scholarly journals Evaluation of Levels of Cadmium, Chromium and Lead in Bio Fertilizer from Various Feed Stocks and in Inorganic Fertilizers Used in Kenya

2020 ◽  
pp. 38-42
Author(s):  
J. G. Kinaichu ◽  
C. G. Nyaga ◽  
P. Njogu ◽  
E. G. Gatebe
Keyword(s):  
Heavy Metals ◽  
Cow Dung ◽  
Local Market ◽  
Inorganic Fertilizers ◽  
Flame Atomic Absorption ◽  
Flame Atomic Absorption Spectrophotometer ◽  
Chicken Litter ◽  
Lead Metal ◽  
Set Up ◽  
Pig Wastes

This study was conducted to compare the levels of selected heavy metals (Pb, Cr and Cd) in inorganic fertilizers and bio slurry from different feed stocks. Bio slurry samples from chicken droppings, cow dung and pig wastes were analyzed for levels of selected heavy metals. Inorganic fertilizers for analysis DAP, CAN, Urea and NPK were procured from local market in Juja town next to Jomo Kenyatta University of Agriculture and Technology (JKUAT). Bio slurry samples were collected from Githunguri Sub County in Kiambu County and from mini digesters set up at JKUAT. Concentrations of Cd, Cr, and Pb were determined by Flame Atomic Absorption Spectrophotometer (Shimadzu 6200). Inorganic fertilizers were found to contain detectable amounts of lead metal. DAP had the highest amount of Pb at 0.03 mg/l followed by CAN (0.02 mg/l) Urea and NPK had 0.01 mg/l each. Bio slurry samples contained lower amounts of lead which was below detectable limit in chicken litter and pig wastes. Inorganic fertilizers contained Cd with the highest levels being in the phosphorous containing fertilizers DAP (0.41 mg/l) and NPK (0.48 mg/l). All samples contained Cr with the highest in bio slurry samples being 0.09 mg/l in cow dung collected from Githunguri. CAN had the highest level of Cr (0.08 mg/l) among the inorganic fertilizers. Bio slurry is a better alternative fertilizer in reducing heavy metal uptake and their subsequent bioaccumulation.

scholarly journals Assessment of Some Toxic Metals in Ziziphora (Ziziphora persica) Obtained from Local Market in Lahijan, Northern Iran

2022 ◽  
Vol 19 (4) ◽  
Author(s):  
Ebrahim Alinia-Ahandani ◽  
Ali Akbar Malekirad ◽  
Habibollah Nazem ◽  
Mohammad Fazilati ◽  
Hossein Salavati ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Toxic Elements ◽  
The Body ◽  
Local Market ◽  
Northern Iran ◽  
Biochemical Pathways ◽  
Flame Atomic Absorption ◽  
Flame Atomic Absorption Spectrophotometer ◽  
Random Samples ◽  
Preliminary Study

: Heavy metals cause significant issues when people are exposed to many specific types of them. They can cause many disorders and affect the biochemical pathways in the body. Herbs are known as one of the richest sources of modern patented drugs, particularly in Iranian references. Many metals, particularly heavy metals, are toxic. Various studies have shown a higher level of heavy metals than standards in some countries like Iran, Pakistan, Egypt, and Nigeria. A preliminary study was conducted to determine some toxic elements in powdered Ziziphora (Ziziphora persica) collected from the local market in Lahijan city, northern Iran. Twenty random samples were gathered from various markets, and a flame atomic absorption spectrophotometer (FAAS) was used to detect some featured toxic elements, including copper (Cu), cadmium (Cd), lead (Pb), zinc (Zn), and mercury (Hg). The results showed higher Pb, Cd, and Hg levels than standards. Besides, Cu and Zn were detected to be lower than standards.

Spatial Distribution and Sources of Heavy Metal Pollution of Surface Dust in Taiyuan, China

2015 ◽  
Vol 737 ◽  
pp. 503-507
Author(s):  
Yong Zhang ◽  
Jing Xia Chen ◽  
Jun Qiu Zhang ◽  
Ying Te Wang
Keyword(s):  
Heavy Metals ◽  
Industrial Area ◽  
Shanxi Province ◽  
Surface Dust ◽  
Flame Atomic Absorption ◽  
Flame Atomic Absorption Spectrophotometer ◽  
Development Area ◽  
High Concentrations ◽  
Functional Areas ◽  
Different Levels

The concentrations of heavy metals (Cr, Cu, Ni, Pb and Mn) were determined using flame atomic absorption spectrophotometer after digested with four acids. The samples were collected from seven kinds of different functional areas in Taiyuan, China. The concentration of the heavy metals were found in Taiyuan is higher than the soil background values in Shanxi Province, which appeared different levels of accumulation. High concentrations of Cr, Ni, Mn were found in the samples from industrial area and Cu was noted from economic development area. The correlational analysis and principle component analysis showed that the heavy metals of surface dust in Taiyuan were mainly influenced by industrial activities.

scholarly journals Bioaccumulation of Some Heavy Metals in Ayre Fish (Sperata Aor Hamilton, 1822), Sediment and Water of Dhaleshwari River in Dry Season

2012 ◽  
Vol 40 (1) ◽  
pp. 147-153 ◽  
Author(s):  
Abu Tweb Abu Ahmed ◽  
Suman Mandal ◽  
Didarul Alam Chowdhury ◽  
Abu Rayhan M Tareq ◽  
M Mizanur Rahman
Keyword(s):  
Heavy Metals ◽  
Nitric Acid ◽  
Atomic Absorption ◽  
Water Samples ◽  
Dry Weight ◽  
Acid Digestion ◽  
Fish Organs ◽  
Flame Atomic Absorption ◽  
Flame Atomic Absorption Spectrophotometer ◽  
Nitric Acid Digestion

The present study was carried out to determine the level of bioaccumulation of some heavy metals in a freshwater fish Ayre (Sperata aor Hamilton, 1822) collected from Rajfulbaria (23°48?56.36? N and 90°14?54.04? E) of  Dhaleshwari river. Four heavy metals, namely chromium (Cr), copper (Cu), lead (Pb), and cadmium (Cd) were selected for this study. Metal concentrations were   determined by Flame Atomic Absorption Spectrophotometer after nitric acid  digestion of samples. The concentrations of accumulated heavy metals in fish were  also compared with the concentrations of metals in the sediments and waters of  that river. The level of bioaccumulations in different organs of S. aor were determined separately and compared among them. Average bioaccumulation levels  in S. aor were Cr: 1.458 mg/kg, Cu: 31.500 mg/kg, Pb: 18.776 mg/kg and Cd:  0.487 mg/kg of dry weight. The levels of heavy metals in sediments were Cr: 27.393 mg/kg, Cu: 37.450 mg/kg, Pb: 15.797 mg/kg and Cd: 2.083 mg/kg, and in water were Cr: 0.130 ppm, Cu: 0.000 ppm, Pb: 0.201 ppm and Cd: 0.001 ppm.The bioaccumulation of these four heavy metals in fish organs, sediment and  water samples were also compared with FAO approved standard levels and other  related studies, and found that the levels of bioaccumulation in the Dhaleshwari river exceeded all the standard levels. DOI: http://dx.doi.org/10.3329/bjz.v40i1.12904 Bangladesh J. Zool. 40(1):147-153, 2012

scholarly journals Non-carcinogenic and Carcinogenic Risk Assessment of Heavy Metals Exposure to Indoor Dust in Kathmandu, Nepal

2021 ◽  
Vol 42 (1) ◽  
pp. 16-28
Author(s):  
Sulakshya Bhandari ◽  
Sudarshana Shakya ◽  
Bijaya Adhikari ◽  
Mahesh Shrestha ◽  
Bindra Devi Shakya ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Land Use ◽  
Hazard Quotient ◽  
Heavy Traffic ◽  
Hazard Index ◽  
Carcinogenic Risk ◽  
Indoor Dust ◽  
Metal Exposure ◽  
Flame Atomic Absorption ◽  
Flame Atomic Absorption Spectrophotometer

The present study was carried out to assess the contamination of heavy metals in indoor household dust of Kathmandu, Nepal, and its adverse effect on the indoor environment and human health. The concentrations of four heavy metals (Cd, Cr, Ni, and Pb) in a total of ninety-three (N = 93) indoor dust samples collected from four different types of land use zones viz., commercial, heavy traffic, residential, and control (undisturbed) of Kathmandu were determined by the flame atomic absorption spectrophotometer (FAAS). The mean concentrations of Cd, Cr, Ni, and Pb in indoor dust samples over the study zones were 0.89, 158.1, 113.3, and 65.3 mg kg−1, respectively. The land use zones showed the various degree of metal contamination in indoor dust ranging from moderate to considerable level. PLI showed a high pollution load in the monitored locations, indicating an alarming condition and the urgent need for immediate remedial actions. Hazard quotient (HQ) values indicated ingestion as the major pathway of indoor dust heavy metal exposure to children while the inhalation pathway remained dominant in adults. Hazard index (HI) values showed no probable non-carcinogenic risk of the heavy metals present in the indoor dust of Kathmandu. For carcinogenic health risk, TLCR values were found within the acceptable safe limit indicating no cancer risk for both the receptor groups.

scholarly journals Evaluation of Heavy metals pollution around Kano municipal solid waste Dumpsites, Kano state, Nigeria

2021 ◽  
Vol 6 (1) ◽  
pp. 146-152
Author(s):  
M. Z. Karkana ◽  
◽  
Mujahid Ajah Matazu
Keyword(s):  
Heavy Metals ◽  
Municipal Solid Waste ◽  
Solid Waste ◽  
Soil Samples ◽  
Pollution Indices ◽  
Surface Soils ◽  
Flame Atomic Absorption ◽  
Flame Atomic Absorption Spectrophotometer ◽  
The Mean ◽  
Mean Concentration

The research was conducted to assess the level of heavy metals contamination using single and integrated pollution indices in soils around municipal solid waste dumpsites of Kano Metropolis, Kano State, Nigeria. Forty two soil samples were collected from seven municipal solid waste dumpsites of Kano metropolis using circular plot method. A stainless hand auger at a depth of (0 to 15) top soils and sub-surface soils (15-30cm) depth were collected and analyzed with Flame atomic absorption spectrophotometer to determine the heavy metal concentration. The mean concentration (mg/kg) of heavy metals from the depth of (15-30 cm) were observed to follow a decreasing order Pb (7.71)>Zn (0.50) > Ni (0.45) > Cr (0.31) > Cd (0.025) while for surface soils (0- 15cm) the mean concentration were in the following order: Pb (1.77) > Ni (0.49) > Zn (0.30) > Cr (0.27) > Cd (0.012).The results showed that calculated CF and Er recorded that investigated soil samples are uncontaminated with Zn, Pb, Cd, Cr and Pb and Ni. The pollution load index (PLI) was less than unity showing that there was minimum pollution in the studied dumpsite. The potential ecological risk showed that soil samples were in the class of low contaminated with the studied heavy metals. The results showed that concentrations of heavy metals of soil samples from dumpsites location at waste dumpsites of Kano Metropolis were within limits of European Union (2002) standards. Keywords: Heavy metals, single and integrated pollution indices Kano, Municipal dumpsites

scholarly journals Assessment of Anions and Heavy Metals in Sediments from River Sio, Busia County, Kenya

2019 ◽  
pp. 1-18
Author(s):  
K. O. Ondoo ◽  
J. K. Kiptoo ◽  
A. O. Onditi ◽  
S. M. Shivaji ◽  
J. K. Ogilo
Keyword(s):  
Heavy Metals ◽  
Surface Runoff ◽  
Anthropogenic Activities ◽  
Contamination Factor ◽  
Water Source ◽  
Pollution Load Index ◽  
Dry Season ◽  
Wet Season ◽  
Flame Atomic Absorption ◽  
Flame Atomic Absorption Spectrophotometer

Agricultural activities, discharge of raw sewage into farms and the rise in urbanization have greatly contributed to soil pollution. During the rainy season, surface runoff from farms find their way into water bodies and deposits these contaminants into Rivers and Lakes which poses a threat to both aquatic and terrestrial organisms that depend on that water source. The objective of this research was to determine the level of anions and heavy metals from sediments in River Sio, Busia County, Kenya. Five sediment samples were taken from five sampling points and the levels of anions and heavy metals in them determined. Anions were determined using Shimadzu 1800 UV/visible spectrophotometer while heavy metals were determined using Shimadzu 6200 flame atomic absorption spectrophotometer (AAS). Copper, lead and nickel were above the allowed WHO limits while cadmium was below detection limit. The levels of nitrates, phosphates and chlorides were higher during the wet season due to surface runoff that carried these nutrients from the farms and deposited them on the bottom of the River. The levels of heavy metals were high during the dry season due to evaporation of water from the River, leading to an increase in the analyte concentration during the dry season. High levels of copper and nickel in the sediments points to the use of herbicides and pesticides in farming and washing of vehicles and motorcycles on the banks of the River. According to Igeo nickel showed moderate pollution during the dry season. The contamination factor for lead was very high during the dry season, while pollution load index confirmed pollution due to anthropogenic activities in sampling sites 1 – 4 during the dry season and no pollution due to anthropogenic activities during the wet season.  The study recommends reduced use of inorganic fertilizers in order to save the River from the danger of eutrophication. Excessive use of agrochemicals such as herbicides and pesticides should be discouraged. In addition, pesticide leaching and the level of microbes in soil and sediments should be considered for further research

scholarly journals Bioakumulasi Logam Berat Pb dan Cu terhadap Penaeus merguiensis di Perairan Teluk Kelabat Bagian Dalam

2019 ◽  
Vol 22 (1) ◽  
pp. 1
Author(s):  
Andini Komalasari ◽  
Budi Afriyansyah ◽  
Muhammad Ihsan ◽  
Mohammad Agung Nugraha
Keyword(s):  
Heavy Metals ◽  
Atomic Absorption ◽  
Bioconcentration Factor ◽  
Sea Water ◽  
Average Concentration ◽  
Atomic Absorption Spectrophotometer ◽  
Average Ability ◽  
Flame Atomic Absorption ◽  
Flame Atomic Absorption Spectrophotometer ◽  
Penaeus Merguiensis

Bioaccumulation of Pb and Cu Heavy Metals to Penaeus merguiensis in the Waters of Inner Kelabat BayThe waters of Kelabat Bay has a wealth of marine resources that is quite important in supporting the economy of Bangka Regency and West Bangka Regency. The purpose of this research was to measure the concentration of heavy metals Pb and Cu (sea water, sediment, and Penaeus merguiensis) and measure the ability of Penaeus merguiensis in accumulating heavy metals Pb and Cu. Heavy metals Pb and Cu in Water, sediments and Penaeus merguiensis analyzed using Flame Atomic Absorption Spectrophotometer (Flame AAS). The results showed that concentration of heavy metals in water with an average range of Pb (0,1042-0,1748 mg/L) and Cu (0,000013-0,000021 mg/L). Average concentration of heavy metals in Pb sediments (7,15-7,73 mg/kg) and Cu (0,0016-0,00219 mg/kg ). Average concentration of Pb heavy metals in Penaeus merguiensis (1,34-1,54 mg/kg) and Cu (0,0003-0,00045 mg/kg). The average ability of Penaeus merguiensis in accumulating heavy metals Pb and Cu is 15,83 to water and 0,19 to sediment. The value of the Bioconcentration Factor is below 250 (FBK <250) so it falls into the low category. Penaeus merguiensis is more exposed to heavy metals dissolved in water than those released from sediment.Perairan Teluk Kelabat memiliki kekayaan sumber daya laut yang cukup penting dalam mendukung perekonomian Kabupaten Bangka dan Kabupaten Bangka Barat. Penelitian ini bertujuan untuk mengukur kandungan logam berat Pb dan Cu (air laut, sedimen, dan Penaeus merguiensis) dan mengukur kemampuan Penaeus merguiensis dalam mengakumulasi logam berat Pb dan Cu. Logam berat Pb dan Cu padaair, sedimen dan Penaeus merguiensisdianalisis menggunakan Flame Atomic Absorption Spectrophotometer (Flame AAS). Hasil penelitian menunjukkan bahwa konsentrasi logam berat dalam air dengan kisaran rata-rata Pb (0,1042-0,1748 mg/L) dan Cu (0,000013-0,000021 mg/L). Kisaran konsentrasi rata-rata logam berat dalam sedimen Pb (7,15-7,73 mg/kg) dan Cu (0,0016-0,00219 mg/kg). Kisaran konsentrasi rata-rata logam berat Pb di Penaeus merguiensis (1,34-1,54 mg/kg) dan Cu (0,0003-0,00045 mg/kg). Kemampuan rata-rata Penaeus merguiensis dalam mengakumulasi logam berat Pb dan Cu yaitu 15,83 terhadap air dan 0,19 terhadap sedimen. Nilai Faktor Biokonsentrasi tersebut di bawah 250 (FBK< 250) sehingga masuk dalam kategori rendah. Penaeus merguiensis lebih banyak terpapar logam berat yang terlarut dalam air daripada yang terlepas dari sedimen. 

Heavy Metal Concentration in Seawater at Villa Beach, Iloilo City, Philippines

2014 ◽  
Vol 11 (1) ◽  
Author(s):  
BRIAN GIL S. SARINAS
Keyword(s):  
Heavy Metals ◽  
Heavy Metal Concentration ◽  
The Philippines ◽  
Arts And Sciences ◽  
Ph Values ◽  
Physiochemical Parameters ◽  
Flame Atomic Absorption ◽  
Flame Atomic Absorption Spectrophotometer ◽  
The Mean ◽  
Seawater Samples

This study was conducted due to the dearth of studies on heavy metals atVilla Beach, Iloilo City. It aimed to determine the presence and quantities ofavailable heavy metals specifically cadmium, chromium and lead in the watercolumn (surface, middle and bottom). Water physiochemical parameters weredetermined such as pH, salinity and temperature. Five sampling areas wereidentified in the shores of Villa Beach. One liter was collected in each layerof each sampling area for a total of 15 seawater samples and was immediatelytransported to the College of Arts and Sciences-Analytical Service Laboratory ofthe University of the Philippines Visayas, Miag-ao, Iloilo for the quantificationof heavy metals through flame atomic absorption spectrophotometer (FAAS). The pH values range from 7.513-7.933, 10.6-11.566 ppm for salinity and 27.5-31.233 °C for five sampling areas. Average dissolved chromium and lead werehighest at station four with 0.545 mg/L and 0.771 mg/L, respectively. Averagecadmium was highest at station one with 0.021 mg/L. The mean of Pb > Cr >Cd < Pb in the water column of the five sampling areas but was not significant. Available cadmium, chromium and lead exceeded the permissive value set by DENR AO No. 34 (1990). This study provides information and awareness tothe public about the present available heavy metals in Villa Beach, Iloilo City. Keywords - Heavy metals, cadmium, chromium, lead, flame atomic absorptionspectrophotometry, Philippines

scholarly journals Horizontal and Vertical Distribution of Heavy Metals in Farm Produce and Livestock around Lead-Contaminated Goldmine in Dareta and Abare, Zamfara State, Northern Nigeria

2017 ◽  
Vol 2017 ◽  
pp. 1-12 ◽  
Author(s):  
O. E. Orisakwe ◽  
O. O. Oladipo ◽  
G. C. Ajaezi ◽  
N. A. Udowelle
Keyword(s):  
Heavy Metals ◽  
Hazard Quotient ◽  
Daily Intake ◽  
Kidney Tissue ◽  
Target Hazard Quotient ◽  
Flame Atomic Absorption ◽  
Flame Atomic Absorption Spectrophotometer ◽  
Lead Zinc ◽  
Farm Produce ◽  
Meat Samples

Background. Hitherto studies in response to the June 2010 lead poisoning, Zamfara State, Nigeria, have focused on clinical interventions without information on livestock and other metals.Objective. This study has investigated the distribution of heavy metals in farm produce and livestock around lead-contaminated goldmine in Dareta and Abare, Zamfara State, Nigeria.Methods. Vegetables, soil, water, blood, and different meat samples were harvested from goat, sheep, cattle, and chicken from Dareta, Abare, and Gusau communities. The samples were digested with 10 mL of a mix of nitric and perchloric acids; the mixture was then heated to dryness. Lead, cadmium, zinc, chromium, copper, magnesium, and nickel were analysed using flame Atomic Absorption Spectrophotometer. The daily intake, bioaccumulation factor, and target hazard quotient (THQ) were calculated.Results. Chicken bone-muscles from Dareta had the highest concentrations of lead, zinc, and nickel (28.2750, 16.1650, and 4.2700 mg/kg, resp.), while chicken brain had the highest levels of cadmium, magnesium (0.3800 and 67.5400 mg/kg), and chromium (6.1650 mg/kg, kidney tissue inclusive).Conclusion. In addition to lead, cadmium may also be of concern in the contaminated mining communities of Zamfara State, Nigeria, given the high levels of cadmium in meat and vegetables samples from these areas.

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