scholarly journals Experimental Investigation on the Effect of Converter Slag Aggregate for Blended Mortar Based on CT Scanning

Materials ◽  
2021 ◽  
Vol 14 (24) ◽  
pp. 7570
Author(s):  
Min Jae Kim ◽  
Woong Ik Hwang ◽  
Won Jung Cho
Keyword(s):  
Compressive Strength ◽  
Converter Slag ◽  
Setting Time ◽  
Ct Scanning ◽  
Length Change ◽  
Basic Oxygen Furnace ◽  
Cement Matrix ◽  
Fundamental Properties ◽  
Bof Slag ◽  
Ct Analysis

This study investigated the air aging converter (Basic Oxygen Furnace, BOF) slag aggregate mortar with pulverized fly ash (PFA) and ferronickel slag (FNS). The chemical composition and mineralogical constituents of BOF incorporated mortar were analyzed. Setting time, flowability, compressive strength, and length change were measured to evaluate the fundamental properties of BOF mortar. The X-ray CT analysis was employed to observe the effect of converter slag in the cement matrix visually. The results showed that the hydration of BOF generated a pore at the vicinity of the aggregate, which decreased the compressive strength and increased the length change of mortar. However, the PFA or FNS incorporation of PFA or FNS can decrease the alkalinity of pore solution and subsequently reduce the reactivity of BOF aggregate. Thus, the incorporation of PFA and FNS can be a way to eliminate the disadvantage of BOF, such as volume expansion.

Preliminary Study on Reaction of Fresh Concrete with Carbon Dioxide

2018 ◽  
Vol 382 ◽  
pp. 230-234
Author(s):  
Ming Ju Lee ◽  
Ming Gin Lee ◽  
Yung Chih Wang ◽  
Yu Min Su ◽  
Jia Lun Deng
Keyword(s):  
Carbon Dioxide ◽  
Compressive Strength ◽  
Fresh Concrete ◽  
Setting Time ◽  
Cement Matrix ◽  
Cement Ratio ◽  
Water Cement Ratio ◽  
Initial Setting Time ◽  
Initial Setting ◽  
Short Time

In order to let fresh concrete react with carbon dioxide sufficiently, the carbon dioxide was added to mixing concrete. The study used three water cement ratio (0.55, 0.65, 0.75), three CO2 pressures (0.2, 0.4, 0.6 MPa), and two CO2 concentration (50% and 100%) to make concrete samples, and observed the effect of carbon dioxide adsorption in the above parameters. Finally, the compressive strength and carbonation degree of concretes were tested after three curing time (7, 14 and 28 days). The research showed that concrete could be more efficient to absorb carbon dioxide by using this pressure method. The results found that the mixing concrete react with carbon dioxide in a short time, and shorten the initial setting time of concrete. But this method would greatly reduce the workability of concrete after mixing with carbon dioxide and it might be enhanced by water or superplasticizer. The bond of cement matrix might cut down after reacting with carbon dioxide. Based on the above, the compressive strength of concrete which was mixed with carbon dioxide would be impaired. The proposed CO2-mixing method has the capacity to uptake 9.5% carbon dioxide based on water cement ratio and CO2 pressure.

scholarly journals Performance and Durability of Rendering and Basecoat Mortars for ETICS with CSA and Portland Cement

2021 ◽  
Vol 6 (4) ◽  
pp. 60
Author(s):  
Tiago Trigo ◽  
Inês Flores-Colen ◽  
Luís Silva ◽  
Nuno Vieira ◽  
Ana Raimundo ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Energy Consumption ◽  
Portland Cement ◽  
Bending Strength ◽  
Setting Time ◽  
Cement Matrix ◽  
Calcium Sulfoaluminate Cement ◽  
Calcium Sulfoaluminate ◽  
Composite Systems

The production of Portland cement (OP) is commonly associated to significant level of energy consumption and gas emissions. The use of calcium sulfoaluminate cement (CSA) can be a sustainable alternative binder, since its production releases about half of the CO2 emissions and its clinker requires 200 °C lower temperatures, when compared to OP. Furthermore, CSA has fast setting time and achieves higher strength in shorter periods, as well as reduced shrinkage. This paper discusses the incorporation of CSA in rendering mortars and basecoat mortars for ETICS (External Thermal Insulation Composite Systems). The physical-mechanical properties of mortars made with OP and CSA cements were experimental evaluated. The results showed that the introduction of CSA generally improves shrinkage, compressive strength, water absorption at low pressure, enhances the tensile bending strength and decreases the setting time. The amount of CSA introduced into the mixture significantly affected the properties of the cement matrix.

Evaluation of strength and set behavior of mortar containing shotcrete set accelerators

2008 ◽  
Vol 35 (4) ◽  
pp. 400-407 ◽  
Author(s):  
Jincheol Kim ◽  
Jonghyun Ryu ◽  
R. D. Hooton
Keyword(s):  
Compressive Strength ◽  
Calcium Aluminate ◽  
Setting Time ◽  
Strength Loss ◽  
Test Methods ◽  
Calcium Aluminate Cement ◽  
Cement Matrix ◽  
Early Age ◽  
Rapid Setting ◽  
Aluminate Cement

The influence of rapid-set accelerating admixtures on the setting behavior and early-age strength of a cement matrix was investigated to evaluate the appropriateness of the specification and test methods for shotcrete set accelerators. The results verified two different rapid setting behaviors according to the types of accelerator. The aluminate-base and the calcium aluminate cement-base accelerators facilitate hydration by formation of a calcium aluminate solid solution, whereas the alkali-free set accelerating agents present rapid setting time by the formation of ettringite. It was also found that the Vicat test was more desirable than the Gillmore test as the standard for setting time evaluation. Additionally, the cement mortar mixed with the aluminate-base and the calcium aluminate cement-base accelerators exhibited very fast development of early-age compressive strength. However, most of the set accelerators, except for alkali-free accelerators, failed to satisfy the specification because of greater than 40% compressive strength loss at 28 d.

scholarly journals Influence of a Retarding Admixture on the Behavior of Mortars Made from Different Types of Cement

2018 ◽  
Vol 7 (4.20) ◽  
pp. 334
Author(s):  
Tumadhir Merawi Borhan ◽  
Munaf A. Al-Ramahee ◽  
Noor Al-Hassnawi ◽  
Zaid Ali AlZaidi
Keyword(s):  
Compressive Strength ◽  
Portland Cement ◽  
Cement Mortar ◽  
Setting Time ◽  
Length Change ◽  
Setting Times ◽  
White Cement ◽  
Cement Mortars ◽  
Different Types ◽  
Positive Effect

The effect of retarding admixture on the fresh and hardened behaviour of different types of cement mortars and pastes when using a retarding admixture was investigated in this study. The types of cement used are; White cement (WhC), Ordinary Portland cement (OPC) and Sulphate Resistant Portland cement (SRC). Different cement mortar and paste mixes were cast, for this purpose, with and without the admixture. Initial and final setting times, compressive strength, length change, absorption and density for these mixes were examined at the curing ages of 3,7,28,45 days. The results showed that the addition of retarding admixture delayed the setting time significantly of WhC paste. The retarding admixture has a positive effect on the compressive strength of the mortar specimens for all types of cement used. regarding the length change test, the admixture was found to reduce the initial expansion for all types of cement at all ages. The results also showed an increase in the density and decrease in water absorption, especially at the later ages for all types of cement.  Among all cement types used, WhC was noticeably the most affected type by using the retarding admixture compared to other types of cement used.  

scholarly journals A New Preparation Method of Cement with Photocatalytic Activity

Materials ◽  
2020 ◽  
Vol 13 (23) ◽  
pp. 5540
Author(s):  
Magdalena Janus ◽  
Szymon Mądraszewski ◽  
Kamila Zając ◽  
Ewelina Kusiak-Nejman
Keyword(s):  
Compressive Strength ◽  
Photocatalytic Activity ◽  
Building Materials ◽  
Water Adsorption ◽  
Crystal Size ◽  
Preparation Method ◽  
Setting Time ◽  
Cement Matrix ◽  
Final Setting Time ◽  
Titanium White

The studies of some mechanical properties and photocatalytic activity of new cements with photocatalytic activity are presented. The new building materials were obtained by addition of semi-product from titanium white production. Semi-product was calcined at 300 and 600 °C for one, three, and five hours and then this material was added to cement matrix in an amount of 1 and 3 wt.%. New materials were characterized by measuring the flexural and compressive strength and the initial and the final setting time. The photocatalytic activity was tested during NOx photooxidation. The cement with photocatalytic activity was also characterized by sulphur content measurements. The measurement of reflectance percentage of TiO2-loaded cements in comparison with pristine cement and TiO2 photocatalyst calcined at 600 °C were also performed. It should be emphasized that although in some cases, the addition of photocatalyst reduced the flexural and the compressive strength of the modified cements, these values were still within the norm PN-EN 197-1:2012. It was also found that the initial and the final setting time is connected with the crystal size of anatase, and the presence of larger crystals significantly delays of the setting time. This was probably caused by a water adsorption on the surface of anatase crystals.

scholarly journals Time-Dependent Strength Behavior, Expansion, Microstructural Properties, and Environmental Impact of Basic Oxygen Furnace Slag-Treated Marine-Dredged Clay in South Korea

2021 ◽  
Vol 13 (9) ◽  
pp. 5026
Author(s):  
Gyeong-o Kang ◽  
Jung-goo Kang ◽  
Jin-young Kim ◽  
Young-sang Kim
Keyword(s):  
Particle Size ◽  
Environmental Impact ◽  
South Korea ◽  
Mechanical Characteristics ◽  
Basic Oxygen Furnace ◽  
Microstructural Properties ◽  
Compression Tests ◽  
Basic Oxygen ◽  
Strength Behavior ◽  
Bof Slag

The aim of this study was to investigate the mechanical characteristics, microstructural properties, and environmental impact of basic oxygen furnace (BOF) slag-treated clay in South Korea. Mechanical characteristics were determined via the expansion, vane shear, and unconfined compression tests according to various curing times. Scanning electron microscopy was conducted to analyze microstructural properties. Furthermore, environmental impacts were evaluated by the leaching test and pH measurements. According to the results, at the early curing stage (within 15 h), the free lime (F-CaO) content of the BOF slag is a significant factor for developing the strength of the adopted sample. However, the particle size of the BOF slag influences the increase in the strength at subsequent curing times. It was inferred that the strength behavior of the sample exhibits three phases depending on various incremental strength ratios. The expansion magnitude of the adopted samples is influenced by the F-CaO content and also the particle size of the BOF slag. Regarding the microstructural properties, the presence of reticulation structures in the amorphous gels with intergrowths of rod-like ettringite formation was verified inside the sample. Finally, the pH values and heavy metal leachates of the samples were determined within the compatible ranges of the threshold effect levels in the marine sediments of the marine environment standard of the Republic of Korea.

scholarly journals Component Modification of Basic Oxygen Furnace Slag with C4AF as Target Mineral and Application

2021 ◽  
Vol 13 (12) ◽  
pp. 6536
Author(s):  
Yanrong Zhao ◽  
Pengliang Sun ◽  
Ping Chen ◽  
Xiaomin Guan ◽  
Yuanhao Wang ◽  
...  
Keyword(s):  
Intermediate Phase ◽  
Raw Materials ◽  
Activity Index ◽  
Basic Oxygen Furnace ◽  
Hydration Products ◽  
Basic Oxygen ◽  
Bof Slag ◽  
Mineral Compositions ◽  
Slag Component ◽  
Basic Oxygen Furnace Slag

In this paper, a new method of basic oxygen furnace (BOF) slag component modification with a regulator was studied. The main mineral was designed as C4AF, C2S and C3S in modified BOF slag, and the batching method, mineral compositions, hydration rate, activation index and capability of resisting sulfate corrode also were studied. XRD, BEI and EDS were used to characterize the mineral formation, and SEM was used to study the morphology of hydration products. The results show that most inert phase in BOF slag can be converted into active minerals of C4AF and C2S through reasonable batching calculation and the amount of regulating agent. The formation of C4AF and C2S in modified BOF slag is better, and a small amount of MgO is embedded in the white intermediate phase, but C3S is not detected. With the increase in the CaO/SiO2 ratio in raw materials, the CaO/SiO2 ratio of calcium silicate minerals in modified BOF slag increases, the contents of f-CaO are less than 1.0%, and the activity index improves. Compared with the BOF slag, the activity index and exothermic rate of modified BOF slag improved obviously, and the activity index of 90 days is close to 100%. With the increase in modified BOF slag B cement, the flexural strength decrease; however, the capability of resisting sulfate corrode is improved due to the constant formation of a short rod-like shape ettringite in Na2SO4 solution and the improvement of the structure densification of the hydration products.

scholarly journals Effect of Calcium Nitrate on the Properties of Portland–Limestone Cement-Based Concrete Cured at Low Temperature

Materials ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1611
Author(s):  
Gintautas Skripkiūnas ◽  
Asta Kičaitė ◽  
Harald Justnes ◽  
Ina Pundienė
Keyword(s):  
Compressive Strength ◽  
Cement Paste ◽  
Setting Time ◽  
Calcium Nitrate ◽  
Curing Temperature ◽  
Hardened Concrete ◽  
Cement Pastes ◽  
Initial Setting Time ◽  
Initial Setting ◽  
Early Strength

The effect of calcium nitrate (CN) dosages from 0 to 3% (of cement mass) on the properties of fresh cement paste rheology and hardening processes and on the strength of hardened concrete with two types of limestone-blended composite cements (CEM II A-LL 42.5 R and 42.5 N) at different initial (two-day) curing temperatures (−10 °C to +20 °C) is presented. The rheology results showed that a CN dosage up to 1.5% works as a plasticizing admixture, while higher amounts demonstrate the effect of increasing viscosity. At higher CN content, the viscosity growth in normal early strength (N type) cement pastes is much slower than in high early strength (R type) cement pastes. For both cement-type pastes, shortening the initial and final setting times is more effective when using 3% at +5 °C and 0 °C. At these temperatures, the use of 3% CN reduces the initial setting time for high early strength paste by 7.4 and 5.4 times and for normal early strength cement paste by 3.5 and 3.4 times when compared to a CN-free cement paste. The most efficient use of CN is achieved at −5 °C for compressive strength enlargement; a 1% CN dosage ensures the compressive strength of samples at a −5 °C initial curing temperature, with high early strength cement exceeding 3.5 MPa but being less than the required 3.5 MPa in samples with normal early strength cement.

scholarly journals Effect of Waste Glass on the Properties and Microstructure of Magnesium Potassium Phosphate Cement

Materials ◽  
2021 ◽  
Vol 14 (8) ◽  
pp. 2073
Author(s):  
Qiubai Deng ◽  
Zhenyu Lai ◽  
Rui Xiao ◽  
Jie Wu ◽  
Mengliang Liu ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Glass Powder ◽  
Setting Time ◽  
Potassium Phosphate ◽  
Heat Of Hydration ◽  
Waste Glass ◽  
Hydration Heat ◽  
Magnesium Potassium Phosphate Cement ◽  
The Matrix ◽  
Powder Content

Waste glass is a bulk solid waste, and its utilization is of great consequence for environmental protection; the application of waste glass to magnesium phosphate cement can also play a prominent role in its recycling. The purpose of this study is to evaluate the effect of glass powder (GP) on the mechanical and working properties of magnesium potassium phosphate cement (MKPC). Moreover, a 40mm × 40mm × 40mm mold was used in this experiment, the workability, setting time, strength, hydration heat release, porosity, and microstructure of the specimens were evaluated. The results indicated that the addition of glass powder prolonged the setting time of MKPC, reduced the workability of the matrix, and effectively lowered the hydration heat of the MKPC. Compared to an M/P ratio (MgO/KH2PO4 mass ratio) of 1:1, the workability of the MKPC with M/P ratios of 2:1 and 3:1 was reduced by 1% and 2.1%, respectively, and the peak hydration temperatures were reduced by 0.5% and 14.6%, respectively. The compressive strength of MKPC increased with an increase in the glass powder content at the M/P ratio of 1:1, and the addition of glass powder reduced the porosity of the matrix, effectively increased the yield of struvite-K, and affected the morphology of the hydration products. With an increase in the M/P ratio, the struvite-K content decreased, many tiny pores were more prevalent on the surface of the matrix, and the bonding integrity between the MKPC was weakened, thereby reducing the compressive strength of the matrix. At less than 40 wt.% glass powder content, the performance of MKPC improved at an M/P ratio of 1:1. In general, the addition of glass powders improved the mechanical properties of MKPC and reduced the heat of hydration.

scholarly journals Cement-Based Renders Manufactured with Phase-Change Materials: Applications and Feasibility

2016 ◽  
Vol 2016 ◽  
pp. 1-6 ◽  
Author(s):  
Luigi Coppola ◽  
Denny Coffetti ◽  
Sergio Lorenzi
Keyword(s):  
Compressive Strength ◽  
Phase Change ◽  
Phase Change Materials ◽  
Residential Buildings ◽  
Setting Time ◽  
Drying Shrinkage ◽  
Hydration Kinetics ◽  
Mechanical Performances ◽  
Entrapped Air ◽  
Kinetics Of

The paper focuses on the evaluation of the rheological and mechanical performances of cement-based renders manufactured with phase-change materials (PCM) in form of microencapsulated paraffin for innovative and ecofriendly residential buildings. Specifically, cement-based renders were manufactured by incorporating different amount of paraffin microcapsules—ranging from 5% to 20% by weight with respect to binder. Specific mass, entrained or entrapped air, and setting time were evaluated on fresh mortars. Compressive strength was measured over time to evaluate the effect of the PCM addition on the hydration kinetics of cement. Drying shrinkage was also evaluated. Experimental results confirmed that the compressive strength decreases as the amount of PCM increases. Furthermore, the higher the PCM content, the higher the drying shrinkage. The results confirm the possibility of manufacturing cement-based renders containing up to 20% by weight of PCM microcapsules with respect to binder.

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