scholarly journals The occurrence of eleven elements in dairy cow´s milk, feed, and soil from three different regions of Slovakia

10.5219/1461 ◽  
2020 ◽  
Vol 14 ◽  
pp. 967-977
Author(s):  
Róbert Toman ◽  
Martina Pšenková ◽  
Vladimír Tančin

The objective of this study was to measure the concentrations of eleven essential, potentially toxic and toxic elements (arsenic – As, calcium – Ca, cadmium – Cd, copper – Cu, iron – Fe, mercury – Hg, magnesium – Mg, nickel – Ni, lead – Pb, selenium – Se, zinc- Zn) in raw cow’s milk (spring, summer, and autumn season), feed (spring and autumn season) and soil (spring season) from three different environments by routine methods in the certified testing laboratory. The samples were collected in the undisturbed region around Novoť, the moderately disturbed region around Tulčík, and the strongly disturbed region around Čečejovce. The concentrations of all toxic elements (As, Cd, Hg, Ni, Pb) and two essential elements (Cu, Se) in milk were under the limits of quantification (LOQ) from all investigated areas and during all seasons. Concentrations of other elements in milk from the undisturbed and disturbed areas were significantly different, generally with the highest levels in summer. In soil samples, the significantly highest concentrations of Ca, Cu, Ni were found in a strongly disturbed area, Mg and As in moderately disturbed area, and Fe, Se, Zn, Hg, and Pb in an undisturbed area. Cadmium was under the LOQ. In feed, the concentrations of essential elements, except of Se, were higher in the autumn. The significantly highest concentration of As, Ni were recorded in a moderately disturbed area and Pb in the undisturbed area in both seasons. Cadmium and Hg were under the LOQ. Despite the higher level of some elements in soil (Fe, Mg, Ca) from all regions, there were not elevated concentrations of any element in feed or milk. The concentrations of all toxic elements in milk were under the permitted limits. Thus, the milk from all investigated areas was not contaminated with the elements posing a health risk for consumers and it is considered safe for human consumption.


2021 ◽  
Author(s):  
Gwyneth A. MacMillan ◽  
Marc Amyot ◽  
Pierre-Yves Daoust ◽  
Mélanie Lemire

ABSTRACTWe measured baseline levels of 19 trace element and mercury speciation for grey seals (Halichoerus grypus) from the Gulf of St. Lawrence (GSL), Québec, Canada. With interest growing in commercializing grey seal products for human consumption in this region, the goal of this study was to measure essential and non-essential trace elements in grey seals to evaluate health concerns and nutritional benefits. From 2015 to 2019, 120 grey seals were sampled by hunters and researchers at 4 sites in the GSL. Muscle, liver, heart and kidney samples were analyzed for 10 non-essential elements (Sb, As, Be, B, Cd, Pb, Hg, Ni, Tl, Sn) and 9 essential elements (Co, Cr, Cu, Fe, Mg, Mn, Mo, Se, Zn). Both total mercury (THg) and methylmercury (MeHg) were analysed for a subset of samples. Many elements were undetected in liver (Sb, As, Be, B, Cr, Co, Pb, Ni, Tl, Sn) and muscle tissues (same, plus Cd, Mn, Mo). Results showed lower element concentrations in the muscle (Fe, Mg, Se) and livers (Cd, Cr, Hg, Mn, Mo, Se) of young-of-the-year harvested in the winter (< 6 weeks old) compared to older animals feeding at sea. For older seals (∼ 5 months to 29 years), we did not observe progressive age-dependent bioaccumulation. Sex-specific differences were not very pronounced, but a few elements were 30 - 70% higher in the muscle (THg, MeHg) and liver (Mn, Zn) of male seals. Comparison to Canadian dietary reference intakes shows that a weekly portion of liver from young-of-the-year (< 6 weeks old) is a good source of essential elements (Cu, Fe) and that muscle and liver from this age category does not exceed reference values for toxic elements (As, Cd, Pb, MeHg). Ongoing discussions with regional public health professionals will help to develop dietary recommendations for the consumption of older grey seals.HIGHLIGHTSWe measured baseline levels of 19 trace elements in grey seals harvested from the Gulf of St. Lawrence.We evaluated nutritional benefits and health concerns of human consumption of grey seal products.Once seals began feeding at sea (∼ 5 mo), many element concentrations increased, but did not bioaccumulate progressively with age afterwards.Some elements were more concentrated in the muscle (mercury) and livers (manganese, zinc) of male seals.Young seal (< 6 we) livers are a good dietary sources of copper and iron, while its muscle and liver were below reference values for toxic elements.GRAPHICAL ABSTRACT



2016 ◽  
Vol 6 (1) ◽  
pp. 69 ◽  
Author(s):  
Keagile Bati ◽  
Oarabile Mogobe ◽  
Wellington R. L. Masamba

Contamination of vegetables with toxic metals is one of the most important contributing factors to ill health throughout the world, more so because vegetables are considered essential for human health and their consumption is highly recommended by health authorities. The aim of this study was to determine the concentrations of selected essential elements (Fe, Cu, Mn, Mo, Zn) and toxic elements (As, Cd, Cr, Pb) in common vegetables sold for human consumption in supermarkets and open market of Maun village, Botswana. Five vegetables (cabbage, rape, tomatoes, onions and potatoes) were purchased from different selling points, washed with de-ionised water, cut into small pieces and digested with aqua regia on a block digester, following the US. EPA method 200 - 7 and analysed for metal content using Inductively Coupled Plasma - Atomic Emission Spectroscopy (ICP-AES). The results showed that concentrations of essential and toxic metals varied with the type of vegetable and also with the market category (supermarket or street vendor). The highest concentration of essential elements was obtained from cabbage with a Zn concentration of 135.4mg/Kg and the lowest was from onion with a Mo concentration of 1.35mg/Kg. For toxic elements the highest concentration was obtained from rape vegetable with a Pb concentration of 4.73mg/Kg and the lowest from the same vegetable with Cr concentration below the detection limit. Also observed was that leafy vegetables, especially cabbage, had the highest concentrations of most trace metals. It was concluded that vegetables sold in Maun had sufficient levels of essential elements but also some had high concentrations of toxic metals. We thus recommend consumption of vegetables from the studied markets with reduced frequency to avoid metal poisoning.



2016 ◽  
Vol 40 (2) ◽  
pp. 152-155 ◽  
Author(s):  
TE Shishniashvili ◽  
NN Suladze ◽  
VV Margvelashvili

Objectives: To study the influence of environmental pollution on the mineralization of dental hard tissues by using biosubstrates: teeth and hair. :Study design: At the first stage epidemiological survey was conducted in polluted and less polluted areas of Tbilisi (Georgia). We studied 525 children aged 3 and 4 years. Caries prevalence and intensity was defined by the methodology of World Health Organization. At the second stage the chemical elements content was studied in hair and teeth hard tissues of 24 children by X - ray fluorescent spectroscopy method. Results: The prevalence of dental caries in the polluted region was 46%, caries intensity − 1.92 (± 2.842). In the less polluted region prevalence was 37%, caries intensity − 1.47 (± 2.571). These data are statistically reliable (p &lt; 0.05). The study of hair and tooth tissues showed that the toxic elements (Pb, Hg, Sn, Ti) content in these tissues was higher in environmentally unfavorable than in favorable conditions. Conclusion: Hair and dental tissues can be used as indicators of environmental pollution. Our survey showed that toxic elements content in dental hard tissues was higher and the level of essential elements was less in polluted than in less polluted areas of Tbilisi.



2011 ◽  
Vol 25 (4) ◽  
pp. 937-940 ◽  
Author(s):  
Tânia Maria de Moura ◽  
Alexandre Magno Sebbenn ◽  
Karina Martins ◽  
Maria Andreia Moreno ◽  
Giancarlo Conde Xavier Oliveira ◽  
...  

This study aimed to compare the genetic diversity of populations of Solanum lycocarpum A.St.-Hil between natural and human disturbed environments, with the assumption that protected areas have greater genetic diversity than disturbed areas. For this study, two populations were sampled in Goiás State, Brazil. One was located in a conservation unit, Serra de Caldas Novas State Park, in the Caldas Novas municipality. The other was located in a pasture area in the municipality of Morrinhos. The two populations are 41 km apart. We sampled 60 individuals from each population, which were genotyped with five microsatellite loci (SSR). The highest number of alleles was recorded in the population of the conservation unit, where we found 11 exclusive and five rare alleles. In the disturbed area, we recorded only three exclusive alleles and one rare allele. Although we did not observe significant inbreeding in these populations, genetic divergence between them was high (G ST (Hedrick)=0.147 =0.147) for a species with long distance seed dispersal. The results corroborate the hypothesis that the population in the less disturbed area harbors greater allelic diversity. They also confirm the effectiveness of using protected areas to preserve the genetic diversity of the species.



Author(s):  
Justin B. Richardson ◽  
Jahziel K. Chase

Wine is a popular beverage and may be a source of nutrient and toxic elements during human consumption. Here, we explored the variation in nutrient and toxic elements from soils to grape berries and commercial white wines (Chardonnay) at five USA vineyards (New York, Vermont, California, Virginia) with strongly contrasting geology, soils, and climates. Samples were analyzed for macronutrients (Ca, K, and Mg), micronutrients (Mn, Cu, and Zn), and toxic elements (As, Cd, and Pb). Our study showed contrasting macronutrient, micronutrient, and toxic element concentrations in soils and in vines, leaves, and grapes. However, plant tissue concentrations did not correspond with total soil concentrations, suggesting a disconnect governing their accumulation. Bioconcentration factors for soil to grape berry transfer suggest the accumulation of Ca, K and Mg in berries while Fe, Mn, Cu, Zn, and Pb were generally not accumulated in our study or in previous studies. Wines from the five vineyards studied had comparable nutrient, micronutrient, and toxic metal concentrations as wines from Germany, Italy, Portugal, Spain, Croatia, Czech Republic, and Japan. The transfer of nutrients and toxic elements from grape berries to wine indicated that only Ca, K, and Mg were added or retained while concentrations of all other micronutrients and toxic elements were somewhat to extensively diminished. Thus, there appears to be a substantial effect on the geochemistry of the wine from the grape from either the fermentation process (i.e., flocculation), or a dilution effect. We conclude that soils, geology, and climate do not appear to generate a unique geochemical terroir as the transfer and concentration of inorganic nutrients appear to be comparable across strongly contrasting vineyards. This has several implications for human health. Nutrients in wine have potential impacts for human nutrition, as wine can meet or exceed the recommended dietary requirements of Ca, K, Mg, and Fe, and toxic metals As and Pb concentrations were also non-trivial.



2018 ◽  
Vol 7 (2.23) ◽  
pp. 260
Author(s):  
Galbadrakh Ragchaa ◽  
Temujin Enkhbat ◽  
Enkhtor Lkhamsuren

In this work inductively coupled plasma - mass spectrometry (ICP-MS) method was used to determine content of harmful to human health heavy elements such as As, Cd, Cr, Pb, Th, U, and other essential elements Zn, Cu, Ni in soil samples collected around fence of two largest in Asia copper (Oyu Tolgoi) and coal (Tavan Tolgoi) deposits. The analyses revealed average content of arsenic in the examined soil samples is exceeding 1.4 times the maximum permissible limit. It is consistent with many previous studies emphasizing on a high occurrence of arsenic in soils, well waters of North and Central Mongolia. But the contents of copper in soil samples collected from three leeward locations of the copper mine Oyu Tolgoi are up to 2.18 times higher than the maximum permitted content established by the government standard of Mongolia. The contents of Cd, Ni, Pb, U, and Zn in soil probes collected from leeward locations of Ukhaa Khudag open pit mine of Tavan Tolgoi coal deposit are higher than that of in probes collected from the windward side of that by factor ranging from 1.34 to 1.64. These facts indicate possible transport and spread of heavy elements by wind from these intense operating open pit mines into adjacent dry and windy deserted region of Mongolia.  



Check List ◽  
2012 ◽  
Vol 8 (1) ◽  
pp. 083 ◽  
Author(s):  
Liliana Piatti ◽  
Paulo Matthes Orlandi de Amaro ◽  
Jhonatas Fernando de Jesus Araújo ◽  
Vitor Quadros Altamore Sanches ◽  
Paulo Sérgio Bernarde

This paper presents a checklist of anurans species and their distribution in a disturbed area in the municipality of Jarú, Rondônia state, Brazil. Nineteen species belonging to eight families were sampled with pitfall traps and time constrained searches. About 70% of the species were found in a secondary forest and 40% were found only in this environment, while about 57% were found in pastures, with 26% of species being registered only in this habitat. Our results were similar to those of previous studies in other disturbed areas of Rondônia. Species that can be found in different habits were unevenly distributed, with forested environments harboring more species. Despite its nearness to Cerrado and the large number of open areas available, most species found are typical of the Amazon forest.



2021 ◽  
Vol 877 (1) ◽  
pp. 012023
Author(s):  
Yasin H Aoeed ◽  
Awaz B Mohammed ◽  
Attalah M. Hameed

Abstract In order to evaluate the quantity of twelve PAHs (Naphthalene, Tetraphan and Acenaphthylene Fluorene, Phenanthrene, Anthracene, Pyrene, Benzo [a] Anthracene, Ovalene, Chrysene, Benzo [a] fluoranthene and DiBenzo [ah] Anthracene) in the soil samples from Kirkuk province, seven sites (Ras El-Gesr, Benja Ali, Wahed Hozeran, North Oil Company (NOC), Lillan, Kubri and Chimen) were selected using Gas Chromatography (GC) during the autumn 2017 and winter 2018. The results showed that the highest concentration of individual hydrocarbons during the autumn season was for the Acenaphthylene compound in the NOC site 131.19 μg/kg, and for Naphthalene compound, was 100.543μg/kg. The NOC recorded the highest concentration of total hydrocarbons 891.65 μg/kg. For the winter season, the highest concentration of polycyclic aromatic hydrocarbons was recorded for the Fluorene compound at the NOC site 79.19 μg/kg. Fluorene and Naphthalene compounds achieved the highest averages for the season (43.24 and 42.984 μg/kg) respectively, and recorded the location of the NOC, the highest summation of total hydrocarbons amounted to 609.77 μg/kg.



2016 ◽  
Vol 13 (1) ◽  
pp. 1-6
Author(s):  
Baghdad Science Journal

Soil invertebrates community an important role as part of essential food chain and responsible for the decomposition in the soil, helps soil aeration , nutrients recycling and increase agricultural production by providing the essential elements necessary for photosynthesis and energy flow in ecosystems.The aim of the present study was to investigate the soil invertebrates community in one of the date palms plantation in Aljaderia district South of Baghdad, , and their relationships with some physical and chemical properties of the soil , as Five randomly distributed replicates of soil samples were collected monthly. Invertebrates samples were sorted from the soil with two methods, direct method to isolate large invertebrates and indirectly to isolate small invertebrates using wet funnel method. The study also included the determination of physical and chemical factors of the soil (Temperature, Salinity, pH, Organic matter, Humidity, In addition to the soil texture).Monthly fluctuations in physical and chemical characteristics of the soil and the total invertebrates community study site were determined. Significant correlations the of the invertebrates community and each of temperature, organic matter, and humidity were observed. The study revealed that the temperature of the soil ranged between 5 to 25 C0 , The salinity concentration ranged between 1.1-1.9 ‰, The pH values ranged between 7.3 to 7.8 and the percentage of soil moisture ranged between 15 - 25% , Soil samples were composed of 44.6 % Clay, 19.7% Silt and 35.5% Sand.A total of 4625 individuals of soil invertebrates belonging to 16 taxa were sorted , within which the adult and larval insects were the most abundant, and from them 1283 individuals were sorted , represented 28% of the total numbers, followed by Isopoda , which 1030 individuals of them were sorted, In addition to Nematode, Oligochaetes Annelids family Enchytraeidae, and Earthworms family Lumbricida, Species of Chilopoda, Diplopoda, mites, land snails and slugs. The highest total individual number were recorded recorded durim moderate temperature months, February, March and April amounted to 838, 801 and 813 individuals, respectively.A significant correlation was mated between total number of soil invertebrates and each of temperature, organic matter and humidity. The significant difference in means was calculated according to LSD test.



2012 ◽  
Vol 3 (1) ◽  
pp. 38-44 ◽  
Author(s):  
Aloísio Freitas Chagas Junior ◽  
Gil Rodrigues Dos Santos ◽  
Rogério Cézar de Lima Melo ◽  
Ariádila Gonçalves De Oliveira ◽  
Bruno Vizioli ◽  
...  

Experiments were performed in a greenhouse to evaluate the effect of natural nodulation in the development of Pacara Earpod Tree (Enterolobium contorsiliquum) and Leucaena (Leucaena leucocephala) is soil with different uses in Tocantins. We used three soil samples of woods, cultivated areas four and in a degraded area, in pots in a completely randomized design with four replications. In both species nodulation was observed in all soils studies areas with better nodulation occurring in soil cultivation, providing a higher accumulation of biomass. Soil from the degraded area the two species showed nodule number and biomass of nodules significant, with potential for use in disturbed areas, with characteristics of degraded soils.



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