Heavy Metal Concentration in Seawater at Villa Beach, Iloilo City, Philippines

2014 ◽  
Vol 11 (1) ◽  
Author(s):  
BRIAN GIL S. SARINAS
Keyword(s):  
Heavy Metals ◽  
Heavy Metal Concentration ◽  
The Philippines ◽  
Arts And Sciences ◽  
Ph Values ◽  
Physiochemical Parameters ◽  
Flame Atomic Absorption ◽  
Flame Atomic Absorption Spectrophotometer ◽  
The Mean ◽  
Seawater Samples

This study was conducted due to the dearth of studies on heavy metals atVilla Beach, Iloilo City. It aimed to determine the presence and quantities ofavailable heavy metals specifically cadmium, chromium and lead in the watercolumn (surface, middle and bottom). Water physiochemical parameters weredetermined such as pH, salinity and temperature. Five sampling areas wereidentified in the shores of Villa Beach. One liter was collected in each layerof each sampling area for a total of 15 seawater samples and was immediatelytransported to the College of Arts and Sciences-Analytical Service Laboratory ofthe University of the Philippines Visayas, Miag-ao, Iloilo for the quantificationof heavy metals through flame atomic absorption spectrophotometer (FAAS). The pH values range from 7.513-7.933, 10.6-11.566 ppm for salinity and 27.5-31.233 °C for five sampling areas. Average dissolved chromium and lead werehighest at station four with 0.545 mg/L and 0.771 mg/L, respectively. Averagecadmium was highest at station one with 0.021 mg/L. The mean of Pb > Cr >Cd < Pb in the water column of the five sampling areas but was not significant. Available cadmium, chromium and lead exceeded the permissive value set by DENR AO No. 34 (1990). This study provides information and awareness tothe public about the present available heavy metals in Villa Beach, Iloilo City. Keywords - Heavy metals, cadmium, chromium, lead, flame atomic absorptionspectrophotometry, Philippines

scholarly journals Evaluation of Heavy metals pollution around Kano municipal solid waste Dumpsites, Kano state, Nigeria

2021 ◽  
Vol 6 (1) ◽  
pp. 146-152
Author(s):  
M. Z. Karkana ◽  
◽  
Mujahid Ajah Matazu
Keyword(s):  
Heavy Metals ◽  
Municipal Solid Waste ◽  
Solid Waste ◽  
Soil Samples ◽  
Pollution Indices ◽  
Surface Soils ◽  
Flame Atomic Absorption ◽  
Flame Atomic Absorption Spectrophotometer ◽  
The Mean ◽  
Mean Concentration

The research was conducted to assess the level of heavy metals contamination using single and integrated pollution indices in soils around municipal solid waste dumpsites of Kano Metropolis, Kano State, Nigeria. Forty two soil samples were collected from seven municipal solid waste dumpsites of Kano metropolis using circular plot method. A stainless hand auger at a depth of (0 to 15) top soils and sub-surface soils (15-30cm) depth were collected and analyzed with Flame atomic absorption spectrophotometer to determine the heavy metal concentration. The mean concentration (mg/kg) of heavy metals from the depth of (15-30 cm) were observed to follow a decreasing order Pb (7.71)>Zn (0.50) > Ni (0.45) > Cr (0.31) > Cd (0.025) while for surface soils (0- 15cm) the mean concentration were in the following order: Pb (1.77) > Ni (0.49) > Zn (0.30) > Cr (0.27) > Cd (0.012).The results showed that calculated CF and Er recorded that investigated soil samples are uncontaminated with Zn, Pb, Cd, Cr and Pb and Ni. The pollution load index (PLI) was less than unity showing that there was minimum pollution in the studied dumpsite. The potential ecological risk showed that soil samples were in the class of low contaminated with the studied heavy metals. The results showed that concentrations of heavy metals of soil samples from dumpsites location at waste dumpsites of Kano Metropolis were within limits of European Union (2002) standards. Keywords: Heavy metals, single and integrated pollution indices Kano, Municipal dumpsites

Optimized atomic absorption spectrophotometry of calcium in erythrocytes.

1987 ◽  
Vol 33 (11) ◽  
pp. 2004-2007 ◽  
Author(s):  
S Nomoto ◽  
S Shoji
Keyword(s):  
Hydrochloric Acid ◽  
Atomic Absorption ◽  
Atomic Absorption Spectrophotometry ◽  
Graphite Tube ◽  
Optimum Conditions ◽  
Absorption Spectrophotometry ◽  
Flame Atomic Absorption ◽  
Flame Atomic Absorption Spectrophotometer ◽  
The Mean ◽  
Mean Concentration

Abstract We sought to establish optimum conditions for measuring calcium in erythrocytes by atomic absorption spectrophotometry. The conditions we selected are as follows. Wash one volume of fresh heparin-treated packed cells once with 30 volumes of isotonic buffered saline (pH 7.4) at a temperature somewhat exceeding 25 degrees C. Dilute the washed packed cells 10-fold with 12 mmol/L hydrochloric acid, and analyze the supernate for calcium. Measure the hematocrit of the washed packed cells, then analyze an aliquot of them for calcium, using a computer-readout type of flame or a non-flame atomic absorption spectrophotometer equipped with a pyrocoated graphite tube. The temperature program is 1000 degrees C for ashing [corrected] and 1800 degrees C for the atomizing cycle. Intraday and day-to-day reproducibility of the assay was 6.55% and 8.19%, respectively, at the mean concentration of calcium in the erythrocytes of healthy adults, which is 4.30 mumol/L.

Spatial Distribution and Sources of Heavy Metal Pollution of Surface Dust in Taiyuan, China

2015 ◽  
Vol 737 ◽  
pp. 503-507
Author(s):  
Yong Zhang ◽  
Jing Xia Chen ◽  
Jun Qiu Zhang ◽  
Ying Te Wang
Keyword(s):  
Heavy Metals ◽  
Industrial Area ◽  
Shanxi Province ◽  
Surface Dust ◽  
Flame Atomic Absorption ◽  
Flame Atomic Absorption Spectrophotometer ◽  
Development Area ◽  
High Concentrations ◽  
Functional Areas ◽  
Different Levels

The concentrations of heavy metals (Cr, Cu, Ni, Pb and Mn) were determined using flame atomic absorption spectrophotometer after digested with four acids. The samples were collected from seven kinds of different functional areas in Taiyuan, China. The concentration of the heavy metals were found in Taiyuan is higher than the soil background values in Shanxi Province, which appeared different levels of accumulation. High concentrations of Cr, Ni, Mn were found in the samples from industrial area and Cu was noted from economic development area. The correlational analysis and principle component analysis showed that the heavy metals of surface dust in Taiyuan were mainly influenced by industrial activities.

scholarly journals Bioaccumulation of Some Heavy Metals in Ayre Fish (Sperata Aor Hamilton, 1822), Sediment and Water of Dhaleshwari River in Dry Season

2012 ◽  
Vol 40 (1) ◽  
pp. 147-153 ◽  
Author(s):  
Abu Tweb Abu Ahmed ◽  
Suman Mandal ◽  
Didarul Alam Chowdhury ◽  
Abu Rayhan M Tareq ◽  
M Mizanur Rahman
Keyword(s):  
Heavy Metals ◽  
Nitric Acid ◽  
Atomic Absorption ◽  
Water Samples ◽  
Dry Weight ◽  
Acid Digestion ◽  
Fish Organs ◽  
Flame Atomic Absorption ◽  
Flame Atomic Absorption Spectrophotometer ◽  
Nitric Acid Digestion

The present study was carried out to determine the level of bioaccumulation of some heavy metals in a freshwater fish Ayre (Sperata aor Hamilton, 1822) collected from Rajfulbaria (23°48?56.36? N and 90°14?54.04? E) of  Dhaleshwari river. Four heavy metals, namely chromium (Cr), copper (Cu), lead (Pb), and cadmium (Cd) were selected for this study. Metal concentrations were   determined by Flame Atomic Absorption Spectrophotometer after nitric acid  digestion of samples. The concentrations of accumulated heavy metals in fish were  also compared with the concentrations of metals in the sediments and waters of  that river. The level of bioaccumulations in different organs of S. aor were determined separately and compared among them. Average bioaccumulation levels  in S. aor were Cr: 1.458 mg/kg, Cu: 31.500 mg/kg, Pb: 18.776 mg/kg and Cd:  0.487 mg/kg of dry weight. The levels of heavy metals in sediments were Cr: 27.393 mg/kg, Cu: 37.450 mg/kg, Pb: 15.797 mg/kg and Cd: 2.083 mg/kg, and in water were Cr: 0.130 ppm, Cu: 0.000 ppm, Pb: 0.201 ppm and Cd: 0.001 ppm.The bioaccumulation of these four heavy metals in fish organs, sediment and  water samples were also compared with FAO approved standard levels and other  related studies, and found that the levels of bioaccumulation in the Dhaleshwari river exceeded all the standard levels. DOI: http://dx.doi.org/10.3329/bjz.v40i1.12904 Bangladesh J. Zool. 40(1):147-153, 2012

scholarly journals Non-carcinogenic and Carcinogenic Risk Assessment of Heavy Metals Exposure to Indoor Dust in Kathmandu, Nepal

2021 ◽  
Vol 42 (1) ◽  
pp. 16-28
Author(s):  
Sulakshya Bhandari ◽  
Sudarshana Shakya ◽  
Bijaya Adhikari ◽  
Mahesh Shrestha ◽  
Bindra Devi Shakya ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Land Use ◽  
Hazard Quotient ◽  
Heavy Traffic ◽  
Hazard Index ◽  
Carcinogenic Risk ◽  
Indoor Dust ◽  
Metal Exposure ◽  
Flame Atomic Absorption ◽  
Flame Atomic Absorption Spectrophotometer

The present study was carried out to assess the contamination of heavy metals in indoor household dust of Kathmandu, Nepal, and its adverse effect on the indoor environment and human health. The concentrations of four heavy metals (Cd, Cr, Ni, and Pb) in a total of ninety-three (N = 93) indoor dust samples collected from four different types of land use zones viz., commercial, heavy traffic, residential, and control (undisturbed) of Kathmandu were determined by the flame atomic absorption spectrophotometer (FAAS). The mean concentrations of Cd, Cr, Ni, and Pb in indoor dust samples over the study zones were 0.89, 158.1, 113.3, and 65.3 mg kg−1, respectively. The land use zones showed the various degree of metal contamination in indoor dust ranging from moderate to considerable level. PLI showed a high pollution load in the monitored locations, indicating an alarming condition and the urgent need for immediate remedial actions. Hazard quotient (HQ) values indicated ingestion as the major pathway of indoor dust heavy metal exposure to children while the inhalation pathway remained dominant in adults. Hazard index (HI) values showed no probable non-carcinogenic risk of the heavy metals present in the indoor dust of Kathmandu. For carcinogenic health risk, TLCR values were found within the acceptable safe limit indicating no cancer risk for both the receptor groups.

scholarly journals Toxic Metal Contamination of Locally Produced Tobacco in Tamale Metropolis in Northern Region of Ghana

2020 ◽  
pp. 15-25
Author(s):  
G. E. Sebiawu ◽  
N. J. Mensah ◽  
E. Amankwah ◽  
S. Antwi-Akomeah
Keyword(s):  
Metal Contamination ◽  
Toxic Metal ◽  
Northern Region ◽  
Contamination Level ◽  
Permissible Limits ◽  
Flame Atomic Absorption ◽  
Flame Atomic Absorption Spectrophotometer ◽  
Tamale Metropolis ◽  
The Mean ◽  
Toxic Metal Contamination

The study was to analyze and determine the toxic metal contamination level of locally produced tobacco sold in the Tamale Metropolis of Northern region. The study was carried out at the Tamale Metropolis of Northern region of Ghana within a period of 12 months. The study focused on the analyses of five (5) toxic metal contaminants in twelve (12) variant locally produced tobacco sold in various spots within the Tamale Metropolis of Ghana. Toxic metals including As, Cd, Hg, Pb and Cr were analyzed using Flame Atomic Absorption Spectrophotometer. The mean recorded concentrations of As, Cd, Hg, Pb and Cr were respectively in the ranges of 0.184 ± 0.011 to 0.515 ± 0.015 µg/kg, 0.0420 ± 0.010 to 3.100 ± 0.000 µg/kg, 0.176 ± 0.016 to 0.291 ± 0.009 µg/kg, 1.169 ± 0.019 to 3.195 ± 0.019 µg/kg and 1.600 ± 0.116 to 3.880 ± 0.369 µg/kg. The mean concentrations of As and Pb measured in all samples tested were below their respective WHO permissible limits of 4.00 ppm and 10.00 ppm. In the case of Cd, mean concentrations measured for all locally produced tobacco tested were above the WHO permissible limits of 0.30 ppm. For the metal Hg, levels measured in 75% of tested locally produced tobacco were slightly above the WHO permissible limit of 0.20 µg/kg. Cr levels measured in 30% of tested locally produced tobacco were below the WHO permissible limits of 2.00 µg/kg. The very presence of these metals typically raises health concerns on consumption in the instances where their levels exceeded permissible guideline limits. The study revealed that Cd, Hg and Cr levels in the locally produced tobacco studied were found to exceed the WHO permissible limits for human consumption by plant uptake with As and Pb levels well below their permissible thresholds. The analyzed locally produced tobacco essentially poses a threat of heavy metal toxicity to consumers via bioaccumulation and bio-concentration in human tissues.

scholarly journals Assessment of Vegetables and Soils from Minjingu Village-Tanzania using WDXRF Technique

2019 ◽  
pp. 1-14
Author(s):  
Yusuf I. Koleleni ◽  
Seriver Tafisa
Keyword(s):  
Heavy Metals ◽  
Matrix Effects ◽  
Heavy Metal Concentration ◽  
Low Back ◽  
Energy Agency ◽  
X Ray ◽  
Vegetable Samples ◽  
Back Ground ◽  
Phosphate Mines ◽  
The Mean

Wavelength dispersive x-ray fluorescence (WDXRF) spectrometer was used to analyze heavy metal concentration in soils and vegetables. The soil and vegetable samples were randomly collected from Minjingu village of Manyara region in Tanzania. The results indicate the soils to be contaminated with heavy metals with mean concentrations of 53±0.4 For Mn, 40±0.2 for Sr, 2059±4.2 for Fe, 760±2.7 for Al, 12±0.3 for Cs and 4±0.04 for Ni in mg/kg which was above the Maximum Tolerable Limits (MTLs). Except Cl was below MDL. While vegetables recorded the mean concentrations of 60±1.2 for Mn, 68±0.1 for Sr, 620±2.36 for Fe, 284±1,13 for Al, 56±0.5 for Cs, 13±0.1 for Ni and 714±0.7 for Cl in mg/kg. The reference and experimental results of soil and vegetables revealed that the optimized machine has given the best results, where the experimental data was very close to the reference values The reference material of soil 7 and International Atomic Energy Agency (IAEA) 395 for vegetables shows the deviation of less than 2%.The Minimum Detection Limit (MDL) for vegetables and soil of the WDXRF spectrometer was obtained under low back ground for different matrix effects. There were high correlation coefficient of heavy metals in soils and vegetables at 99% level. The findings indicate that Minjingu soils and grown vegetables were highly contaminated with heavy metals mainly from soils and polluted air, at levels able to pose detrimental health effects to the consumers. Thus need of regular monitoring of the grown vegetables around phosphate mines is recommended.

scholarly journals Assessment of Anions and Heavy Metals in Sediments from River Sio, Busia County, Kenya

2019 ◽  
pp. 1-18
Author(s):  
K. O. Ondoo ◽  
J. K. Kiptoo ◽  
A. O. Onditi ◽  
S. M. Shivaji ◽  
J. K. Ogilo
Keyword(s):  
Heavy Metals ◽  
Surface Runoff ◽  
Anthropogenic Activities ◽  
Contamination Factor ◽  
Water Source ◽  
Pollution Load Index ◽  
Dry Season ◽  
Wet Season ◽  
Flame Atomic Absorption ◽  
Flame Atomic Absorption Spectrophotometer

Agricultural activities, discharge of raw sewage into farms and the rise in urbanization have greatly contributed to soil pollution. During the rainy season, surface runoff from farms find their way into water bodies and deposits these contaminants into Rivers and Lakes which poses a threat to both aquatic and terrestrial organisms that depend on that water source. The objective of this research was to determine the level of anions and heavy metals from sediments in River Sio, Busia County, Kenya. Five sediment samples were taken from five sampling points and the levels of anions and heavy metals in them determined. Anions were determined using Shimadzu 1800 UV/visible spectrophotometer while heavy metals were determined using Shimadzu 6200 flame atomic absorption spectrophotometer (AAS). Copper, lead and nickel were above the allowed WHO limits while cadmium was below detection limit. The levels of nitrates, phosphates and chlorides were higher during the wet season due to surface runoff that carried these nutrients from the farms and deposited them on the bottom of the River. The levels of heavy metals were high during the dry season due to evaporation of water from the River, leading to an increase in the analyte concentration during the dry season. High levels of copper and nickel in the sediments points to the use of herbicides and pesticides in farming and washing of vehicles and motorcycles on the banks of the River. According to Igeo nickel showed moderate pollution during the dry season. The contamination factor for lead was very high during the dry season, while pollution load index confirmed pollution due to anthropogenic activities in sampling sites 1 – 4 during the dry season and no pollution due to anthropogenic activities during the wet season.  The study recommends reduced use of inorganic fertilizers in order to save the River from the danger of eutrophication. Excessive use of agrochemicals such as herbicides and pesticides should be discouraged. In addition, pesticide leaching and the level of microbes in soil and sediments should be considered for further research

scholarly journals Bioakumulasi Logam Berat Pb dan Cu terhadap Penaeus merguiensis di Perairan Teluk Kelabat Bagian Dalam

2019 ◽  
Vol 22 (1) ◽  
pp. 1
Author(s):  
Andini Komalasari ◽  
Budi Afriyansyah ◽  
Muhammad Ihsan ◽  
Mohammad Agung Nugraha
Keyword(s):  
Heavy Metals ◽  
Atomic Absorption ◽  
Bioconcentration Factor ◽  
Sea Water ◽  
Average Concentration ◽  
Atomic Absorption Spectrophotometer ◽  
Average Ability ◽  
Flame Atomic Absorption ◽  
Flame Atomic Absorption Spectrophotometer ◽  
Penaeus Merguiensis

Bioaccumulation of Pb and Cu Heavy Metals to Penaeus merguiensis in the Waters of Inner Kelabat BayThe waters of Kelabat Bay has a wealth of marine resources that is quite important in supporting the economy of Bangka Regency and West Bangka Regency. The purpose of this research was to measure the concentration of heavy metals Pb and Cu (sea water, sediment, and Penaeus merguiensis) and measure the ability of Penaeus merguiensis in accumulating heavy metals Pb and Cu. Heavy metals Pb and Cu in Water, sediments and Penaeus merguiensis analyzed using Flame Atomic Absorption Spectrophotometer (Flame AAS). The results showed that concentration of heavy metals in water with an average range of Pb (0,1042-0,1748 mg/L) and Cu (0,000013-0,000021 mg/L). Average concentration of heavy metals in Pb sediments (7,15-7,73 mg/kg) and Cu (0,0016-0,00219 mg/kg ). Average concentration of Pb heavy metals in Penaeus merguiensis (1,34-1,54 mg/kg) and Cu (0,0003-0,00045 mg/kg). The average ability of Penaeus merguiensis in accumulating heavy metals Pb and Cu is 15,83 to water and 0,19 to sediment. The value of the Bioconcentration Factor is below 250 (FBK <250) so it falls into the low category. Penaeus merguiensis is more exposed to heavy metals dissolved in water than those released from sediment.Perairan Teluk Kelabat memiliki kekayaan sumber daya laut yang cukup penting dalam mendukung perekonomian Kabupaten Bangka dan Kabupaten Bangka Barat. Penelitian ini bertujuan untuk mengukur kandungan logam berat Pb dan Cu (air laut, sedimen, dan Penaeus merguiensis) dan mengukur kemampuan Penaeus merguiensis dalam mengakumulasi logam berat Pb dan Cu. Logam berat Pb dan Cu padaair, sedimen dan Penaeus merguiensisdianalisis menggunakan Flame Atomic Absorption Spectrophotometer (Flame AAS). Hasil penelitian menunjukkan bahwa konsentrasi logam berat dalam air dengan kisaran rata-rata Pb (0,1042-0,1748 mg/L) dan Cu (0,000013-0,000021 mg/L). Kisaran konsentrasi rata-rata logam berat dalam sedimen Pb (7,15-7,73 mg/kg) dan Cu (0,0016-0,00219 mg/kg). Kisaran konsentrasi rata-rata logam berat Pb di Penaeus merguiensis (1,34-1,54 mg/kg) dan Cu (0,0003-0,00045 mg/kg). Kemampuan rata-rata Penaeus merguiensis dalam mengakumulasi logam berat Pb dan Cu yaitu 15,83 terhadap air dan 0,19 terhadap sedimen. Nilai Faktor Biokonsentrasi tersebut di bawah 250 (FBK< 250) sehingga masuk dalam kategori rendah. Penaeus merguiensis lebih banyak terpapar logam berat yang terlarut dalam air daripada yang terlepas dari sedimen. 

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