VÝVOJ PŮD NA OPUŠTĚNÝCH HALDÁCH PO TĚŽBĚ POLYMETALICKÝCH RUD NA HAVLÍČSKOBRODSKU

Old slags situated in the areas of former exploitation of polymetallic ore mineralization are places where initial steps of soil evolution in specific conditions can be investigated. Two soil profi les of different age have been studied in the Utín (2nd half of 13th century to 1st half of the 14th century) and Dlouhá Ves (60’s of 20th century) localities. Soil samples of fine fraction were studied including vertical distribution of selected elements (Fe, Pb, As, Ag, Cu; AAS) in context to other soil parameters including loss on ignition (LOI), sequential extraction analysis (SEA), soil exchangeable acidity (pH/KCl), mass specific (χ) and frequency dependent (χFD) magnetic susceptibility. There were higher concentration of Pb (up to 4,700 ppm), Cu and Ag (both up to 100 ppm) in the Utín soils observed mostly in upper part of the soil profile. Arsenic contamination occurs in entire soil profile with average concentration about 3,000 ppm. In the Dlouhá Ves soils, the higher concentrations of Ag, Cu (about 500 ppm) and As (near 13,000 ppm; 70 cm) occur rather in bottom horizons of soil profile. Noticeable positive correlations of LOI vs. Pb (r = 0.96), Cu (r = 0.90), Fe (r = 0.87), Ag (r = 0.94) together with SEA values from Utín soils indicate that studied elements have in fraction bound to organic matter and sulphides have a tendency to be bound rather to organic compounds. This is the main difference between the two localities because the studied elements in Dlouhá Ves soils have in the same fraction tendency to be bound just to sulphides. In addition to presupposed higher pedogenesis degree in distinctly older Utín soils, the difference between two soil profiles is acidobazic conditions in Dlouhá Ves soil profile, in which the pH/KCl is very low. Decomposition of organic matter is also slower in this environment. The lower degree of pedogenesis in Dlouhá Ves is also supported by in average lower values of frequency dependent magnetic susceptibility (χFD = 1–5 %).

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Detection of the pedogenic magnetic fraction in volcanic soils developed on basalts using frequency-dependent magnetic susceptibility: comparison of two instruments

Geophysical Journal International ◽

10.1093/gji/ggx037 ◽

2017 ◽

Vol 209 (2) ◽

pp. 654-660 ◽

Cited By ~ 4

Author(s):

Hana Grison ◽

Eduard Petrovsky ◽

Ales Kapicka ◽

Hana Hanzlikova

Keyword(s):

Magnetic Susceptibility ◽

Soil Profile ◽

Magnetic Particles ◽

Chemical Properties ◽

Coarse Fraction ◽

Magnetic Fraction ◽

Dual Frequency ◽

Frequency Dependent ◽

Specific Magnetic Susceptibility ◽

Frequency Meter

Abstract In studies of the magnetic properties of soils, the frequency-dependent magnetic susceptibility percentage (χFD%) is often used for the identification of ultrafine magnetically superparamagnetic/stable single-domain (SP/SSD) particles. This parameter is commonly used as an indicator for increased pedogenesis. In strongly magnetic soils, the SP/SSD magnetic signal (mostly bio-pedogenic) may be masked by lithological signals; making pedogenesis hard to detect. In this study, we compare results for the detection of ultrafine SP/SSD magnetic particles in andic soils using two instruments: a Bartington MS2B dual-frequency meter and an AGICO Kappabridge MFK1-FA. In particular, the study focuses on the effect of pedogenesis by investigating the relationship between specific soil magnetic and chemical properties (soil organic carbon and pHH2O). The values of χFD% obtained with the MS2B varied from 2.4 to 5.9 per cent, and mass-specific magnetic susceptibility (χLF) from 283 to 1688 × 10−8 m3 kg−1, while values of χFD% and χLF obtained with the MFK1-FA varied from 2.7 to 8.2 per cent and from 299 to 1859 × 10−8 m3 kg−1, respectively. Our results suggest that the detection of the SP/SSD magnetic fraction can be accomplished by comparing relative trends of χFD% along the soil profile. Moreover, the discrimination between bio-pedogenic and lithogenic magnetic contributions in the SP/SSD fraction is possible by comparing the χFD% and χLF data determined in the fine earth (<2 mm) and the coarse fraction (4–10 mm) samples down the soil profile.

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Multi-Proxy Study of a Holocene Soil Profile from Romania and Its Relevance for Speleothem Based Paleoenvironmental Reconstructions

Minerals ◽

10.3390/min11080873 ◽

2021 ◽

Vol 11 (8) ◽

pp. 873

Author(s):

Luchiana Faur ◽

Virgil Drăgușin ◽

Daniela Dimofte ◽

Ferenc Lázár Forray ◽

Maria Ilie ◽

...

Keyword(s):

Organic Matter ◽

Soil Profile ◽

Stable Carbon Isotopes ◽

Fine Fraction ◽

Clay Mineralogy ◽

Luminescence Dating ◽

Interglacial Period ◽

Last Interglacial ◽

Deep Soil ◽

Two Samples

In this study, we describe a sedimentary deposit situated above Ascunsă Cave (SW Romania) that should be in depositional connection with coeval stalagmites from the cave. We excavated a 2.5 m deep soil profile and took contiguous bulk samples every 5 cm. Soil samples were analyzed for clay mineralogy, grain size, chemical composition, magnetic susceptibility, and stable carbon isotopes. Radiocarbon dating revealed that the soil is of Holocene age, and presents a depositional hiatus between 5.4 and 2.3 thousand years before the present. Due to the open system behavior of soils and mobility of organic matter, a few hundred years of uncertainty should be considered for the duration of this hiatus. The fine fraction is dominated by silt, while the clay mineralogical association is made of illite, chlorite, kaolinite, vermiculite, and illite–vermiculite and illite–chlorite mixed layered minerals. The sediment source of this soil is represented by a nearby mélange complex, as well as by an underlying terra rossa-type soil. As this latter type of soil is widespread in our study area, we performed luminescence dating on two samples from a representative location close to our site and it appears that this type of Mediterranean soil was formed during the Last Interglacial period. δ13C variability in soil organic matter and a stalagmite from the cave are comparing well, and could help future studies identify modifications in isotopic fractionation processes within the cave.

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Geochemical and Mineralogical Characteristics of Airborne Particulate Matter in Relation to Human Health Risk

Minerals ◽

10.3390/min10100866 ◽

2020 ◽

Vol 10 (10) ◽

pp. 866 ◽

Cited By ~ 1

Author(s):

Marzena Rachwał ◽

Małgorzata Wawer ◽

Mariola Jabłońska ◽

Wioletta Rogula-Kozłowska ◽

Patrycja Rogula-Kopiec

Keyword(s):

Magnetic Susceptibility ◽

Particulate Matter ◽

Human Health ◽

Magnetic Particles ◽

Rank Order ◽

Human Health Risk ◽

Airborne Particulate Matter ◽

Ambient Air ◽

Average Concentration ◽

Health Indices

The main objective of this research was the determination of the geochemical and mineralogical properties of particulate matter: TSP (total suspended particles) and, especially PM1 (particles with aerodynamic diameter not greater than 1 µm) suspended in the air of a selected urban area in southern Poland. Identification of the emission sources of metals and metalloids bound in TSP and PM1 as well as the assessment of potential risk of urban ambient air to human health using hazard indices was an additional aim of this investigation. The daily TSP and PM1 quartz fiber filters collected during heating season were subjected to mass magnetic susceptibility (χ) measurements, SEM (Scanning Electron Microscopy) observations and geochemical analyses. Obtained results revealed that the concentration of TSP and PM1 well correlated with their mass-specific magnetic susceptibility. The good relationship between the PM concentration and χ suggests that magnetic susceptibility measurements can be a good proxy of low-level atmospheric dust pollution. The rank order of potentially toxic elements (PTE) based on average concentration was Ba > Zn > Al > Fe > Pb > Mn > Ti > Cu > Cr > Ni >As > Cd > V > Tl, both for TSP and PM1. PM1/TSP ratios for PTE concentrations and χ were around or slightly above unity, which indicated that PM1 was the main carrier of PTE (with the exception of cadmium, copper and lead) and technogenic magnetic particles. The non-carcinogenic and carcinogenic risks were confirmed by very high values of human health indices.

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The Relationship between Soil Electrical Parameters and Compaction of Sandy Clay Loam Soil

Agriculture ◽

10.3390/agriculture11020114 ◽

2021 ◽

Vol 11 (2) ◽

pp. 114

Author(s):

Katarzyna Pentoś ◽

Krzysztof Pieczarka ◽

Kamil Serwata

Keyword(s):

Electrical Conductivity ◽

Magnetic Susceptibility ◽

Precision Agriculture ◽

Soil Compaction ◽

Soil Layer ◽

Soil Parameters ◽

Soil Electrical Conductivity ◽

Electrical Parameters ◽

Management Zones ◽

Additional Information

Soil spatial variability mapping allows the delimitation of the number of soil samples investigated to describe agricultural areas; it is crucial in precision agriculture. Electrical soil parameters are promising factors for the delimitation of management zones. One of the soil parameters that affects yield is soil compaction. The objective of this work was to indicate electrical parameters useful for the delimitation of management zones connected with soil compaction. For this purpose, the measurement of apparent soil electrical conductivity and magnetic susceptibility was conducted at two depths: 0.5 and 1 m. Soil compaction was measured for a soil layer at 0–0.5 m. Relationships between electrical soil parameters and soil compaction were modelled with the use of two types of neural networks—multilayer perceptron (MLP) and radial basis function (RBF). Better prediction quality was observed for RBF models. It can be stated that in the mathematical model, the apparent soil electrical conductivity affects soil compaction significantly more than magnetic susceptibility. However, magnetic susceptibility gives additional information about soil properties, and therefore, both electrical parameters should be used simultaneously for the delimitation of management zones.

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Source and Health Risk Assessment of Heavy Metals in Soil–Ginger System in the Jing River Basin of Shandong Province, North China

International Journal of Environmental Research and Public Health ◽

10.3390/ijerph18136749 ◽

2021 ◽

Vol 18 (13) ◽

pp. 6749

Author(s):

Songtao Wang ◽

Zongjun Gao ◽

Yuqi Zhang ◽

Hairui Zhang ◽

Zhen Wu ◽

...

Keyword(s):

Heavy Metals ◽

Risk Assessment ◽

River Basin ◽

Soil Profile ◽

Pollution Index ◽

Potential Ecological Risk ◽

Average Concentration ◽

Anthropogenic Factors ◽

Multivariate Statistical ◽

Cr Content

This study investigated the characteristics and sources of heavy metals in a soil–ginger system and assessed their health risks. To this end, 321 topsoil samples and eight soil samples from a soil profile, and 18 ginger samples with root–soil were collected from a ginger-planting area in the Jing River Basin. The average concentration of heavy metals in the topsoil followed the order: Cr > Zn > Pb > Ni > Cu > As > Cd > Hg. In the soil profile, at depths greater than 80 cm, the contents of Cr, Ni, and Zn tended to increase with depth, which may be related to the parent materials, whereas As and Cu contents showed little change. In contrast, Pb content decreased sharply from top to bottom, which may be attributable to external environmental and anthropogenic factors. Multivariate statistical analysis showed that Cr, Ni, Cu, Zn, and Cd contents in soil are affected by natural sources, Pb and As contents are significantly affected by human activities, and Hg content is affected by farmland irrigation. Combined results of the single pollution index (Pi), geo-accumulation index (Igeo), and potential ecological risk assessment (Ei and RI) suggest that soil in the study area is generally not polluted by heavy metals. In ginger, Zn content was the highest (2.36 mg/kg) and Hg content was the lowest (0.0015 mg/kg). Based on the bioconcentration factor, Cd and Zn have high potential for enrichment in ginger. With reference to the limit of heavy metals in tubers, Cr content in ginger exceeds the standard in the study area. Although Cr does not accumulate in ginger, Cr enrichment in soil significantly increases the risk of excessive Cr content in ginger.

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Influence of Physicochemical Characteristics of Bean Crop Soil in Trichoderma spp. Development

Agronomy ◽

10.3390/agronomy11020274 ◽

2021 ◽

Vol 11 (2) ◽

pp. 274

Author(s):

Sara Mayo-Prieto ◽

Alejandra J. Porteous-Álvarez ◽

Sergio Mezquita-García ◽

Álvaro Rodríguez-González ◽

Guzmán Carro-Huerga ◽

...

Keyword(s):

Organic Matter ◽

Sandy Loam ◽

C:N Ratio ◽

Physicochemical Characteristics ◽

Soil Parameters ◽

Physical Parameters ◽

Silt Loam ◽

Chemical Methods ◽

Trichoderma Spp ◽

Trichoderma Species

Spain has ranked 6th on the harvested bean area and 8th in bean production in the European Union (EU). The soils of this area have mixed silt loam and sandy loam texture, with moderate clay content, neutral or acidic pH, rich in organic matter and low carbonate levels, providing beans with high water absorption capacity and better organoleptic qualities after cooking. Similar to other crops, it is attacked by some phytopathogens. Hitherto, chemical methods have been used to control these organisms. However, with the Reform of the Community Agrarian Policy in the EU, the number of authorized plant protection products has been reduced to prevail food security, as well as to be sustainable in the long term, giving priority to the non-chemical methods that use biological agents, such as Trichoderma. This study aimed to investigate the relative importance of various crop soil parameters in the adaptation of Trichoderma spp. autoclaved soils (AS) and natural soils (NS) from the Protected Geographical Indication (PGI) “Alubia La Bañeza—León” that were inoculated with Trichoderma velutinum T029 and T. harzianum T059 and incubated in a culture chamber at 25 °C for 15 days. Their development was determined by quantitative PCR. Twelve soil samples were selected and analyzed from the productive zones of Astorga, La Bañeza, La Cabrera, Esla-Campos and Páramo. Their physicochemical characteristics were different by zone, as the texture of soils ranged between sandy loam and silt loam and the pH between strongly acid and slightly alkaline, as well as the organic matter (OM) concentration between low and remarkably high. Total C and N concentrations and their ratio were between medium and high in most of the soils and the rest of the micronutrients had an acceptable concentration except for Paramo’s soil. Both Trichoderma species developed better in AS than in NS, T. velutinum T029 grew better with high levels of OM, total C, ratio C:N, P, K, Fe, and Zn than T. harzianum T059 in clay soils, with the highest values of cation exchange capacity (CEC), pH, Ca, Mg and Mn. These effects were validated by Canonical Correlation Analysis (CCA), texture, particularly clay concentration, OM, electrical conductivity (EC), and pH (physical parameters) and B and Cu (soil elements) are the main factors explaining the influence in the Trichoderma development. OM, EC, C:N ratio and Cu are the main soil characteristics that influence in T. velutinum T029 development and pH in the development of T. harzianum T059.

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Chemical and Phytocoenological Characteristics of Two Different Slovak Peatlands

Plants ◽

10.3390/plants10071290 ◽

2021 ◽

Vol 10 (7) ◽

pp. 1290

Author(s):

Danica Fazekašová ◽

Gabriela Barančíková ◽

Juraj Fazekaš ◽

Lenka Štofejová ◽

Ján Halas ◽

...

Keyword(s):

Organic Matter ◽

Soil Profile ◽

Agricultural Land ◽

Nitrogen Supply ◽

Point Of View ◽

Statistical Testing ◽

Plant Residues ◽

Soil Reaction ◽

Chemical Parameters

This paper presents the results of pedological and phytocoenological research focused on the detailed research of chemical parameters (pH, organic carbon, and nutrients), risk elements (As-metalloid, Cd, Co, Cr, Cu, Ni, Pb, and Zn), and species composition of the vegetation of two different peatlands on the territory of Slovakia—Belianske Lúky (a fen) and Rudné (a bog). Sampling points were selected to characterize the profile of the organosol within the peatland, the soil profile between the peatland and the agricultural land, and the soil profile of the outlying agricultural land, which is used as permanent grassland. Based on phytocoenological records, a semi-quantitative analysis of taxa in accordance with the Braun–Blanquet scale was performed. The study revealed that the thickness of the peat horizon of the fen in comparison with the bog is very low. In terms of the quality of organic matter, the monitored peatlands are dominated by fresh plant residues such as cellulose and lignin. Differences between individual types of peatlands were also found in the soil reaction and the supply of nitrogen to the organic matter of peat. The values of the soil exchange reaction were neutral on the fen, as well as slightly alkaline but extremely low on the bog. A significantly higher nitrogen supply was found in the organic matter of the fen in contrast to the bog. At the same time, extremely low content of accessible P and an above-limit content of As in the surface horizons were also found on the fen. From the phytocoenological point of view, 22 plant species were identified on the fen, while only five species were identified on the bog, which also affected the higher diversity (H’) and equitability (e). The results of the statistical testing confirmed the diversity of the studied peatlands and the different impact of environmental variables on plant diversity.

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Soil stripping and replacement for the rehabilitation of bauxite-mined land at Weipa. I. Initial changes to soil organic matter and related parameters

Soil Research ◽

10.1071/sr99043 ◽

2000 ◽

Vol 38 (2) ◽

pp. 345 ◽

Cited By ~ 18

Author(s):

G. D. Schwenke ◽

D. R. Mulligan ◽

L. C. Bell

Keyword(s):

Organic Matter ◽

Soil Organic Matter ◽

Field Experiments ◽

Surface Soil ◽

Soil Disturbance ◽

Microbial Biomass C ◽

Low Grade ◽

Double Pass ◽

Organic C ◽

The Difference

At Weipa, in Queensland, Australia, sown tree and shrub species sometimes fail to establish on bauxite-mined land, possibly because surface-soil organic matter declines during soil stripping and replacement. We devised 2 field experiments to investigate the links between soil rehabilitation operations, organic matter decline, and revegetation failure. Experiment 1 compared two routinely practiced operations, dual-strip (DS) and stockpile soil, with double-pass (DP), an alternative method, and subsoil only, an occasional result of the DS operation. Other treatments included variations in stripping-time, ripping-time, fertiliser rate, and cultivation. Dilution of topsoil with subsoil, low-grade bauxite, and ironstone accounted for the 46% decline of surface-soil (0–10 cm) organic C in DS compared with pre-strip soil. In contrast, organic C in the surface-soil (0–10 cm) of DP plots (25.0 t/ha) closely resembled the pre-strip area (28.6 t/ha). However, profile (0–60 cm) organic C did not differ between DS (91.5 t/ha), DP (107 t/ha), and pre-strip soil (89.9 t/ha). Eighteen months after plots were sown with native vegetation, surface-soil (0–10 cm) organic C had declined by an average of 9% across all plots. In Experiment 2, we measured the potential for post-rehabilitation decline of organic matter in hand-stripped and replaced soil columns that simulated the DS operation. Soils were incubated in situ without organic inputs. After 1 year’s incubation, organic C had declined by up to 26% and microbial biomass C by up to 61%. The difference in organic C decline between vegetated replaced soils (Expt 1) and bare replaced soils (Expt 2) showed that organic inputs affect levels of organic matter more than soil disturbance. Where topsoil was replaced at the top of the profile (DP) and not ploughed, inputs from volunteer native grasses balanced oxidation losses and organic C levels did not decline.

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Heteronuclear Ni(ii)–Ln(iii) (Ln = La, Pr, Tb, Dy) complexes: synthesis and single-molecule magnet behaviour

Dalton Transactions ◽

10.1039/c5dt04102c ◽

2016 ◽

Vol 45 (8) ◽

pp. 3616-3626 ◽

Cited By ~ 25

Author(s):

Apoorva Upadhyay ◽

Chinmoy Das ◽

Stuart K. Langley ◽

Keith S. Murray ◽

Anant K. Srivastava ◽

...

Keyword(s):

Magnetic Susceptibility ◽

Schiff Base ◽

Crystal Structures ◽

Single Molecule ◽

Schiff Base Ligand ◽

Ac Magnetic Susceptibility ◽

Frequency Dependent ◽

Single Molecule Magnet

The crystal structures are reported for three heterometallic Ni2Ln and a Ni2Dy2 complex, using the Schiff base ligand 2-methoxy-6-[(E)-phenyliminomethyl] phenol. Detailed dc and ac magnetic susceptibility studies were reported for all the complexes. The complexes 3 and 4 shows frequency dependent out-of-phase susceptibility signals.

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An assessment of the quality of forage from its cell-wall content and amount of cell wall digested

The Journal of Agricultural Science ◽

10.1017/s0021859600026241 ◽

1972 ◽

Vol 78 (3) ◽

pp. 355-362 ◽

Cited By ~ 16

Author(s):

K. W. Moir

Keyword(s):

Cell Wall ◽

Organic Matter ◽

Ammonium Oxalate ◽

Physical Structure ◽

Tropical Species ◽

Average Amount ◽

Lignin Concentration ◽

Digestible Organic Matter ◽

The Difference

SUMMARYGrasses and legumes comprising poor to good quality temperate and tropical species were fed to either cattle or sheep in 36 digestibility experiments. Cell wall in these forages was the ash-free and protein-free residue after sequential extraction with acidpepsin, organic solvents and either water for grasses or ammonium oxalate for legumes. The average amount of cell wall digested per 100 g forage OM was 40·0±0·59 g in grasses and 19·8±1·85 g in legumes. It was considered that within grasses and within legumes the physiology of ruminant digestion, rather than forage quality, was the main determinant of the average amount of cell wall digested and the difference between grasses and legumes was due to interaction of the ruminant digestion process with the physical structure of the cell wall. Of forage factors governing variation about the physiological average, the total cell wall had some effect on the amount of cell wall digested, but the lignin concentration in the cell wall had no effect.Among grasses and legumes the average, apparently undigested, protein-free non-cell-wall component was 6·2±0·13 g per 100 g forage OM. This component and digestible protein relative to total protein varied among different sets of data. It was concluded that only the component of digestible organic matter which was governed by the relative proportions of cell walls and cellular contents was predictable from chemical composition. It was considered that selection in plant breeding should be based on both digestible cell wall and cell-wall content instead of digestible organic matter.

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