SUMMARY OF STUDIES OF COREXIT DISPERSANT DROPLET IMPACT BEHAVIOR INTO OIL SLICKS AND DISPERSANT DROPLET EVAPORATION1,2
ABSTRACT This paper presents the results of two related studies concerning the aerial application of dispersants. The first study characterized the interactions of various sized Corexit 9500 and 9527 dispersant droplets with oil films of from 0.1 mm to 3.0 mm thickness. A film thickness of 0.1 mm was selected as the end point since this is the thinnest oil film recommended for the application of dispersants. The results of the high speed video droplet impact analysis showed that droplet diameters of 1,000 microns will not pass through an oil slick of 0.1 mm and mix with the underlying water column and that slick thickness of 0.2 mm or more will prevent even 2,000 micron diameter droplets from passing through the slick. These droplet sizes are considerably larger than the current ASTM Standard recommended droplet size of 300–500 microns for dispersant application. Additionally, it was shown that droplets that do pass through an oil slick will in whole or in part rise back up to the oil water interface. The second study characterized and compared the evaporation rates of Corexit 9500 and 9527 droplets with water over a 20 minute period under varying conditions of humidity and temperature. Under high evaporative conditions of high temperature (90° F) and low humidity (40%), droplets ranging from 0.25 to 1 uL showed 2–10% evaporative loss for Corexit 9500, 28–35% evaporative loss for Corexit 9527, and complete evaporative loss for water. When tested at low evaporative conditions of low temperature (40° F) and high humidity (95%), no evaporative loss was recorded for droplets of either 9500 or 9527, and water lost 18%.