Effect of Uniaxial Tension-Induced Plastic Strain on the Microstructure and Corrosion Behavior of 13Cr Martensitic Stainless Steel

CORROSION ◽  
10.5006/3516 ◽  
2020 ◽  
Vol 76 (12) ◽  
Author(s):  
Salar Salahi ◽  
Mostafa Kazemipour ◽  
Ali Nasiri
Keyword(s):  
Stainless Steel ◽  
Plastic Strain ◽  
Corrosion Behavior ◽  
Chromium Carbide ◽  
Martensitic Stainless Steel ◽  
Electrochemical Impedance ◽  
Passive Layer ◽  
High Concentration ◽  
Pitting Potential ◽  
Heat Treated Sample

This study aims to understand the correlation between the manufacturing process-induced plastic deformation, microstructure, and corrosion behavior of a 13Cr martensitic stainless steel tubing material (UNS S42000). Comparisons were made between the microstructure, crystallographic orientation, and corrosion performance of a texture-free, heat-treated sample and uniaxially tensioned samples to the elongations of 5% and 22%. Cyclic potentiodynamic polarization tests and electrochemical impedance spectroscopy were performed on all samples in aerated 3.5 wt% NaCl electrolyte at room temperature. Overall, the corrosion resistance of the samples was found to decrease with increasing deformation level. A more stable and higher corrosion potential and pitting potential values with a better stability of the passive film were derived for the nondeformed sample, whereas the 5% and 22% elongated samples exhibited lower corrosion and pitting potential values and were characterized by having a less stable passive layer. All samples consistently revealed micropit formation on the lath boundaries where a high concentration of chromium carbide precipitates was detected. Increasing the level of plastic strain in 13Cr stainless steel was found to enlarge the size of sensitized regions along the matrix/coarse chromium carbide precipitates interface, leading to more regions susceptible to initiation and propagation of pitting.

Electrochemical Properties of Passive Film Formed on Supermartensitic Stainless Steel in a Chloride Medium

CORROSION ◽  
10.5006/3230 ◽  
2020 ◽  
Vol 76 (9) ◽  
pp. 884-890
Author(s):  
Renata B. Soares ◽  
Wagner R.C. Campos ◽  
Pedro L. Gastelois ◽  
Waldemar A.A. Macedo ◽  
Luís F.P. Dick ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Stainless Steel ◽  
Passive Film ◽  
Electrochemical Behavior ◽  
Photoelectron Spectroscopy ◽  
Oil And Gas ◽  
Electrochemical Impedance ◽  
Passive Layer ◽  
Open Circuit ◽  
Pitting Potential

The electrochemical behavior and the electronic properties of passive films formed on a super martensitic stainless steel (SMSS) used in oil and gas industries were investigated in aqueous 0.6 M and 2.1 M NaCl solutions with additions of sodium acetate and acetic acid (pH 4.5). Open-circuit potential transients, electrochemical impedance spectroscopy, cyclic voltammetry, and x-ray photoelectron spectroscopy were measured to characterize the passive film formed on SMSS. The electrochemical behavior of the steel in an aqueous solution of 0.6 M NaCl presented the highest pitting potential and the highest polarization resistance in relation to the NaCl/NaAc solution. The passive film of SMSS in an aqueous solution of NaCl presented a thickness of 18.40 nm, three times the thickness of the oxide film in NaCl/NaAc, and consisted of FeO, Cr2O3, MoO2, and spinels such as FeCr2O4 species that are a p-type semiconductor, but may also contain a small fraction of the Fe2O3 and MoO3 oxides. Additionally, it was shown that the passive layer after immersion in a saline solution also contains hydroxides such as FeOOH and Cr(OH)3.

Effect of Cl- Content, pH Value and CO2 on Electrochemical Corrosion Features of Cr15 Super Martensitic Stainless Steel

2013 ◽  
Vol 738 ◽  
pp. 92-96
Author(s):  
Jin Ming Long ◽  
Quan Bin Liu ◽  
Kun Yu Zhao ◽  
Qi Long Yong ◽  
Jie Su
Keyword(s):  
Stainless Steel ◽  
Martensitic Stainless Steel ◽  
Electrochemical Impedance ◽  
Ph Value ◽  
Charge Transfer Resistance ◽  
Uniform Corrosion ◽  
Nacl Solution ◽  
Transfer Resistance ◽  
Pitting Potential ◽  
Super Martensitic Stainless Steel

The corrosion behavior of a Cr15 super martensitic stainless steel (Cr15 SMSS) was investigated in NaCl solutions by means of potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). Effects of Cl-content, pH value and saturated CO2on corrosion were sdudied. It was found that the parameters of maintaining passivity current density (ip), the critical pitting potential (Eb) and charge transfer resistance (Rt) of Cr15 SMSS varied widely under different conditions. The corrosion resistance of Cr15 SMSS decrease with increasing Cl-concentration and lowering pH value. BothipandEbincrease for Cr15 SMSS in CO2-saturated NaCl solution, which verified that the CO2in NaCl solution can result in lower pitting sensitivity and higher uniform corrosion rate to Cr15 SMSS.

CTS-BD30P ALLOY

Alloy Digest ◽  
2013 ◽  
Vol 62 (8) ◽  
Keyword(s):  
Stainless Steel ◽  
Wear Resistance ◽  
Corrosion Resistance ◽  
Physical Properties ◽  
Martensitic Stainless Steel ◽  
Heat Treating ◽  
Powder Metal ◽  
High Concentration ◽  
Vanadium Carbides

Abstract Carpenter CTS-BD30P alloy is a powder metal processed, air-hardening, martensitic stainless steel that offers corrosion resistance comparable with Type 440C stainless, combined with excellent toughness and wear resistance attributed to a high concentration of vanadium carbides. The Carpenter CTS family of alloys is used for many blade applications. This datasheet provides information on composition and physical properties. It also includes information on corrosion resistance as well as heat treating and powder metal forms. Filing Code: SS-1154. Producer or source: Carpenter Specialty Alloys.

Corrosion behavior of a new 25Cr-3Ni-7Mn-0.66 N duplex stainless steel in artificial seawater

2021 ◽  
Vol 63 (6) ◽  
pp. 505-511
Author(s):  
Songkran Vongsilathai ◽  
Anchaleeporn Waritswat Lothongkum ◽  
Gobboon Lothongkum
Keyword(s):  
Stainless Steel ◽  
Duplex Stainless Steel ◽  
Passive Film ◽  
Corrosion Behavior ◽  
Electrochemical Impedance ◽  
Melting Furnace ◽  
Artificial Seawater ◽  
Vacuum Arc ◽  
Significant Difference ◽  
Type Semiconductor

Abstract A new duplex 25Cr-3Ni-7Mn-0.66 N alloy was prepared in a vacuum arc re-melting furnace and characterized by metallographic and EPMA methods. Its corrosion behavior was investigated by potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and a Mott-Schottky (M-S) analysis in artificial seawater at room temperature and compared with those of super and normal commercial duplex stainless steel (SDSS and DSS). No significant difference in the open circuit potentials and pitting potentials was observed. Its passive film current density lies between those of SDSS and DSS. This was confirmed by EIS analysis. A pit attack was observed on the δ-phase for all duplex samples, because the PREN16 of the δ-phase was lower than that of the γ-phase. From the Mott-Schottky analysis, the passive films were found to be composed of bi-layer structures, a p-type semiconductor inner layer, and a n-type semiconductor outer layer. The degree of defect as well as the effect of nitrogen in passive film layer are discussed with respect to the point defect model.

Evaluation of the corrosion behavior of AZ31 magnesium alloy with different protein concentrations

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Yucong Ma ◽  
Mohd Talha ◽  
Qi Wang ◽  
Zhonghui Li ◽  
Yuanhua Lin
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Behavior ◽  
Electrochemical Impedance ◽  
Surface Film ◽  
Energy Dispersive Spectrometer ◽  
Inhibitory Effect ◽  
Corrosion Process ◽  
High Concentration ◽  
Content Type ◽  
Atomic Force

Purpose The purpose of this paper is to study systematically the corrosion behavior of AZ31 magnesium (Mg) alloy with different concentrations of bovine serum albumin (BSA) (0, 0.5, 1.0, 1.5, 2.0 and 5.0 g/L). Design/methodology/approach Electrochemical impedance spectroscopy and potential dynamic polarization tests were performed to obtain corrosion parameters. Scanning electrochemical microscopy (SECM) was used to analyze the local electrochemical activity of the surface film. Atomic force microscope (AFM), Scanning electron microscope-Energy dispersive spectrometer and Fourier transform infrared spectroscopy were used to determine the surface morphology and chemical composition of the surface film. Findings Experimental results showed the presence of BSA in a certain concentration range (0 to 2.0 g/L) has a greater inhibitory effect on the corrosion of AZ31, however, the presence of high-concentration BSA (5.0 g/L) would sharply reduce the corrosion resistance. Originality/value When the concentration of BSA is less than 2.0 g/L, the corrosion resistance of AZ31 enhances with the concentration. The adsorption BSA layer will come into being a physical barrier to inhibit the corrosion process. However, high-concentration BSA (5.0 g/L) will chelate with dissolved metal ions (such as Mg and Ni) to form soluble complexes, which increases the roughness of the surface and accelerates the corrosion process.

scholarly journals Erosion-Corrosion Protection Due to Cr3C2-NiCr Cermet Coating on Stainless Steel

Coatings ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 1042
Author(s):  
Panneer Selvam Kevin ◽  
Abhishek Tiwari ◽  
Saravanan Seman ◽  
Syed Ali Beer Mohamed ◽  
Rengaswamy Jayaganthan
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
Corrosion Behavior ◽  
Potentiodynamic Polarization ◽  
Electrochemical Impedance ◽  
Turbine Blades ◽  
Continuous Exposure ◽  
Hydro Power ◽  
Cermet Coating ◽  
Erosion Corrosion

Cr3C2–NiCr coatings have been used extensively to combat the erosion corrosion of hydro power turbine blades made of stainless steel. Cr3C2–NiCr coatings are also used in aqueous corrosive environments due to the high corrosion resistance rendered by the NiCr binder. In this investigation, both erosion and corrosion environments are introduced to cermet coating to study corrosion behavior using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques. The cermet coatings are useful for reducing the risk of deterioration of mechanical properties of hydro power turbines due to the continuous exposure to the erosive and corrosive action of the corrosive environment containing silt. It was observed that Cr3C2–NiCr coating offered a reasonable improvement in corrosion resistance when compared to bare substrate. The corrosion behavior of the coating was studied in a 150 mL solution of 0.1 M NaCl with 2 gms of quartz particles (0.2–0.8 mm) at various rotation speeds (3000, 4500, 6000 rpm) of the solution over a 1 h immersion using potentiodynamic polarization and EIS studies in a specifically designed experimental set-up for erosion corrosion. When compared to the bare stainless steel samples at 3000 rpm and 6000 rpm, the coating showed the highest improvement at 6.57 times and the least improvement at 3.79 times, respectively.

scholarly journals Effect of Rare Earth Oxides on Microstructure and Corrosion Behavior of Laser-Cladding Coating on 316L Stainless Steel

Coatings ◽  
2019 ◽  
Vol 9 (10) ◽  
pp. 636 ◽  
Author(s):  
Xu ◽  
Wang ◽  
Chen ◽  
Qiao ◽  
Zhang ◽  
...  
Keyword(s):  
Stainless Steel ◽  
Rare Earth ◽  
Corrosion Behavior ◽  
Laser Cladding ◽  
316L Stainless Steel ◽  
Electrochemical Impedance ◽  
Salt Spray ◽  
Rare Earth Oxides ◽  
X Ray Diffraction ◽  
X Ray

The effect of rare earth oxides on the microstructure and corrosion behavior of laser-cladding coating on 316L stainless steel was investigated using hardness measurements, a polarization curve, electrochemical impedance spectroscopy (EIS), a salt spray test, X-ray diffraction, optical microscopy, and scanning electron microscopy (SEM). The results showed that the modification of rare earth oxides on the laser-cladding layer caused minor changes to its composition but refined the grains, leading to an increase in hardness. Electrochemical and salt spray studies indicated that the corrosion resistance of the 316L stainless steel could be improved by laser cladding, especially when rare earth oxides (i.e., CeO2 and La2O3) were added as a modifier.

Influence of Electromagnetic Treatment on Corrosion Behavior of Carbon Steel and 316L Stainless Steel in Simulated Cooling Water

2011 ◽  
Vol 347-353 ◽  
pp. 3135-3138
Author(s):  
Hong Hua Ge ◽  
Jie Ting Tao ◽  
Xiao Ming Gong ◽  
Cheng Jun Wei ◽  
Xue Min Xu
Keyword(s):  
Stainless Steel ◽  
Carbon Steel ◽  
Corrosion Behavior ◽  
316L Stainless Steel ◽  
Cooling Water ◽  
Stainless Steel Electrode ◽  
Transfer Resistance ◽  
Steel Electrode ◽  
Pitting Potential ◽  
Electromagnetic Treatment

Abstract: The effect of electromagnetic treatment on corrosion behavior of carbon steel and stainless steel in simulated cooling water was investigated by electrochemical impedance spectroscopy, potentiodynamic polarization techniques and water analysis. It was found that the charge transfer resistance decreased and the corrosion current density increased after electromagnetic treatment for carbon steel electrode, which shows that such treatment promotes corrosion of carbon steel in simulated cooling water. In contrast, the pitting potential of 316L stainless steel electrode rose which revealed that electromagnetic treatment of the experimental water exhibited corrosion inhibition to 316L stainless steel. Reasons for different corrosion behavior of the two metals were discussed.

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