Hydrocracking of Heavy Fischer–Tropsch Wax Distillation Residues and Its Blends with Vacuum Gas Oil Using Phonolite-Based Catalysts

The Fischer–Tropsch heavy fraction is a potential feedstock for transport-fuels production through co-processing with fossil fuel fraction. However, there is still the need of developing new and green catalytic materials able to process this feedstock into valuable outputs. The present work studies the co-hydrocracking of the Fisher–Tropsch heavy fraction (FT-res.) with vacuum gas oil (VGO) at different ratios (FT-res. 9:1 VGO, FT-res. 7:3 VGO, and FT-res. 5:5 VGO) using phonolite-based catalysts (5Ni10W/Ph, 5Ni10Mo/Ph, and 5Co10Mo/Ph), paying attention to the overall conversion, yield, and selectivity of the products and properties. The co-processing experiments were carried out in an autoclave reactor at 450 °C, under 50 bars for 1 and 2 h. The phonolite-based catalysts were active in the hydrocracking of FT-res.:VGO mixtures, presenting different yields to gasoline, diesel, and jet fuel fractions, depending on the time of reaction and type of catalyst. Our results enable us to define the most suitable metal transition composition for the phonolite-based support as a hydrocracking catalyst.

Influence of particles size distribution on the carbon content throughout sinter bed height

By the previous studies it was established that the character of solid fuel distribution throughout the bed height considerably effects the sintering machines productivity and the sinter quality. The purpose of the study was assessment of solid fuel distribution in the agglomerated burden throughout the height of bed at sintering machine. Sinter mix samples were taken from three sections of the bed: 150 mm - top part, 150 mm - middle part and 170 mm - bottom part at the sintering machines of NLMK. After screening the samples, particle size distribution was determined, as well as carbon content throughout the bed height and in the particles of different sizes. It was found that all solid fuel, irrespective of the size, gets balled into sinter mix granules, fine fuel (fraction -0.63 mm) was almost evenly distributed over the granules of different sizes, while coarse fuel (+3 mm) is mainly picked up by large granules. Solid fuel of -3 mm +0.63 mm fraction is mostly balled into 3-5 mm granules. Such nature of solid fuel distribution in the granules of the pelletized mix results in suboptimal distribution of fuel throughout the bed height at sintering machines No. 1, 2, despite satisfactory size segregation of the mix: it changes from low content in the top part to a higher content at the bottom of the bed. At sintering machines No. 3, 4 where there was no size segregation of the mix, fuel distribution throughout the bed height changes from optimal to non-optimal (low content in the top part). To optimize solid fuel distribution throughout the bed height with both good and poor segregation of the mix, it is necessary to reduce the content of 0-0.5 mm particles fraction in coke breeze.

Conversion of Palm Oil (CPO) into Fuel Biogasoline through Thermal Cracking Using a Catalyst Based Na-Bentonite and Limestone of Soil Limestone NTT

Cracking catalytic palm oil (CPO) into hydrocarbon fuel by saponification pretreatment has been carried out with bentonite and limestone-based catalysts. The catalysts used were Na-bentonite and Limestone NTT which were first analyzed using XRF, XRD, and SEM. Saponification pretreatment was carried out on CPO to facilitate the cracking process using a catalyst. The saponification product in the form of a mixture of soap and glycerol was then analyzed by DSC to determine the degradation temperature. Catalytic cracking is carried out in two stages, namely, the first stage hydrocracking at a temperature of 250-350°C using a stainless steel reactor is the source of catalyst Fe / Cr. The resulting distillate was then cracked again using a Na-bentonite catalyst and a TKNTT catalyst. The resulting fuel is a hydrocarbon fuel which is confirmed from the FT-IR results which indicate the presence of long-chain hydrocarbon compounds. This data is also supported by the results of the GC-MS analysis which shows that the fuel fraction produced is mostly biogasoline. Where cracking using a Na-bentonite catalyst produces a biogasoline fraction of 61.36% and a biodiesel fraction of 38.63%, THAT produces a biogasoline fraction of 88.88% and a biodiesel fraction of 11.11%. The characteristics of the hydrocarbon fuels that have been analyzed show that the calorific value of combustion is 6101 cal/g which is determined using a bomb calorimeter, and the cetane index is 62 which is analyzed using CCI. Both types of hydrocarbon fuels have met the physical requirements that must be possessed by biogasoline fuel based on SNI standards.

Design Study of Gas Cooled Fast Reactor (GFR) with Uranium Plutonium Carbide (UC-PuC) as Fuel with Addition Protactinium (Pa-231)

Analysis performance of uranium plutonium carbide (UC-PuC) as fuel in gas cooled fast reactor (GFR) with addition of protactinium as a burnable poisons has been done. Neutronic analysis in this research was carried out using the SRAC code from JAERI with a nuclear library based on JENDL 4.0. The calculation is carried out by two steps, the first step is the PIJ calculation which calculates the fuel cell and the second step is the CITATION calculation which calculates the various configurations of the reactor core. The first calculation determines the k-eff value in a homogeneous core configuration. The results obtained show that the percentage of 10% is the sloping result with a k-eff value of 1%. The second calculation determines the k-eff value in the heterogeneous core configuration. The results obtained indicate that the fuel variation 8% -10% -12% is the most critical percentage with a peak power density value of less than 100 Watt/cc. Furthermore, the addition of protactinium with a variation of 0% to 5%. At a protactinium 4% percentage and 63% fuel fraction, the excess reactivity value is 1.02% or close to 1% which indicates that the reactor is in a critical condition.

Fischer–Tropsch synthesis with periodical draining of a liquid-filled catalyst by hydrogenolysis

Investigation of a transient Fischer–Tropsch/hydrogenolysis process for productivity enhancement and increasing the selectivity towards the liquid fuel fraction C5–C20.

Influence of Ethanol-Gasoline Fuel Fractions on Variable Compression Ratio Engine

Increase in demand of ethanol as blending fuel with gasoline is increasing. For noting the performance of the engine, experimentations are required to be done on engine, fuelled with various percentages of ethanol in gasoline. In this study, fuel fractions of ethanol and gasoline were taken for observing the performance of spark ignition engine. One-cylinder gasoline engine was used for conducting the experiments and to analyse the effects of ethanol-gasoline fuel fraction on performance of the engine. The engine was tested at Full Open Throttle condition. The load on the engine was changed by changing the load on Eddy Current Dynamometer to vary the engine speed from 1300 to 1700 rpm in the interval of 100 rpm. Gasoline is blended with ethanol to make five fuel fractions from 0 % ethanol (E0) to 40 % ethanol (E40) in gasoline at the interval of 10% by volume. Engine performance was observed at various Compression Ratio (CR) of the engine as 7,8,9 and 10. Calorific Value (CV) of the fuel fractions observed decreasing from E0 to E40 as CV of ethanol is less than base gasoline. Increase in Brake Specific Fuel Consumption was not very significant with rise in ethanol percentage. Power outputs in terms of Brake Power (BP) was increasing with increase in speed of the engine and observed decreasing with increase in ethanol percentage at constant CR. However various engine output parameters like BP, Mechanical Efficiency found decreasing with increase in fuel fractions ratio. Brake Thermal Efficiency (BTE) was observed decreasing with increase in fuel fractions. However, BTE was observed increasing with increase in CR.