Softening of Vulcanized Carbon Black-Loaded Rubber during Extension

1955 ◽  
Vol 28 (4) ◽  
pp. 1123-1132
Author(s):  
D. G. Marshall ◽  
D. L. Walker ◽  
J. G. Smith

Abstract The results of the observations recorded in this paper may be summarized by the following items. 1. A difference between the first and second load-extension curves is to be expected in any viscoelastic material, although the behavior of black-loaded rubber at large extensions differs in some fundamental respects from a simple viscoelastic material. 2. Within the experimental limits of about ±10 per cent, all of the energy used in softening the black-loaded rubbers studied appears as heat. 3. The ratio between the area of the hysteresis cycle obtained on first stretching a specimen of black-loaded rubber and that obtained during the second extension varies only slightly from compound to compound in the range of extensions studied. 4. Although the modulus of a black-loaded rubber decreases with increasing temperature, the ratio between the hysteresis area of the first extension and that of the second extension remains roughly constant over the temperature range studied. 5. There are electrical resistance changes that correspond closely to the mechanical softening effects experienced with black-loaded rubber. Result (2) suggests that if cross-linkage breaking or changes of state of rubber are specified as mechanisms for producing softening, then the potential energy changes required must be small, compared with the mechanical energy available. Result (5) shows that changes in arrangement of the carbon black particles are associated with the softening process, and therefore suggests that the softening is related to internal strains in the rubber. These results do not prove that the softening observed in rubber is similar in principle to the behavior of a simple viscoelastic model during the first and other extensions. However, these observations are consistent with this view, except for the difficulty connected with the relationship between the softening and the permanent set in the simple viscoelastic material, and the difficulty connected with the persistence of softening. A simple linear model is obviously bound to have considerable limitations in describing the properties of a black-loaded rubber at high extensions. The limitations may arise from the nonlinearity of rubber elasticity and the non-Newtonian nature of rubber flow; alternatively, it may be necessary to postulate some entirely different process, such as rubber heterogeneity or mechanical bond breaking.

2010 ◽  
Vol 168-170 ◽  
pp. 1021-1024
Author(s):  
Guo Xuan Xiong ◽  
Zhi Bin Zhang ◽  
Min Deng ◽  
Yu Fen Zhou

The cement-based composite shielding materials filled with carbon materials such as ordinary carbon materials (graphite, coke and carbon black), carbon fiber and nano-carbon materials (carbon nano-tube and nano-carbon black) were prepared. The relationship of conductivity and shielding effectiveness in a frequency range of 100 KHz~1.5 GHz was studied. The electric properties of cement-based composites filled with carbon fiber is better than other carbon materials. With the contents of carbon fiber of 5.vol%, the average shielding effectiveness is about 37 dB and the maximum shielding effectiveness reaches 40 dB.


1928 ◽  
Vol 1 (3) ◽  
pp. 485-497 ◽  
Author(s):  
C. R. Johnson

Abstract The rates of evolution of gas from carbon black with variation of time, temperature, and pressure have been determined. Complete analyses have been made of five types of carbon black, which involve an organic combustion of the original sample, an organic combustion of the sample after the gases have been removed, a determination of the loss in weight represented by the gases removed, analyses of the gases removed, and finally a complete accounting, or balance, of the carbon in the steps considered. In an attempt to supply some missing information not revealed by the foregoing, some special gas analyses under varying conditions were made. The relationship between the amount and composition of volatile matter evolved from carbon blacks and the properties imparted to vulcanized rubber when compounded with these blacks has been studied.


2010 ◽  
Vol 73 (8) ◽  
pp. 1502-1505 ◽  
Author(s):  
WENJING PAN ◽  
DONALD W. SCHAFFNER

Tomato-associated Salmonella outbreaks have recently become a significant food safety concern. Temperature abuse of cut tomatoes may have played a role in some of these outbreaks. The purpose of this study was to develop a mathematical model to describe the growth of Salmonella on cut tomatoes at various temperatures. Four Salmonella serotypes (Typhimurium, Newport, Javiana, and Braenderup) obtained from previous tomato-linked cases of salmonellosis were used in this study. These four serotypes were cultured separately, combined into a cocktail, and inoculated onto whole red round tomatoes and allowed to dry overnight. The tomatoes were then cut into pieces and incubated at a predetermined range of temperatures (10, 12.5, 15, 17.5, 20, 22.5, 25, 27.5, 30, and 35°C). Salmonella concentration was measured at specified time intervals to determine the growth curve for Salmonella on cut tomatoes at each temperature. The growth rates were calculated using DMFit and used to build a mathematical model to illustrate the relationship between the growth rates of Salmonella on tomatoes and incubation temperatures from 10 to 35°C. The resulting model compared favorably with a Salmonella growth model for raw poultry developed by our laboratory. The Pathogen Modeling Program underpredicted growth at low temperatures and overpredicted growth at high temperatures. ComBase predicted consistently slower growth rates than were observed in tomatoes but showed parallel increases in growth rate with increasing temperature.


2011 ◽  
Vol 317-319 ◽  
pp. 616-620 ◽  
Author(s):  
Guang Qing Wang ◽  
Zhong Wei Zhao

In this article, a novel electro-mechanical energy conversion model of power harvesting from the vibration-induced the piezoelectric stator of the traveling wave rotary ultrasonic motor was proposed. Based on the curvature basis approach, the relationship between the deduced voltage and the mechanical stain induced by piezoelectric polarization was formulated. In addition to the relationships between the maximum induced voltages at the resonance frequency, the conversion energy density and the dimensions of the piezoelectric stator were also derived. The analytical model shows that the vibration-induced voltage is proportional to the exciting electrical voltage magnitude and square of height of the piezoelectric ceramic (PZT) but is inversely proportional to the permittivity of PZT and the damping coefficient of the stator. Some simulations and experimental results demonstrate that the maximum output voltage coincides with the energy conversion analytical model.


Author(s):  
M. Benhaddou ◽  
M. Ghammouri ◽  
Z. Hammouch ◽  
F. Latrache

The main originality of this work consists in investigating low cycle fatigue of cylindrical test piece with wings under imposed constraint and for the temperature 20°c, 200°c, 400°c. Based on a combination between the fatigue parameter of Jiang-Sehitoglu and the relationship of Coffin-Manson, a numerical model for the prediction of the number of cycles at break. It was found that the CuCrZr cylindrical test piece showed a reduction in fatigue life with increasing temperature.


2019 ◽  
Vol 37 (9-10) ◽  
pp. 745-763 ◽  
Author(s):  
Zhijun Wang ◽  
Xiaojuan Wang ◽  
Weiqin Zuo ◽  
Xiaotong Ma ◽  
Ning Li

The capacity of coal to adsorb methane is greatly affected by temperature and, in recent years, temperature-dependent adsorption has been studied by many researchers. Even so, comprehensive conclusions have not been reached and conflicting experimental results are common. This paper reviews the current state of research regarding the temperature-dependent adsorption of methane in coal and catalogs the conclusions from experiments conducted on that subject by 28 researchers, as published between 1995 and 2017. Probability theory and statistics are used to show that the conclusion generally accepted by most researchers is that the amount of methane adsorbed by coal decreases with increasing temperature. It is highly likely that the Langmuir volume decreases as the temperature rises, and it is also probable that the Langmuir pressure increases at higher temperatures. Equations are presented that express the relationships between methane adsorption, Langmuir volume, Langmuir pressure, and temperature. Future research should be directed toward determining the relationship between Langmuir pressure and temperature. The results of the study presented herein provide a theoretical basis for predicting the gas content in coal seams and improving the efficiency of coalbed methane development.


1994 ◽  
Vol 266 (2) ◽  
pp. H730-H740 ◽  
Author(s):  
K. Hata ◽  
Y. Goto ◽  
O. Kawaguchi ◽  
T. Takasago ◽  
A. Saeki ◽  
...  

The effect of acidosis on left ventricular (LV) mechanoenergetics was assessed in seven excised, cross-circulated dog hearts with the use of the frameworks of the contractility index (Emax) and the relationship between myocardial oxygen consumption (VO2) and pressure-volume area (PVA; a measure of the LV total mechanical energy). Acidosis was stably maintained without hypoxia by appropriately mixing CO2 and air in a membrane oxygenator in the coronary arterial perfusion circuit. Acidosis [pH: 6.98 +/- 0.09 (SD), PCO2: 91 +/- 25 mmHg in the coronary arterial blood] decreased Emax by 45 +/- 12% (P < 0.01) and PVA by 47 +/- 12% (P < 0.01) at a fixed LV volume. When the preacidosis Emax level was restored by Ca2+ infusion during acidosis, unloaded VO2 (the VO2 intercept of the VO2-PVA relation) exceeded the control value by 19 +/- 17% (P < 0.05), indicating that acidosis required higher VO2 for nonmechanical activities at a matched Emax. Moreover, the oxygen cost of enhanced contractility (the incremental ratio of unloaded VO2 to Emax) was 1.53 +/- 0.40 times higher (P < 0.01) during acidosis than preacidosis. We conclude that acidosis results in LV contractile dysfunction accompanied by an increased oxygen cost of contractility. This increased energy cost of the excitation-contraction coupling can be accounted for by a decreased Ca2+ sensitivity of the contractile proteins during acidosis.


2010 ◽  
Vol 132 (10) ◽  
Author(s):  
Sina Ocal ◽  
M. Umut Ozcan ◽  
Ipek Basdogan ◽  
Cagatay Basdogan

The liver harvested from a donor must be preserved and transported to a suitable recipient immediately for a successful liver transplantation. In this process, the preservation period is the most critical, since it is the longest and most tissue damage occurs during this period due to the reduced blood supply to the harvested liver and the change in its temperature. We investigate the effect of preservation period on the dynamic material properties of bovine liver using a viscoelastic model derived from both impact and ramp and hold experiments. First, we measure the storage and loss moduli of bovine liver as a function of excitation frequency using an impact hammer. Second, its time-dependent relaxation modulus is measured separately through ramp and hold experiments performed by a compression device. Third, a Maxwell solid model that successfully imitates the frequency- and time-dependent dynamic responses of bovine liver is developed to estimate the optimum viscoelastic material coefficients by minimizing the error between the experimental data and the corresponding values generated by the model. Finally, the variation in the viscoelastic material coefficients of bovine liver are investigated as a function of preservation period for the liver samples tested 1 h, 2 h, 4 h, 8 h, 12 h, 24 h, 36 h, and 48 h after harvesting. The results of our experiments performed with three animals show that the liver tissue becomes stiffer and more viscous as it spends more time in the preservation cycle.


Water ◽  
2019 ◽  
Vol 11 (10) ◽  
pp. 2108 ◽  
Author(s):  
Ari Guna ◽  
Jiquan Zhang ◽  
Siqin Tong ◽  
Yongbin Bao ◽  
Aru Han ◽  
...  

Based on the 1965–2017 climate data of 18 meteorological stations in the Songliao Plain maize belt, the Coupled Model Intercomparision Project (CMIP5) data, and the 1998–2017 maize yield data, the drought change characteristics in the study area were analyzed by using the standardized precipitation evapotranspiration index (SPEI) and the Mann–Kendall mutation test; furthermore, the relationship between meteorological factors, drought index, and maize climate yield was determined. Finally, the maize climate yields under 1.5 °C and 2.0 °C global warming scenarios were predicted. The results revealed that: (1) from 1965 to 2017, the study area experienced increasing temperature, decreasing precipitation, and intensifying drought trends; (2) the yield of the study area showed a downward trend from 1998 to 2017. Furthermore, the climate yield was negatively correlated with temperature, positively correlated with precipitation, and positively correlated with SPEI-1 and SPEI-3; and (3) under the 1.5 °C and the 2.0 °C global warming scenarios, the temperature and the precipitation increased in the maize growing season. Furthermore, under the studied global warming scenarios, the yield changes predicted by multiple regression were −7.7% and −15.9%, respectively, and the yield changes predicted by one-variable regression were −12.2% and −21.8%, respectively.


Sign in / Sign up

Export Citation Format

Share Document