Role of structural inheritances in the development of the Mountain Front Flexure in the Lurestan region of the Zagros belt

Author(s):  
Stefano Tavani ◽  
Giovanni Camanni ◽  
Michele Nappo ◽  
Marco Snidero ◽  
Alessandra Ascione ◽  
...  

<p>The Mountain Front Flexure is a major structure of the Zagros orogenic system, and is underlain by the deeply rooted and seismically active Mountain Front Fault system. These coupled structural features divide the belt from its foreland and their trace is sinuous, forming salients and recesses. The origin and tectonic significance of the Mountain Front Fault system and its sinuosity are still unclear, with most of hypotheses pointing to a strong structural control exerted by geological inheritances. In this work we combine interpretation of seismic reflection profiles, earthquake data, geomorphic analysis, and geological observations, to build a balanced cross section across the Mountain Front Flexure in the Lurestan region. Our data are suggestive of a hybrid tectonic style for the Lurestan region, characterised by a major and newly developed crustal ramp in the frontal portion of the belt (i.e the Mountain Front Fault) and by the reactivation of steeply dipping pre-existing basin-bounding faults, along with a minor amount of shortening, in the inner area. Specifically, the integration of our results with previous knowledge indicates that the Mountain Front Fault system developed in the necking domain of the Jurassic rift system, ahead of an array of inverted Jurassic extensional faults, in a structural fashion which resembles that of a crustal-scale footwall shortcut. Within this structural context, the sinusoidal shape of the Mountain Front Flexure in the Lurestan area arises from the re-use of the original segmentation of the inverted Jurassic rift system.</p>

2018 ◽  
Author(s):  
Stefano Tavani ◽  
Mariano Parente ◽  
Francesco Puzone ◽  
Amerigo Corradetti ◽  
Gholamreza Gharabeigli ◽  
...  

Abstract. The 2017 Mw Iran-Iraq earthquake occurred in a region where the pattern of major plate convergence is well constrained, but limited information is available on the seismogenic structures. Geological observations, interpretation of seismic reflection profiles, and well data are used in this paper to build a regional balanced cross-section that provides a comprehensive picture of the geometry and dimensional parameters of active faults in the hypocentral area. Our results indicate: (i) coexistence of thin- and thick-skinned thrusting, (ii) reactivation of inherited structures, and (iii) occurrence of weak units promoting heterogeneous deformation within the Paleo-Cenozoic sedimentary cover and partial decoupling from the underlying basement. According to our study, the main shock of the November 2017 seismic sequence is located within the basement, along the low-angle Mountain Front Fault. Aftershocks unzipped the up-dip portion of the same fault. This merges with a detachment level located at the base of the Paleozoic succession, to form a crustal-scale fault-bend anticline. Size and geometry of the Mountain Front Fault are consistent with a down-dip rupture width of 30 km, which is required for an Mw 7.3 earthquake.


Solid Earth ◽  
2018 ◽  
Vol 9 (3) ◽  
pp. 821-831 ◽  
Author(s):  
Stefano Tavani ◽  
Mariano Parente ◽  
Francesco Puzone ◽  
Amerigo Corradetti ◽  
Gholamreza Gharabeigli ◽  
...  

Abstract. The 2017 Mw 7.3 Iran–Iraq earthquake occurred in a region where the pattern of major plate convergence is well constrained, but limited information is available on the seismogenic structures. Geological observations, interpretation of seismic reflection profiles, and well data are used in this paper to build a regional, balanced cross section that provides a comprehensive picture of the geometry and dimensional parameters of active faults in the hypocentral area. Our results indicate (i) the coexistence of thin- and thick-skinned thrusting, (ii) the reactivation of inherited structures, and (iii) the occurrence of weak units promoting heterogeneous deformation within the palaeo-Cenozoic sedimentary cover and partial decoupling from the underlying basement. According to our study, the main shock of the November 2017 seismic sequence is located within the basement, along the low-angle Mountain Front Fault. Aftershocks unzipped the up-dip portion of the same fault. This merges with a detachment level located at the base of the Paleozoic succession, to form a crustal-scale fault-bend anticline. Size and geometry of the Mountain Front Fault are consistent with a down-dip rupture width of 30 km, which is required for an Mw 7.3 earthquake.


Author(s):  
Nadine S. Rögner ◽  
Veronika Mall ◽  
Martin Steinhaus

AbstractAn odorant screening by gas chromatography–olfactometry (GC–O) and a crude aroma extract dilution analysis (AEDA) applied to the volatiles isolated from a light and a dark liquid malt extract (LME) by solvent extraction and solvent-assisted flavour evaporation (SAFE) identified 28 odorants. Fifteen major odorants were subsequently quantitated and odour activity values (OAVs) were calculated as ratio of the concentration to the respective odour threshold value (OTV). Important odorants in the light LME included 3-(methylsulfanyl)propanal (OAV 1500), (E)-β-damascenone (OAV 430), and 4-ethenyl-2-methoxyphenol (OAV 91). In the dark LME, sotolon (OAV 780), 3-(methylsulfanyl)propanal (OAV 550), (E)-β-damascenone (OAV 410), acetic acid (OAV 160), and maltol (OAV 120) were of particular importance. To get an insight into the changes during malt extract production, the quantitations were extended to the malt used as the starting material for both LMEs. Addition of a minor amount of water to malt before volatile extraction was shown to be effective to cover the free as well as the bound malt odorants. Results showed that some LME odorants originated from the starting material whereas others were formed during processing. Important process-induced LME odorants included (E)-β-damascenone and 4-ethenyl-2-methoxyphenol in the light LME as well as maltol, sotolon, (E)-β-damascenone, and 2-methoxyphenol in the dark LME. In summary, the odorant formation during LME production was shown to be more important than the transfer of odorants from the malt.


1975 ◽  
Vol 55 (2) ◽  
pp. 225-233 ◽  
Author(s):  
H. KODAMA ◽  
M. D. WEBBER

Two specimens of hydroxy aluminum phosphate interlayer materials in montmorillonite clay were prepared with 7.20 meq Al and 11.29 meq H3PO4/g clay and with 14.40 meq Al and 22.58 meq H3PO4/g clay, and the resulting complexes studied by chemical and mineralogical methods. Both interlayer materials were slightly positively charged and except for different water contents their chemical compositions were almost identical. They contained Al, PO4 and H2O and a minor amount of Ca and approximated hydrous AlPO4∙nH2O. The mole ratios of Al:Ca:PO4:OH were 1.00:0.08:0.92:0.24 and 1.00:0.05:0.91:0.24, respectively. The interlayer materials appeared to be loosely packed and distributed sparsely in interspaces of the montmorillonite. The degree of packing was greater for the preparation with the larger amount of interlayer material. The materials increased the montmorillonite basal spacing to 23.3 Å under air-dry condition (30–40% relative humidity) but did not affect the lateral dimensions. The basal spacing varied somewhat with relative humidity at room temperature and decreased markedly as water was driven off by heating. Heat treatments between room temperature and 300 C sharply reduced the d001 spacings to 16.7 Å which persisted up to 700 C. It is postulated that the large basal spacings occur because the hydrated interlayer materials have a framework structure with tunnels along the c-axis. This being so, changes in the spacings with different humidities might result from the movement of water molecules among interstitial spaces existing around and between the loosely distributed molecules of interlayer material. The 16.7 Å spacing for the dehydrated phase corresponds to the sum of 7.0 Å, the edge dimension of an orthorhombic anhydrous AlPO4 and 9.7 Å, the silicate layer thickness.


2014 ◽  
Vol 42 (6) ◽  
pp. 1773-1779 ◽  
Author(s):  
Lubna Freihat ◽  
Victor Muleya ◽  
David T. Manallack ◽  
Janet I. Wheeler ◽  
Helen R. Irving

Over 30 receptor-like kinases contain a guanylate cyclase (GC) catalytic centre embedded within the C-terminal region of their kinase domain in the model plant Arabidopsis. A number of the kinase GCs contain both functional kinase and GC activity in vitro and the natural ligands of these receptors stimulate increases in cGMP within isolated protoplasts. The GC activity could be described as a minor or moonlighting activity. We have also identified mammalian proteins that contain the novel GC centre embedded within kinase domains. One example is the interleukin 1 receptor-associated kinase 3 (IRAK3). We compare the GC functionality of the mammalian protein IRAK3 with the cytoplasmic domain of the plant prototype molecule, the phytosulfokine receptor 1 (PSKR1). We have developed homology models of these molecules and have undertaken in vitro experiments to compare their functionality and structural features. Recombinant IRAK3 produces cGMP at levels comparable to those produced by PSKR1, suggesting that IRAK3 contains GC activity. Our findings raise the possibility that kinase-GCs may switch between downstream kinase-mediated or cGMP-mediated signalling cascades to elicit desired outputs to particular stimuli. The challenge now lies in understanding the interaction between the GC and kinase domains and how these molecules utilize their dual functionality within cells.


1980 ◽  
Vol 58 (21) ◽  
pp. 2199-2202 ◽  
Author(s):  
R. A. Burt ◽  
Y. Chiang ◽  
A. J. Kresge

The hydrolysis of 2-methoxy-2,3-dihydropyran shows a normal isotope effect (kH/kD > 1) under catalysis by the hydrogen ion and gives an accurately linear dependence of reaction rate upon undissociated acid concentration in cyanoacetic acid and formic acid buffer solutions. This substrate, therefore, unlike its higher homolog, 9-methoxyoxacyclonon-2-ene, provides no evidence in support of an anything but a normal mechanism for vinyl ether hydrolysis. Analysis of the hydrogen isotope effect suggests that a minor amount (8%) of this hydrolysis occurs via reaction of the acetal functional group.


2021 ◽  
Vol 11 (23) ◽  
pp. 11410
Author(s):  
Gea Prioglio ◽  
Silvia Agnelli ◽  
Stefano Pandini ◽  
Maurizio Galimberti

Silica-based rubber composites have tremendous importance, as they allow the reduction in hysteresis in demanding dynamic-mechanical applications such as tire compounds and hence have a lower environmental impact. However, they also present drawbacks such as poor rheological behavior. In this work, an innovative silica-based hybrid filler system was developed, obtaining a rubber composite with an improved set of properties. A nanosized high surface area graphite (HSAG) was functionalized with 2-(2,5-dimethyl-1H-pyrrol-1-yl)propane-1,3-diol, serinol pyrrole (SP), through a simple process characterized by a high carbon efficiency. The HSAG-SP adduct, with about nine parts of SP per hundred parts of carbon filler, was used to form a hybrid filler system with silica. An elastomeric composite, with poly(styrene-co-butadiene) from anionic polymerization and poly(1,4-cis-isoprene) from Hevea brasiliensis was prepared with 50 parts of silica, which was replaced in a minor amount (15%) by either pristine HSAG or HSAG-SP. The best set of composite properties was obtained with HSAG-SP: the same dynamic rigidity and hysteresis and tensile properties of the silica-based material and appreciably better rheological properties, particularly in terms of flowability. This work paves the way for a new generation of silica-based composites, with improved properties, based on a hybrid filler system with a nanosized edge functionalized graphite.


1997 ◽  
Vol 12 (3) ◽  
pp. 805-811 ◽  
Author(s):  
Wei-Chang Lee ◽  
Shyan-Lung Chung

A combustion synthesis (SHS) process has been developed for the synthesis of Si3N4 powder under low nitrogen pressures. Si and NaN3 powders were used as the reactants, and NH4Cl powder was added as a catalytic agent. These powders were mixed and pressed into a cylindrical compact. The compact was wrapped up with an igniting agent (i.e., Ti + C), and the synthesis reaction was triggered by the combustion of the igniting agent. Addition of NH4Cl was found necessary for the combustion synthesis reaction under low nitrogen pressures (< 1.2 MPa). The product as synthesized is mostly in the form of agglomerated fine particles (0.1–1 μm in diameter) and is composed mainly of α-phase and a minor amount of β-phase. Effects of various experimental parameters (N2 pressure, NaN3, NH4Cl, and Si3N4 contents) on the product conversion and the combustion temperature were investigated. A possible reaction mechanism was proposed that explains the effects of the experimental parameters on the synthesis reaction.


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