/Ta2O5 = 1–1,2; FeO/MnO = 2,5–6) prevail. Columbite-tantalites are characterised by high contents of admixture elements present (%): TiO2 – to 5,88; WO3 – to 3,70; SnO2 – to 9,20; Sc2O3 – to 5,40. Scandium ores occur as scandium-rich minerals that are mostly confined to the minerals of columbite-tantalite series found in Polohivka ore field. On the Ukrainian Shield high contents of Sc2O3 in tantalo-niobates are established for the first time. Minerals of ilmenorutile-struverite series do not quantitatively yield to minerals of columbite-tantalite series. For minerals of this series Nb2O5/Ta2O5 ratio varies in the range of 0,6-1,4. Among characteristic admixture-elements are prevailed (%): SnO2 – to 3,1, V2O5 – to 5,05; FeO – to 11,51, Cr2O3 – to 1,20. Minerals of pyrochlore-microlite series are of subordinate importance. For the first time by results of U-Pb dating of columbite-tantalites from Mostove ore manifestation (Shpoliano-Tashlyk area) the age of Ta-Nb mineralization is established to be about 1965 ± 25 million years.


2019 ◽  
Vol 55 (3) ◽  
pp. 343-349
Author(s):  
U. Erdenebold ◽  
C.-M. Sung ◽  
J.-P. Wang

Gold flotation concentrate may contain relatively high concentrations of valuable metals such as iron, copper, and zinc, and occasionally, even precious metals such as gold. The major components of the concentrate are SiO2, Fe2O3, and Al2O3, but it also contains reactive sulphide minerals such as pyrite. The sulphides in the flotation concentrate are fully converted into an oxide form during oxidative roasting, therefore, the chemical composition of the roasted concentrate is considered to be a copper slag. High temperature smelting with additives to dissolve Au from the gold concentrate into a molten copper was used in the research. Gold greatly dissolved at 1600?? under a CaO/SiO2 ratio of 1.25, suggesting the increase in the dissolution of gold into molten copper with decreasing viscosity of the molten slag-like concentrate at high temperatures.


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