scholarly journals CHARACTERIZATION OF EQUILIBRIUM CONDITIONS OF ADSORBED SILICA–GEL/WATER BED ACCORDING TO DUBININ–ASTAKHOV AND FREUNDLICH

2005 ◽  
Vol 4 (1) ◽  
pp. 03 ◽  
Author(s):  
M. R. A. Afonso ◽  
V. Silveira Jr.

Systems of adsorption have been studied as an alternative for the cooling systems for saving electrical energy. The main advantage is the heat as the driving sources, for example, hot water or waste heat, widely used in the industries, and solar energy. The pair adsorbent/ adsorbate determines the behavior of these systems. Therefore, the knowledge of the equilibrium conditions between the adsorbent and the adsorbate is very important. The pair silica gel/water has the advantage of exploiting low-temperature heat sources. In this paper, the equilibrium conditions of the pair silica gel/water were investigated and the data were used to identify the coefficients of Dubinin-Astakhov equation and Freundlich equation. The experiments consisted of measuring temperature and pressure for different adsorbed mass of water in the adsorbent (silica gel). The amount of adsorbed mass (kg) per adsorbent mass (kg) used were: 0.007, 0.013, 0.024, 0.047, 0.092, 0.162 and 0.209. Both equations showed good agreement with experimental data, the coefficients of regression (R2) were 0.991 on the Dubinin-Astakhov equation and 0.993 for the Freundlich equation.

2005 ◽  
Vol 4 (1) ◽  
Author(s):  
M. R. A. Afonso ◽  
V. Silveira Jr.

Systems of adsorption have been studied as an alternative for the cooling systems for saving electrical energy. The main advantage is the heat as the driving sources, for example, hot water or waste heat, widely used in the industries, and solar energy. The pair adsorbent/ adsorbate determines the behavior of these systems. Therefore, the knowledge of the equilibrium conditions between the adsorbent and the adsorbate is very important. The pair silica gel/water has the advantage of exploiting low-temperature heat sources. In this paper, the equilibrium conditions of the pair silica gel/water were investigated and the data were used to identify the coefficients of Dubinin-Astakhov equation and Freundlich equation. The experiments consisted of measuring temperature and pressure for different adsorbed mass of water in the adsorbent (silica gel). The amount of adsorbed mass (kg) per adsorbent mass (kg) used were: 0.007, 0.013, 0.024, 0.047, 0.092, 0.162 and 0.209. Both equations showed good agreement with experimental data, the coefficients of regression (R2) were 0.991 on the Dubinin-Astakhov equation and 0.993 for the Freundlich equation.


2017 ◽  
Author(s):  
◽  
Shaveen Maharaj

Industrial plants are excellent sources of waste heat and provide many opportunities for energy harvesting using thermo-electric principles. A thermoelectric generator (TEG) is utilized in this study for harvesting expended heat from various sources. The main challenge associated with this type of technology lies in the creation of a sufficient thermal gradient between the hot side and the cold side of the TEG device. This is necessary for the module to generate an appreciable quantity of electrical energy. The performance of the TEG generator is tested using different configurations, different heat sources and different cooling methods. Heat sources included electrically driven devices, gas, biomass and gel fuel. Expended heat from different sites within an industrial environment was also chosen for operating the TEG device. The power produced by the generator is sufficient to operate low power LED lights, a DC radio receiver and a cellular phone charger.


2019 ◽  
Vol 142 (4) ◽  
Author(s):  
Md. Tareq Chowdhury ◽  
Esmail M. A. Mokheimer

Abstract Even though the renewable technologies are getting a gradually increasing share of the energy industry, the momentum of its growth is far away from outweighing the dominance of fossil fuel. Due to the concern for ozone depletion, global warming, and many more environmental hazards caused by fossil fuels, it is essential to substitute the conventional energy sources with renewables. Since this replacement cannot be done overnight, the conventional energy technologies should be integrated with renewables to minimize the pace of adverse effects on fossil fuel–based industries in the meantime. This way, the industries can be more efficient by utilizing waste heat, which accounts for 50% of the total energy generated now. This review paper outlines the role of solar energy in the generation of power and cooling systems that are capable of utilizing low-temperature heat sources below 400 °C. The review is primarily concentrated on line-focused concentrated solar power (CSP)-assisted solar technologies to be integrated with organic Rankine cycle (ORC) and absorption cooling systems. Photovoltaic and similar multigeneration systems are also discussed in brief.


2013 ◽  
Vol 21 (02) ◽  
pp. 1350010 ◽  
Author(s):  
SEUNG TAEK OH ◽  
BIDYUT BARAN SAHA ◽  
KEISHI KARIYA ◽  
YOSHINORI HAMAMOTO ◽  
HIDEO MORI

In the present paper, the effect of desorption temperature on the performance of adsorption cooling systems driven by waste heat from fuel cells was analyzed. The studied adsorption cooling systems employ activated carbon fiber (ACF) of type A-20–ethanol and RD type silica gel–water as adsorbent–refrigerant pairs. Two different temperature levels of waste heat from polymer electrolyte fuel cell (PEFC) and solid oxide fuel cell (SOFC) are used as the heat source of the adsorption cooling systems. The adsorption cycles consist of one pair of adsorption–desorption heat exchanger, a condenser and an evaporator. System performance in terms of specific cooling capacity (SCC) and coefficient of performance (COP) are determined and compared between the studied two systems. Results show that silica gel–water based adsorption cooling system is preferable for effective utilization of relatively lower temperature heat source. At relatively high temperature heat source, COP of ACF–ethanol based adsorption system shows better performance than that of silica gel–water based adsorption system.


Author(s):  
A Rezk ◽  
R Al-Dadah ◽  
S Mahmoud ◽  
A Elsayed

Adsorption cooling is a promising technology that can effectively utilise waste heat from many industrial processes for refrigeration and air conditioning. The choice of the adsorbent in this technology is vital to produce efficient and compact systems. Metal organic frameworks are new microporous materials with exceptionally high porosity and large surface area that can be used as adsorbents. This article experimentally investigates the characteristics of seven metal organic frameworks in terms of water adsorptivity compared to silica gel RD-2060. The adsorption characteristics were determined using an advanced gravimetric dynamic vapour sorption test facility. Results revealed that HKUST-1produced the highest water adsorption uptake with up to 95.7% increase compared to silica gel RD-2060 but showed deterioration in water adsorptivity with time. Throughout the temperature range tested, Fe-BTC has shown little hysteresis and produced up to 26.8% higher maximum water uptake value than silica gel RD-2060. These results highlight the potential of using certain metal organic frameworks materials to improve the efficiency of adsorption cooling systems; however, the thermal instability of some metal organic frameworks remains an issue that needs to be resolved.


2014 ◽  
Author(s):  
Sukanta Mondal ◽  
Kaniz Ferdous ◽  
M. Rakib Uddin ◽  
Maksudur R. Khan ◽  
M. A. Islam ◽  
...  
Keyword(s):  

Foods ◽  
2021 ◽  
Vol 10 (6) ◽  
pp. 1301
Author(s):  
Zully J. Suárez Montenegro ◽  
Gerardo Álvarez-Rivera ◽  
Jose A. Mendiola ◽  
Elena Ibáñez ◽  
Alejandro Cifuentes

This work reports the use of GC-QTOF-MS to obtain a deep characterization of terpenoid compounds recovered from olive leaves, which is one of the largest by-products generated by the olive oil industry. This work includes an innovative supercritical CO2 fractionation process based on the online coupling of supercritical fluid extraction (SFE) and dynamic adsorption/desorption for the selective enrichment of terpenoids in the different olive leaves extracts. The selectivity of different commercial adsorbents such as silica gel, zeolite, and aluminum oxide was evaluated toward the different terpene families present in olive leaves. Operating at 30 MPa and 60 °C, an adsorbent-assisted fractionation was carried out every 20 min for a total time of 120 min. For the first time, GC-QTOF-MS allowed the identification of 40 terpenoids in olive leaves. The GC-QTOF-MS results indicate that silica gel is a suitable adsorbent to partially retain polyunsaturated C10 and C15 terpenes. In addition, aluminum oxide increases C20 recoveries, whereas crystalline zeolites favor C30 terpenes recoveries. The different healthy properties that have been described for terpenoids makes the current SFE-GC-QTOF-MS process especially interesting and suitable for their revalorization.


Sensors ◽  
2021 ◽  
Vol 21 (4) ◽  
pp. 1259
Author(s):  
Dmitry Kozlov ◽  
Irina Munina ◽  
Pavel Turalchuk ◽  
Vitalii Kirillov ◽  
Alexey Shitvov ◽  
...  

A new implementation of a beam-steering transmitarray is proposed based on the tiled array architecture. Each pixel of the transmitarray is manufactured as a standalone unit which can be hard-wired for specific transmission characteristics. A set of complementary units, providing reciprocal phase-shifts, can be assembled in a prescribed spatial phase-modulation pattern to perform beam steering and beam forming in a broad spatial range. A compact circuit model of the tiled unit cell is proposed and characterized with full-wave electromagnetic simulations. Waveguide measurements of a prototype unit cell have been carried out. A design example of a tiled 10 × 10-element 1-bit beam-steering transmitarray is presented and its performance benchmarked against the conventional single-panel, i.e., unibody, counterpart. Prototypes of the tiled and single-panel C-band transmitarrays have been fabricated and tested, demonstrating their close performance, good agreement with simulations and a weak effect of fabrication tolerances. The proposed transmitarray antenna configuration has great potential for fifth-generation (5G) communication systems.


Author(s):  
Gautam Sharma ◽  
Vineet Kumar Pandey ◽  
Shouvik Datta ◽  
Prasenjit Ghosh

Thermoelectric materials are used for conversion of waste heat to electrical energy. The transport coefficients that determine their thermoelectric properties depend on the band structure and the relaxation time of...


Energies ◽  
2019 ◽  
Vol 12 (23) ◽  
pp. 4561 ◽  
Author(s):  
Nguyen T. Hung ◽  
Ahmad R. T. Nugraha ◽  
Riichiro Saito

Thermoelectric (TE) material is a class of materials that can convert heat to electrical energy directly in a solid-state-device without any moving parts and that is environmentally friendly. The study and development of TE materials have grown quickly in the past decade. However, their development goes slowly by the lack of cheap TE materials with high Seebeck coefficient and good electrical conductivity. Carbon nanotubes (CNTs) are particularly attractive as TE materials because of at least three reasons: (1) CNTs possess various band gaps depending on their structure, (2) CNTs represent unique one-dimensional carbon materials which naturally satisfies the conditions of quantum confinement effect to enhance the TE efficiency and (3) CNTs provide us with a platform for developing lightweight and flexible TE devices due to their mechanical properties. The TE power factor is reported to reach 700–1000 W / m K 2 for both p-type and n-type CNTs when purified to contain only doped semiconducting CNT species. Therefore, CNTs are promising for a variety of TE applications in which the heat source is unlimited, such as waste heat or solar heat although their figure of merit Z T is still modest (0.05 at 300 K). In this paper, we review in detail from the basic concept of TE field to the fundamental TE properties of CNTs, as well as their applications. Furthermore, the strategies are discussed to improve the TE properties of CNTs. Finally, we give our perspectives on the tremendous potential of CNTs-based TE materials and composites.


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